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NASA NTRS1998

Introduction to special section: early Mars

Ongoing studies of the evolution of the Martian cratered highlands, the nature of the planet's early climate, and the recent announcement of possible evidence of ancient life in the ALH 84001 meteorite have reinvigorated interest in the conditions that prevailed on Mars during its first billion years of geologic history. To address this interest and assess our current understanding of these issues, the Lunar and Planetary Institute hosted a 4-day Conference on Early Mars in Houston in April of 1997. The papers contained in this special section are a product of that meeting. The purpose of the conference was twofold: (1) to consider how impacts, volcanism, and the presence of abundant water affected the physical and chemical environment that existed on Mars 4 Gyr ago, particularly as it related to the nature of the global climate, the origin of the valley networks, the geologic and mineralogic evolution of the surface, the aqueous geochemistry of groundwater, and the existence of local environments that may have been conducive to the development of indigenous life and the preservation of its signature in the geologic record; and (2) to discuss what observations or experiments might he included in future spacecraft missions to test the ideas and expectations arising from purpose 1. While pertinent issues of early atmospheric and solar evolution were also addressed, the primary discussion at the conference focused on the evidence and constraints provided by the geologic records of Earth, the Moon, and Mars and analysis of the SNC meteorites. The papers contained in this special section span the full range of these topics, including the stability of the early atmosphere to erosion by the solar wind, the geologic environment from which the SNC meteorites originated, geomorphic evidence regarding the nature of the early Martian climate and hydrologic cycle, the potential impact of the past and present environment on the preserved signature of ancient life, and a discussion of the capabilities of a lander-based X ray diffraction and fluorescence instrument to assess the potential for past fossilization from the mineralogy of the current local surface environment. The issues raised at the conference, and by the papers included in this special section, will be the focus of ongoing attention as the intensity and scope of Mars exploration increases over the next decade.

NASA Center ARC↗

NASA NTRS2004

Hydrogen and Ferric Iron in Mars Materials

Knowledge of oxygen and hydrogen fugacity is of paramount importance in constraining phase equilibria and crystallization processes of melts, as well as understanding the partitioning of elements between the cope and silicate portions of terrestrial planets. H and Fe(3+) must both be analyzed in order to reconstruct hydrogen and oxygen fugacities on Mars. To date, SIMS data have elucidated D/H and H contents of hydrous phases in SNC meteorites, but until now anhydrous martian minerals have not been systematically examined for trace hydrogen. Ferric iron has been quantified using XANES in many martian phases, but integrated studies of both Fe(3+) and H on the same spots are really needed to address the H budget. Finally, the effects of shock on both Fe(3+) and H in hydrous and anhydrous phases must be quantified. Thus, the overall goal of this research was to understand the oxygen and hydrogen fugacities under which martian samples crystallized. In this research one-year project, we approached this problem by 1) characterizing Fe(3+) and H contents of SNC meteorites using both bulk (Mossbauer spectroscopy and uranium extraction, respectively) and microscale (synchrotron micro-XANES and SIMS) methods; 2) relating Fe(3+) and H contents of martian minerals to their oxygen and hydrogen fugacities through analysis of experimentally equilibrated phases (for pyroxene) and through study of volcanic rocks in which the oxygen and hydrogen fugacities can be independently constrained (for feldspar); and 3) studying the effects of shock processes on Fe(3+) and H contents of the phases of interest. Results have been used to assess quantitatively the distribution of H and Fe(3+) among phases in the martian interior, which will better constrain the geodynamic processes of the interior, as well as the overall hydrogen and water budgets on Mars. There were no inventions funded by this research.

Dyar, Melinda D.↗

NASA NTRS2005

Isotopic Constraints on the Petrology of Martian Meteorites

The SNC (martian) meteorites exhibit complex isotopic characteristics that yield information both about the ages of individual meteorites as well as information about the petrogenetic processes that produced both individual samples and about the origins of suites and sub-suites within the SNC clan. Here I review these data, reiterate earlier interpretations, and offer some new conclusions.

