Multimodal Spectroscopic Study of Surface Termination Evolution in Cr 2 TiC 2 T x MXene
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99 GENERAL AND MISCELLANEOUS↗
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Nonlinear stratified flow over localized topographic obstacles on Mars
The current dynamical influence of the Martian atmosphere on the surface is clearly revealed by dark surface albedo features which are associated with localized topographic relief and were described in detail and classified as Type I(d) wind streaks. The contrast of the streaks diminishes or disappears during the global dust storms, and the streaks are observed to quickly reform after the termination of the storms; the streaks remain stable after L(sub S) = 0 deg until the next dust storm. These observations, together with the ragged edges of the streaks, were used to infer that the dark streaks are formed by the removal of bright dust from a darker substrate.
Magalhaes, J. A.↗
Wind-tunnel investigation of an NACA 23012 airfoil with several arrangements of slotted flaps with extended lips
An investigation was made in the NACA 7- by 10-foot wind tunnel to determine the effect of slot-lip location on the aerodynamic section characteristics of an NACA 23012 airfoil with a 30-percent-chord slotted flap. Tests were made with slot lips located at 90 and 100 percent of the airfoil chord and with two different flap shapes. The results are compared with a slotted flap previously developed by the National advisory Committee for Aeronautics with a slot lip located at 83 percent of the airfoil chord. The extension of the slot lip to the rear increased the section lift and pitching-moment coefficients. Comparisons made on a basis of pitching moment for a given tail length show that the Fowler type flap, lip extended to trailing edge of the airfoil, has the greatest section lift coefficient. For moderate tail lengths, 2 to 3 chord lengths, there was only a slight difference between the previously developed slotted flap and the slotted flap with slot lip extended to 90 percent of the airfoil chord. Of the three flaps tested, the Fowler flap had the lowest drag coefficient at high lift coefficients. The extension of the lower surface at the leading edge of the slot had a negligible effect on the profile drag of the airfoil-flap arrangement with the flap deflected when the lip terminated at 90 percent of the airfoil chord.
WING FLAPS, SLOTTED - FULL-SPAN(30%-CHORD)↗
Introducing metal–sulfur active sites in metal–organic frameworks via post-synthetic modification for hydrogenation catalysis
Metal–sulfur active sites play a central role in catalytic processes such as hydrogenation and dehydrogenation, yet the majority of active sites in these compounds reside on the surfaces and edges of catalyst particles, limiting overall efficiency. Here we present a strategy to embed metal–sulfur active sites into metal–organic frameworks (MOFs) by converting bridging or terminal chloride ligands into hydroxide and subsequently into sulfide groups through post-synthetic modification. We apply this method to two representative MOF families: one featuring one-dimensional metal–chloride chains and another containing discrete multinuclear metal clusters. Crystallographic and spectroscopic analyses confirm structural integrity and sulfide incorporation, and the transformation is monitored by in situ total scattering methods. The sulfided MOFs display enhanced catalytic activity in the selective hydrogenation of nitroarenes using molecular hydrogen. Density functional theory calculations indicate that sulfur incorporation promotes homolytic metal–ligand bond cleavage and facilitates H 2 activation. This work establishes an approach to construct MOFs featuring accessible metal–sulfide sites.
Catalyst synthesis↗
Selenium Migration and Local Structures in Cu‐Doped CdSeTe Solar Cells after Aging
Selenium grading plays a critical role in state-of-the-art Cadmium Telluride photovoltaic cells by enhancing long-wavelength absorption and extending minority carrier lifetimes —key to enabling the current performance record of 23.08%. However, very little is understood about selenium motion. In this study, a comprehensive, multimodal, and multiscale approach is employed to investigate Se migration and local structural changes in copper (Cu)-doped CdSeTe solar cells subjected to accelerated stress. X-ray fluorescence (XRF) microscopy shows unexpected levels of Se diffusion after 500 h under heat (75°C) and light (0.8 suns, 80 mW/cm 2 ), suggesting the coexistence of fast and slow diffusion channels even at low temperatures, with unexpectedly low activation energies (<0.85 eV). X-ray Absorption Near Edge Structure (XANES) analysis indicates a preferential migration of Se atoms to anionic lattice sites and a reduction in Se-Cl co-passivation at Te-terminated dislocation cores. Furthermore, these findings point to a reconfiguration of Se local environments and highlight the potential role of extended structural defects in enabling Se transport at low temperatures. Additionally, XANES results suggest that the presence of metallic Cu across the absorber layer may contribute to back-contact degradation and reduced hole density in both fresh and aged devices.
