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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8

Extracting electrode space charge limited current: Charge injection into conjugated polyelectrolytes with a semiconductor electrode

Conjugated polyelectrolytes and related mixed ionic-electronic conductors (MIECs) are being explored for energy applications including solid-state lighting and photovoltaics. Fundamental models of charge injection into MIECs have been primarily developed for MIECs contacted with highly conductive or metal electrodes (MEs), despite many potential applications involving semiconductors. We theoretically and experimentally demonstrate that an appropriate semiconductor electrode (SE), n-type for electron or p-type of hole injection, can limit injection into MIECs. When the SE is the injecting electrode and is under accumulation, there is little difference from a ME. When the SE acts as the extracting electrode, however, injection into the MIEC can be limited because a fraction of any applied bias must support charge depletion in the semiconductor rather than charge injection into the MIEC. In a ME/MIEC/SE system, this can lead to significant asymmetry in current-voltage and injected charge-voltage behavior.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Effects of Channel Implant Variation on Radiation-Induced Edge Leakage Currents in n-Channel MOSFETs

The effects of radiation-induced defects and statistical variation in the dose and energy of MOSFET channel implants in a modern bulk CMOS technology are modeled using a process simulator in combination with analytical computations. The model integrates doping profiles obtained from process simulations and experimentally determined defect potentials into implicit surface potential equations. Solutions to these equations are then used to model radiation-induced edge leakage currents in 90-nm bulk CMOS n-channel MOSFETs. The results indicate that slight variations in the channel implant parameters can have a significant impact on the doping profile along the shallow trench isolation sidewall and thus the radiation-induced edge leakage currents.

42 ENGINEERING↗

Current–voltage characteristics of Schottky diodes at high current densities under the injection of minority carriers

An analytical expression is derived for the current–voltage characteristic of a Schottky diode at a high injection level of minority carriers. It is shown that, even at very high current densities, the higher the base doping level, the larger the voltage drop across the diode. The physical mechanism responsible for this “paradoxical” result is analyzed. The validity of the analytical result is confirmed by a numerical calculation with software that takes into account the whole set of nonlinear effects caused by a high injection level in the base layer and by heavy doping of the emitter region.

36 MATERIALS SCIENCE↗

Probing neutrino mass hierarchy by comparing the charged-current and neutral-current interaction rates of supernova neutrinos

The neutrino mass hierarchy is one of the neutrino fundamental properties yet to be determined. We introduce a method to determine neutrino mass hierarchy by comparing the interaction rate of neutral current (NC) interactions, ν(ν-bar)+p→ν(ν-bar)+p, and inverse beta decays (IBD), ν-bar{sub e}+p→n+e{sup +}, of supernova neutrinos in scintillation detectors. Neutrino flavor conversions inside the supernova are sensitive to neutrino mass hierarchy. Due to Mikheyev-Smirnov-Wolfenstein effects, the full swapping of ν-bar{sub e} flux with the ν-bar{sub x} (x=μ, τ) one occurs in the inverted hierarchy, while such a swapping does not occur in the normal hierarchy. As a result, more high energy IBD events occur in the detector for the inverted hierarchy than the high energy IBD events in the normal hierarchy. By comparing IBD interaction rate with the mass hierarchy independent NC interaction rate, one can determine the neutrino mass hierarchy.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Electroweak Currents from Chiral Effective Field Theory

Since the pioneering work of Weinberg, Chiral Effective Field Theory (EFT) has been widely and successfully utilized in nuclear physics to study many-nucleon interactions and associated electroweak currents. Here, nuclear EFT has now developed into an intense field of research and is applied to study light to medium mass nuclei. In this contribution, we focus on the development of electroweak currents from EFT and present applications to selected nuclear electroweak observables.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Current advances in synchrotron radiation instrumentation for MX experiments

Following pioneering work 40 years ago, synchrotron beamlines dedicated to macromolecular crystallography (MX) have improved in almost every aspect as instrumentation has evolved. Beam sizes and crystal dimensions are now on the single micron scale while data can be collected from proteins with molecular weights over 10 MDa and from crystals with unit cell dimensions over 1000 Å. Furthermore it is possible to collect a complete data set in seconds, and obtain the resulting structure in minutes. The impact of MX synchrotron beamlines and their evolution is reflected in their scientific output, and MX is now the method of choice for a variety of aims from ligand binding to structure determination of membrane proteins, viruses and ribosomes, resulting in a much deeper understanding of the machinery of life. A main driving force of beamline evolution have been advances in almost every aspect of the instrumentation comprising a synchrotron beamline. In this review we aim to provide an overview of the current status of instrumentation at modern MX experiments. The most critical optical components are discussed, as are aspects of endstation design, sample delivery, visualisation and positioning, the sample environment, beam shaping, detectors and data acquisition and processing.

