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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS2009

Extraction of Water from Lunar Permafrost

Remote sensing indicates the presence of hydrogen rich regions associated with the lunar poles. The logical hypothesis is that there is cryogenically trapped water ice located in craters at the lunar poles. Some of the craters have been in permanent darkness for a billion years. The presence of water at the poles as well as other scientific advantages of a polar base, have influenced NASA plans for the lunar outpost. The lunar outpost has water and oxygen requirements on the order of 1 ton per year scaling up to as much as 5 tons per year. Microwave heating of the frozen permafrost has unique advantages for water extraction. Proof of principle experiments have successfully demonstrated that microwaves will couple to the cryogenic soil in a vacuum and the sublimed water vapor can be successfully captured on a cold trap. Dielectric property measurements of lunar soil simulant have been measured. Microwave absorption and attenuation in lunar soil simulant has been correlated with measured dielectric properties. Future work will be discussed.

Ethridge, Edwin C.↗
NASA NTRS2005

Aligned Single Wall Carbon Nanotube Polymer Composites Using an Electric Field

While high shear alignment has been shown to improve the mechanical properties of single wall carbon nanotubes (SWNT)-polymer composites, it is difficult to control and often results in degradation of the electrical and dielectric properties of the composite. Here, we report a novel method to actively align SWNTs in a polymer matrix, which allows for control over the degree of alignment of SWNTs without the side effects of shear alignment. In this process, SWNTs are aligned via field-induced dipolar interactions among the nanotubes under an AC electric field in a liquid matrix followed by immobilization by photopolymerization while maintaining the electric field. Alignment of SWNTs was controlled as a function of magnitude, frequency, and application time of the applied electric field. The degree of SWNT alignment was assessed using optical microscopy and polarized Raman spectroscopy and the morphology of the aligned nanocomposites was investigated by high resolution scanning electron microscopy. The structure of the field induced aligned SWNTs is intrinsically different from that of shear aligned SWNTs. In the present work, SWNTs are not only aligned along the field, but also migrate laterally to form thick, aligned SWNT percolative columns between the electrodes. The actively aligned SWNTs amplify the electrical and dielectric properties in addition to improving the mechanical properties of the composite. All of these properties of the aligned nanocomposites exhibited anisotropic characteristics, which were controllable by tuning the applied field conditions.

Park, Cheol↗
DOE OSTI2021

Dynamical origins of weakly coupled relaxor behavior in Sn-doped (Ba,Ca)TiO 3 -BiScO 3

The peculiar characteristics of relaxors, viz., a frequency-dependent dielectric permittivity peak and good functional properties (dielectric, electromechanical, electrocaloric, etc.), are attributed to nanoscale regions with correlated dipoles, or polar nanoregions (PNRs). However, the exact nature of PNRs and their contribution to relaxor behavior remains debatable. In recent years, solid solutions of BaTiO3-BiMeO3 (where Me is a metal), have emerged as an interesting system with characteristics in between that of relaxors and dipole glasses. Here, we have examined the atomistic origins of weakly coupled relaxor behavior, specifically with regard to formation of PNRs, in Sn-doped (1-x)(Ba,Ca)TiO 3-x BiScO 3 using macroscopic polarization and neutron dynamic pair distribution function measurements. We show that the short-range atomic correlations observed within the PNRs dynamically fluctuate with frequencies of the order of THz. Furthermore the composition-dependent dielectric and polarization behaviors are critically influenced by the relative stability of the atomic correlations near ~1 THz, while the instantaneous atomic correlations are largely independent of x. The current results are discussed based on a model of intrinsic local modes distributed in a dielectrically soft matrix.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2023

Anisotropic Properties of Epitaxial Ferroelectric Lead-Free 0.5[Ba(Ti 0.8 Zr 0.2 )O 3 ]-0.5(Ba 0.7 Ca 0.3 )TiO 3 Films

As the energy demand is expected to double over the next 30 years, there has been a major initiative towards advancing the technology of both energy harvesting and storage for renewable energy. In this work, we explore a subset class of dielectrics for energy storage since ferroelectrics offer a unique combination of characteristics needed for energy storage devices. We investigate ferroelectric lead-free 0.5[Ba(Ti 0.8 Zr 0.2 )O 3 ]-0.5(Ba 0.7 Ca 0.3 )TiO 3 epitaxial thin films with different crystallographic orientations grown by pulsed laser deposition. We focus our attention on the influence of the crystallographic orientation on the microstructure, ferroelectric, and dielectric properties. Our results indicate an enhancement of the polarization and strong anisotropy in the dielectric response for the (001)-oriented film. The enhanced ferroelectric, energy storage, and dielectric properties of the (001)-oriented film is explained by the coexistence of orthorhombic-tetragonal phase, where the disordered local structure is in its free energy minimum.