14 SOLAR ENERGY↗
Air Traffic Management Research at NASA Ames
The Aviation Systems Division at the NASA Ames Research Center conducts leading edge research in air traffic management concepts and technologies. This overview will present concepts and simulation results for research in traffic flow management, safe and efficient airport surface operations, super density terminal area operations, separation assurance and system wide modeling and simulation. A brief review of the ongoing air traffic management technology demonstration (ATD-1) will also be presented. A panel discussion, with Mr. Davis serving as a panelist, on air traffic research will follow the briefing.
Davis, Thomas J.↗
Chemistry of Titanium Deposition Precursors for Area-Selective Deposition of Functionalized Silicon [Posters]
Area-selective atomic layer deposition (AS-ALD) is an appealing bottom-up fabrication technique that can produce atomic-scale device features, overcoming challenges in current industrial techniques such as edge alignment errors. TiCI 4 is a common thermal ALD precursor for Ti0 2 thin films, which are appealing candidates for DRAM capacitors due to their excellent dielectric constants. Hydrogen and chlorine termination passivate the Si surface, allowing for selective deposition of TiCI 4 onto HO-terminated areas. However, selectivity loss occurs after several ALD cycles. Ti oxide nucleates onto surface defects on Cl- and H-Si resists. Previously, the use of H-Si as an ALD resist has been studied extensively, but less work has focused on chemical forces driving nucleation, especially for Cl-Si. Here, formation of defect nuclei was investigated with selectivity loss during Ti0 2 ALD with TiCI 4 and water on the (100) and (111) crystal surfaces of hydrogenated, chlorinated, and oxidized Si.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Analysis of the EM scattering from arbitrary open-ended waveguide cavities using axial Gaussian Beam tracking
The electromagnetic (EM) scattering from a planar termination located inside relatively arbitrarily shaped open-ended waveguide cavities with smoothly curved interior walls is analyzed using a Gaussian Beam (GB) expansion of the incident plane wave fields in the open end. The cavities under consideration may contain perfectly-conducting interior walls with or without a thin layer of material coating, or the walls may be characterized by an impedance boundary condition. In the present approach, the GB's are tracked only to the termination of the waveguide cavity via beam reflections from interior waveguide cavity walls. The Gaussian beams are tracked approximately only along their beam axes; this approximation which remains valid for relatively well focussed beams assumes that an incident GB gives rise to a reflected GB with parameters related to the incident beam and the radius of curvature of the wall. It is found that this approximation breaks down for GB's which come close to grazing a convex surface and when the width of the incident beam is comparable to the radius of curvature of the surface. The expansion of the fields at the open end depend on the incidence angle only through the expansion coefficients, so the GB's need to be tracked through the waveguide cavity only once for a wide range of incidence angles. At the termination, the sum of all the GB's are integrated using a result developed from a generalized reciprocity principle, to give the fields scattered from the interior of the cavity. The rim edge at the open end of the cavity is assumed to be sharp and the external scattering from the rim is added separately using Geometrical Theory of Diffraction. The results based on the present approach are compared with solutions based on the hybrid asymptotic modal method. The agreement is found to be very good for cavities made up of planar surfaces, and also for cavities with curved surfaces which are not too long with respect to their width.
Burkholder, R. J.↗
The Primordial Anisotropy Polarization Pathfinder Array (PAPPA): Instrument Overview and Status
PAPPA is a balloon-based experiment designed to measure the polarization of the Cosmic Microwave Background using candidate technology for an eventual Inflation Probe mission. It will survey a 20 x 20 degree patch of sky with 1 degree angular resolution covering 3 passbands centered at 100,200 and 300 GHz. Detection will be accomplished via antenna-coupled transition edge sensors (TESs) with SQUID-based readouts. In the eventual flight package, band defining filters and MEMS-based polarization modulators will be incorporated into the superconducting microstrip transmission lines that terminate in resistors that are thermally coupled to the TESs. The MEMS switches will allow on-chip polarization modulation that is faster than significant detector gain variations. The initial configuration will incorporate a simplified focal plane augmented by quasioptical polarization modulation. We describe the overall instrument design and present a summary of the current progress.
Chuss, David↗
Concurrent hypercube system with improved message passing
A network of microprocessors, or nodes, are interconnected in an n-dimensional cube having bidirectional communication links along the edges of the n-dimensional cube. Each node's processor network includes an I/O subprocessor dedicated to controlling communication of message packets along a bidirectional communication link with each end thereof terminating at an I/O controlled transceiver. Transmit data lines are directly connected from a local FIFO through each node's communication link transceiver. Status and control signals from the neighboring nodes are delivered over supervisory lines to inform the local node that the neighbor node's FIFO is empty and the bidirectional link between the two nodes is idle for data communication. A clocking line between neighbors, clocks a message into an empty FIFO at a neighbor's node and vica versa. Either neighbor may acquire control over the bidirectional communication link at any time, and thus each node has circuitry for checking whether or not the communication link is busy or idle, and whether or not the receive FIFO is empty. Likewise, each node can empty its own FIFO and in turn deliver a status signal to a neighboring node indicating that the local FIFO is empty. The system includes features of automatic message rerouting, block message transfer and automatic parity checking and generation.
