Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “density modification”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Second Target Station Bunker Shielding with Populated and Unpopulated Neutron Beamlines: Preliminary Design

At the U.S. Department of Energy’s Oak Ridge National Laboratory, the Second Target Station (STS) beamline sources for preliminary design have been used to perform a shielding analysis of the bunker. Prompt total effective dose rates (i.e., neutron plus photon effective dose rates when the proton beam is on) were calculated on top of the bunker roof and outside the bunker wall. These areas outside the bunker will be generally accessible, so the prompt total dose rate in these areas should not exceed 2.5 μSv . h -1 (0.25 mrem . h -1 ). This paper presents the required shielding thicknesses to meet this dose rate limit. In one instance, this dose rate limit is not met: For a combination of populated and unpopulated beamlines, the prompt total dose rate outside the bunker across from the unpopulated beamline, which has less shielding because of the lack of beamline shielding, slightly exceeds 2.5 μSv . h -1 . In conclusion, once more details are known regarding the STS high-density concrete density and composition, a future analysis will investigate the shielding modifications required to reduce the calculated prompt total dose rates for this configuration to less than 2.5 μSv . h -1 .

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2023

Collective enhancement in the exciton model

The preequilibrium reaction mechanism is considered in the context of the exciton model. A modification to the one-particle–one-hole state density is studied which can be interpreted as a collective enhancement. The magnitude of the collective enhancement is estimated by simulating the Lawrence Livermore National Laboratory (LLNL) pulsed-spheres neutron-leakage spectra. Here the impact of the collective enhancement is explored in the context of the highly deformed actinide, 239 Pu. A consequence of this enhancement is the removal of fictitious levels in the distorted-wave Born approximation often used in modern nuclear reaction codes.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2022

Surface stress tensor and junction conditions on a rotating null horizon

The general form of the surface stress tensor of an infinitesimally thin shell located on a rotating null horizon is derived, when different interior and exterior geometries are joined there. Even though the induced metric on the surface must be the same approached from either side, the first derivatives of the metric need not be. Such discontinuities lead to a Dirac δ-distribution in the Einstein tensor localized on the horizon. For a general stationary axisymmetric geometry the surface stress tensor can be expressed in terms of two geometric invariants that characterize the surface, namely the discontinuities [κ] and [J] of the surface gravity κ and angular momentum density J. The Komar energy and angular momentum are given in coordinates adapted to the Killing symmetries, and the surface contributions to each determined in terms of [κ] and [J] . Guided by these, a simple modification of the original Israel junction conditions is verified directly from the Einstein tensor density to give the correct finite result for the surface stress, when the normal n to the surface is allowed to tend continuously to a null vector. The relation to Israel’s original junction conditions, which fail on null surfaces, is given. The modified junction conditions are suitable to the matching of a rotating “black hole” exterior to any interior geometry joined at the Kerr null horizon surface, even when the surface normal is itself discontinuous and the Barrabès-Israel formalism is also inapplicable. This joining on a rotating null horizon is purely of the matter shell type and does not contain a propagating gravitational shock wave.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1980

FFT methods in signal processing of the coal interface detector radar

The FM radar for the coal interface detector, operating in the frequency band 2 to 4 GHz, is intended for the display of thicknesses between 2 cm and 20 cm. Because of such a short range, the thickness information is contained in the very few lowest spectral components of the output signal. To overcome this inconvenience, the Fourier series of the output signal was augmented to approximate a Fourier integral. This modification in the signal processing resulted in a higher spectral density, which in turn enabled an easier identification of the interface position in the laboratory. The orientation and spacing of the receiving and transmitting antennas is found to have an important influence on the system performance.

Kajfez, D.↗
NASA NTRS1991

Bending waves and orbital inclinations

Disk tides may play an important role in the formation of a planetary system. Modification of protoplanet semi-major axes and eccentricities through density waves was suggested and calculations of linear and non-linear protoplanet-nebula interactions were carried out by a number of researchers. The possible significance of radial drift to the accretion process was discussed, while the evolution of orbital eccentricities was studied for a perturber orbiting external to a ring and for a perturber embedded in the ring. The possible importance of bending waves to the early evolution of protoplanet inclinations is described.

