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At least 145 records · Page 8

Thermal imaging spectroscopy in the Kelso-Baker Region, California

The ability of the Thermal Infrared Multispectral Scanner (TIMS) data to identify rock composition using thermal-infrared spectroscopy was assessed. A region was selected with a wide range of rock and soil types in an arid environment, and the spectra acquired by TIMS was compared to laboratory spectra of collected samples. A TIMS image was acquired of the Kelso-Baker region in the Mojave desert of California at a surface resolution of approximately 7 m. This image was then used to map the areal extent of each geologic component. The TIMS data provided an excellent means for discriminating and mapping rocks of very similar mineralogy. These findings suggest that thermal-infrared spectroscopy can provide a powerful tool for identifying and mapping rock composition on the Earth and other terrestrial planets.

Christensen, Philip R.↗

Calculation of day and night emittance values

In July 1983, the Thermal Infrared Multispectral Scanner (TIMS) was flown over Death Valley, California on both a midday and predawn flight within a two-day period. The availability of calibrated digital data permitted the calculation of day and night surface temperature and surface spectral emittance. Image processing of the data included panorama correction and calibration to radiance using the on-board black bodies and the measured spectral response of each channel. Scene-dependent isolated-point noise due to bit drops, was located by its relatively discontinuous values and replaced by the average of the surrounding data values. A method was developed in order to separate the spectral and temperature information contained in the TIMS data. Night and day data sets were processed. The TIMS is unique in allowing collection of both spectral emittance and thermal information in digital format with the same airborne scanner. For the first time it was possible to produce day and night emittance images of the same area, coregistered. These data add to an understanding of the physical basis for the discrimination of difference in surface materials afforded by TIMS.

Kahle, Anne B.↗

Affordable In-Space Transportation: An Advanced Concepts Project - Phase 2

The Affordable In-Space Transportation (AIST) program was established by the NASA Office of Space Access to improve transportation and lower the costs from Low Earth Orbit (LEO) to Geostationary Earth Orbit (GEO) and beyond (to Lunar orbit, Mars orbit, inner solar system missions, and return to LEO). A goal was established to identify and develop radically innovative concepts for new upper stages for Reusable Launch Vehicles (RLV) and Highly Reusable Space Transportation (HRST) systems. New architectures and technologies are being identified which have the potential to meet a cost goal of $1,000 to $2,000 per pound for transportation to GEO and beyond for overall mission cost (including the cost to LEO). A Technical Interchange Meeting (ITM) was held on October 16 and 17, 1996 in Huntsville, Alabama to review previous studies, present advanced concepts and review technologies that could be used to meet the stated goals. The TIM was managed by NASA-Mar-shaU Space Flight Center (MSFC) Advanced Concepts Office with Mr. Alan Adams providing TIM coordination. Mr. John C. Manidns of NASA Headquarters provided overall sponsorship. The University of Alabama in Huntsville (UAH) Propulsion Research Center hosted the TM at the UAH Research Center. Dr. Clark Hawk, Center Director, was the principal investigator. Technical support was provided by Christensen Associates. Approximately 70 attendees were present at the meeting. This Executive Summary provides a record of the key discussions and results of the TIM in a summary format. It incorporates the response to the following basic issues of the TPA, which addressed the following questions: 1. What are the cost drivers and how can they be reduced? 2. What are the operational issues and their impact on cost? What is the current Technology Readiness Level (TRL) and what will it take to reach TRL 6? 4. What are the key enabling technologies and sequence for their accomplishment? 5. What is the proposed implementation time frame? See Appendix A for the TIM Agenda and Appendix C for the AIST Program Terms of Reference.