36 MATERIALS SCIENCE↗
NASA NTRS1980

Permittivity of ice and water at millimeter wavelengths

Measurements of reflectivity of water and ice at 100 GHz, 140 GHz, and 180 GHz are reported. Measurements on water covered the temperature range 0 C to 50 C. No anomalies in the dielectric properties of water due to the presence of either salts or organic matter were found. The reflectivity of water and its temperature dependence are consistent with recent dielectric property models derived from data at other wavelengths. The index of refraction of fresh ice is constant at 1.78 throughout this regions.

Blue, M. D.↗
NASA NTRS2004

Lunar and Planetary Science XXXV: Mars: Radar, Gamma Ray Spectrometer, and Cratering Mineralogy

The session "Mars: Radar, Gamma Ray Spectrometer, and Cratering Mineralogy" contained the following reports:The Dielectric Properties of Martian Soil Simulant JSC Mars-1 in the Range from 20Hz to 10kHz; Eastern Sahara Geology from Orbital Radar: Potential Analog to Mars On the Dielectric Properties of the Martian-like Surface Sediments; Radar Observations of Recent Mars Landing Sites; Sounding of Subsurface Water Through Conductive Media in Mars Analog Environments Using Transient Electromagnetics and Low Frequency Ground-penetrating Radar; Burial Depth of the Reservoirs of Hydrogen at the Equatorial Latitudes on Mars; Elemental Composition Variations for Large Dusty and Rocky Regions on Mars Using Gamma-Ray Data from the Mars Odyssey Gamma-Ray Spectrometer; The Distribution of Non-Volatile Elements on Mars: Mars Odyssey GRS Results; Using Mars Odyssey GRS Data to Assess Models for the Bulk Composition of Mars; Mars: The Terra Arabia Low Epithermal Neutron Flux Anomaly; The Isidis Basin of Mars: New Results from MOLA, MOC, and THEMIS; Remote Sensing of the Haughton Impact Structure (HIS): A Terrestrial Proof of Concept for Using the Remote Sensing of Martian Craters as a Probe of Subsurface Composition;and Thermal Emission Spectra of Impact Glass and Shocked Deccan Basalt from Lonar Crater, India and Implications for Remote Sensing of Mars.

Source record↗
NASA NTRS1981

Vertical-structure effects on planetary microwave brightness temperature measurements - Applications to the lunar regolith

An attempt to constrain the effects of vertical variations in dielectric properties on lunar microwave observations is presented. A numerical approach for deriving the reflectivity and microwave weighting function of a vertically varying half-space is used, assuming variance in the dielectric properties with depth only, and negligible magnetic effects. The cases of continuous and stratified models of vertical structures are discussed, and a concentration of emitted energy in upper layers is found. The total emitted energy oscillates, varying with the thickness of the upper soil layer, but averaging out interference effects due to random variations in the substrate depth. Consideration is also given to the vertical structure effects on the lunation-mean disk-center brightness temperature, its variations, and the regolith electrical loss, and predicted reflectivity effects by feasible models of the lunar regolith dielectric profile.

Keihm, S. J.↗
NASA NTRS1974

Dielectric comparison of lunar and terrestrial fines at lunar conditions

The dielectric properties of lunar fines 74241,2 in the audio-frequency range under lunarlike conditions are presented. Results suggest that volatiles are released during storage and transport of the lunar sample. Apparently, subsequent adsorption of volatiles on the sample surface alters its dielectric response. The assumed volatile influence disappears after evacuation. A comparison of the dielectric properties of lunar and terrestrial materials as a function of density, temperature, and frequency indicates that if the terrestrial sample analyzed were completely devoid of atmospheric moisture, it would present dielectric losses smaller than those of the lunar sample. It is concluded that density prevails over temperature as the controlling factor of dielectric permittivity in the lunar regolith and that dielectric losses vary slowly with depth.