Ward, William R.↗
NASA NTRS2007

Impact of Ring Current Ions on Electromagnetic Ion Cyclotron Wave Dispersion Relation

Effect of the ring current ions in the real part of electromagnetic ion Cyclotron wave dispersion relation is studied on global scale. Recent Cluster observations by Engebretson et al. showed that although the temperature anisotropy of is energetic (> 10 keV) ring current protons was high during the entire 22 November 2003 perigee pass, electromagnetic ion cyclotron waves were observed only in conjunction with intensification of the ion fluxes below 1 keV by over an order of magnitude. To study the effect of the ring current ions on the wave dispersive properties and the corresponding global wave redistribution, we use a self-consistent model of interacting ring current and electromagnetic ion cyclotron waves, and simulate the May 1998 storm. The main findings of our simulation can be summarized as follows: First, the plasma density enhancement in the night MLT sector during the main and recovery storm phases is mostly caused by injection of suprathermal plasma sheet H + (approximately < 1 keV), which dominate the thermal plasma density. Second, during the recovery storm phases, the ring current modification of the wave dispersion relation leads to a qualitative change of the wave patterns in the postmidnight-dawn sector for L > 4.75. This "new" wave activity is well organized by outward edges of dense suprathermal ring current spots, and the waves are not observed if the ring current ions are not included in the real part of dispersion relation. Third, the most intense wave-induced ring current precipitation is located in the night MLT sector and caused by modification of the wave dispersion relation. The strongest precipitating fluxes of about 8 X 10(exp 6)/ (cm(exp 2) - s X st) are found near L=5.75, MLT=2 during the early recovery phase on 4 May. Finally, the nightside precipitation is more intense than the dayside fluxes, even if there are less intense waves, because the convection field moves ring current ions into the loss cone on the nightside, but drives them out of the loss cone on the dayside. So convection and wave scattering reinforce each other in the nightside, but interfere in the dayside sector.

Khazanov, G. V.↗
NASA NTRS2000

Gas storage using fullerene based adsorbents

This invention is directed to the synthesis of high bulk density high gas absorption capacity adsorbents for gas storage applications. Specifically, this invention is concerned with novel gas absorbents with high gravimetric and volumetric gas adsorption capacities which are made from fullerene-based materials. By pressing fullerene powder into pellet form using a conventional press, then polymerizing it by subjecting the fullerene to high temperature and high inert gas pressure, the resulting fullerene-based materials have high bulk densities and high gas adsorption capacities. By pre-chemical modification or post-polymerization activation processes, the gas adsorption capacities of the fullerene-based adsorbents can be further enhanced. These materials are suitable for low pressure gas storage applications, such as oxygen storage for home oxygen therapy uses or on-board vehicle natural gas storage. They are also suitable for storing gases and vapors such as hydrogen, nitrogen, carbon dioxide, and water vapor.

Loutfy, Raouf O.↗
NASA NTRS2013

Radiative Transfer Theory Verified by Controlled Laboratory Experiments

We report the results of high-accuracy controlled laboratory measurements of the Stokes reflection matrix for suspensions of submicrometer-sized latex particles in water and compare them with the results of a numerically exact computer solution of the vector radiative transfer equation (VRTE). The quantitative performance of the VRTE is monitored by increasing the volume packing density of the latex particles from 2 to 10. Our results indicate that the VRTE can be applied safely to random particulate media with packing densities up to 2. VRTE results for packing densities of the order of 5 should be taken with caution, whereas the polarized bidirectional reflectivity of suspensions with larger packing densities cannot be accurately predicted. We demonstrate that a simple modification of the phase matrix entering the VRTE based on the so-called static structure factor can be a promising remedy that deserves further examination.

