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A structural and functional biomimetic Ni( ii )N 3 O complex, capable of O 2 mediated dioxygenase like C–C bond cleavage, via a putative high-valent Ni intermediate.
A method for deriving constrained or fixed-base modes and frequencies from free-free modes of a structure with mass-loaded boundaries is developed. Problems associated with design and development of test fixtures can be avoided with such an approach. The analytical methodology presented is used to assess applicability of the mass-additive method for three types of structures and to determine the accuracy of derived constrained modes and frequencies. Results show that mass loading of the boundaries enables local interface modes to be measured within a desired frequency bandwidth, thus allowing constrained modes to be derived with considerably fewer free-free modes than for unloaded boundaries. Good convergence was obtained for a simple beam and a truss-like Shuttle payload, both of which had well-spaced modes and stiff interface support structures. Slow convergence was obtained for a space station module prototype, a shell-like structure having high modal density.
The paper presents a novel approach to model woven composite using the computationally efficient one-dimensional models. The framework is built within the scheme of the Carrera Unified Formulation (CUF), a generalized hierarchical formulation that generates variable kinematic structural theories. Various components of the woven composite unit cell are modeled using a combination of straight and curved one-dimensional CUF models. By employing a component-wise approach, a modeling technique within CUF, the complex geometry of the woven composite components is modeled precisely. The ability of CUF models to accurately resolve stress and strain fields are exploited to capture complex deformation within a woven composite unit cell. Numerical results include analyses of a non-crimped textile composite, a curved tow under tension, and a dry woven textile unit cell.
NASA Environmentally Responsible Aviation (ERA) project and the Boeing Company are collabrating to advance the unitized damage arresting composite airframe technology with application to the Hybrid-Wing-Body (HWB) aircraft. The testing of a HWB fuselage section with Pultruded Rod Stitched Efficient Unitized Structure (PRSEUS) construction is presently being conducted at NASA Langley. Based on lessons learned from previous HWB structural design studies, improved finite-element models (FEM) of the HWB multi-bay and bulkhead assembly are developed to evaluate the performance of the PRSEUS construction. In order to assess the comparative weight reduction benefits of the PRSEUS technology, conventional cylindrical skin-stringer-frame models of a cylindrical and a double-bubble section fuselage concepts are developed. Stress analysis with design cabin-pressure load and scenario based case studies are conducted for design improvement in each case. Alternate analysis with stitched composite hat-stringers and C-frames are also presented, in addition to the foam-core sandwich frame and pultruded rod-stringer construction. The FEM structural stress, strain and weights are computed and compared for relative weight/strength benefit assessment. The structural analysis and specific weight comparison of these stitched composite advanced aircraft fuselage concepts demonstrated that the pressurized HWB fuselage section assembly can be structurally as efficient as the conventional cylindrical fuselage section with composite stringer-frame and PRSEUS construction, and significantly better than the conventional aluminum construction and the double-bubble section concept.
A new analytical method is presented for generating component shape vectors, or Ritz vectors, for use in component synthesis. Based on the concept of a block-Krylov subspace, easily derived recurrence relations generate blocks of Ritz vectors for each component. The subspace spanned by the Ritz vectors is called a block-Krylov subspace. The synthesis uses the new Ritz vectors rather than component normal modes to reduce the order of large, finite-element component models. An advantage of the Ritz vectors is that they involve significantly less computation than component normal modes. Both 'free-interface' and 'fixed-interface' component models are derived. They yield block-Krylov formulations paralleling the concepts of free-interface and fixed-interface component modal synthesis. Additionally, block-Krylov reduced-order component models are shown to have special disturbability/observability properties. Consequently, the method is attractive in active structural control applications, such as large space structures. The new fixed-interface methodology is demonstrated by a numerical example. The accuracy is found to be comparable to that of fixed-interface component modal synthesis.
