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All sourcesNASA NTRSDOE OSTI
NASA NTRS2015

Rover Traverse Planning to Support a Lunar Polar Volatiles Mission

Studies of lunar polar volatile depositsare of interest for scientific purposes to understandthe nature and evolution of the volatiles, and alsofor exploration reasons as a possible in situ resource toenable long term exploration and settlement of theMoon. Both theoretical and observational studies havesuggested that significant quantities of volatiles exist inthe polar regions, although the lateral and horizontaldistribution remains unknown at the km scale and finerresolution. A lunar polar rover mission is required tofurther characterize the distribution, quantity, andcharacter of lunar polar volatile deposits at thesehigher spatial resolutions. Here we present two casestudies for NASA’s Resource Prospector (RP) missionconcept for a lunar polar rover and utilize this missionarchitecture and associated constraints to evaluatewhether a suitable landing site exists to support an RPflight mission.

NASAaEuro(TM)s Resource Prospector (RP) mission↗
NASA NTRS2015

Neutron Spectrometer Prospecting in the Mojave Volatiles Project Analog Field Test

We know that volatiles are sequestered at the poles of the Moon. While we have evidence of water ice and a number of other compounds based on remote sensing, the detailed distribution, and physical and chemical form are largely unknown. Additional orbital studies of lunar polar volatiles may yield further insights, but the most important next step is to use landed assets to fully characterize the volatile composition and distribution at scales of tens to hundreds of meters. To achieve this range of scales, mobility is needed. Because of the proximity of the Moon, near real-time operation of the surface assets is possible, with an associated reduction in risk and cost. This concept of operations is very different from that of rovers on Mars, and new operational approaches are required to carry out such real-time robotic exploration. The Mojave Volatiles Project (MVP) was a Moon-Mars Analog Mission Activities (MMAMA) program project aimed at (1) determining effective approaches to operating a real-time but short-duration lunar surface robotic mission, and (2) performing prospecting science in a natural setting, as a test of these approaches. Here we describe some results from the first such test, carried out in the Mojave Desert between 16 and 24 October, 2014. The test site was an alluvial fan just E of the Soda Mountains, SW of Baker, California. This site contains desert pavements, ranging from the late Pleistocene to early-Holocene in age. These pavements are undergoing dissection by the ongoing development of washes. A principal objective was to determine the hydration state of different types of desert pavement and bare ground features. The mobility element of the test was provided by the KREX-2 rover, designed and operated by the Intelligent Robotics Group at NASA Ames Research Center. The rover-borne neutron spectrometer measured the neutron albedo at both thermal and epithermal energies. Assuming uniform geochemistry and material bulk density, hydrogen as either hydroxyl/water in mineral assemblages or as moisture will significantly enhance the return of thermalized neutrons. However, in the Mojave test setting there is little uniformity, especially in bulk material density. We find that lighter toned materials (immature pavements, bar and swale, and wash materials) have lower thermal neutron flux, while mature, darker pavements with the greatest desert varnish development have higher neutron fluxes. Preliminary analysis of samples from the various terrain types in the test area indicates a prevailing moisture content of 2-3 wt% H2O. However, soil mineralogy suggests that the welldeveloped Av1 soil horizon beneath the topmost dark pavement clast layer contains the highest clay content. Structural water (including hydroxyl) in these clays may explain the enhanced neutron albedo over dark pavements. On the other hand, surface and subsurface bulk density can also play a role in neutron albedo - lower density of materials found in washes, for example, can result in a reduction in neutron flux. Analysis is ongoing.

rover-borne neutron spectrometer↗
NASA NTRS2016

Resource Prospector: An Update on the Lunar Volatiles Prospecting and ISRU Demonstration Mission

Over the last two decades a wealth of new observations of the moon have demonstrated a lunar water system dramatically more complex and rich than was deduced following the Apollo era. Lunar water, and other volatiles, have the potential to be a valuable or enabling resource for future exploration. The NASA Human Exploration and Operations Mission Directorate (HEOMD) have selected a lunar volatiles prospecting mission for a concept study and potential flight in CY2021. The mission includes a rover-borne payload that (1) can locate surface and near-subsurface volatiles, (2) excavate and analyze samples of the volatile-bearing regolith, and (3) demonstrate the form, extractability and usefulness of the materials.