Radiative transfer↗
NASA NTRS1994

Dynamics and Thermodynamics of Dense and Dilute Clusters of Drops

Collective drop behavior is encountered in sprays produced for a variety of applications. The existence of clusters of drops indicates that the interaction among the drops is important in determining the dynamics of the drops because the drop proximity changes the flow around the individual drops in a way that affects the drag on each drop. Additionally, if there is a phase change between the liquid drops and the gaseous surroundings (either evaporation or condensation), this will also influence the flow around the individual drops; and phase change is also affected by the drop proximity. What will be discussed are studies of collections of drops where the dynamics and thermodynamics of the drops are coupled. This means the modification of the drag force due to the drop number density, the evaporation rate and the slip velocity are all taken into account. In turn, the enhancement in the evaporation rate due to the slip velocity , and the hindering of evaporation due to the drop proximity are also part of the models.

thermodynamics↗
DOE OSTI2021

Determining the electrical conductivity of metals using the 2 MA Thor pulsed power driver

We present the development of a pulsed power experimental technique to infer the electrical conductivity of metals from ambient to high energy density conditions. The method is implemented on Thor, a moderate scale (1–2 MA) pulsed power driver. The electrical conductivity of copper at elevated temperature (>4000 K) and pressure (>10 GPa) is determined, and a new tabular material model is developed, guided by density functional theory, which preserves agreement with existing experimental data. Minor modifications (<10%) are found to be necessary to the previous Lee–More–Desjarlais model isotherms in the vicinity of the melt transition in order to account for observed discrepancies with the new experimental data. An analytical model for magnetic direct drive flyer acceleration and Joule heating induced vaporization based on the Tsiolkovsky “rocket equation” is presented to assess sensitivity of the method to minor changes in electrical conductivity.

47 OTHER INSTRUMENTATION↗
DOE OSTI2024

Iterative Stress Reconstruction Algorithm to Estimate Three-Dimensional Residual Stress Fields in Manufactured Components

Residual stress (RS) significantly impacts the mechanical performance of components. Measurement of RS often provides incomplete data in terms of components of stress and spatial density. Employing such fields in finite element simulations results in significant modification of the field to achieve equilibrium and compatibility among strains. To overcome this, an iterative stress reconstruction algorithm (ISRA) is developed to estimate 3D RS fields that satisfy equilibrium, are stress component-wise complete, and represent the characterized data sampled. An Al 7075-T651 plate and an additively manufactured (AM) A36 steel wall are considered for RS reconstruction using measurement data from the literature. A maximum variation of ~2.5 MPa in the Al plate, and ~10 MPa in the steel wall are observed between the reconstructed and measured stresses. Furthermore, unknown stress components emerge and reach significant magnitudes (upto ~2.3 MPa in the Al plate and ~45 MPa in the AM wall) during ISRA. Indeed, it is found that minor errors in measurement or data processing are eliminated through the physical requirements during ISRA. Employing a reconstructed RS field is hence not just more accurate given its compatibility, but it additionally corrects for minor errors in measurement. Furthermore, it is found that spatially dense measurement data result in convergence with fewer iterations. Finally, although ISRA yields a nonunique solution dependent on boundary conditions, measurement errors, fitting errors, and mesh density, it accommodates for uncertainties and inaccuracies in measurement, as opposed to failing to reach a physically realistic converged solution.

42 ENGINEERING↗
NASA NTRS1976

Air transportation energy efficiency - Alternatives and implications

Results from recent studies of air transportation energy efficiency alternatives are discussed, along with some of the implications of these alternatives. The fuel-saving alternatives considered include aircraft operation, aircraft modification, derivative aircraft, and new aircraft. In the near-term, energy efficiency improvements should be possible through small improvements in fuel-saving flight procedures, higher density seating, and higher load factors. Additional small near-term improvements could be obtained through aircraft modifications, such as the relatively inexpensive drag reduction modifications. Derivatives of existing aircraft could meet the requirements for new aircraft and provide energy improvements until advanced technology is available to justify the cost of a completely new design. In order to obtain significant improvements in energy efficiency, new aircraft must truly exploit advanced technology in such areas as aerodynamics, composite structures, active controls, and advanced propulsion.