Alvarez, R.↗
NASA NTRS2008

Microwave Extraction of Lunar Water for Rocket Fuel

Nearly 50% of the lunar surface is oxygen, present as oxides in silicate rocks and soil. Methods for reduction of these oxides could liberate the oxygen. Remote sensing has provided evidence of significant quantities of hydrogen possibly indicating hundreds of millions of metric tons, MT, of water at the lunar poles. If the presence of lunar water is verified, water is likely to be the first in situ resource exploited for human exploration and for LOX-H2 rocket fuel. In-Situ lunar resources offer unique advantages for space operations. Each unit of product produced on the lunar surface represents 6 units that need not to be launched into LEO. Previous studies have indicated the economic advantage of LOX for space tugs from LEO to GEO. Use of lunar derived LOX in a reusable lunar lander would greatly reduce the LEO mass required for a given payload to the moon. And Lunar LOX transported to L2 has unique advantages for a Mars mission. Several methods exist for extraction of oxygen from the soil. But, extraction of lunar water has several significant advantages. Microwave heating of lunar permafrost has additional important advantages for water extraction. Microwaves penetrate and heat from within not just at the surface and excavation is not required. Proof of concept experiments using a moon in a bottle concept have demonstrated that microwave processing of cryogenic lunar permafrost simulant in a vacuum rapidly and efficiently extracts water by sublimation. A prototype lunar water extraction rover was built and tested for heating of simulant. Microwave power was very efficiently delivered into a simulated lunar soil. Microwave dielectric properties (complex electric permittivity and magnetic permeability) of lunar regolith simulant, JSC-1A, were measured down to cryogenic temperatures and above room temperature. The microwave penetration has been correlated with the measured dielectric properties. Since the microwave penetration depth is a function of temperature and frequency, an extraction system can be designed for water removal from different depths.

Ethridge, Edwin C.↗
DOE OSTI2025

First-principles study of structural, elastic, electronic, transport properties, and dielectric breakdown of Cs 2 Te photocathode

The pursuit to operate photocathodes at high accelerating gradients to increase brightness of electron beams is gaining interests within the accelerator community, particularly for applications such as free electron lasers (FEL) and compact accelerators. Cesium telluride (Cs 2 Te) is a widely used photocathode material and it is presumed to offer resilience to higher gradients because of its wider band gap compared to other semiconductors. Despite its advantages, crucial material properties of Cs 2 Te remain largely unknown both in theory and experiments. In this study, we employ first-principles calculations to provide detailed structural, elastic, electronic and transport properties of Cs 2 Te. It is found that Cs 2 Te has an intrinsic mobility of 20 cm 2 /Vs for electrons and 2.0 cm 2 /Vs for holes at room temperature. The low mobility is primarily limited by the strong polar optical phonon scattering. Cs 2 Te also exhibits ultralow lattice thermal conductivity of 0.2 W/(m*K) at room temperature. Based on the energy gain/loss balance under external field and electron–phonon scattering, we predict that Cs 2 Te has a dielectric breakdown field in the range from ~ 60 to ~ 132 MV/m at room temperature dependent on the doping level of Cs 2 Te. Our results are crucial to advance the understanding of applicability of Cs 2 Te photocathodes for high-gradient operation.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Millimeter-wave dielectric tunability driven by topological polar structure switching in PbTiO 3 /SrTiO 3 superlattices

Dielectric tunability induced by an external electric field in materials underpins radio frequency signal modulation devices such as phase shifters, which are critical components in wireless communication and sensing systems. However, the tunability and integrability of current devices have yet to be enhanced for emerging applications, particularly at millimeter-wave frequencies. Here, we demonstrate that topological polar structures formed in PbTiO 3 /SrTiO 3 superlattices exhibit large tunable in-plane dielectric properties, as determined by their multiscale structural configurations and polarization switching behaviors. Under a moderate field of 30 kV cm −1 , the dipole wave structure maintains a tunability exceeding 15% at 70 GHz and above 8% over the measured range up to 110 GHz, contrasting with the weakly tunable flux closure structure. Based on in situ structural characterizations and molecular dynamics simulations, we delineate the polarization switching processes and elucidate the mechanisms underlying the observed tunable millimeter-wave dielectric responses. Our results provide new insights into the high-frequency dielectric properties of topological polar phases, potentially broadening the versatility of these materials in next-generation integrated electronic applications.

