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NASA NTRS1972

The abundances of the elements.

For the immediate cosmic environs, there are three traditional sources of element abundance data, including chondritic meteorites, the solar atmosphere, and a certain type of average of stars near the sun. Cosmic ray material, or at least the particles that were accelerated to very high energies, includes contributions from great distances in the Galaxy, and perhaps from outside the Milky Way system itself. Problems in the determination of solar system abundances are discussed together with some factors affecting the profiles of spectral lines, the abundances of some elements in the solar atmosphere, young stars and the interstellar medium, the helium to hydrogen ratio, the helium isotopes, and abundances of light elements in the Galaxy and in neighboring galaxies.

Aller, L. H.↗
NASA NTRS1974

Elemental abundances in meteoritic and terrestrial matter

Major and trace element analyses of over 180 individual chondrules from 12 carbonaceous chondrites are reported, including individual analyses of 60 chondrules from Pueblito de Allende. Siderophile elements in most chondrules are depleted, compared to the whole chondrite. Correlations of Al-Ir and Ir-Sc among chondrules high in Ca and Al were observed. A Cu-Mn correlation was also found for chondrules from some meteorites. No correlation was observed between Au and other siderophile elements (Fe, Ni, Co and Ir). It is suggested that these elemental associations were present in the material from which the chondrules formed. Compositionally, chondrules appear to be a multicomponent mixture of remelted dust. One component displaying an Al-Ir correlation is identified as Allende-type white aggregates. The other components are a material chemically similar to the present matrix and sulfides-plus-metal material. Abundances of the REE (rare earth elements) were measured in ordinary Allende chondrules and were 50% higher than REE abundances in Mokoia chondrules; REE abundances in Ca-Al rich chondrules were similar to REE abundances in Ca-rich white aggregates.

Schmitt, R. A.↗
NASA NTRS1974

The solar abundance of germanium

Spectral scans of the wavelength regions around 3039 A and 3269 A were used as a basis for the determination of the solar abundance of germanium. A solar model similar to the one given by Elste (1968) was used in the analysis of the data. The germanium abundance values obtained are presented in a table. Taking into account an abundance compilation for the solar system conducted by Cameron (1973), it is concluded that the 'solar system' and solar atmospheric abundances of germanium are in accord.

Ross, J. E.↗
NASA NTRS1975

Abundance of Fe relative to H at 1.5 solar radii

The abundance of Fe relative to H is obtained by using resonantly scattered intensities of lambda 284 of Fe XV that were measured with OSO-7 and resonantly scattered intensities of L-alpha of H I that were obtained by Gabriel (1971). Because of possible differences in electron densities along lines of sight for these non-simultaneous measurements and in relative calibrations, results are rather uncertain but still indicate that the average Fe abundance relative to H in the corona appears to be at least as large as a recent photospheric abundance. Some limitations in using this method for obtaining abundances are examined for future experiments with simultaneous measurements and well calibrated detectors.

Nakada, M. P.↗
NASA NTRS1976

The relative abundance of neon and magnesium in the solar corona

A technique is proposed for specifically determining the relative solar coronal abundance of neon and magnesium. The relative abundance is calculated directly from the relative intensity of the resonance lines of Ne X (12.134A) and Mg XI (9.169A) without the need for the development of a detailed model of the thermal structure of the corona. Moderate resolution Bragg crystal spectrometer results from the OVI-10 satellite were used to determine a coronal neon to magnesium relative abundance of 1.47 + or - 0.38. The application of this technique to a recent higher resolution rocket observation gave an abundance ratio of approximately 0.93 + or - 0.15.

Rugge, H. R.↗
NASA NTRS1975

Determination of the light ion abundances in the strong-helium star HR 3089

Using line blanketed model stellar atmospheres and a spectrum synthesis approach, a differential abundance study of the ultraviolet spectrum of HR 3089 relative to the normal star lambda Sco was performed. Both stars were found to have the same abundances of carbon and silicon, but the helium and nitrogen are significantly enhanced in HR 3089. The atmospheric parameters and the distribution of abundances found for HR 3089 agree well with the results of Osmer and Peterson on sharp-lined helium-rich stars. The rotational velocity of 160 km/sec found for HR 3089 places a constraint on the role of diffusion in producing the abundance anomalies. Examination of the resonance lines of C II, N II, Si III and Si IV shows no evidence for mass loss in either star.

Lester, J. B.↗
NASA NTRS1977

An investigation of techniques for the measurement and interpretation of cosmic ray isotopic abundances

An instrument, the Caltech High Energy Isotope Spectrometer Telescope was developed to measure isotopic abundances of cosmic ray nuclei by employing an energy loss - residual energy technique. A detailed analysis was made of the mass resolution capabilities of this instrument. A formalism, based on the leaky box model of cosmic ray propagation, was developed for obtaining isotopic abundance ratios at the cosmic ray sources from abundances measured in local interstellar space for elements having three or more stable isotopes, one of which is believed to be absent at the cosmic ray sources. It was shown that the dominant sources of uncertainty in the derived source ratios are uncorrelated errors in the fragmentation cross sections and statistical uncertainties in measuring local interstellar abundances. These results were applied to estimate the extent to which uncertainties must be reduced in order to distinguish between cosmic ray production in a solar-like environment and in various environments with greater neutron enrichments.

