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At least 145 records · Page 8

Isothermal aging effects on PMR-15 resin

Specimens of PMR-15 polyimide neat resin were aged in air at temperatures of 288, 316, and 343 C. Weight losses and dimensional changes were monitored during the course of the exposure time. Physical changes were also observed by optical and electron microscopy. It was found that polyimide polymer degradation occurred within a thin surface layer that developed and grew during thermal aging. The cores of the polymer specimens were protected from oxidative degradation, and they were relatively unchanged by the thermal treatment. Surface cracking was observed at 343 C and was probably due to an interaction between voids and stresses that developed in the surface layer.

Bowles, Kenneth J.↗

Isothermal aging effects on PMR-15 resin

Specimens of PMR-15 polyimide neat resin were aged in air at temperatures of 288, 316, and 343 C. Weight losses and dimensional changes were monitored during the course of the exposure time. Physical changes were also observed by optical and electron microscopy. It was found that polyimide polymer degradation occurred within a thin surface layer that developed and grew during thermal aging. The cores of the polymer specimens were protected from oxidative degradation, and they were relatively unchanged by the thermal treatment. Surface cracking was observed at 343 C and was probably due to an interaction between voids and stresses that developed in the surface layer.

Bowles, Kenneth J.↗

Boundary conditions on faster-than-light transportation systems

In order to be consistent with current physical theories, any proposal of a faster-than light (FTL) transportation system must satisfy several critical conditions. It must predict the mass, space, and time dimensional changes predicted by relativity physics when velocity falls below the speed of light. It must also not violate causality, and remain consistent with quantum physics in the limit of microscopic systems. It is also essential that the proposal conserve energy.

Bennett, Gary L.↗

The seismic response of an aquifer to the propagation of an impact generated shock wave: A possible trigger of the Martian outflow channels?

Aquifer dilation from shock waves produced by the 8.4 magnitude Alaskan earthquake of 1964 led to water and sediment ejection from the ground up to 400 km away from the earthquake's epicenter. Groundwater disturbances were observed as far away as Perry, Florida (approximately 5500 km), where well water fluctuations with an amplitude of as much as 2.3 m were reported. The martian cratering record provides evidence that the planet has experienced numerous seismic events of a similar, and often much greater, magnitude. Given this fact, and the photogeologic evidence for abundant water in the early crust, the response of a basalt aquifer to the propagation of compressional waves (P-waves) produced by impacts in the 33-1000 km diameter size range were investigated. The resulting one-dimensional changes in effective stress and pore pressure were calculated - as a function of both distance and time - based on the following assumptions: (1) that all of the seismic energy radiated by an impact is transmitted as a single compressional wave; (2) that both the host rock and groundwater are compressible; and (3) that there is no net flow between the water-filled pores.

Leyva, Ivett A.↗

Convective flow effects on protein crystal growth

The long-term stability of the interferometric setup for the monitoring of protein morphologies has been improved. Growth or dissolution of a crystal on a 100 A scale can now be clearly distinguished from dimensional changes occurring within the optical path of the interferometer. This capability of simultaneously monitoring the local interfacial displacement at several widely-spaced positions on the crystal surface with high local depth resolution, has already yielded novel results. We found with lysozyme that (1) the normal growth rate is oscillatory, and (2) the mean growth step density is greater at the periphery of a facet than in its center. The repartitioning of Na(+) and Cl(-) ions between lysozyme solutions and crystals was studied for a wide range of crystallization conditions. A nucleation-growth-repartitioning model was developed to interpret the large body of data in a unified way. The results strongly suggests that (1) the ion to lysozyme ratio in the crystal depends mostly on kinetic rather than crystallographic parameters, and (2) lysozyme crystals possess a salt-rich core with a diameter on the order of 10 microns. The computational model for diffusive-convective transport in protein crystallization (see the First Report) has been applied to a realistic growth cell geometry, taking into account the findings of the above repartitioning studies. These results show that some elements of a moving boundary problem must be incorporated into the model in order to obtain a more realistic description. Our experimental setup for light scattering investigations of aggregation and nucleation in protein solutions has been extensively tested. Scattering intensity measurements with a true Rayleigh scatterer produced systematically increased forward scattering, indicating problems with glare. These have been resolved. Preliminary measurements with supersaturated lysozyme solutions revealed that the scatterers grow with time. Work has begun on a computer program for the unified evaluation of simultaneously obtained, multi-angle static and dynamic light scattering data.