FEM studies are presented of the nozzle and the low-pressure fuel-pump inducer designs for the Space Shuttle Main Engine (SSME) to analyze the effects of structural vibrations. FEM preprocessing software based on a CAD system is employed to develop a model of the component's sophisticated geometry. The nozzle geometry is also defined by means of the preprocessing technique and subsequently analyzed with respect to time-transient loading. The analysis is conducted with a Cray supercomputer using the SPAR/EAL FEM program. The investigation of the nozzle demonstrates the advantageous use of symmetry in the determination of nozzle response to SSME start-up transients. Plots of time vs strain are developed for gages on the nozzle wall and steerhorn tubing. The results of the inducer modeling are found to be adequate for investigating the component's principle modes, and the nozzle results indicate the suitability of the FEM techniques for optimizing the design of engine components.
High-entropy oxides (HEOs) are single phase solid solutions where five or more metals share the same sublattice, giving rise to unexpected features in various fields of applications. Recently, HEOs have emerged as an alternative conversion electrode anode material for next-generation Li-ion batteries, where the combination of several different elements in a single solid solution can synergistically act to overcome some of its main drawbacks, improving performance. Due to their chemical complexity, x-ray absorption spectroscopy (XAS) emerges as an appropriate technique to study the electronic (x-ray absorption near edge structure, XANES) and local structure (extended x-ray absorption fine structure, EXAFS) of these compounds as a function of cycling. This work aims to highlight the capabilities of XAS as an element-specific probe to understand a material’s structure at the atomistic level through EXAFS modeling of (MgFeCoNiCuZn)O high-entropy system and how to extract valuable information about the bond distance, number of near neighbors, and local disorder, which are crucial to a full understanding of the electrochemical reaction mechanisms of such battery electrodes.
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In the aircraft industry, full scale and large component testing is a very necessary, time consuming, and expensive process. It is essential to find ways by which this process can be minimized without loss of reliability. One possible alternative is the use of scaled down models in testing and use of the model test results in order to predict the behavior of the larger system, referred to herein as prototype. This viewgraph presentation provides justifications and motivation for the research study, and it describes the necessary conditions (similarity conditions) for two structural systems to be structurally similar with similar behavioral response. Similarity conditions provide the relationship between a scaled down model and its prototype. Thus, scaled down models can be used to predict the behavior of the prototype by extrapolating their experimental data. Since satisfying all similarity conditions simultaneously is in most cases impractical, distorted models with partial similarity can be employed. Establishment of similarity conditions, based on the direct use of the governing equations, is discussed and their use in the design of models is presented. Examples include the use of models for the analysis of cylindrical bending of orthotropic laminated beam plates, of buckling of symmetric laminated rectangular plates subjected to uniform uniaxial compression and shear, applied individually, and of vibrational response of the same rectangular plates. Extensions and future tasks are also described.
The Underwater Explosions Research Division (UERD) of the David Taylor Naval Ship Research and Development Center makes extensive use of NASTRAN/COSMIC on a CDC 176 to evaluate the structural response of ship structures subjected to underwater explosion shock loadings in the time domain. As relatively new users, UERD engineers have experienced difficulties with the checkpoint/restart feature because of the vague instructions in the user manual. Working procedures for the application of the checkpoint/restart feature to the transient analysis using NASTRAN/COSMIC are illustrated.
This paper outlines the process of developing a parametric model for a vehicle that can withstand Earth launch and Mars entry conditions. This model allows the user to change a variety of parameters ranging from dimensions and meshing to materials and atmospheric entry angles to perform finite element analysis on the model for the specified load cases. While this work focuses on an aeroshell for Earth launch aboard the Space Launch System (SLS) and Mars entry, the model can be applied to different vehicles and destinations. This specific project derived from the need to deliver large payloads to Mars efficiently, safely, and cheaply. Doing so requires minimizing the structural mass of the body as much as possible. The code developed for this project allows for dozens of cases to be run with the single click of a button. The end result of the parametric model gives the user a sense of how the body reacts under different loading cases so that it can be optimized for its purpose. The data are reported in this paper and can provide engineers with a good understanding of the model and valuable information for improving the design of the vehicle. In addition, conclusions show that the frequency analysis drives the design and suggestions are made to reduce the significance of normal modes in the design.