Jones, J. H.↗

NASA NTRS2008

Duration of a Magma Ocean and Subsequent Mantle Overturn in Mars: Evidence from Nakhlites

It is now generally accepted that the heat produced by accretion, short-lived radioactive elements such as Al-26, and gravitational energy from core formation was sufficient to at least partially melt the silicate portions of terrestrial planets resulting in a global-scale magma ocean. More particularly, in Mars, the geochemical signatures displayed by shergottites, are likely inherited from the crystallization of this magma ocean. Using the short-lived chronometer Sm-146 - Nd-142 (t(sup 1/2) = 103 Myr), the duration of the Martian magma ocean (MMO) has been evaluated to being less than 40 Myr, while recent and more precise ND-142/ND-144 data were used to evaluate the longevity of the MMO to approximately 100 Myr after the solar system formation. In addition, it has been proposed that the end of the crystallization of the MMO may have triggered a mantle overturn, as a result of a density gradient in the cumulate layers crystallized at different levels. Dating the mantle overturn could hence provide additional constraint on the duration of the MMO. Among SNC meteorites, nakhlites are characterized by high epsilon W-182 of approximately +3 and an epsilon Nd-142 similar to depleted shergottites of +0.6-0.9. It has hence been proposed that the source of nakhlites was established very early in Mars history (approximately 8-10 Myr). However, the times recorded in HF-182-W-182 isotope system, i.e. when 182Hf became effectively extinct (approximately 50 Myr after solar system formation) are less than closure times recorded in the Sm-146-Nd-142 isotope system (with a full coverage of approximately 500 Myr after solar system formation). This could result in decoupling between the present-day measured epsilon W-182 and epsilon Nd-142 as the SM-146 may have recorded later differentiation events in epsilon ND-142 not observed in epsilon W-182 values. With these potential complexities in short-lived chronological data for SNC's in mind, new Hf-176/Hf-177, Nd-143/Nd-144 and Nd-142/Nd-144 were obtained for three nakhlites (Nakhla, MIL03346 and Yamato000593). These new data are combined with previous epsilon W-182 data, to investigate potential discrepancies between the Hf-182-W-182 and Sm-146-Nd-142 systematics, and the relationship between the source of nakhlites and a crystallizing magma ocean

Debaille, V.↗

NASA NTRS2006

Observation and Analysis of In Situ Carbonaceous Matter in Naklha

The search for indigenous carbon components on Mars has been a challenge. The first attempt was the Viking GC-MS in situ experiment which gave inconclusive results at two sites on Mars [1]. After the discovery that the SNC meteorites were from Mars [2], [3-5] reported C isotopic compositional information which suggested a reduced C component present in the martian meteorites. [6 & 7] reported the presence of reduced C components (i.e., polycyclic aromatic hydrocarbons) associated with the carbonate globules in ALH84001. Jull et al. [8] noted in Nakhla there was an acid insoluble C component present with more than 75% of its C lacking any C-14, which is modern-day carbon. This C fraction was believed to be either indigenous martian or ancient meteoritic carbon. Fisk et al. [9, 10] have shown textural evidence along with C-enriched areas within fractures in Nakhla and ALH84001. To further understand the nature of possible indigenous reduced C components, we have carried out a variety of measurements on martian meteorites. For this presentation we will discuss only the Nakhla results. Interior samples from the Nakhla SNC meteorite, recently made available by the British Museum of Natural History, were analyzed. Petrographic examination [11, McKay et al., this volume] of Nakhla showed evidence of fractures (approx.0.5 micron wide) filled with dark brown to black dendritic material [Fig. 1] with characteristics similar to those observed by [10]. Iddingsite is also present along fractures in olivine. Fracture filling and dendritic material was examined by SEM-EDX, TEM-EDX, Focused Electron Beam microscopy, Laser Raman Spectroscopy, Nano-SIMS Ion Micro-probe, and Stepped-Combustion Static Mass Spectrometry.

Gibson, E. K., Jr.↗

NASA NTRS2010

Is EETA79001 Lithology B A True Melt Composition?

EETA79001 is a member of the SNC (shergottite, nakhlite, chassignite) group of Martian meteorites. Most SNC meteorites are cumulates or partial cumulates [1] inhibiting calculation of parent magma compositions; only two (QUE94201 and Y- 980459) have been previously identified as true melt compositions. The goal of this study is to test whether EETA79001-B may also represent an equilibrium melt composition, which could potentially expand the current understanding of martian petrology.