Human Exploration and Operations Mission Directora↗
NASA NTRS2017

Documenting Surface and Sub-surface Volatiles While Drilling in Frozen Lunar Simulant

NASA's Resource Prospector (RP) mission is intended to characterize the three-dimensional nature of volatiles in lunar polar regions and permanently shadowed regions. RP is slated to carry two instruments for prospecting purposes. These include the Neutron Spectrometer System (NSS) and Near-Infrared Volatile Spectrometer System (NIRVSS). A Honybee Robotics drill (HRD) is intended to sample to depths of 1 m, and deliver a sample to a crucible that is processed by the Oxygen Volatile Extraction Node (OVEN) where the soil is heated and evolved gas is delivered to the gas chromatograph / mass spectrometer of the Lunar Advanced Volatile Analysis system (LAVA). For several years, tests of various sub-systems have been undertaken in a large cryo-vacuum chamber facility (VF-13) located at Glenn Research Center. In these tests a large tube (1.2 m high x 25.4 cm diameter) is filled with lunar simulant, NU-LHT-3M, prepared with known abundances of water. There are thermo-couples embedded at different depths, and also across the surface of the soil tube. The soil tube is placed in the chamber and cooled with LN2 as the pressure is reduced to approx.5-6x10(exp -6) Torr. Here we discuss May 2016 tests where two soil tubes were prepared and placed in the chamber. Also located in the chamber were 5 crucibles, an Inficon mass spectrometer, and a trolly permitting x-y translation, where the HRD and NIRVSS, were mounted. The shroud surrounding the soil tube was held at different temperatures for each tube to simulate a warm and cold lunar environment.

Oxygen Volatile Extraction Node↗
NASA NTRS2017

Resource Prospector: An Update on the Lunar Volatiles Prospecting and ISRU Demonstration Mission

Over the last two decades a wealth of new observations of the moon have demonstrated a lunar water system dramatically more complex and rich than was deduced following the Apollo era. Lunar water, and other volatiles, have the potential to be a valuable or enabling resource for future exploration. The NASA Human Exploration and Operations Mission Directorate (HEOMD) have selected a lunar volatiles prospecting mission for a concept study and potential flight in CY2021. The mission includes a rover-borne payload that (1) can locate surface and near-subsurface volatiles, (2) excavate and analyze samples of the volatile- bearing regolith, and (3) demonstrate the form, extractability and usefulness of the materials.

Moon↗
NASA NTRS2015

Mojave Volatiles Prospector (MVP): Science and Operations Results from a Lunar Polar Rover Analog Field Campaign

The Mojave Volatiles Prospector (MVP) project is a science-driven field program with the goal of producing critical knowledge for conducting robotic exploration of the Moon. MVP feeds science, payload, and operational lessons learned to the development of a real-time, short-duration lunar polar volatiles prospecting mission. MVP achieved these goals through a simulated lunar rover mission to investigate the composition and distribution of surface and subsurface volatiles in a natural and a priori unknown environment within the Mojave Desert, improving our understanding of how to find, characterize, and access volatiles on the Moon.

xGDS real-time science tools↗
NASA NTRSDate not supplied

Initial Analysis of Volatile Components in the Hayabusa2 Samples

The major objectives of the Hayabusa2-initial-analysis volatile team are (1) to determine the pristine volatile components in the parental materials of the returned Ryugu samples, and (2) to elucidate the origin and chronological history of the asteroid Ryugu, as well as the evolution of the solar system through determination of volatile carrier phases and abundances of volatile components (e.g., presolar grain abundances). Our analytical data will be linked with remote sensing (NIRS3, ONCs, TIR, and LIDAR) data and theoretical modeling [e.g., 1-5]. For example, the erosion rate and the degree of gardening of the surface layer of the asteroid Ryugu can be estimated based on trapped solar wind (SW) and cosmic ray produced (cosmogenic) nuclides, which will be discussed in conjunction with the results based on the remote sensing data [3-5]. Taken together, these will provide characteristics of the surface materials, such as the degree and duration of the alteration by SW/cosmic ray irradiation and micrometeorite bombardments.

volatiles↗
NASA NTRS2024

Combining Multi-Faceted Laboratory Studies of 74001-2 and Regional Remote Sensing to Address How Pyroclastic Eruptions Record and Affect the Lunar Volatile Budget

