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136 records · Page 8

Distributed Real-time Plume Monitoring for Deep Sea Mineral Extraction​

In the emerging industry of deep-sea mining for minerals and deposits (e.g. polymetallic nodules for nickel, cobalt, copper, and manganese), more data is required to understand the effects of sediment plume generation and predict the distribution of disturbed sediment. There are two main sources of plume generation, the first being at the active mining site where the “collector” directly removes the top layer of the sea floor. The other is the “midwater plume” consisting of unwanted sediment that was collected during extraction that is pumped back into the aphotic zone. The vast majority of plume generation is caused by the collector, causing detrimental and long-lasting impacts on seafloor ecosystems due to the lack of wave activity or strong currents at the sea floor. Therefore, it is crucial to invest in the infrastructure to support the study and constant monitoring over a large area of the sea floor where plume generation is present. Due to the limited number of usable channels and power requirements, current subsea wireless communications technologies are not well suited to instrumenting the large areas of the sea floor needed to monitor plume migration. The scope of this effort is to transition experimental demonstrations of high-bandwidth, full-duplex scalable underwater laser communications to the seafloor in an open ocean environment. Specifically tackling challenges associated with the dynamic nature of the subsea world, including but not limited to, deployment logistics, sustainability, and range. The goal is to enable the internet of underwater things for deep sea industries by broadening the capabilities of subsea communications. By using high-precision laser transmitters, many of the challenges current subsea optical systems face can be circumvented, such as power consumption, interference, and bandwidth limitations. This approach lends itself to wireless interlinking multi-node networks, in series or parallel, facilitating the implementation of a wide array of sensor types. This interlinking allows all the data gathered from the network to be processed through a single hardline uplink to the surface, lowering the complexity required for near real-time data processing. Additionally, the laser control systems produce metadata that can be used to help characterize the water column between the nodes. Combining data from various sensors such as turbidity, temperature, current velocity with metadata such as beam attenuation and deflection can produce a high-resolution model of sea floor conditions around an active mining zone. The resulting near real-time model can be used to optimize location and flow rate of the mining operation to minimize and quantify the environmental impact.

Mons, Ishan↗

Efficient Precoding for Single Carrier Modulation in Multi-User Massive MIMO Networks

Abstract—Frequency domain (FD) multi-user detection (MUD) and precoding has been shown to be an effective means of approaching the theoretical per-user capacity for single carrier modulation (SCM) schemes in massive MIMO scenarios with highly dispersive channels. When a cyclic prefix is added to the SCM waveform, the circulant structures of the resulting convolutional channel matrix allows for relatively simple expressions for the FD detection and precoding. In this paper, we further refine the computationally efficient minimum mean squared error (MMSE) FD-MUD technique in a time-division duplexing (TDD) massive MIMO setup by pre-computing the scale factor needed to produce an unbiased estimate. The resulting scale factor and the matrix inverse that was calculated for the uplink is then reused for the downlink to form a computationally efficient precoding scheme with superior performance compared to zero-forcing (ZF) precoding. Performance analysis is provided and confirmed through simulation results.

5G and Beyond Communications↗

Compatibility Of Steels At 450°-650°C In Supercritical CO2 With O2 And H2O Additions

Direct-fired supercritical CO2 (sCO2) power cycles are being commercialized to revolutionize fossil energy as a low-emission power source. However, the cycle will increase O2 and H2O in the sCO2 and the implications of these additions have not been fully studied, particularly for lower cost steels that are needed in the lower temperature segments of the plant. Representative 9 and 12%Cr ferritic-martensitic (FM) steels and conventional and advanced austenitic steels were evaluated at 450-650°C to determine the maximum use temperatures in sCO2 with 1%O2 and 0.1%H2O at 300 bar. Compared to research grade (low impurity) sCO2 in indirect-fired cycles, the mass gains and scale thickness were not significantly changed for FM steels: both formed thick duplex Fe-rich scales. For stainless steels, higher mass gains were observed in all cases with increased Fe-rich oxide nodule formation. After 1000h at 650°C, the measured bulk C content was high for all of the steels with the addition of impurities suggesting a lower maximum operating temperature for steels. The post-exposure impact of the environment on room temperature tensile properties also will be discussed.