Williams, L. J.↗
DOE OSTI2022

Graphene coating on silicon anodes enabled by thermal surface modification for high-energy lithium-ion batteries

Silicon is a high-energy density anode material for lithium-ion batteries, but it possesses shortcomings such as poor electronic conductivity, interfacial instability and mechanical fracturing that hinder its battery cycling. Carbon coating has been an important strategy for stabilizing silicon anodes, but the effects of the silicon surface properties on carbon coating morphology and the consequent silicon cycling stability have not been clearly elucidated. Herein, we find that thermal oxidation of the silicon anodes followed by chemical vapor deposition of carbonaceous precursors leads to a well-ordered graphene coating, whereas disordered graphite coating is formed on the native silicon surface. Graphene-coated silicon exhibits superior cycling performance, retaining a discharge capacity of ~1300 mAh g -1 after 300 cycles, whereas the disordered graphite-coated silicon suffers continuous degradation, retaining only~600 mAh g -1 after 300 cycles. Cryogenic electron microscopy reveals the mechanism behind the difference in cycling stabilities; graphene coated silicon is able to withstand the large mechanical strains induced during extended cycling, whereas disordered graphite coating is ruptured, exposing silicon surfaces to the electrolyte, leading to extensive buildup of SEI and poor cycling performance. Characterization of the silicon surface reveals that thermal treatment yields an oxygen-rich surface layer, which is hypothesized to play a decisive role in dictating the carbon coating. This work highlights the effect of silicon surface properties on carbon coating microstructure, and presents thermal treatment as a facile avenue to attain graphene coating on silicon anodes.

25 ENERGY STORAGE↗
NASA NTRS2024

Airfoil Table Modification for Improved Calculation of Ingenuity Rotor Performance

To better characterize the behavior of the Ingenuity helicopter, multiple test campaigns were conducted. These tests included the Engineering Design Model 1 (EDM1) tests and the Transonic Rotor Test (TRT), both of which assessed Ingenuity rotor performance at various conditions. Using a comprehensive rotorcraft analysis tool, CAMRAD II, test setups of the two different Ingenuity test campaigns were simulated. The EDM1 test used coaxial test stand which focused on varying collective at various feasible Martian atmospheric densities and the TRT test used a single rotor test stand which focused on varying RPM to assess performance at different blade tip Mach numbers. Initial CAMRAD II analyses yielded performance results which differed significantly from experimental results. To reconcile the experimental results and the CAMRAD II analyses, modifications were made to the input airfoil decks for CAMRAD II. After several iterations of modifications, a specific method of modification was found that more accurately predicted experimental behavior at all tested densities for the coaxial rotor. This same modification was less successful for the single rotor test results. There are a number of differences between coaxial and single rotor aerodynamics and between the two test stands (hub and control system); also, there is a small influence of RPM (mainly tip Mach number) on dimensionless performance. These differences may be causing the coaxial rotor modifications not being successful for the single rotor.

Airfoil↗
DOE OSTI2025

Molecular Modifications of Crystalline Poly(triazine imide) for Advancing Its Structure–Property Relationships in Light-Driven Catalysis