Basaltic magmatism is an efficient process for bringing volatiles from a planetary interior to its surface, with the possibility of generation of a transient lunar atmosphere as abundant volcanic materials de-gassed. However, pyroclastic deposits are locations where trapped gases may be studied [e.g., 2,3]. Volatile-rich pyroclastic deposits occur over a wide surface area of the Moon, indicating that the transport of volatiles and associated pyroclastic materials from the Moon’s mantle to the surface was a wide-spread phenomenon. Numerous studies analyzing remotely sensed data and using empirical modeling have demonstrated that various stages of pyroclastic eruptions significantly influence gas release patterns, morphology, and mineralogy of the deposit. Many observations based on mare basalts and pyroclastic deposits have identified potential histories of gas release [e.g., 2-10] and their influence on volatiles and their stable isotopes [e.g., 11-13]. The best representation of these pyroclastic deposits in the sample collection is core sample 74001-74002 that was collected during the Apollo 17 mission to the Taurus-Littrow Valley (TLV). The double drive tube penetrated a part of a regional-scale pyroclastic deposit and sampled approximately 68.1 cm of that deposit in the TLV. Remnants of this and other pyroclastic depos-its are represented throughout and beyond the TLV [e.g., 14-16]. The stratigraphy of this core has been investigated and defined by numerous studies. The CASA Moon SSERVI research team is conducting a multi-faceted analytical study of this deposit. Data generated from revisiting the stratigraphy of 74001-74002 will be used to place stable isotopes (H, B, Cl, S, Zn, Cu, Rb, Ga, Pb), Ar-Ar and U-Pb chronology, geochemistry, nanometer-scale observations of mineral surfaces, orbital observations, and experiments and modeling within a stratigraphic, eruptive, and geologic context. It is important to place these data into such a context. For example, recent S isotope measurements reported by Dottin et al. show differences within this core that may be related to either changes in source or eruptive process over the course of the eruption (vs. multiple eruptions). A fuller understanding of the stratigraphy is fundamental to resolving this interpretation. This comprehensive approach can only be achieved within the context of a program such as SSERVI. In addition, imaging produced in this project will be incorporated into a citizen scientist program to further identify many of the textural features of this double drive tube.

SSERVI↗
DOE OSTI2022

Preservation of high-pressure volatiles in nanostructured diamond capsules

High pressure induces dramatic changes and novel phenomena in condensed volatiles(1,2) that are usually not preserved after recovery from pressure vessels. In this study we report a process that pressurizes volatiles into nanopores of type 1 glassy carbon precursors, converts glassy carbon into nanocrystalline diamond by heating and synthesizes free-standing nanostructured diamond capsules (NDCs) capable of permanently preserving volatiles at high pressures, even after release back to ambient conditions for various vacuum-based diagnostic probes including electron microscopy. As a demonstration, we perform a comprehensive study of a high-pressure argon sample preserved in NDCs. Synchrotron X-ray diffraction and high-resolution transmission electron microscopy show nanometre-sized argon crystals at around 22.0 gigapascals embedded in nanocrystalline diamond, energy-dispersive X-ray spectroscopy provides quantitative compositional analysis and electron energy-loss spectroscopy details the chemical bonding nature of high-pressure argon. The preserved pressure of the argon sample inside NDCs can be tuned by controlling NDC synthesis pressure. To test the general applicability of the NDC process, we show that high-pressure neon can also be trapped in NDCs and that type 2 glassy carbon can be used as the precursor container material. Additional experiments on other volatiles and carbon allotropes open the possibility of bringing high-pressure explorations on a par with mainstream condensed-matter investigations and applications.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Chalcogen isotopes reveal limited volatile contribution from late veneer to Earth

The origin of Earth’s volatile elements is highly debated. Comparing the chalcogen isotope ratios in the bulk silicate Earth (BSE) to those of its possible building blocks, chondritic meteorites, allows constraints on the origin of Earth’s volatiles; however, these comparisons are complicated by potential isotopic fractionation during protoplanetary differentiation, which largely remains poorly understood. Using first-principles calculations, we find that core-mantle differentiation does not notably fractionate selenium and tellurium isotopes, while equilibrium evaporation from early planetesimals would enrich selenium and tellurium in heavy isotopes in the BSE. The sulfur, selenium, and tellurium isotopic signatures of the BSE reveal that protoplanetary differentiation plays a key role in establishing most of Earth’s volatile elements, and a late veneer does not substantially contribute to the BSE’s volatile inventory.