Source record↗

Analysis of Vegetation Within A Semi-Arid Urban Environment Using High Spatial Resolution Airborne Thermal Infrared Remote Sensing Data

High spatial resolution (5 m) remote sensing data obtained using the airborne Thermal Infrared Multispectral Scanner (TIMS) sensor for daytime and nighttime have been used to measure thermal energy responses for 2 broad classes and 10 subclasses of vegetation typical of the Salt Lake City, Utah urban landscape. Polygons representing discrete areas corresponding to the 10 subclasses of vegetation types have been delineated from the remote sensing data and are used for analysis of upwelling thermal energy for day, night, and the change in response between day and night or flux, as measured by the TIMS. These data have been used to produce three-dimensional graphs of energy responses in W/ sq m for day, night, and flux, for each urban vegetation land cover as measured by each of the six channels of the TIMS sensor. Analysis of these graphs provides a unique perspective for both viewing and understanding thermal responses, as recorded by the TIMS, for selected vegetation types common to Salt Lake City. A descriptive interpretation is given for each of the day, night, and flux graphs along with an analysis of what the patterns mean in reference to the thermal properties of the vegetation types surveyed in this study. From analyses of these graphs, it is apparent that thermal responses for vegetation can be highly varied as a function of the biophysical properties of the vegetation itself, as well as other factors. Moreover, it is also seen where vegetation, particularly trees, has a significant influence on damping or mitigating the amount of thermal radiation upwelling into the atmosphere across the Salt Lake City urban landscape. Published by Elsevier Science Ltd.

Quattrochi, Dale A.↗

System Study: Technology Assessment and Prioritizing

The objective of this NASA funded project is to assess and prioritize advanced technologies required to achieve the goals for an "Intelligent Propulsion System" through collaboration among GEAE, NASA, and Georgia Tech. Key GEAE deliverables are parametric response surface equations (RSE's) relating technology features to system benefits (sfc, weight, fuel burn, design range, acoustics, emission, etc...) and listings of Technology Impact Matrix (TIM) with benefits, debits, and approximate readiness status. TIM has been completed for GEAE and NASA proposed technologies. The combined GEAE and NASA TIM input requirement is shown in Table.1. In the course of building the RSE's and TIM, significant parametric technology modeling and RSE accuracy improvements were accomplished. GEAE has also done preliminary ranking of the technologies using Georgia Tech/GEAE USA developed technology evaluation tools. System level impact was performed by combining beneficial technologies with minimum conflict among various system figures of merits to assess their overall benefits to the system. The shortfalls and issues with modeling the proposed technologies are identified, and recommendations for future work are also proposed.

Source record↗

Estimating Thruster Impulses From IMU and Doppler Data

A computer program implements a thrust impulse measurement (TIM) filter, which processes data on changes in velocity and attitude of a spacecraft to estimate the small impulsive forces and torques exerted by the thrusters of the spacecraft reaction control system (RCS). The velocity-change data are obtained from line-of-sight-velocity data from Doppler measurements made from the Earth. The attitude-change data are the telemetered from an inertial measurement unit (IMU) aboard the spacecraft. The TIM filter estimates the threeaxis thrust vector for each RCS thruster, thereby enabling reduction of cumulative navigation error attributable to inaccurate prediction of thrust vectors. The filter has been augmented with a simple mathematical model to compensate for large temperature fluctuations in the spacecraft thruster catalyst bed in order to estimate thrust more accurately at deadbanding cold-firing levels. Also, rigorous consider-covariance estimation is applied in the TIM to account for the expected uncertainty in the moment of inertia and the location of the center of gravity of the spacecraft. The TIM filter was built with, and depends upon, a sigma-point consider-filter algorithm implemented in a Python-language computer program.

Lisano, Michael E.↗

Proceedings of the NASA Technical Interchange Meeting on Active Optical Systems for Supporting Science, Exploration, and Aeronautics Measurements Needs

Active optical (Laser/Lidar) measurement techniques are critical for the future National Aeronautics and Space Administration (NASA) Earth, Planetary Science, Exploration, and Aeronautics measurements. The latest science decadal surveys recommend a number of missions requiring active optical systems to meet the science measurement objectives and the aeronautics community continues to use Laser/Lidar technologies to meet the aeronautics measurement objectives. With these drivers, the NASA Agency Program Management Council (APMC), chaired by the NASA Associate Administrator, has tasked the NASA Sensors and Instrumentation (S&I) Capability Leadership Team (CLT) Leader to determine if the Agency has the necessary expertise and capabilities to execute successfully the active optical-based systems necessary to make the required measurements for Science, Exploration, and Aeronautics. This NASA Technical Interchange Meeting (TIM) was a forum to exchange perspectives on the current state of the discipline’s technologies and the direction NASA needs to take in the future to raise the Technical Readiness Level (TRL) of the measurement technologies to meet these measurement needs in the applications domains. The information developed at this TIM was used in formulating the Agency-level strategy and solutions for advancing high-risk Laser/Lidar technologies that are not currently being sufficiently planned, developed, or risk-reduced to meet NASA’s mission requirements. Given the crosscutting synergies in critical Active Optical measurements for NASA Science, Exploration, and Aeronautics, a strategic approach is needed to identify areas where NASA should “lead, leverage or collaborate” with existing national and international industries to meet its future needs. The TIM aimed at focusing NASA’s directions to attain the necessary TRLs to meet the Agency-level priority Active Optical measurements in Space and Aeronautics. The TIM presentations and strategic inputs were synthesized by the NASA Active Optical Tiger Team for presentation to the NASA APMC with a suggested strategy to address the Agency’s needs in a crosscutting, synergistic and cost-effective manner.