Carbon-nitride materials represent light-absorbing structures composed of earth-abundant elements capable of being leveraged for semiconductor photocatalysis at their surfaces. This study systematically investigates the addition of molecular modifiers to the synthesis of crystalline carbon nitrides to assess their effects on the materials’ structure, optical bandgap, and photocatalytic activity for hydrogen (H 2 ) and oxygen (O 2 ) evolution under ultraviolet and visible-light irradiation. Melamine and five pyrimidine-centered analogs were employed as building blocks to modify various heteroatoms within the polymeric framework. The modified materials were characterized with attention to the differences introduced by the monomeric modifiers and their influence on the resulting structures and compositions. The findings indicate that these changes significantly broaden the visible-light absorption range, albeit with the gradual loss of the bulk crystalline structure. As the loading of modifiers increased beyond 50%, a predominantly amorphous form of carbon nitride emerged. XPS, 13 C solid-state NMR, and SEM analyses corroborated the changes, which were attributed to modifications of the elemental composition and a reduced amount of Li cations and charge-balancing Cl anions owing to fewer binding sites in the intralayer cavities. In photocatalytic measurements under an ultraviolet 390 nm LED, and aided by photodeposited nanoparticle cocatalysts, the unmodified PTI-LiCl framework demonstrated the highest H 2 evolution rate (HER; 3.44 mmol·g –1 ·h –1 ) with an apparent quantum yield of 5.4%, along with total water splitting at rates of 163 μmol of H 2 ·g –1 ·h –1 and 75.6 μmol·O 2 g –1 ·h –1 . While PTI-LiCl showed trace activity under a visible-light 440 nm LED, all modified materials exhibited enhanced reactivity with as low as 5% molecular modifiers. The photocatalytic rates peaked at a 15% modification level when using 2,4,6-triaminopyrimidine, with rates of 33 μmol·g –1 ·h –1 for HER, along with 19.7 μmol of H 2 ·g –1 ·h –1 and 8.7 μmol of O 2 ·g –1 ·h –1 for total water splitting. Density functional theory calculations were used to probe electronic structure changes resulting from the modifications. Furthermore, these results elucidate the structural, optical, and electronic changes arising from the five selected molecular modifiers and their impact on the semiconductors’ photocatalytic properties.

Electrical conductivity↗
DOE OSTI2025

Transforming Boron Carbon Nitride: A Carbon-to-Oxygen Switch to Boost Propane Oxidative Dehydrogenation

Hexagonal boron nitride (h-BN) catalysts exhibit high alkene selectivity in the oxidative dehydrogenation of propane (ODHP). Nevertheless, the conversion-selectivity trade-off persisted primarily due to the low density of oxygen-containing boron active species, while simple and controllable modification strategies for h-BN still face challenges. Herein, we developed an in situ carbon-to-oxygen switch strategy within a tailored boron carbon nitride (BCN) framework, in which uniformly embedded B–C 3 were transformed into B–O 3 via oxidative treatment (denoted as BNO x ). The structural evolution from B–C 3 to B–O 3 was well characterized by spectroscopy and soft X-ray absorption techniques. The resulting BNO x catalysts, enriched with B–O 3 units, demonstrated performance in ODHP, achieving a propane conversion of 50.4% with 32.7% olefin yield at 500 °C. Density functional theory (DFT) calculations confirmed that B–O 3 species preferentially lower activation barriers, rendering the process thermodynamically more favorable. In conclusion, this work introduced an in situ reconstruction method for atomic-level heteroatom-engineered h-BN catalysts, opening an avenue for advanced catalyst design across energy conversion systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1984

Edge Stabilized Ribbon (ESR); Stress, Dislocation Density and Electronic Performance

The edge stabilized ribbon (ESR) silicon ribbon was grown in widths of 1, 2.2 and 4.0 inches at speeds ranging from .6 to 7 in/min, which result in ribbon thicknesses of 5 to 400 microns. One of the primary problems remaining in ESR growth is that of thermally induced mechanical stresses. This problem is manifested as ribbon with a high degree of residual stress or as ribbon with buckled ribbon. Thermal stresses result in a high dislocation density in the grown material, resulting in compromised electronic performance. Improvements in ribbon flatness were accomplished by modification of the ribbon cooling profile. Ribbon flatness and other experimental observations of ESR ribbon are discussed. Laser scanner measurements show a good correlation between diffusion length and dislocation density which indicates that the high dislocation densities are the primary cause of the poor current performance of ESR materials. Dislocation densities were reduced and improved electronic performance resulted. Laser scanner data on new and old material are presented.

Sachs, E. M.↗