58 GEOSCIENCES↗
DOE OSTI2023

Source characterization of volatile organic compounds at Carlsbad Caverns National Park

Carlsbad Caverns National Park (CAVE), located in southeastern New Mexico, experiences elevated ground-level ozone (O 3 ) exceeding the National Ambient Air Quality Standard (NAAQS) of 70 ppbv. It is situated adjacent to the Permian Basin, one of the largest oil and gas (O&G) producing regions in the US. In 2019, the Carlsbad Caverns Air Quality Study (CarCavAQS) was conducted to examine impacts of different sources on ozone precursors, including nitrogen oxides (NO x ) and volatile organic compounds (VOCs). Here, we use positive matrix factorization (PMF) analysis of speciated VOCs to characterize VOC sources at CAVE during the study. Seven factors were identified. Three factors composed largely of alkanes and aromatics with different lifetimes were attributed to O&G development and production activities. VOCs in these factors were typical of those emitted by O&G operations. Associated residence time analyses (RTA) indicated their contributions increased in the park during periods of transport from the Permian Basin. These O&G factors were the largest contributor to VOC reactivity with hydroxyl radicals (62%). Two PMF factors were rich in photochemically generated secondary VOCs; one factor contained species with shorter atmospheric lifetimes and one with species with longer lifetimes. RTA of the secondary factors suggested impacts of O&G emissions from regions farther upwind, such as Eagle Ford Shale and Barnett Shale formations. The last two factors were attributed to alkenes likely emitted from vehicles or other combustion sources in the Permian Basin and regional background VOCs, respectively. Implications: Carlsbad Caverns National Park experiences ground-level ozone exceeding the National Ambient Air Quality Standard. Volatile organic compounds are critical precursors to ozone formation. Measurements in the Park identify oil and gas production and development activities as the major contributors to volatile organic compounds. Emissions from the adjacent Permian Basin contributed to increases in primary species that enhanced local ozone formation. Observations of photochemically generated compounds indicate that ozone was also transported from shale formations and basins farther upwind. Therefore, emission reductions of volatile organic compounds from oil and gas activities are important for mitigating elevated O 3 in the region.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

In Vitro Antimicrobial Activity of Volatile Compounds from the Lichen Pseudevernia furfuracea (L.) Zopf. Against Multidrug-Resistant Bacteria and Fish Pathogens

Lichens are symbiotic organisms with unique secondary metabolism. Various metabolites from lichens have shown antimicrobial activity. Nevertheless, very few studies have investigated the antimicrobial potential of the volatile compounds they produce. This study investigates the chemical composition and antimicrobial properties of volatile compounds from Pseudevernia furfuracea collected in two regions of Morocco. Hydrodistillation was used to obtain volatile compounds from samples collected in the High Atlas and Middle Atlas. Gas chromatography–mass spectrometry (GC-MS) analysis identified phenolic cyclic compounds as the primary constituents, with atraric acid and chloroatranol being the most abundant. Additionally, eight compounds were detected in lichens for the first time. The antimicrobial activity of these compounds was assessed using disc diffusion and broth microdilution methods. Both samples demonstrated significant antimicrobial effects against multidrug-resistant human bacteria, reference microorganisms, fish pathogens, and Candida albicans, with minimum inhibitory concentrations (MICs) ranging from 1000 µg/mL to 31.25 µg/mL. This study provides the first report on the volatile compounds from Pseudevernia furfuracea and their antimicrobial effects, particularly against fish pathogens, suggesting their potential as novel antimicrobial agents for human and veterinary use. Further research is warranted to explore these findings in more detail.

Essadki, Yasser (ORCID:0009000648460075)↗
DOE OSTI2021

Mass accommodation and gas–particle partitioning in secondary organic aerosols: dependence on diffusivity, volatility, particle-phase reactions, and penetration depth

Abstract. Mass accommodation is an essential process for gas–particle partitioning of organic compounds in secondary organic aerosols (SOA). The mass accommodation coefficient is commonly described as the probability of a gas molecule colliding with the surface to enter the particle phase. It is often applied, however, without specifying if and how deep a molecule has to penetrate beneath the surface to be regarded as being incorporated into the condensed phase (adsorption vs. absorption). While this aspect is usually not critical for liquid particles with rapid surface–bulk exchange, it can be important for viscous semi-solid or glassy solid particles to distinguish and resolve the kinetics of accommodation at the surface, transfer across the gas–particle interface, and further transport into the particle bulk. For this purpose, we introduce a novel parameter: an effective mass accommodation coefficient αeff that depends on penetration depth and is a function of surface accommodation coefficient, volatility, bulk diffusivity, and particle-phase reaction rate coefficient. Application of αeff in the traditional Fuchs–Sutugin approximation of mass-transport kinetics at the gas–particle interface yields SOA partitioning results that are consistent with a detailed kinetic multilayer model (kinetic multilayer model of gas–particle interactions in aerosols and clouds, KM-GAP; Shiraiwa et al., 2012) and two-film model solutions (Model for Simulating Aerosol Interactions and Chemistry, MOSAIC; Zaveri et al., 2014) but deviate substantially from earlier modeling approaches not considering the influence of penetration depth and related parameters. For highly viscous or semi-solid particles, we show that the effective mass accommodation coefficient remains similar to the surface accommodation coefficient in the case of low-volatility compounds, whereas it can decrease by several orders of magnitude in the case of semi-volatile compounds. Such effects can explain apparent inconsistencies between earlier studies deriving mass accommodation coefficients from experimental data or from molecular dynamics simulations. Our findings challenge the approach of traditional SOA models using the Fuchs–Sutugin approximation of mass transfer kinetics with a fixed mass accommodation coefficient, regardless of particle phase state and penetration depth. The effective mass accommodation coefficient introduced in this study provides an efficient new way of accounting for the influence of volatility, diffusivity, and particle-phase reactions on SOA partitioning in process models as well as in regional and global air quality models. While kinetic limitations may not be critical for partitioning into liquid SOA particles in the planetary boundary layer (PBL), the effects are likely important for amorphous semi-solid or glassy SOA in the free and upper troposphere (FT–UT) as well as in the PBL at low relative humidity and low temperature.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1973