Singh, Upendra N↗

Outcomes of a NASA Human Research Program’s (HRP) Space Radiation Element-sponsored Mini-Technical Interchange Meeting/workshop on Cardiovascular Disease Risk from Space Radiation

The NASA HRP’s Space Radiation Element funds research to characterize and mitigate adverse health outcomes from space radiation including cardiovascular risks to astronauts to enable deep space exploration and sustained human presence in space. Non-cancer effects such as damage to the cardiovascular system have been observed at clinically relevant high doses of ionizing radiation. However, an association between lower doses and risk of cardiovascular disease (CVD) remains somewhat controversial, especially in relation to the existence of low dose thresholds, radiation quality, and dose-rate effects, as well as gaps in characterizing the mechanisms and major pathways of disease. To facilitate, accelerate, and incubate new ideas to characterize and mitigate this risk, the Element is planning to organize a series of miniature technical interchange meetings (Tiny-TIMs) to provide a venue for HRP-funded investigators and thought leaders to present ongoing work and engage in open discussion on presented results, limitations of current approaches, incorporating better experimental strategies, model systems, etc. The initial Tiny-TIM held during the NASA HRP Investigators’ Workshop earlier this year – Upping the ante on characterizing and mitigating cardiovascular disease risk from space radiation exposure – aimed to stimulate discussion on the current state of scientific knowledge of CVD risk from space-like radiation exposure. The Tiny-TIM consisted of two 90-minute sessions; the first session concentrated on current knowledge of CVD risk from space radiation and the second session focused on innovative ideas, newer approaches, and techniques to accelerate research. The second session was followed by an open spirited discussion amongst peers on the current issues impeding the characterization of CVD risk from space radiation. The Element facilitated the discussion using a set of pressing open questions/gaps in knowledge that need to be addressed by the scientific community. The outcomes of the Tiny-TIM will be presented along with a plan of proposed future workshops and other initiatives of the Space Radiation Element.

Janapriya Saha↗

Analytical Determination of Radioactive Strontium and Cesium by Thermal Ionization Mass Spectrometry

Thermal ionization mass spectrometry (TIMS) has been evaluated for the detection of the radioactive isotopes of strontium and cesium. The instrument was investigated for the analysis of isotopic ratios of 89Sr to 90Sr and 135Cs to 137Cs in the presence of atomic isobars (Y and Zr for Sr analysis and Ba for Cs analysis). Signicant discrimination using TIMS was found for both Sr and Cs through evaluation using stable isotopes. Fusion procedures with different flux were evaluated for preparation of sample matrices. Chemical separations were developed and used after fusion to isolate the Sr and Cs from a prepared background matrix (i.e., Montana Soil). A graded approach, increasing in stable background isotopes, was performed to monitor the chemistry and instrument response. A thermal neutron irradiation was performed to produce a sample that contained the radioisotopes of Sr and Cs. Even though the irradiated sample was not a certified standard it does provide accurate expectation values via published, well understood cumulative fission yield data. The results presented in this work correlate extremely well with the published data. Furthermore, a significant decrease in uncertainty (by a factor of 5 { 10) was found for the isotopic ratios measured with TIMS compared to the published values.