36 MATERIALS SCIENCE↗
NASA NTRS2015

Core Analysis Combining MT (TIPPER) and Dielectric Sensors (Sans EC) in Earth and Space

On terrestrial planets and moons of our solar system cores reveal details about a geological structure's formation, content, and history. The strategy for the search for life is focused first on finding water which serves as a universal solvent, and identifying the rocks which such solvent act upon to release the constituent salts, minerals, ferrites, and organic compounds and chemicals necessary for life. Dielectric spectroscopy measures the dielectric properties of a medium as a function of frequency. Reflection measurements in the frequency range from 300 kHz to 300 MHz were carried out using RF and microwave network analyzers interrogating SansEC Sensors placed on clean geological core samples. These were conducted to prove the concept feasibility of a new geology instrument useful in the field and laboratory. The results show that unique complex frequency spectra can be acquired for a variety of rock core samples. Using a combination of dielectric spectroscopy and computer simulation techniques the magnitude and phase information of the frequency spectra can be converted to dielectric spectra. These low-frequency dielectric properties of natural rock are unique, easily determined, and useful in characterizing geology. TIPPER is an Electro-Magnetic Passive-Source Geophysical Method for Detecting and Mapping Geothermal Reservoirs and Mineral Resources. This geophysical method uses distant lightning and solar wind activity as its energy source. The most interesting deflections are caused by the funneling of electrons into more electrically conductive areas like mineralized faults, water or geothermal reservoirs. We propose TIPPER to be used with SansEC for determining terrain/ocean chemistry, ocean depth, geomorphology of fracture structures, and other subsurface topography characteristics below the ice crust of Jovian moons. NASA envisions lander concepts for exploration of these extraterrestrial icy surfaces and the oceans beneath. One such concept would use a nuclear powered heated tip for melting through the ice sheath of Europa and inserting a down hole SansEC with TIPPER interface. NASA's Juno space probe already on the way to Jupiter as part of the Exploration New Frontiers Program and the planned Europa mission will conduct detailed reconnaissance of Jupiter's moon Europa and investigate whether the icy moon could harbor conditions suitable for life. It has already been observed that Jovian moons have auroras that may serve as naturally occurring active energy sources for a TIPPER instrument.

Mound, Michael C.↗
DOE OSTI2020

Microscopic Theory of Plasmons in Substrate-Supported Borophene

Here, we compute the dielectric properties of freestanding and metal-supported borophene from first-principles time-dependent density functional theory. We find that both the low- and high-energy plasmons of borophene are fully quenched by the presence of a metallic substrate at borophene–metal distances smaller than ≃9 Å. Based on these findings, we derive an electrodynamic model of the interacting, momentum-dependent polarizability for a two-dimensional metal on a model metallic substrate, which quantitatively captures the evolution of the dielectric properties of borophene as a function of metal–borophene distance. Applying this model to a series of metallic substrates, we show that maximizing the plasmon energy detuning between borophene and substrate is the key material descriptor for plasmonic performance.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2025

Dielectric constant engineering of nonfullerene acceptors enables a record fill factor of 83.58% and a high efficiency of 20.80% in organic solar cells

Organic solar cells (OSCs) have achieved power conversion efficiencies (PCEs) surpassing 20%, but their development remains hindered by the inherently low dielectric constant (εr) of organic semiconductors, which limits charge transport and contributes to serious recombination losses. Herein, we present a comprehensive strategy to overcome the challenge by engineering the dielectric properties of nonfullerene acceptors (NFAs). Two Y-series NFAs of BTP-N3F and BTP-C3F have been synthesized featuring trifluoromethyl (CF 3 ) end-capped alkyl side chains. This molecular design significantly enhances the dipole moment and ε r (up to ∼5.9) when compared to the reference acceptor Y6 (∼3), reducing the exciton binding energy (E b ) and improving charge transport. Furthermore, the incorporation of a high-εr polymer additive, poly(pentafluorostyrene) (PPFS), synergistically improves the active layer morphology and dielectric properties, enabling efficient charge extraction and reduced recombination losses. Devices based on the optimized D18-Cl/BTP-C3F system have achieved a record-high fill factor (FF) of 83.58% and an impressive PCE of 20.80%, setting a new benchmark for OSCs. Finally, our results underscore the pivotal role of ε r in enhancing device performance and establish a versatile pathway for advancing OSC efficiency and stability through molecular and morphological optimization.

36 MATERIALS SCIENCE↗
NASA NTRS1982

High Frequency Scattering from Arbitrarily Oriented Dielectric Disks

Calculations have been made of electromagnetic wave scattering from dielectric disks of arbitrary shape and orientation in the high frequency (physical optics) regime. The solution is obtained by approximating the fields inside the disk with the fields induced inside an identically oriented slab (i.e. infinite parallel planes) with the same thickness and dielectric properties. The fields inside the disk excite conduction and polarization currents which are used to calculate the scattered fields by integrating the radiation from these sources over the volume of the disk. This computation has been executed for observers in the far field of the disk in the case of disks with arbitrary orientation and for arbitrary polarization of the incident radiation. The results have been expressed in the form of a dyadic scattering amplitude for the disk. The results apply to disks whose diameter is large compared to wavelength and whose thickness is small compared to diameter, but the thickness need not be small compared to wavelength. Examples of the dependence of the scattering amplitude on frequency, dielectric properties of the disk and disk orientation are presented for disks of circular cross section.