Pint, Bruce↗

Stabilization of colloidal crystals engineered with nucleic acid

A post-synthetic method for stabilizing colloidal crystals programmed from nucleic acid is disclosed herein. In some embodiments, the method relies on Ag + ions to stabilize the particle-connecting nucleic acid duplexes within the crystal lattice, essentially transforming them from loosely bound structures to ones with very strong interparticle links. In some embodiments, the nucleic acid is DNA. Such crystals do not dissociate as a function of temperature like normal DNA or DNA-interconnected colloidal crystals, and they can be moved from water to organic media or the solid state, and stay intact. The Ag + -stabilization of the nucleic acid (e.g., DNA) bonds is accompanied by a nondestructive contraction of the lattice, and both the stabilization and contraction are reversible with the chemical extraction of the Ag + ions, e.g., by AgCl precipitation with NaCl.

Mirkin, Chad A.↗

Single Carrier Modulation Resource Allocation for Massive MIMO with Virtual Antennas

Today’s Massive MIMO cellular operation is dominated by orthogonal frequency division multiplexing (OFDM) modulation. One of the advantages of OFDM is the flexibility to carve up the available spectrum into resource blocks (RBs) that can operate adjacent to one another. Massive MIMO adds spatial multiplexing layers on top of the RBs, enabling the simultaneous operation of dozens of UEs. Cyclic prefixed single carrier modulation (CP-SCM) is an alternative to OFDM that also benefits from massive MIMO and is useful as an OFDM alternative in specific scenarios. However, until recently, no resource allocation method has been proposed for CP-SCM. In this paper, we present a CP-SCM resource allocation scheme using virtual antennas in a massive MIMO time domain duplexed scenario. By creating several virtual antennas for each physical antenna, the benefits of massive MIMO are achieved with a smaller physical antenna count. Resources are quantized into data streams, and each user can be assigned a variable number of simultaneous streams. This paper presents a detailed development and analysis of multi-stream processing (MSP) for both uplink detection and downlink precoding. We also introduce heterogeneous MSP, where CP-SCM and OFDM signals can be processed in the same MSP framework.

5G and beyond communications↗

Corrosion of Stainless and Carbon Steel in Aqueous Piperazine for CO2 Capture

Current obstacles that prevent commercial implementation of amine-scrubbing CO2 capture are the high costs. Reducing capital costs by appropriate selection of construction materials, which requires knowledge of material corrosion performance for the process, will improve the economic feasibility of this technology. Corrosion was evaluated in three pilot plant campaigns using aqueous piperazine with the Advanced Stripper (PZAS). 316L stainless steel (SS) experienced higher corrosion than 304 SS and 2205 duplex SS, and the corrosion rate showed strong dependence on the temperature. 304 and 2205 performed well at all locations and should be good construction materials for PZAS. Degraded PZ exacerbated 316L corrosion, and removal of PZ degradation products using a carbon adsorption bed significantly reduced corrosion. Carbon steel (CS) corrosion showed a weak temperature effect because the corrosion was more dependent on the protective siderite film. The protectiveness of the films was related to fluid velocity. Ni-based alloys corroded in PZ, and the rate increased with temperature. Corrosion of C1010 CS and SS (304, 316L, 430) was measured at absorber and water wash conditions on the bench-scale. Corrosion rate decreases with increasing PZ. 8 With more than 0.003 m PZ in solution, CS has acceptable corrosion performance. Corrosion of CS increases with increasing partial pressure of CO2, suggesting loading is another dominant parameter for carbon steel corrosion. Temperature has a less significant effect than PZ concentration and loading. CS corrosion increases with increasing flow velocity at both absorber and water wash conditions. SS had little corrosion at this lower temperature. Performance of siderite (FeCO3) protective films on CS was studied at representative stripper conditions on the bench-scale. Siderite films can deposit on the surface of CS in CO2-loaded PZ solution at temperatures >100 °C and protect CS from corrosion. The protection may fail in degraded PZ. Ethylenediamine (EDA) is one of the major contributors for the loss of film protectiveness or can be the surrogate for the effect of PZ degradation on siderite film protection. A link between protectiveness and the apparent density of siderite films was discovered. The apparent density of siderite films decreases with increasing flow velocity and decreasing CO2 loading, resulting in higher corrosion of CS.