Rosenberger, Franz↗

Low-Earth orbit effects on organic composite materials flown on LDEF

Over 35 different types of organic matrix composites were flown as part of 11 different experiments onboard the NASA Long Duration Exposure Facility (LDEF) satellite. This materials and systems experiment satellite flew in low-earth orbit (LEO) for 69 months. For that period, the experiments were subjected to the LEO environment including atomic oxygen (AO), ultraviolet (UV) radiation, thermal cycling, microvacuum, meteoroid and space debris (M&D), and particle radiation. Since retrieval of the satellite in January of 1990, the principal experiment investigators have been deintegrating, examining, and testing the materials specimens flown. The most detrimental environmental effect on all organic matrix composites was material loss due to AO erosion. AO erosion of uncoated organic matrix composites (OMC) facing the satellite ram direction was responsible for significant mechanical property degradations. Also, thermal cycling-induced microcracking was observed in some nonunidirectional reinforced OMC's. Thermal cycling and outgassing caused significant but predictable dimensional changes as measured in situ on one experiment. Some metal and metal oxide-based coatings were found to be very effective at preventing AO erosion of OMC's. However, M&D impacts and coating fractures which compromised these coatings allowed AO erosion of the underlying OMC substrates. The findings for organic matrix composites flown on the LDEF are summarized and the LEO environmental factors, their effects, and the influence on space hardware design factors for LEO applications are identified.

George, Pete E.↗

Effects of Thermal Cycling on Thermal Expansion and Mechanical Properties of Sic Fiber-reinforced Reaction-bonded Si3n4 Composites

Thermal expansion curves for SiC fiber-reinforced reaction-bonded Si3N4 matrix composites (SiC/RBSN) and unreinforced RBSN were measured from 25 to 1400 C in nitrogen and in oxygen. The effects of fiber/matrix bonding and cycling on the thermal expansion curves and room-temperature tensile properties of unidirectional composites were determined. The measured thermal expansion curves were compared with those predicted from composite theory. Predicted thermal expansion curves parallel to the fiber direction for both bonding cases were similar to that of the weakly bonded composites, but those normal to the fiber direction for both bonding cases resulted in no net dimensional changes at room temperature, and no loss in tensile properties from the as-fabricated condition. In contrast, thermal cycling in oxygen for both composites caused volume expansion primarily due to internal oxidation of RBSN. Cyclic oxidation affected the mechanical properties of the weakly bonded SiC/RBSN composites the most, resulting in loss of strain capability beyond matrix fracture and catastrophic, brittle fracture. Increased bonding between the SiC fiber and RBSN matrix due to oxidation of the carbon-rich fiber surface coating and an altered residual stress pattern in the composite due to internal oxidation of the matrix are the main reasons for the poor mechanical performance of these composites.

Bhatt, R. T.↗

Chemical and Thermal Analysis

Thermal decomposition activation energies have been determined using two methods of Thermogravimetric Analysis (TGA), with good correlation being obtained between the two techniques. Initial heating curves indicated a two-component system for Coflon (i.e. polymer plus placticizer) but a single component system for Tefzel. Two widely differing activation energies were for Coflon supported this view, 15 kcl/mol being associated with plasticizer, and 40 kcal/mol with polymer degradation. With Tefzel, values were 40-45 kcal/mol, the former perhaps being associated with a low molecular weight fraction. Appropriate acceleration factors have been determined. Thermomechanical Analysis (TMA) has shown considerable dimensional change during temperature cycles. For unaged pipe sections heating to 100 C and then holding the temperature resulted in a stable thickness increase of 2%, whereas the Coflon thickness decreased continuously, reaching -4% in 2.7 weeks. Previously strained tensile bars of Tefzel expanded on cooling during TMA. SEM performed on H2S-aged Coflon samples showed significant changes in both physical and chemical nature. The first may have resulted from explosive decompression after part of the aging process. Chemically extensive dehydrofluorination was indicated, and sulfur was present as a result of the aging. These observations indicate that chemical attack of PVDF can occur in some circumstances.