Levine, D. M.↗
NASA NTRS1992

Dielectric surface properties of Venus

It has been known for over a decade that certain high-altitude regions on Venus exhibit bizarre radar-scattering and radiothermal-emission behavior. For example, observed values for normal-incidence power reflection coefficients in these areas can exceed 0.5; enhanced back scatter in some mountainous areas in the Magellan SAR images creates a bright surface with the appearance of snow; and reduced thermal emission in the anomalous areas makes the surface there appear hundreds of degrees cooler than the corresponding physical surface temperatures. The inferred radio emissivity in several of these regions falls to 0.3 for horizontal linear polarization at viewing angles in the range 20 deg - 40 deg. Several explanations have been offered for these linked phenomena. One involves single-surface reflection from a sharp discontinuity separating two media that have extremely disparate values of electromagnetic propagation. The mismatch may occur in either or both the real (associated with propagation velocity) or imaginary (associated with absorption) components of the relevant indices of refraction, and the discontinuity must take place over a distance appreciably shorter than a wavelength. An example of such an interaction of Earth would occur at the surface of a body of water. At radio wavelengths, water has an index of refraction of 9 (dielectric permittivity of about 80), and an associated loss factor that varies strongly with the amount of dissolved salts, but is generally significant. Its single-surface radar reflectivity at normal incidence is about 0.65, and the corresponding emissivity (viewed at the same angle) is therefore 0.35. Both these values are similar to the extremes found on Venus, but in the absence of liquid water, the process on Venus requires a different explanation. Two of the present authors (Pettengill and Ford) have suggested that scattering from a single surface possessing a very high effective dielectric permittivity could explain many of the unusual characteristics displayed by the Venus surface. A second explantion relates to the volume scattering that results from successive interactions with one or more interfaces interior to the planetary surface. If the near-surface material has a moderately low index of refraction (to ensure that a substantial fraction of the radiation incident from outside is not reflected, but rather penetrates into the surface), and a very low internal propagation loss, successive internal reflections can eventually redirect much of the energy back through the surface toward the viewer. The necessary conditions for this process to be effective are a low internal propagation loss coupled with efficient internal reflection. At sufficiently low temperatures, fractured water ice displays both the necessary low loss and near-total internal reflection. The possibility that this mechanism might be acting on Venus has recently been put forward.

Pettengill, G. H.↗
NASA NTRS1992

Evaluation of high temperature dielectric films for high voltage power electronic applications

Three high temperature films, polyimide, Teflon perfluoroalkoxy and poly-P-xylene, were evaluated for possible use in high voltage power electronic applications, such as in high energy density capacitors, cables and microelectronic circuits. The dielectric properties, including permittivity and dielectric loss, were obtained in the frequency range of 50 Hz to 100 kHz at temperatures up to 200 C. The dielectric strengths at 60 Hz were determined as a function of temperature to 250 C. Confocal laser microscopy was performed to diagnose for voids and microimperfections within the film structure. The results obtained indicate that all films evaluated are capable of maintaining their high voltage properties, with minimal degradation, at temperatures up to 200 C. However, above 200 C, they lose some of their electrical properties. These films may therefore become viable candidates for high voltage power electronic applications at high temperatures.

Suthar, J. L.↗
DOE OSTI2023

Dielectric and Structural Properties of the Hybrid Material Polyvinylidene Fluoride-Bacterial Nanocellulose-Based Composite

In the search for environmentally friendly materials with a wide range of properties, polymer composites have emerged as a promising alternative due to their multifunctional properties. This study focuses on the synthesis of composite materials consisting of four components: bacterial nanocellulose (BNC) modified with magnetic Fe 3 O 4 , and a mixture of BaTiO 3 (BT) and polyvinylidene fluoride (PVDF). The BT powder was mechanically activated prior to mixing with PVDF. The influence of BT mechanical activation and BNC with magnetic particles on the PVDF matrix was investigated. The obtained composite films’ structural characteristics, morphology, and dielectric properties are presented. This research provides insights into the relationship between mechanical activation of the filler and structural and dielectric properties in the PVDF/BT/BNC/Fe 3 O 4 system, creating the way for the development of materials with a wide range of diverse properties that support the concept of green technologies.

36 MATERIALS SCIENCE↗