Liu, Ching-Ting↗

Disrupting autorepression circuitry generates “open-loop lethality” to yield escape-resistant antiviral agents

Across biological scales, gene-regulatory networks employ autorepression (negative feedback) to maintain homeostasis and minimize failure from aberrant expression. In this study, we present a proof of concept that disrupting transcriptional negative feedback dysregulates viral gene expression to therapeutically inhibit replication and confers a high evolutionary barrier to resistance. We find that nucleic-acid decoys mimicking cis-regulatory sites act as “feedback disruptors,” break homeostasis, and increase viral transcription factors to cytotoxic levels (termed “open-loop lethality”). Feedback disruptors against herpesviruses reduced viral replication >2-logs without activating innate immunity, showed sub-nM IC 50 , synergized with standard-of-care antivirals, and inhibited virus replication in mice. In contrast to approved antivirals where resistance rapidly emerged, no feedback-disruptor escape mutants evolved in long-term cultures. For SARS-CoV-2, disruption of a putative feedback circuit also generated open-loop lethality, reducing viral titers by >1-log. These results demonstrate that generating open-loop lethality, via negative-feedback disruption, may yield a class of antimicrobials with a high genetic barrier to resistance.

59 BASIC BIOLOGICAL SCIENCES↗

Evolution of {delta}ferrite in a CF3 cast stainless steel upon neutron irradiation to 3, 5, 10, 20, and 40 dpa

The microstructural evolution of delta ferrite in a CF3 cast stainless steel irradiated to 3, 5, 10, 20, and 40 dpa with two dose rates was studied with atom probe tomography (APT) and transmission electron mi-croscopy. Spinodal decomposition and G-phase precipitates induced by neutron irradiation and thermal aging were quantified systematically. The neutron irradiation significantly enhances the spinodal decom-position in delta ferrite as both the spinodal wavelength (i.e. a characteristic repeat distance) and am-plitude (i.e. magnitude of elemental concentration fluctuation) increase after irradiation. The wavelength only varies slightly when the dose increases from 5 to 40 dpa, while the amplitude increases dramatically from 10 to 20 dpa and starts to saturate before 20 dpa. The dose rate and irradiation temperature also have a notable effect on the spinodal wavelength and amplitude. The study shows that higher dose rate promotes a larger wavelength at given irradiation doses. Regarding the G-phase precipitates, a slightly lower irradiation temperature would result in a smaller mean size of G-phase precipitates, while a lower irradiation dose rate would lead to a larger G-phase precipitates at a given temperature and dose. Over-all, the spinodal decomposition and G-phase precipitates in the delta ferrite continue to evolve with the increasing dose beyond 10 dpa. This study confirms that the formation of G-phase precipitates at the in-terdomain region between alpha and alpha-prime is facilitated by the Si and Mo atoms rejected from Fe rich alpha phase and the Ni and Mn atoms rejected from Cr rich alpha-prime phase. Neutron irradiation plays a dominant role in the ferrite instability, and the effect of prior thermal aging at 400 degrees C for 10,000 hours is negligible as the dose is 3 dpa and above.

duplex stainless steel↗

Combined modeling and experiments to predict corrosion and embrittlement in dual-phase stainless steels within the MARMOT framework

Extending service of Light Water Reactors (LWRs) to beyond 60 years will demand high integrity of materials and components in the reactors. The accurate evaluation and prediction of materials performance under anticipated operating conditions are of particular importance for ensuring the safety of nuclear power plants over their extended lifetime. Stainless steels are extensively used as structural alloys in light water reactor (LWR) systems because of their excellent combination of mechanical properties and corrosion resistance. Austenitic stainless steel welds and cast austenitic stainless steels (CASS) contain significant amounts of ferrite ~5-30% and are ubiquitous in LWR piping (elbows, pump casings, valves) and internal structural components. During their lifetime, these components are subjected to thermal aging at the temperature range of 288-327°C for pressurized water reactors (PWR). A phase transformation within the ferrite phase of these materials leads to embrittlement and degradation in corrosion resistance, which undermines the materials selection criteria.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