Peterson, John C.↗
Orientation of acetic acid hydrogen bonded to acetate terminated TiO 2 (110)
Acetic acid is a common pollutant for which photocatalytic degradation over titania provides a mitigating strategy. Knowledge of the bonding of acetate/acetic acid to this substrate is needed to aid interpretation of the photocatalytic data. In this work we use ambient pressure near edge X-ray absorption fine structure to measure the coverage and geometry of acetate in the TiO 2 (110) contact layer as well as acetic acid in an additional layer. A saturation coverage of 0.5 monolayers in both layers is found up to an acetic acid pressure of 10 -1 Torr at 266 K. The geometry of acetate appears to be unchanged by adsorption of an additional layer of acetic acid, with the contact layer involving a majority acetate species bidentate bonded to neighboring Ti 5c sites and a minority acetate species bonded in a perpendicular geometry. Acetic acid has a similar geometry dictated by hydrogen bonding to the contact layer as well as the substrate.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Simulation of patch and slot antennas using FEM with prismatic elements and investigations of artificial absorber mesh termination schemes
Year 1 progress can be characterized with four major achievements which are crucial toward the development of robust, easy to use antenna analysis code on doubly conformal platforms. (1) A new FEM code was developed using prismatic meshes. This code is based on a new edge based distorted prism and is particularly attractive for growing meshes associated with printed slot and patch antennas on doubly conformal platforms. It is anticipated that this technology will lead to interactive, simple to use codes for a large class of antenna geometries. Moreover, the codes can be expanded to include modeling of the circuit characteristics. An attached report describes the theory and validation of the new prismatic code using reference calculations and measured data collected at the NASA Langley facilities. The agreement between the measured and calculated data is impressive even for the coated patch configuration. (2) A scheme was developed for improved feed modeling in the context of FEM. A new approach based on the voltage continuity condition was devised and successfully tested in modeling coax cables and aperture fed antennas. An important aspect of this new feed modeling approach is the ability to completely separate the feed and antenna mesh regions. In this manner, different elements can be used in each of the regions leading to substantially improved accuracy and meshing simplicity. (3) A most important development this year has been the introduction of the perfectly matched interface (PMI) layer for truncating finite element meshes. So far the robust boundary integral method has been used for truncating the finite element meshes. However, this approach is not suitable for antennas on nonplanar platforms. The PMI layer is a lossy anisotropic absorber with zero reflection at its interface. (4) We were able to interface our antenna code FEMA_CYL (for antennas on cylindrical platforms) with a standard high frequency code. This interface was achieved by first generating equivalent magnetic currents across the antenna aperture using the FEM code. These currents were employed as the sources in the high frequency code.
Gong, J.↗
Colloidal Germanium Quantum Dots with Broadly Tunable Size and Light Emission
Germanium (Ge) colloidal quantum dots (CQDs) were synthesized by thermal decomposition of GeI 2 using capping ligand mixtures of oleylamine (OAm), octadecene (ODE), and trioctylphosphine (TOP). Average diameters could be tuned across a wide range, from 3 to 18 nm, by adjusting reactant concentrations, heating rates, and reaction temperatures. OAm promotes decomposition of GeI 2 to Ge and serves as a weakly bound capping ligand. ODE displaces OAm during the reaction to terminate particle growth and prevent surface oxidation. TOP is necessary for obtaining nanocrystals larger than 11 nm. In conclusion, the Ge CQDs have relatively narrow size distributions and exhibit size-dependent, band-edge photoluminescence (PL), with peak energies from 0.8 to 1.34 eV, across a wide spectral range in the infrared (IR).
Noh, Jungchul [Univ. of Texas, Austin, TX (United ↗
Propulsive re-entry aerodynamics Interim report, 1 Jun. 1967 - 1 Jun. 1968
This report discusses the progress accomplished during the first year of a two-year contract to study Propulsive Re-Entry Aerodynamics. Analytical methods were developed during the first year to predict the flow field in the immediate vicinity of a planetary entry system composed of an aeroshell with a single retrorocket which exhausts into a subsonic or supersonic counterflowing planetary atmosphere. In the second year a digital computer program will be developed for the analytical solutions, and the analytical model will be tested by performing an experimental test program and comparing the experimental results with the analytical predictions. The analytical investigation considers the flow field due to a single supersonic retrorocket exhausting from an aeroshell into oncoming subsonic, transonic, or supersonic streams in the large thrusting coefficient regime, 0.5 < C(sub T) = T/q(sub ∞) A(sub m) < 15, which is the range of thrusting coefficients encountered during the terminal landing phase for planetary landing on Mars or Venus. Analyses are provided for all the geometrical features of the flow field such as the location of the terminal shock, jet boundary, and the profile for the interface between the jet and atmospheric gases. In addition, analyses are developed which describe the growth of the mixing layers along the interface and at the edge of the jet boundary and dead-air region and the reattachment of the shear layer to the aeroshell or the recompression of the shear layer in wake type flow. A comprehensive discussion of the experimental wind tunnel test program to be accomplished in Phase II is presented.