Mass spectrometric analysis of the volatiles released by heating or crushing rocks

Vacuum extraction with subsequent mass spectrometric analysis of evolved volatiles was selected as the analytical procedure. The high-vacuum gas-handling system was constructed of stainless steel. The system was completely free from mercury, grease, or volatile organic materials. The furnace for heating the samples is discussed together with the high-vacuum crusher, the mass spectrometer, and approaches for water determination. The analytical procedure is considered, giving attention to the extraction of volatiles, adsorption studies, and the analysis of volatiles.

Barker, C.↗
NASA NTRS1974

Release of volatile mercury from vascular plants

Volatile, organic solvent soluble mercury has been found in leaves and seeds of several angiosperms. Leaves of garlic vine, avocado, and haole-koa release mercury in volatile form rapidly at room temperature. In garlic vine, the most active release is temperature dependent, but does not parallel the vapor-pressure temperature relationship for mercury. Mercury can be trapped in nitric-perchloric acid digestion fluid, or n-hexane, but is lost from the hexane unless the acid mixture is present. Seeds of haole-koa also contain extractable mercury but volatility declines in the series n-hexane (90%), methanol (50%), water (10%). This suggests that reduced volatility may accompany solvolysis in the more polar media.

Siegel, S. M.↗
NASA NTRS1974

Volatile-element systematics and green glass in Apollo 15 lunar soils

A number of volatiles in Apollo 15 soils correlate with each other and with decreasing distance from the Apennine Front. These correlations can be understood in terms of a deposition of green glass and cogenetic volatiles on the flanks of the Front followed by addition of secondary magmatic volatiles including excess Ar-40. Mixing of these materials with mare-type regolith resulted in the observed volatile-element patterns. The absence of an increase in siderophilic element content with decreasing distance from the Front probably resulted from the failure of the steeply sloping front to develop a highlands-type mature regolith. Breccia 15015 has a siderophilic element signature typical of a mature Apollo 15 soil, which tends to rule out its transport to the site as part of an Autolycus or Aristillus ray.

Chou, C.-L.↗
NASA NTRS1980

The role of volatiles and lithology in the impact cratering process

A survey of published descriptions of 32 of the largest, least eroded terrestrial impact structures shows that the amount of melt at craters in crystalline rocks is approximately two orders of magnitude greater than that at craters in sedimentary rocks. A model is proposed for the impact process, and it is examined whether the difference in melt abundance is due to differences in the amount of melt generated in various target materials or due to differences in the fate of the melt during late stages of the impact. The model accounts semiquantitatively for the effects of porosity and water and volatile content on the cratering process. Important features of the model are noted. Even if the recondensation of released volatiles is very efficient, the cumulative effect of repeated impacts on accreting planets would be to continually transfer volatiles toward the outer surface. By this process, volatiles might be enriched toward the outer layer of a growing planet.

Kieffer, S. W.↗
NASA NTRS1982

Analysis of volatile metabolites in biological fluids as indicators of prodromal disease condition

The volatile profile cannot be defined as a single class of substances, rather it is a broad spectrum of materials of different polarities characterized by having a boiling-point in the low to medium range (up to approximately 300 C) and the fact that the compounds are suitable for gas chromatography without derivatization. The organic volatile profiles are very complex mixtures of metabolic byproducts, intermediates, and terminal products of enzymatic degradations composed mainly of alcohols, ketones, aldehydes, pyrazines, sulfides, isothiocyanates, pyrroles, and furans. The concentration of organic volatiles in biological fluids covers a wide range with many important components present at trace levels. The complexity of the organic volatile fraction requires the use of capillary columns for their separation.

Zlatkis, A.↗