59 BASIC BIOLOGICAL SCIENCES↗

Minimizing Current and Voltage Losses to Reach 25% Efficient Monolithic Two-Terminal Perovskite–Silicon Tandem Solar Cells

The rapid rise in efficiency and tunable bandgap of metal-halide perovskites makes them highly attractive for use in tandems on silicon. Recently we demonstrated a perovskite–silicon monolithic two-terminal tandem with 23.6% power conversion efficiency. Here, we present work on optical optimization to improve light harvesting that includes thinning out the top transparent electrode to reduce front-surface reflection and parasitic absorption; introducing metal fingers to minimize series resistance losses; and further minimizing reflection loss with a polydimethylsiloxane (PDMS) stamp with random, pyramidal texture. Additionally, to reduce voltage loss while achieving current matching, we employ poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] (PTAA) as a hole transport material instead of NiO x and a wider 1.68 eV bandgap perovskite composition. Furthermore, these optimizations boost the open-circuit voltage to 1.77 V and the short-circuit current density to 18.4 mA/cm 2 , culminating in a 25% efficient perovskite–silicon tandem with a 1 cm 2 active area.

14 SOLAR ENERGY↗

Carbon Outgassing in the Antarctic Circumpolar Current Is Supported by Ekman Transport From the Sea Ice Zone in an Observation‐Based Seasonal Mixed‐Layer Budget

Despite its importance for the global cycling of carbon, there are still large gaps in our understanding of the processes driving annual and seasonal carbon fluxes in the high-latitude Southern Ocean. This is due in part to a historical paucity of observations in this remote, turbulent, and seasonally ice-covered region. Here, we use autonomous biogeochemical float data spanning 6 full seasonal cycles and with circumpolar coverage of the Southern Ocean, complemented by atmospheric reanalysis, to construct a monthly climatology of the mixed layer budget of dissolved inorganic carbon (DIC). We investigate the processes that determine the annual mean and seasonal cycle of DIC fluxes in two different zones of the Southern Ocean—the Sea Ice Zone (SIZ) and Antarctic Southern Zone (ASZ). We find that, annually, mixing with carbon-rich waters at the base of the mixed layer supplies DIC which is, in the ASZ, either used for net biological production or outgassed to the atmosphere. In contrast, in the SIZ, where carbon outgassing and the biological pump are weaker, the surplus of DIC is instead advected northward to the ASZ. In other words, carbon outgassing in the southern Antarctic Circumpolar Current (ACC), which has been attributed to remineralized carbon from deep water upwelled in the ACC, is also due to the wind-driven transport of DIC from the SIZ. These results stem from the first observation-based carbon budget of the circumpolar Southern Ocean and thus provide a useful benchmark to evaluate climate models, which have significant biases in this region.

Sauvé, Jade↗

Thermal generation of spin current in epitaxial CoFe 2 O 4 thin films

The longitudinal spin Seebeck effect (LSSE) has been investigated in high-quality epitaxial CoFe 2 O 4 (CFO) thin films. The thermally excited spin currents in the CFO films are electrically detected in adjacent Pt layers due to the inverse spin Hall effect (ISHE). The LSSE signal exhibits a linear increase with increasing temperature gradient, yielding a LSSE coefficient of –100 nV/K at room temperature. The temperature dependence of the LSSE is investigated from room temperature down to 30 K, showing a significant reduction at low temperatures, revealing that the total amount of thermally generated magnons decreases. Moreover, we demonstrate that the spin Seebeck effect is an effective tool to study the magnetic anisotropy induced by epitaxial strain, especially in ultrathin films with low magnetic moments.

36 MATERIALS SCIENCE↗

A two-fluid study of oblique tearing modes in a force-free current sheet

Kinetic simulations have demonstrated that three-dimensional reconnection in collisionless regimes proceeds through the formation and interaction of magnetic flux ropes, which are generated due to the growth of tearing instabilities at multiple resonance surfaces. Since kinetic simulations are intrinsically expensive, it is desirable to explore the feasibility of reduced two-fluid models to capture this complex evolution, particularly, in the strong guide field regime, where two-fluid models are better justified. With this goal in mind, this paper compares the evolution of the collisionless tearing instability in a force-free current sheet with a two-fluid model and fully kinetic simulations. Our results indicate that the most unstable modes are oblique for guide fields larger than the reconnecting field, in agreement with the kinetic results. The standard two-fluid tearing theory is extended to address the tearing instability at oblique angles. The resulting theory yields a flat oblique spectrum and underestimates the growth of oblique modes in a similar manner to kinetic theory relative to kinetic simulations.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