Bulluck, J. W.↗

Materials Selection and Their Characteristics as Used in Rapid Prototyping

NASA's Marshall Space Flight Center (MSFC) conducted a program to evaluate six technologies used in Rapid Prototyping (RP) to produce investment casting patterns. In this paper, RP refers to the collective additive fabrication technologies known as Solid Free-Form Fabrication. Such technologies are being used with increasing frequency in manufacturing applications, due in part to their rapidly expanding capabilities to fabricate models from many types of materials. This study used ABS plastic, polycarbonate, TrueForm PM6, epoxy resin, paper, starch, and wax. The baseline model was a semi-complex prototype fuel pump housing, intended for use in the X-33 reusable launch vehicle. All models were shelled in a production- grade colloidal silica ceramic. Primary coats were zircon-base flour with zircon backup, while secondary coats were silica grains with a tabular alumina backup. Each model was shelled in an identical manner, using the same atmospheric conditions and drying times, as well as the same number of layers. Bake-outs and firing cycles were consistent with the leach ability of each material. Preheat and bath temperatures were also kept consistent. All molds were cast in vacuum using a hydrogen-resistant superalloy (NASA- 23) that was developed in-house. The final technical evaluation included detailed measurements of the model and the final casting, in order to determine any dimensional changes caused by different pattern materials, as well as documentation of all defects and any obvious refractory/model reactions. Prototype production costs were estimated for each method and taken into consideration during trade-off analysis.

Cooper, K.↗

Multi-Tethered Space-Based Interferometers: Particle System Model

Dynamics models are presented for a class of space-based interferometers comprised of multiple component bodies, interconnected in various arrangements, by low-mass flexible tethers of variable length. The tethered constellations are to perform coordinated rotational scanning accompanied by baseline dimensional changes, as well as spin axis realignments and spin-up/spin-down maneuvers. The mechanical idealization is a system of N point masses interconnected by massless tethers of variable length. Both extensible and inextensible tethers are considered. Expressions for system angular and linear momenta are developed. The unrestricted nonlinear motion equations are derived via Lagranges equations. Rheonomic constraints are introduced to allow prescribed motion of any degrees of freedom, and the associated physical forces are determined. The linearized equations of motion are obtained for the steady rotation of a system with extensible tethers of constant unstrained length.

Gates, Stephen S.↗

A Study on a Microwave-Driven Smart Material Actuator

NASA s Next Generation Space Telescope (NGST) has a large deployable, fragmented optical surface (greater than or = 2 8 m in diameter) that requires autonomous correction of deployment misalignments and thermal effects. Its high and stringent resolution requirement imposes a great deal of challenge for optical correction. The threshold value for optical correction is dictated by lambda/20 (30 nm for NGST optics). Control of an adaptive optics array consisting of a large number of optical elements and smart material actuators is so complex that power distribution for activation and control of actuators must be done by other than hard-wired circuitry. The concept of microwave-driven smart actuators is envisioned as the best option to alleviate the complexity associated with hard-wiring. A microwave-driven actuator was studied to realize such a concept for future applications. Piezoelectric material was used as an actuator that shows dimensional change with high electric field. The actuators were coupled with microwave rectenna and tested to correlate the coupling effect of electromagnetic wave. In experiments, a 3x3 rectenna patch array generated more than 50 volts which is a threshold voltage for 30-nm displacement of a single piezoelectric material. Overall, the test results indicate that the microwave-driven actuator concept can be adopted for NGST applications.

Choi, Sang H.↗

Single-Crystal Elastic Constants of Yttria (Y2O3) Measured to High Temperatures

Yttria, or yttrium sesquioxide (Y2O3), has been considered for use in nuclear applications and has gained interest relatively recently for use in infrared optics. Single crystals of yttria have been grown successfully at the NASA Glenn Research Center using a laser-heated float zone technique in a fiber and rod. Such samples allow measurement of the single-crystal elastic properties, and these measurements provide useful property data for the design of components using single crystals. They also yield information as to what degree the elastic properties of yttria ceramics are a result of the intrinsic properties of the yttria crystal in comparison to characteristics that may depend on processing, such as microstructure and intergranular phases, which are common in sintered yttria. The single-crystal elastic moduli are valuable for designing such optical components. In particular, the temperature derivatives of elastic moduli allow the dimensional changes due to heating under physical constraints, as well as acoustic excitation, to be determined. The single-crystal elastic moduli of yttria were measured by Brillouin spectroscopy up to 1200 C. The room-temperature values obtained were C(sub 11) = 223.6 + 0.6 GPa, C(sub 44) = 74.6 + 0.5 GPa, and C(sub 12) = 112.4 + 1.0 GPa. The resulting bulk and (Voigt-Reuss-Hill) shear moduli were K = 149.5 + 1.0 GPa and G(sub VRH) = 66.3 + 0.8 GPa, respectively. Linear least-squares regressions to the variation of bulk and shear moduli with temperature resulted in derivatives of dK/dT = -17 + 2 MPa/C and dG(sub VRH)/dT = -8 + 2 MPa/ C. Elastic anisotropy was found to remain essentially constant over the temperature range studied.