Wiedenbeck, M. E.↗
NASA NTRS1978

Abundances and spectra for cosmic-ray nuclei from lithium to iron for 2 to 150 GeV per nucleon

Measurements of primary cosmic-ray composition and energy spectra made with a balloon-borne superconducting magnetic spectrometer are described. Results for both 6.7 g/sq cm equivalent vertical atmospheric depth and the top of the atmosphere are presented for the absolute and relative integral abundances, the differential energy spectra, and the spectral indices for cosmic-ray nuclei from Li to Fe and energies of 2 to 50 GeV/n. It is found that propagation effects can explain essentially all the elemental abundances, that the abundances of Li, Be, and B for rigidities below 10 GV/c are consistent with an energy-independent mean interstellar path length of 4.5 + or - 0.5 g/sq cm for the 'leaky box' propagation model, that the abundances of all elements above 10 GV/c are consistent with a path length that decreases as the inverse n-th power of rigidity, and that n equals 0.6 (+0.4, -0.3) for the simplest assumptions made in fitting the source spectra.

Orth, C. D.↗
NASA NTRS1979

Cosmic-ray abundances of individual elements in the Z interval between 26 and 30

The relative abundances of Fe, Co, Ni, Cu, and Zn in the cosmic rays have been measured using a large-area balloon-borne electronic detector system. The abundance ratios Ni/Fe and Zn/Fe are 5.0 + or - 0.2% and 0.06 + or - 0.01%, respectively. The Zn abundance is low (40%) compared with the Cameron (1973) (C1) solar system, and is best consistent with the solar system C2 meteorite abundances. The ratios Co/Fe and Cu/Fe, extrapolated to the top of the atmosphere, are 0.68 + or - 0.14% and 0.066 + or - 0.030% respectively; since charge peaks are not resolved at Co and Cu, these results are taken as upper limits of 0.8% and 0.1%, respectively. The Co upper limit is consistent with complete decay of Co-57 at the source and implies a lower limit of 2 years for the time between nucleosynthesis and acceleration of these nuclei.

Tueller, J.↗
NASA NTRS1979

The isotopic and elemental abundances of neon nuclei accelerated in solar flares

The relative isotopic abundances of Ne-20 and Ne-22 in seven solar flares were determined from measurements of the satellite IMP 8, yielding the ratio Ne-20/Ne-22 = 7.7 (+2.3, -1.5) for solar chromospheric matter. This value is in agreement with the ratio for the component neon-A (the 'primordial' component) found in carbonaceous chondrites. An elemental abundance ratio Ne/O = 0.14 + or - 0.01 also has been obtained which agrees closely with earlier reported measurements. It is shown that the effects of preferential acceleration relative to solar-system abundances with increasing charge number observed for some solar flares - though biasing the elemental ratio - does not appear to influence the neon isotopic abundances.

Dietrich, W. F.↗
NASA NTRS1979

Chemical abundances in Hg-Mn stars

An abundance analysis has been conducted of 21 elements in 21 Hg-Mn, two Si-Cr, and six normal stars using model atmospheres and high-dispersion spectroscopy in the visible and UV. Manganese line strengths imply abundances that correlate well with stellar effective temperature. Within the studied sample of Hg-Mn stars there appears to be no correlation of abundances of any element with projected rotational velocity. Abundances in several Hg-Mn stars show patterns that are probably consistent with diffusion but difficult to reconcile with equilibrium nucleosynthesis. In general, no combination of gross stellar physical parameters is sufficient to characterize the patterns of line strengths observed in Hg-Mb Hg-Mn stars.

Heacox, W. D.↗
NASA NTRS1981

The abundance and excitation of the carbon chains in interstellar molecular clouds

Emission lines from the carbon chains HC3N, HC5N, HC7N and HC9N were observed at 3 mm, 7 mm, and 1.4 cm in a number of dark clouds, Orion A and IRC(plus)10216. Non-LTE models were constructed to describe excitation and column densities. Component models for the Taurus dark cloud TMC-1 suggested that relative molecular abundances do not vary substantially along the cloud ridge, whereas the H2 density does by a factor of three. Data available for other dark clouds showed that the decrease in abundance with length from one carbon chain to the next is nearly constant, being close to 2.3. The decline in carbon chain abundance with length is steeper in Orion KL than in dark clouds by a factor of approximately four. Abundance ratios derived for the carbon star IRC(plus)10216 are uncertain, due to difficulties in modeling excitation rates in this environment.