Arauza, S. J.↗

NASA NTRS2010

Organic Carbon Exists in Mars Meteorites: Where is it on the Martian Surface?

The search for organic carbon on Mars has been a major challenge. The first attempt was the Viking GC-MS in situ experiment which gave inconclusive results at two sites oil. After the discovery that the SNC meteorites were from Mars, reported C isotopic compositional information which suggested a reduced C component present in the Martian meteorites reported the presence of reduced C components (i.e., polycyclic aromatic hydrocarbons) associated with the carbonate globules in ALH84001. Jull et al. noted in Nakhla there was acid insoluble C component present with more than 75% of its C lacking any C-14, which is modern-day terrestrial carbon. This C fraction was believed to be either indigenous martian or ancient meteoritic carbon. Fisk et al. have shown textural evidence along with C-enriched areas within fractures in Nakhla and ALH84001. Westall et al. have shown the presence of a large irregular fragment of organic material completely embedded within a chip of ALH84001. Interior samples from the Naklnla SNC made available by the British Museum of Natural History, were analyzed. Petrographic examination of Nakhla showed evidence of fractures (approx.0.5 microns wide) filled with dark brown to black dendritic material with characteristics similar to those observed by. Iddingsite is also present along fractures in olivine. Fracture filling and dendritic material was examined by SEM-EDX, TEM-EDX, Focused Electron Beam microscopy, Laser Raman Spectroscopy, Nano-SIMS Ion Micro-probe, and Stepped-Combustion Static Mass Spectrometry. Observations from the first three techniques are discussed.

McKay, D. S.↗

NASA NTRS2011

ALH84001: The Key to Unlocking Secrets About Mars-15 Years and Counting

From the December 27, 1984 discovery of ALH84001, and its subsequent identification as a sample of Mars in 1993, mystery and debate has surrounded the meteorite [1]. With the realization that the ALH84001 sample was a orthopyroxenite and one of the oldest SNC meteorites (approx.4.09 Ga) [2] available to study, important and critical information about the Martian hydrosphere and atmosphere along with the early history and evolution of the planet could be obtained by studying the unique carbonate globules (approx.3.9 Ga) in the sample [3]. The initial work showed the carbonate globules were deposited within fractures and cracks in the host-orthopyroxene by low-temperature aqueous fluids [4]. Ideas that the carbonates were formed at temperatures [5] approaching 800 C were ruled out by later experiments [6]. The 1996 announcement by McKay et al. [7] that ALH84001 contained features which could be interpreted as having a biogenic origin generated considerable excitement and criticism. The NASA Administrator Dan Golden said the 1996 ALH84001 announcement saved NASAs Mars planetary exploration program and injected $6 billion dollars over five years into the scientific research and analysis efforts [8]. All of the original four lines of evidence for possible biogenic features within ALH84001 offered by McKay et al. have withstood the test of time. Criticism has been directed at the interpretation of the 1996 analytical data. Research has expanded to other SNC meteorites. Despite the numerous attacks on the ideas, the debate continues after 15 years. The 2009 paper by Thomas-Keprta et al. [9] on the origins of a suite of magnetites within the ALH84001 has offered strong arguments that some of the magnetites can only be formed by biogenic processes and not from thermal decomposition or shock events which happened to the meteorite. NASA s Astrobiology Institute was formed from the foundation laid by the ALH84001 hypothesis of finding life beyond the Earth. The strong astrobiology outreach programs have expanded because of the work done on the Martian meteorites. De-spite the criticism on the biogenic-like features in ALH84001, the meteorite has opened a window into the early history of Mars. Clearly low-temperature fluids have left their signatures within the ALH84001 meteorite and subsequent cratering events on Mars have been recorded on observable features within the meteorite. The 15 years of detailed study on ALH84001 and its unique carbonate globules have clearly shown formational and secondary processes at work on Mars. Now we need a well-documented Mars sample return mission.