TIMS, environmental contamination, radiostrontium,↗

Enhanced Pu emission with solution-loaded laser ablation modified sources (SLLAMS) for thermal ionization mass spectrometry

This study presents a new approach to filament modification by laser ablation for analysis of femtograms of plutonium (Pu) by thermal ionization mass spectrometry (TIMS). This method simplifies the often rigorous and labor-intensive sample loading necessary for low-level analyses by TIMS with solution-loaded laser ablation modified sources (SLLAMS). By applying a para-film coating to the surface of the filament and then ablating through the film to reveal metal beneath, a point source is created. A solution containing ppt-levels of Pu can then be applied over the ablated region, dried slowly into the crater, and then carburized. All analyses were made by multiple ion counting system of a Nu Instruments TIMS. Furthermore, we report errors of 10% 2σ for 240 Pu/ 239 Pu of CRM-137 samples totaling 5 – 7 femtograms (fg; 1E-15 g) with an average sample utilization efficiency of 1.3%. Results from SLLAMS demonstrate an improvement in precision, accuracy and ease of use over resin bead loads.

47 OTHER INSTRUMENTATION↗

Designing Porous Ion Emitters for Thermal Ionization Mass Spectrometry: Evaluating Metal-Organic Frameworks

In this work we describe the first exploration of metal-organic frameworks (MOFs) as ‘next generation’ ion emitters for thermal ionization mass spectrometry (TIMS). MOFs were identified as promising candidates for this application given the synthetic control over their desired structural properties. This tunability results in well-ordered, high surface area, high porosity frameworks with targeted sorption affinities. Here we explored an aluminum-based, bipyridine-containing MOF (MOF-253) with and without incorporating the high work function metal, rhenium (Re). After analysis of a Nd-bearing MOF, we hypothesized that the well-dispersed, sponge-like interconnected network of the degraded structure would enhance Nd ionization more than traditional TIMS loading activators (i.e., phosphoric acid). Compared to filaments loaded with phosphoric acid that require an additional benzene carburization step, the Nd ionization efficiencies (atoms detected relative to atoms loaded) for heated filaments loaded with MOF-253 were similar (~1%). Electron microscopy after TIMS analysis demonstrated that the MOF was retained on the filament and, as hypothesized, preserved sub-micron porosity post analysis. While these results are preliminary, they demonstrate that MOFs have potential to enhance ionization and exceed the performance of traditional loading techniques by forming nano-porous ion emitters (nano-PIEs). Thus, further experimentation is likely to exceed this performance through more specific selection of the base MOF structure and modifications to porosity and composition. This work represents a novel application of MOFs and a next step in the pursuit of advanced thermal ionization with potential to expand across the periodic table.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Enhancement of Uranium Ionization Efficiencies Using Zn-MOF-74 Derived Nanoporous Ion Emitters for Thermal Ionization Mass Spectrometry

The recent introduction of nano-porous ion emitters (nano-PIEs) formed from metal organic frameworks (MOFs) has demonstrated the potential to enhance sensitivity for thermal ionization mass spectrometry (TIMS). Nano-PIEs take advantage of the parent MOF’s chemical and structural tunability to form scaffolds for ion emitters. A study by Barpaga et al. 2023 on MOF-74 as the parent material found that with high volatility metals in their framework uranium sample utilization efficiency (SUE) increases by up to nine-fold (e.g., Zn-MOF-74) compared to that of the analyte on a bare filament (~0.05%). Here, in this study, we investigate the performance of Zn-MOF-74 to maximize uranium efficiencies at the trace level (= 10 -12 g) by altering the parent MOF morphology and chemistry (i.e., MOF crystal sizes and thermal degradation) and optimizing its integration with TIMS (i.e., MOF mass on a filament and ramp conditions). We observed improvement in SUE up to 20 times (≤1.0%) that of a bare filament load when nano-PIEs derived from nanocrystals of Zn-MOF-74 were heated under a specific current ramp condition. This demonstrates that rates of nano-PIE structural collapse during TIMS analysis and the subsequently formed nanomaterials (and their features) can be tuned to control analyte ionization.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Robust and Spectrally Selective Aerogels for Solar Receivers