Philip O Jarvinen↗
The wind-disk interaction in X-ray burst sources
The interaction between a radiatively driven wind from the surface of a neutron star and an accretion disk surrounding the star is considered. A bow shock forms if the wind is supersonic when it reaches the inner edge of the disk. The resultant heating of the wind material can enhance the X-ray luminosity of the source, but this effect is important only if the wind is very strong. If the terminal velocity of the wind is at least about 0.99c and the integrated kinetic energy flux of the wind is at least about 30 times the Eddington limit, then super-Eddington X-ray luminosities will be generated. The conditions that are required for the formation of such a wind are briefly discussed. Also developed are estimates for the spectral shape, color temperature, and X-ray luminosity resulting from the wind-disk interaction, and it is shown that these results are consistent with the observed properties of type I cosmic X-ray bursts.
Melia, F.↗
Characterization of Dual-Band Infrared Detectors for Application to Remote Sensing
NASA Langley Research Center (LaRC), in partnership with the Rensselaer Polytechnic Institute (RPI), developed photovoltaic infrared (IR) detectors suitable at two different wavelengths using Sb-based material systems. Using lattice-matched InGaAsSb grown on GaSb substrates, dual wavelength detectors operating at 1.7 and 2.5 micron wavelengths can be realized. P-N junction diodes are fabricated on both GaSb and InGaAsSb materials. The photodiode on GaSb detects wavelengths at 1.7 micron and the InGaAsSb detector detects wavelengths at 2.2 micron or longer depending on the composition. The films for these devices are grown by metal-organic vapor phase epitaxy (MOVPE). The cross section of the independently accessed back-to-back photodiode dual band detector consists of a p-type substrate on which n-on-p GaInAsSb junction is grown, followed by a p-on-n GaSb junction. There are three ohmic contacts in this structure, one to the p-GaSb top layer, one to the n-GaSb/n-GaInAsSb layer and one to the p-type GaSb substrate. The common terminal is the contact to the n-GaSb/n-GaInAsSb layer. The contact to the n-GaSb/p-GaInAsSb region of the photodiode in the dual band is electrically connected and is accessed at the edge of the photodiode. NASA LaRC acquired the fabricated dual band detector from RPI and characterized the detector at its Detector Characterization Laboratory. Characterization results, such as responsivity, noise, quantum efficiency, and detectivity will be presented.
Abedin, M. Nurul↗
Wraparound-contact solar cells
Positive and negative electrical contacts are on back surface of wraparound-contact solar cell. With both terminals on nonilluminated side, cells can be connected back-to-back, and interconnection of many cells can be automated by using printed-circuit techniques. Cells are made by screen-printing layer of dielectric around edge of cell and extending top contact over dielectric to back surface. Wraparound also facilitates application of transparent covers and encapsulants. Efficiencies of cells are in excess of seventeen percent.
Baraona, C. R.↗
A simple hyperbolic model for communication in parallel processing environments
We introduce a model for communication costs in parallel processing environments called the 'hyperbolic model,' which generalizes two-parameter dedicated-link models in an analytically simple way. Dedicated interprocessor links parameterized by a latency and a transfer rate that are independent of load are assumed by many existing communication models; such models are unrealistic for workstation networks. The communication system is modeled as a directed communication graph in which terminal nodes represent the application processes that initiate the sending and receiving of the information and in which internal nodes, called communication blocks (CBs), reflect the layered structure of the underlying communication architecture. The direction of graph edges specifies the flow of the information carried through messages. Each CB is characterized by a two-parameter hyperbolic function of the message size that represents the service time needed for processing the message. The parameters are evaluated in the limits of very large and very small messages. Rules are given for reducing a communication graph consisting of many to an equivalent two-parameter form, while maintaining an approximation for the service time that is exact in both large and small limits. The model is validated on a dedicated Ethernet network of workstations by experiments with communication subprograms arising in scientific applications, for which a tight fit of the model predictions with actual measurements of the communication and synchronization time between end processes is demonstrated. The model is then used to evaluate the performance of two simple parallel scientific applications from partial differential equations: domain decomposition and time-parallel multigrid. In an appropriate limit, we also show the compatibility of the hyperbolic model with the recently proposed LogP model.
Stoica, Ion↗