Gibson, Everett K.↗

NASA NTRS2011

ALH84001: The Key to Unlocking Secrets About Mars-15 Years and Counting

From the December 27, 1984 discovery of ALH84001, and its subsequent identification as a sample of Mars in 1993, mystery and debate has surrounded the meteorite. With the realization that the ALH84001 sample was a orthopyroxenite and one of the oldest SNC meteorites (~4.09 Ga) available to study, important and critical information about the Martian hydrosphere and atmosphere along with the early history and evolution of the planet could be obtained by studying the unique carbonate globules (~3.9 Ga) in the sample. The initial work showed the carbonate globules were deposited within fractures and cracks in the host-orthopyroxene by low-temperature aqueous fluids. Ideas that the carbonates were formed at temperatures approaching 800oC were ruled out by later experiments. The 1996 announcement by McKay et al. that ALH84001 contained features which could be interpreted as having a biogenic origin generated considerable excitement and criticism. The NASA Administrator Dan Golden said the 1996 ALH84001 announcement saved NASA s Mars planetary exploration program and injected $6 billion dollars over five years into the scientific research and analysis efforts. All of the original four lines of evidence for possible biogenic features within ALH84001 offered by McKay et al. have withstood the test of time. Criticism has been directed at the interpretation of the 1996 analytical data. Research has expanded to other SNC meteorites. Despite the numerous attacks on the ideas, the debate continues after 15 years. The 2009 paper by Thomas-Keprta et al. on the origins of a suite of magnetites within the ALH84001 has offered strong arguments that some of the magnetites can only be formed by biogenic processes and not from thermal decomposition or shock events which happened to the meteorite. NASA s Astrobiology Institute was formed from the foundation laid by the ALH84001 hypothesis of finding life beyond the Earth. The strong astrobiology outreach programs have expanded because of the work done on the Martian meteorites. Despite the criticism on the biogenic-like features in ALH84001, the meteorite has opened a window into the early history of Mars. Clearly low-temperature fluids have left their signatures within the ALH84001 meteorite and subsequent cratering events on Mars have been recorded on observable features within the meteorite. The 15 years of detailed study on ALH84001 and its unique carbonate globules have clearly shown formational and secondary processes at work on Mars. The evidence for biogenic processes operating on early Mars along with ground water activity within the last 15% of the life of Mars offers clear evidence that another niche for life may be possible within our solar system. Now we need a well-documented Mars sample return mission.