Sayir, Ali↗

Characterization of a Ultra-high Temperature Ceramic Composite

Ultra-high temperature ceramics (UHTC) are of interest for hypersonic vehicle leading edge applications. Monolithic UHTCs are of concern because of their low fracture toughness and brittle behavior. UHTC composites (UHTCC) are being investigated as a possible approach to overcome these deficiencies. In this study a small sample of a UHTCC was evaluated by limited mechanical property tests, furnace oxidation exposures, and oxidation exposures in a flowing environment. The composite was prepared from a carbon fiber perform using ceramic particulates and a preceramic polymer. The as-received composite plate was non-uniform from front to back surface. Plate dimensions were 150 x 150 x 6 mm. The back surface had a fibrous, uniform appearance; XRD analysis revealed the presence of Sic and C. The front surface was smooth and non-uniform in appearance with evidence of a coarse grain structure produced by a liquid phase; XRD analysis revealed the presence of HfB2. Microcracks were present throughout the thickness as one might expect from a carbon fiber reinforced composite with attendant large thermal expansion mismatch between the matrix phases and the fibers. The HfB2 phase on the front surface was comparable in thickness to a fiber ply or about 0.6 mm, and surface microcracks were evident. Limited four point flexural tests were carried out at span to depth ratios of approximately 14 and 16 with markedly different results. Tests were run with the front or the back surface in tension. At the shorter span to depth failures occurred under a loading pin for both orientations. At a span to depth of 16 failures occurred in the center of the span with fracture clearly initiating from a tensile failure. Ultimate flexural strength, strain at ultimate stress, stress and strain at deviation from linear elastic behavior are reported. Strains at ultimate stress ranged from about 0.6 to 0.7 % for the back surface in tension, and 0.4 to 0.6 for the front surface in tension. At constant span to depth the strain at ultimate stress was about 0.2% greater for the back surface in tension and the ultimate strength was also higher. Strengths were in line with predictions from theory. Furnace oxidation studies were carried out at 1627 and 1927OC in a static furnace environment using ten minute cycles and one, five, and ten cycles. Limited oxidation studies were also carried out in a flowing oxyacetylene torch environment. Specimens were photographed, and weight and dimensional changes were determined. XRD and SEM characterizations were performed. Weight losses were attributed primarily to carbon fiber oxidation. The composite survived the torch test with little visible distress. Further details will be determined once metallographic studies are completed.

Levine, Stanley R.↗

Testing in Support of Fission Surface Power System Qualification

The strategy for qualifying a FSP system could have a significant programmatic impact. The US has not qualified a space fission power system since launch of the SNAP-10A in 1965. This paper explores cost-effective options for obtaining data that would be needed for flight qualification of a fission system. Qualification data could be obtained from both nuclear and non-nuclear testing. The ability to perform highly realistic nonnuclear testing has advanced significantly throughout the past four decades. Instrumented thermal simulators were developed during the 1970s and 1980s to assist in the development, operation, and assessment of terrestrial fission systems. Instrumented thermal simulators optimized for assisting in the development, operation, and assessment of modern FSP systems have been under development (and utilized) since 1998. These thermal simulators enable heat from fission to be closely mimicked (axial power profile, radial power profile, temperature, heat flux, etc.) and extensive data to be taken from the core region. For transient testing, pin power during a transient is calculated based on the reactivity feedback that would occur given measured values of test article temperature and/or dimensional changes. The reactivity feedback coefficients needed for the test are either calculated or measured using cold/warm zero-power criticals. In this way non-nuclear testing can be used to provide very realistic information related to nuclear operation. Non-nuclear testing can be used at all levels, including component, subsystem, and integrated system testing. FSP fuels and materials are typically chosen to ensure very high confidence in operation at design burnups, fluences, and temperatures. However, facilities exist (e.g. ATR, HFIR) for affordably performing in-pile fuel and materials irradiations, if such testing is desired. Ex-core materials and components (such as alternator materials, control drum drives, etc.) could be irradiated in university or DOE reactors to ensure adequate radiation resistance. Facilities also exist for performing warm and cold zero-power criticals.