In this study, we tested the impact of a revised set of soil, vegetation and land cover parameters on the performance of three different state-of-the-art land surface models (LSMs) within the NASA Land Information System (LIS). The impact of this revision was tested over the South American Dry Chaco, an ecoregion characterized by deforestation and forest degradation since the 1980s. Most large-scale LSMs may lack the ability to correctly represent the ongoing deforestation processes in this region, because most LSMs use climatological vegetation indices and static land cover information. The default LIS parameters were revised with improved soil parameters, satellite-based interannually varying vegetation indices (leaf area index and green vegetation fraction) instead of climatological vegetation indices, and yearly land cover information instead of static land cover. A relative comparison in terms of water budget components and “efficiency space” for various baseline and revised experiments showed that large regional and long-term differences in the simulated water budget partitioning relate to different LSM structures, whereas smaller local differences resulted from updated soil, vegetation and land cover parameters. Furthermore, the different LSM structures redistributed water differently in response to these parameter updates. A time-series comparison of the simulations to independent satellite-based estimates of evapotranspiration and brightness temperature (Tb) showed that no LSM setup significantly outperformed another for the entire region and that not all LSM simulations improved with updated parameter values. However, the revised soil parameters generally reduced the bias between simulated surface soil moisture and pixel-scale in situ observations and the bias between simulated Tb and regional Soil Moisture Ocean Salinity (SMOS) observations. Our results suggest that the different hydrological responses of various LSMs to vegetation changes may need further attention to gain benefits from vegetation data assimilation.
Early lunar missions have provided a basic understanding of the physical and strength properties of lunar regolith, which have been shown to differ from those of dry terrestrial granular soils. Lunar regolith is predominantly a fine sand of which nearly 40 percent can be characterized as silt with a particle size smaller than 100 micrometers. The top 10 to 20 cm of the regolith can be characterized as being in a loose to medium-loose state. The density of the regolith, however, rapidly increases below a depth of 20 cm. The highly irregular and angular shapes of the regolith particles tend to interlock and create relatively strong mechanical bonds that give the particulate mass substantial cohesive properties and smaller amounts of tensile strength properties. In addition, the friction angle of lunar regolith at medium to high densities is quite high and often exceeds 55 degrees. These known properties of lunar regolith have been matched in a terrestrially-manufactured analog known as Minnesota Lunar Simulant. A variety of experiments were conducted using this simulant to both verify existing information and generate new information on the physical and constitutive properties of lunar regolith. These experiments include maximum and minimum density determinations, specific mass of solids, grain-size distribution, conventional triaxial compression and extension, isotropic compression, one-dimensional compression, direct shear, and direct tension. Direct shear experiments were conducted under atmospheric and vacuum conditions. Results of the physical and strength experiments compare closely to results obtained from lunar missions. Results of simulant strength experiments performed in vacuum indicated no observable difference from results obtained in air. A test bed currently under study is one involving a regolith shield covering a first-generation human habitat module. It is understood that regolith in depths ranging from 3 to 5 meters is required for radiation shielding for habitation and workspace. The habitat module is treated as a rigid cylindrical tube with a smooth exterior. By making the cylinder rigid, a complex interaction problem is reduced to a situation where we can consider the support regolith and the shielding regolith as behaving independently of the structural properties of the cylindrical structure. Medium-dense lunar simulant was placed around a scaled model of the habitat module to provide a radiation shield. This embankment-type shield was constructed in relatively thin but fine layers by compacting, by mechanical vibratory means, layer upon layer of simulant placed adjacent to the horizontally-aligned cylinder. The slope angles were constructed at 55 degrees. The model described above was studied in a geotechnical centrifuge, which allows for the scaling of model dimensions to prototype dimensions by increasing the acceleration of gravity on the model. The deformation response can be scaled up to prototype dimensions to provide an assessment of the deformation patterns of the lunar structure. The actual process of local and/or global growth of instabilities or skip planes can also be observed.