Gibson, Everett K.↗

NASA NTRS2009

Proceedings of the 40th Lunar and Planetary Science Conference

The 40th Lunar and Planetary Science Conference included sessions on: Phoenix: Exploration of the Martian Arctic; Origin and Early Evolution of the Moon; Comet Wild 2: Mineralogy and More; Astrobiology: Meteorites, Microbes, Hydrous Habitats, and Irradiated Ices; Phoenix: Soil, Chemistry, and Habitability; Planetary Differentiation; Presolar Grains: Structures and Origins; SPECIAL SESSION: Venus Atmosphere: Venus Express and Future Missions; Mars Polar Caps: Past and Present; SPECIAL SESSION: Lunar Missions: Results from Kaguya, Chang'e-1, and Chandrayaan-1, Part I; 5 Early Nebula Processes and Models; SPECIAL SESSION: Icy Satellites of Jupiter and Saturn: Cosmic Gymnasts; Mars: Ground Ice and Climate Change; SPECIAL SESSION: Lunar Missions: Results from Kaguya, Chang'e-1, and Chandrayaan-1, Part II; Chondrite Parent-Body Processes; SPECIAL SESSION: Icy Satellites of Jupiter and Saturn: Salubrious Surfaces; SNC Meteorites; Ancient Martian Crust: Primary Mineralogy and Aqueous Alteration; SPECIAL SESSION: Messenger at Mercury: A Global Perspective on the Innermost Planet; CAIs and Chondrules: Records of Early Solar System Processes; Small Bodies: Shapes of Things to Come; Sulfur on Mars: Rocks, Soils, and Cycling Processes; Mercury: Evolution and Tectonics; Venus Geology, Volcanism, Tectonics, and Resurfacing; Asteroid-Meteorite Connections; Impacts I: Models and Experiments; Solar Wind and Genesis: Measurements and Interpretation; Mars: Aqueous Processes; Magmatic Volatiles and Eruptive Conditions of Lunar Basalts; Comparative Planetology; Interstellar Matter: Origins and Relationships; Impacts II: Craters and Ejecta Mars: Tectonics and Dynamics; Mars Analogs I: Geological; Exploring the Diversity of Lunar Lithologies with Sample Analyses and Remote Sensing; Chondrite Accretion and Early History; Science Instruments for the Mars Science Lander; . Martian Gullies: Morphology and Origins; Mars: Dunes, Dust, and Wind; Mars: Volcanism; Early Solar System Chronology; Seek Out and Explore: Upcoming and Future Missions; Mars: Early History and Impact Processes; Mars Analogs II: Chemical and Spectral; Achondrites and their Parent Bodies; and Planning for Future Exploration of the Moon The poster sessions were: Lunar Missions: Results from Kaguya, Chang'e-1, and Chandrayaan-1; LRO and LCROSS; Geophysical Analysis of the Lunar Surface and Interior; Remote Observation and Geologic Mapping of the Lunar Surface; Lunar Spectroscopy; Venus Geology, Geophysics, Mapping, and Sampling; Planetary Differentiation; Bunburra and Buzzard Coulee: Recent Meteorite Falls; Meteorites: Terrestrial History; CAIs and Chondrules: Records of Early Solar System Processes; Volatile and Organic Compounds in Chondrites; Crashing Chondrites: Impact, Shock, and Melting; Ureilite Studies; Petrology and Mineralogy of the SNC Meteorites; Martian Meteorites; Phoenix Landing Site: Perchlorate and Other Tasty Treats; Mars Polar Atmospheres and Climate Modeling; Mars Polar Investigations; Mars Near-Surface Ice; Mars: A Volatile-Rich Planet; Mars: Geochemistry and Alteration Processes; Martian Phyllosilicates: Identification, Formation, and Alteration; Astrobiology; Instrument Concepts, Systems, and Probes for Investigating Rocks and Regolith; Seeing is Believing: UV, VIS, IR, X- and Gamma-Ray Camera and Spectrometer Instruments; Up Close and Personal: In Situ Analysis with Laser-Induced Breakdown Spectroscopy and Mass Spectrometry; Jupiter and Inscrutable Io; Tantalizing Titan; Enigmatic Enceladus and Intriguing Iapetus; Icy Satellites: Cryptic Craters; Icy Satellites: Gelid Geology/Geophysics; Icy Satellites: Cool Chemistry and Spectacular Spectroscopy; Asteroids and Comets; Comet Wild 2: Mineralogy and More; Hypervelocity Impacts: Stardust Models, LDEF, and ISPE; Presolar Grains; Early Nebular Processes: Models and Isotopes; Solar Wind and Genesis: Measurements and Interpretation; Education and Public Outreach; Mercury; Pursuing Lunar Exploration; Sources and Eruptionf Lunar Basalts; Chemical and Physical Properties of the Lunar Regolith; Lunar Dust and Transient Surface Phenomena; Lunar Databases and Data Restoration; Meteoritic Samples of the Moon; Chondrites, Their Clasts, and Alteration; Achondrites: Primitive and Not So Primitive; Iron Meteorites; Meteorite Methodology; Antarctic Micrometeorites; HEDs and Vesta; Dust Formation and Transformation; Interstellar Organic Matter; Early Solar System Chronology; Comparative Planetology; Impacts I: Models and Experiments; Impacts II: Craters and Ejecta; Mars: Volcanism; Mars: Tectonics and Dynamics; Martian Stratigraphy: Understanding the Geologic History of Mars Through the Sedimentary Rock Record; Mars: Valleys and Valley Networks; Mars: Aqueous Processes in Valles Marineris and the Southern Highlands; Mars: Aqueous Geomorphology; Martian Gullies: Morphology and Origins; Mars: Dunes, Dust, and Wind; Mars: Remote Sensing; Mars: Geologic Mapping, Photogrammetry, and Cratering; Martian Mineralogy: Constraints from Missions and Laboratory Investigations; Mars Analogs: Chemical and Physical; Mars Analogs: Sulfates and Sulfides; Missions: Approaches, Architectures, Analogs, and Actualities; Not Just Skin Deep: Electron Microscopy, Heat Flow, Radar, and Seismology Instruments and Planetary Data Systems, Techniques, and Interpretation.