Houts, Mike↗

Polymeric blends for sensor and actuation dual functionality

The invention described herein supplies a new class of electroactive polymeric blend materials which offer both sensing and actuation dual functionality. The blend comprises two components, one component having a sensing capability and the other component having an actuating capability. These components should be co-processable and coexisting in a phase separated blend system. Specifically, the materials are blends of a sensing component selected from the group consisting of ferroelectric, piezoelectric, pyroelectric and photoelectric polymers and an actuating component that responds to an electric field in terms of dimensional change. Said actuating component includes, but is not limited to, electrostrictive graft elastomers, dielectric electroactive elastomers, liquid crystal electroactive elastomers and field responsive polymeric gels. The sensor functionality and actuation functionality are designed by tailoring the relative fraction of the two components. The temperature dependence of the piezoelectric response and the mechanical toughness of the dual functional blends are also tailored by the composition adjustment.

St. Clair, Terry L.↗

EKG and ultrasonoscope display

A system is disclosed which permits simultaneous display of an EKG waveform in real time in conjunction with a two-dimensional cross-sectional image of the heart, so that the EKG waveform can be directly compared with dimensional changes in the heart. The apparatus of the invention includes an ultrasonoscope for producing a C-scan cross-sectional image of the heart. An EKG monitor circuit along with EKG logic circuitry is combined with the ultrasonoscope circuitry to produce on the same oscilloscope screen a continuous vertical trace showing the EKG waveform simultaneously with the heart image. The logic circuitry controls the oscilloscope display such that the display of both heart and EKG waveforms occurs on a real time basis.

Lee, Robert D.↗

Long-Term Impacts of Selective Logging on Amazon Forest Dynamics from Multi-Temporal Airborne LiDAR

Forest degradation is common in tropical landscapes, but estimates of the extent and duration of degradation impacts are highly uncertain. In particular, selective logging is a form of forest degradation that alters canopy structure and function, with persistent ecological impacts following forest harvest. In this study, we employed airborne laser scanning in 2012 and 2014 to estimate three-dimensional changes in the forest canopy and understory structure and aboveground biomass following reduced-impact selective logging in a site in Eastern Amazon. Also, we developed a binary classification model to distinguish intact versus logged forests. We found that canopy gap frequency was significantly higher in logged versus intact forests even after 8 years (the time span of our study). In contrast, the understory of logged areas could not be distinguished from the understory of intact forests after 6–7 years of logging activities. Measuring new gap formation between LiDAR acquisitions in 2012 and 2014, we showed rates 2 to 7 times higher in logged areas compared to intact forests. New gaps were spatially clumped with 76 to 89% of new gaps within 5 m of prior logging damage. The biomass dynamics in areas logged between the two LiDAR acquisitions was clearly detected with an average estimated loss of -4.14 +/- 0.76 MgC/hay. In areas recovering from logging prior to the first acquisition, we estimated biomass gains close to zero. Together, our findings unravel the magnitude and duration of delayed impacts of selective logging in forest structural attributes, confirm the high potential of airborne LiDAR multitemporal data to characterize forest degradation in the tropics, and present a novel approach to forest classification using LiDAR data.

Pinage, Ekena Rangel↗

Multi-axis Heterodyne Interferometry at MHz Frequencies: a Short-Arm Measurement Demonstration for LISA with Off-The-Shelf Hardware

We report the design, construction, and operation of a multi-axis heterodyne interferometry (MAHI) system operating at MHz heterodyne frequencies, which provides a testbed for technologies to be used in the Laser Interferometer Space Antenna (LISA) space-based gravitational wave mission. The system was calibrated for measurement of the piston, pitch, and yaw of a three-axis piezo-actuated mirror, giving measured calibration values that closely match those predicted by a simulation based on Gaussian beam tracing. The piston sensitivity of the MAHI system in the LISA band was measured to be below 10pmHz 1/2 10pmHz1/2 for frequencies above 4 mHz and below 1pmHz 1/2 1pmHz1/2 for frequencies above 35 mHz. The sensitivity is limited above 2 Hz by the mechanical vibrations of the apparatus and below 1 mHz by dimensional changes caused by temperature fluctuations. Evidence points towards scattered light as the limiting noise source at intermediate frequencies. The angular sensitivity of the MAHI system was measured to be close to or below 10nradHz 1/2 10nradHz1/2 for frequencies above 4 mHz and below 1nradHz 1/2 1nradHz1/2 for frequencies above 100 mHz. Noise budgets for both length and angle were determined, indicating the areas in which improvements must be made in order to reach increased sensitivity. The current operating sensitivity already provides a useful testbed for LISA technologies and a potential blueprint for future ground segment equipment.

Fulda, P.↗