Bujarrabal, V.↗
NASA NTRS1981

Chemical abundances in comets

Photoelectric filter photometry and spectrophotometry undertaken to establish homogeneous, quantitative data on chemical abundances in comets is discussed. Absolute column densities of a particular species were derived from a comparison of the absolute flux of an emission feature due to the species with a fluorescence calculation, and converted into species production rates by the use of a Haser model and the species lifetime. Observations of C2 and CN reveal a constant production rate ratio at heliocentric distances up to 1.5-2.0 AU, which implies a compositional homogeneity with depth and the formation of most comets from a homogeneous volume in the solar nebula. Observations of the trace species C3 indicate no apparent variation in relative abundances, while observations of low levels of NH2 and CH imply that NH3 and CH4 are not abundant species. H2O is considered to be the most abundant species based on detections of O, H and OH, while variations in CO or CO2 content may account for the very large differences in cometary gas-to-dust ratios and morphologies.

Ahearn, M. F.↗
NASA NTRS1982

The carbon abundance in the Magellanic Clouds from IUE observations of H II regions

Results are given of observations of the UV spectra of several H II regions in the Magellanic Clouds, with emphasis on obtaining the carbon abundance from the UV lines of C II, C III, and C IV. The observations and results are described, and theoretical model calculations are presented of the H II regions and the relative abundances of H, He, C, N, O, S, Cl, and Ar computed from the UV and visual spectra. In addition, the abundance results for the Magellanic Clouds are compared with the sun, the Orion Nebula, and galactic planetary nebulae. In comparison with solar abundances, carbon is found to be depleted relative to hydrogen in the Magellanic Clouds by an amount larger than that of nitrogen and oxygen in the SMC and by an amount between that of nitrogen and oxygen in the LMC. It is noted that the results are consistent with a scenario that nitrogen and oxygen have greater primary yields in massive stars than carbon, which may be produced predominantly in less massive stars (such that C/N and C/O in galaxies are initially very low and subsequently increase with evolution). Subsequently, the C/N ratio may decrease as secondary production of nitrogen in less massive stars becomes significant.

Dufour, R. J.↗
NASA NTRS1982

OB associations and the nonuniversality of the cosmic abundances - Implications for cosmic rays and meteorites

The formation of the solar system inside an OB association is examined with particular attention to the elemental abundances which would have been ejected by the association's first few supernovae. It is found that the solar system material may have been significantly contaminated by these supernovae and thus the average interstellar composition may differ from the solar system composition. In particular, we find that many of the so-called isotopic and elemental abundance anomalies (e.g., Ne, C, O, s-process/r-process, etc.) found in meteoritic inclusions and in cosmic rays may be more representative of the average interstellar abundance. In other words, it may be that the average solar system abundances are what is 'anomalous'.

Olive, K. A.↗
NASA NTRS1982

A survey of interstellar neutral potassium. I - Abundances and physical conditions in clouds toward 188 early-type stars

Observations of interstellar absorption in the resonance doublet 7664, 7698 A of neutral potassium toward 188 early-type stars at a spectral resolution of 8 km/s are reported. The 7664 A line is successfully separated from nearly coincident telluric O2 absorption for all but a few of the 165 stars for which K I absorption is detected, making possible an abundance analysis by the doublet ratio method. The relationships between the potassium abundances and other atomic abundances, the abundance of molecular hydrogen, and interstellar reddening are investigated.

Chaffee, F. H., Jr.↗
NASA NTRS1983

The effect of cross-section uncertainties on the derivation of source abundances from cosmic-ray composition observations

It is pointed out that the derivation of source abundances from the composition observed near the earth requires that the secondary contribution to the observed nuclidic abundances be calculated from a model of cosmic-ray propagation. A crucial element in such a calculation is the choice of nuclear fragmentation cross sections. Uncertainties in these cross sections give rise to uncertainties in the derived source abundances. It is shown here that the uncertainties in fragmentation cross sections can, in certain important cases, contribute significantly to the uncertainties in cosmic ray source abundances deduced from the observed composition. For this reason, it is essential that reliable estimates of the effect of cross section uncertainties be made when interpreting the source composition deduced from cosmic ray observations. In addition, formulas are presented which can be used to obtain such estimates with a minimum of computational effort.

Wiedenbeck, M. E.↗
NASA NTRS1984

Abundances in galactic H2 regions, 3: G25.4-0.2, G45.5+0.06, M8, S159 and DR22

Measurements of the ARII (6.99 microns), ArIII (8.99 microns), NeII (12.81 microns), SIII (18.71 microns), and SIV (10.51 microns) lines are presented for five compact HII regions along with continuum spectroscopy. From these data and radio data, lower limits to the elemental abundances of Ar, S, and Ne were deduced. The complex G25.4-0.2 is only 5.5 kpc from the galactic center, and is considerably overabundant in all these elements. Complex G45.5+0.06 is at seven kpc from the galactic center, and appears to be approximately consistent with solar abundance. The complex S159 in the Perseus Arm, at 12 kpc from the galactic center, has solar abundance, while M8 in the solar neighborhood may be somewhat overabundant in Ar and Ne. Complex DR 22, at 10 kpc from the galactic center in the Cygnus Arm, is overabundant in Ar. A summary of results from a series of papers on abundances is given.

Pipher, J. L.↗