The development of next generation concentrated solar thermal (CST) plants requires solar receivers to reach high temperatures (> 600°C) while minimizing costs. Efficiently generating such high temperatures using a line-focusing collector and an air-stable receiver has the potential to change the current CSP paradigm because it would: (1) result in large improvements in system-level efficiency of line-focusing systems by enabling the use of high-efficiency supercritical CO 2 power cycles; (2) decrease the LCOE of line-focusing systems to meet SETO 2030 goals; (3) maintain performance over the lifetime of the CSP plant by avoiding issues related to breakdown of vacuum. The use of aerogels as transparent insulating materials (TIMs) in solar thermal receivers has the potential to enable such improvements. Specifically, aerogels can be placed in front of a black (or partially selective) high-temperature absorber to allow sunlight to transmit to the absorber but block heat from escaping. These materials can improve the efficiency and simplify the complexity of thermal transport systems by enabling operation at moderate or no vacuum levels. These potential benefits have been explicitly identified by SETO as ‘high impact’. The use of mesoporous silica as a TIM has already led to large improvements in solar collection efficiency. Nevertheless, these materials inherently lose structural integrity and the ability to suppress radiation losses at high temperatures. Here, we address these challenges by leveraging 1-cycle atomic layer deposition of aluminum oxide onto a silica aerogel to form a thermally stable interfacial layer that is transparent to sunlight but broadly absorbs in the mid-infrared. This interfacial absorption results in a two-fold reduction in measured heat losses from an absorber at 700°C and solar thermal efficiency of 81% at 700°C under 60 Suns, based on measurements of heat loss and solar transmittance. Extended-duration heat treatment reveals that the multicomponent aerogel is stable at high temperatures relative to a silica aerogel. Furthermore, we experimentally demonstrate the concept of using infrared plasmon resonances to selectively enhance the thermal absorption coefficient of TIMs in order to strongly suppress thermal radiative losses at high temperatures. We term this mechanism plasmon-enhanced greenhouse selectivity (PEGS). Unlike silica aerogels, where much of the IR absorption is lost at high temperatures, local surface plasmon resonances (LSPRs) in doped oxide nanoparticles overlap a significant portion of the blackbody spectrum and are maintained at high temperatures. Overall, this work paves the way for next-generation solar thermal energy using thermally robust transparent insulating materials.

14 SOLAR ENERGY↗

Robust and Spectrally Selective Aerogels for Solar Receivers (Final Technical Report)

The development of next generation concentrated solar thermal (CST) plants requires solar receivers to reach high temperatures (> 600°C) while minimizing costs. Efficiently generating such high temperatures using a line-focusing collector and an air-stable receiver has the potential to change the current CSP paradigm because it would: (1) result in large improvements in system-level efficiency of line-focusing systems by enabling the use of high-efficiency supercritical CO2 power cycles; (2) decrease the LCOE of line-focusing systems to meet SETO 2030 goals; (3) maintain performance over the lifetime of the CSP plant by avoiding issues related to breakdown of vacuum. The use of aerogels as transparent insulating materials (TIMs) in solar thermal receivers has the potential to enable such improvements. Specifically, aerogels can be placed in front of a black (or partially selective) high-temperature absorber to allow sunlight to transmit to the absorber but block heat from escaping. These materials can improve the efficiency and simplify the complexity of thermal transport systems by enabling operation at moderate or no vacuum levels. These potential benefits have been explicitly identified by SETO as ‘high impact’. The use of mesoporous silica as a TIM has already led to large improvements in solar collection efficiency. Nevertheless, these materials inherently lose structural integrity and the ability to suppress radiation losses at high temperatures. Here, we address these challenges by leveraging 1-cycle atomic layer deposition of aluminum oxide onto a silica aerogel to form a thermally stable interfacial layer that is transparent to sunlight but broadly absorbs in the mid-infrared. This interfacial absorption results in a two-fold reduction in measured heat losses from an absorber at 700°C and solar thermal efficiency of 81% at 700°C under 60 Suns, based on measurements of heat loss and solar transmittance. Extended-duration heat treatment reveals that the multicomponent aerogel is stable at high temperatures relative to a silica aerogel. Furthermore, we experimentally demonstrate the concept of using infrared plasmon resonances to selectively enhance the thermal absorption coefficient of TIMs in order to strongly suppress thermal radiative losses at high temperatures. We term this mechanism plasmon-enhanced greenhouse selectivity (PEGS). Unlike silica aerogels, where much of the IR absorption is lost at high temperatures, local surface plasmon resonances (LSPRs) in doped oxide nanoparticles overlap a significant portion of the blackbody spectrum and are maintained at high temperatures. Overall, this work paves the way for next-generation solar thermal energy using thermally robust transparent insulating materials.