NASA and its contractors have developed an integrated, interdisciplinary CAD/analysis system designated IDEAS(double asterisk)2 in order to conduct evaluations of alternative Space Station concepts' performance over the projected course of the Station's evolution in orbit. Attention is presently given to the requirements associated with automated FEM-building methods applicable to Space Station system-level structural dynamic analysis, and the ways in which IDEAS(double asterisk)2 addresses these requirements. Advantage is taken of the interactive capabilities of the SUPERTAB FEM preprocessor system for Space Station model manipulation and modification.
The derivative of vitamin B1 thiamin pyrophosphate (TPP) is a cofactor of enzymes performing catalysis in pathways of energy production, including (i) decarboxylation of alpha-keto acids followed by (ii) transketolation. These enzymes have shown a common mechanism of TPP activation by imposing an active V-conformation of this coenzyme that brings the N4 atom of the aminopyrimidine ring to the distance required for the intramolecular C-H N hydrogen-bonding with the C2- atom of the thiazolium ring. The reactive C2 atom of TPP is the nucleophile that attacks the carbonyl carbon of different substrates used by the TPP-dependent enzymes. The structure of the heterotetrameric human pyruvate dehydrogenase (Elp) recently determined in our laboratory (1) revealed the association pattern of the subunits and the specifics of two chemically equivalent cofactor binding sites. Dynamic nonequivalence of these two cofactor sites directs the flip-flop action of this enzyme, depending upon which two active sites effect each other (2). The crystal structure derived from the holo-form of Elp provided the basis for the model of the flip-flop action of Elp in which different steps of the catalytic reaction are performed in each of the two cofactor sites at any given moment, where these steps are governed by the concerted shuttle-like motion of the subunits. It is further proposed that balancing a hydrogen-bond network and related cofactor geometry determine the continuity of catalytic events.
For steady state time harmonic problems (rigid format 8), the NASTRAN program as currently configured treats internal structural damping through the introduction of a single structural element damping coefficient that typically is viewed as the ratio of the complex to real modulus of elasticity. For problems dealing with two or three dimensional dynamic linear viscoelasticity (e.g. a Kelvin-Voigt viscoelastic model), the present NASTRAN capability cannot directly handle this situation wherein two independent damping coefficients are required to properly model the dissipation phenomenon. A technique is presented whereby the user can adapt the standard versions of NASTRAN (without resorting to either DMAP and/or FORTRAN coding changes) for the purpose of treating this class of problem.
This presentation will discuss the methodology behind Model Class Definition--the use of separate model assemblies of the same product, at different fidelities, driven by the same skeleton files. These fidelities can be used to convey only the detail that the end user needs, by allowing the end user to pick and choose between model classes for assembly creation. The usefulness of MPA for the Windchill Release Process will be demonstrated, along with its usefulness in minimizing CPU resources during design. The presentation will include an overview the ML product, how to structure complex products in a flexible modular architecture, and how to maximize system resources.
During the developmental static fire program for NASAs Reusable Solid Rocket Motor-V (RSRMV), an anomalous erosion condition appeared on the nozzle Carbon Cloth Phenolic nose ring that had not been observed in the space shuttle RSRM program. There were regions of augmented erosion located on the bottom of the forward nose ring (FNR) that measured nine tenths of an inch deeper than the surrounding material. Estimates of heating conditions for the RSRMV nozzle based on limited char and erosion data indicate that the total heat loading into the FNR, for the new five segment motor, is about 40-50% higher than the baseline shuttle RSRM nozzle FNR. Fault tree analysis of the augmented erosion condition has lead to a focus on a thermomechanical response of the material that is outside the existing experience base of shuttle CCP materials for this application. This paper provides a sensitivity study of the CCP material thermo-structural response subject to the design constraints and heating conditions unique to the RSRMV Forward Nose Ring application. Modeling techniques are based on 1-D thermal and porous media calculations where in-depth interlaminar loading conditions are calculated and compared to known capabilities at elevated temperatures. Parameters such as heat rate, in-depth pressures and temperature, degree of char, associated with initiation of the mechanical removal process are quantified and compared to a baseline thermo-chemical material removal mode. Conclusions regarding postulated material loss mechanisms are offered.