A hybrid Rayleigh-Taylor-current-driven coupled instability in a magnetohydrodynamically collimated cylindrical plasma with lateral gravity

We present an MHD theory of Rayleigh-Taylor instability on the surface of a magnetically confined cylindrical plasma flux rope in a lateral external gravity field. The Rayleigh-Taylor instability is found to couple to the classic current-driven instability, resulting in a new type of hybrid instability that cannot be described by either of the two instabilities alone. The lateral gravity breaks the axisymmetry of the system and couples all azimuthal modes together. The coupled instability, produced by combination of helical magnetic field, curvature of the cylindrical geometry, and lateral gravity, is fundamentally different from the classic magnetic Rayleigh-Taylor instability occurring at a two-dimensional planar interface. The theory successfully explains the lateral Rayleigh-Taylor instability observed in the Caltech plasma jet experiment [Moser and Bellan, Nature 482, 379 (2012)]. Potential applications of the theory include magnetic controlled fusion, solar emerging flux, solar prominences, coronal mass ejections, and other space and astrophysical plasma processes.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

A simple approximation for the current-voltage characteristics of high-power, relativistic diodes

A simple approximation for the current-voltage characteristics of a relativistic electron diode is presented. The approximation is accurate from non-relativistic through relativistic electron energies. Although it is empirically developed, it has many of the fundamental properties of the exact diode solutions. The approximation is simple enough to be remembered and worked on almost any pocket calculator, so it has proven to be quite useful on the laboratory floor.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Radial direct bandgap p-i-n GaNP microwire solar cells with enhanced short circuit current

We report the demonstration of dilute nitride heterostructure core/shell microwire solar cells utilizing the combination of top-down reactive-ion etching to create the cores (GaP) and molecular beam epitaxy to create the shells (GaNP). Systematic studies of cell performance over a series of microwire lengths, array periods, and microwire sidewall morphologies examined by transmission electron microscopy were conducted to shed light on performance-limiting factors and to optimize the cell efficiency. We show by microscopy and correlated external quantum efficiency characterization that the open circuit voltage is degraded primarily due to the presence of defects at the GaP/GaNP interface and in the GaNP shells, and is not limited by surface recombination. Compared to thin film solar cells in the same growth run, the microwire solar cells exhibit greater short circuit current but poorer open circuit voltage due to greater light absorption and number of defects in the microwire structure, respectively. The comprehensive understanding presented in this work suggests that performance benefits of dilute nitride microwire solar cells can be achieved by further tuning of the epitaxial quality of the underlying materials.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Surface-enhanced spin current to charge current conversion efficiency in CH3NH3PbBr3-based devices

Hybrid organic-inorganic perovskites have shown great promise for spintronic applications due to their large spin-orbit coupling induced by the Pb and halogen atoms. Particularly, the large observed surface-induced Rashba splitting in CH3NH3PbBr3 indicates efficient spin-current-to-charge-current (StC) conversion, which, however, has not been demonstrated yet. In this work, the StC conversion efficiency in ferromagnet/CH3NH3PbBr3-based devices is studied using the pulsed spin-pumping technique measured by the inverse spin Hall effect. We found that the StC conversion efficiency is anomalous in that it increases at small perovskite layer thickness. This indicates the existence of a surface-dominated StC mechanism such as the inverse Rashba-Edelstein effect. By inserting a thin LiF layer between the ferromagnet and the perovskite film, the StC conversion efficiency is greatly suppressed, validating the existence of a Rashba surface in the CH3NH3PbBr3 film.

Sun, Dali (ORCID:0000000346623265)↗

Coil current and vacuum magnetic flux calculation for axisymmetric equilibria

In fixed-boundary axisymmetric equilibrium calculations the plasma shape is assigned from input. In several circumstances, the plasma shape may not be known a priori, or one may desire to also compute the magnetic field in the volume surrounding the plasma through the calculation of a free-boundary equilibrium. This requires either the coil currents or the magnetic poloidal flux on a curve in the vacuum region to be assigned as input for the free-boundary equilibrium calculation. The FREE-FIX code presented in this article is a general tool for calculating coil currents being given a fixed-boundary calculation. Finally, a new formulation is presented, which considerably reduces the computational cost of the calculation. FREE-FIX performs well for different geometries and experiments.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