14 SOLAR ENERGY↗

Mineralogic information from a new airborne thermal infrared multispectral scanner

The thermal IR multispectral scanner (TIMS) has been developed for airborne geologic surveys. The resststrahlen band between 8-11 microns is exhibited by interatomic stretching vibrations of Si and oxygen bound up in the crystal lattice of silicate rocks. The crystal structure of the component minerals influence the depth and position of the detected band. The TIMS has six channels, an 80 deg field of view, and a sensitivity sufficient to detect a noise equivalent change in spectral emissivity of 0.002-0.006. The six bands measured are 8.2-8.6, 8.6-9.0, 9.4-10.2, 10.2-11.2, and 11.2-12.2 microns, using HgCdTe detectors. The data are analyzed with respect to emissivity variations as a function of wavelength, using the component transformation technique called a decorrelation stretch, with spectral differences being displayed as different colors. Sample scenes from Death Valley and the Nevada Cuprite mining district are compared with visible and near-IR color composites of the same areas, revealing the superior distinctions that are available with the TIMS.

Kahle, A. B.↗

Estimation of absolute water surface temperature based on atmospherically corrected thermal infrared multispectral scanner digital data

Airborne remote sensing systems, as well as those on board Earth orbiting satellites, sample electromagnetic energy in discrete wavelength regions and convert the total energy sampled into data suitable for processing by digital computers. In general, however, the total amount of energy reaching a sensor system located at some distance from the target is composed not only of target related energy, but, in addition, contains a contribution originating from the atmosphere itself. Thus, some method must be devised for removing or at least minimizing the effects of the atmosphere. The LOWTRAN-6 Program was designed to estimate atmospheric transmittance and radiance for a given atmospheric path at moderate spectral resolution over an operational wavelength region from 0.25 to 28.5 microns. In order to compute the Thermal Infrared Multispectral Scanner (TIMS) digital values which were recorded in the absence of the atmosphere, the parameters derived from LOWTRAN-6 are used in a correction equation. The TIMS data were collected at 1:00 a.m. local time on November 21, 1983, over a recirculating cooling pond for a power plant in southeastern Mississippi. The TIMS data were analyzed before and after atmospheric corrections were applied using a band ratioing model to compute the absolute surface temperature of various points on the power plant cooling pond. The summarized results clearly demonstrate the desirability of applying atmospheric corrections.

Anderson, James E.↗

Multisensor classification of sedimentary rocks

A comparison is made between linear discriminant analysis and supervised classification results based on signatures from the Landsat TM, the Thermal Infrared Multispectral Scanner (TIMS), and airborne SAR, alone and combined into extended spectral signatures for seven sedimentary rock units exposed on the margin of the Wind River Basin, Wyoming. Results from a linear discriminant analysis showed that training-area classification accuracies based on the multisensor data were improved an average of 15 percent over TM alone, 24 percent over TIMS alone, and 46 percent over SAR alone, with similar improvement resulting when supervised multisensor classification maps were compared to supervised, individual sensor classification maps. When training area signatures were used to map spectrally similar materials in an adjacent area, the average classification accuracy improved 19 percent using the multisensor data over TM alone, 2 percent over TIMS alone, and 11 percent over SAR alone. It is concluded that certain sedimentary lithologies may be accurately mapped using a single sensor, but classification of a variety of rock types can be improved using multisensor data sets that are sensitive to different characteristics such as mineralogy and surface roughness.

Evans, Diane↗

Measurements of short-term thermal responses of coniferous forest canopies using thermal scanner data

Thermal Infrared Multispectral Scanner (TIMS) data were collected over a coniferous forest in western Oregon. Concurrent radiosonde measurements of atmospheric profiles of air temperature and moisture provided inputs to LOWTRAN6 for atmospheric radiance corrections of the TIMS data. Surface temperature differences measured by the TIMS over time between flight lines were combined with surface radiative energy balance estimates to develop thermal response numbers (TRN). These numbers characterized the thermal response of the diffent surface types. Barren surfaces had the lowest TRN, whereas the forested surfaces had the highest.

Luvall, J. C.↗