Source record↗

NASA NTRS2016

Calibration of the Fluorine, Chlorine and Hydrogen Content of Apatites With the ChemCam LIBS Instrument

Determining the composition of apatites is important to understand the behavior of volatiles during planetary differentiation. Apatite is an ubiquitous magmatic mineral in the SNC meteorites. It is a significant reservoir of halogens in these meteorites and has been used to estimate the halogen budget of Mars. Apatites have been identified in sandstones and pebbles at Gale crater by ChemCam, a Laser-Induced Breakdown Spectroscometer (LIBS) instrument onboard the Curiosity rover. Their presence was inferred from correlations between calcium, fluorine (using the CaF molecular band centered near 603 nm, whose detection limit is much lower that atomic or ionic lines and, in some cases, phosphorus (whose detection limit is much larger). An initial quantification of fluorine, based on fluorite (CaF2)/basalt mixtures and obtained at the LANL laboratory, indicated that the excess of F/Ca (compared to the stoichiometry of pure fluorapatites) found on Mars in some cases could be explained by the presence of fluorite. Chlorine was not detected in these targets, at least above a detection limit of 0.6 wt% estimated from. Fluorapatite was later also detected by X-ray diffraction (with CheMin) at a level of approx.1wt% in the Windjana drill sample (Kimberley area), and several points analyzed by ChemCam in this area also revealed a correlation between Ca and F. The in situ detection of F-rich, Cl-poor apatites contrasts with the Cl-rich, F-poor compositions of apatites found in basaltic shergottites and in gabbroic clasts from the martian meteorite NWA 7034, which were also found to be more Cl-rich than apatites from basalts on Earth, the Moon, or Vesta. The in situ observations could call into question one of the few possible explanations brought forward to explain the SNC results, namely that Mars may be highly depleted in fluorine. The purpose of the present study is to refine the calibration of the F, Cl, OH and P signals measured by the ChemCam LIBS instrument, initiated for F, for Cl in soils, for P, and estimate their limit of detection. For this purpose, different types of apatites and mixtures of basalt powder and apatites were analyzed using ChemCam Engineering Qualification Model (EQM) at IRAP, Toulouse. The present abstract presents the initial results from the laboratory analyses. Differences between the response function of the EQM and the Flight Model of ChemCam are still to be refined to apply these new results to the Martian dataset.

Meslin, P.-Y.↗

NASA NTRSDate not supplied

Modal Test and Model Correlation of NASA Plum Brook Station Mechanical Vibration Facility Head Expander –Lessons Learned from the Perspective of an Early-Career Engineer

In preparation for the Sierra Nevada Corporation’s (SNC) Dream Chaser spacecraft vibration test campaign at the Mechanical Vibration Facility (MVF) at NASA Plum Brook Station (PBS) in Sandusky, Ohio, a test-verified model of MVF is needed in order to be able to perform accurate pretest analysis used for determining response limits and abort levels. MVF was designed to vibration test MPCV Orion and was used to perform the system level vibration test of the European Service Module Structural Test Article (E-STA) in 2016. MVF is comprised of an 18 ft diameter annulus table that is driven with sixteen hydraulic vertical actuator assemblies and four hydraulic horizontal actuator assemblies, which allow it to perform single axis vibration testing in the vertical axis and in each of the two orthogonal horizontal axes without the need for reconfiguring the test article. A head expander for the MVF Table has been designed and built that fills in the center opening providing a continuous flat mounting surface with a maximum diameter of 16.25feet that expands the vibration testing capabilities of MVF. The MVF Table with this head expander will be used during the SNC Dream Chaser spacecraft vibration test campaign. Therefore, a critical element in a test-verified model of the MVF will be a test correlated finite element model (FEM) of the head expander. To obtain this, engineers from the Structural Dynamics Lab (SDL) at NASA Glenn Research Center (GRC) in Cleveland, Ohio performed a modal pretest analysis, conducted a modal test in July 2019, and most recently correlated the head expander finite element model to the modal test data up to 300 Hz. From the initial test preparations to the final delivery of a correlated finite element model, all efforts mentioned were led by the same early-career engineers at NASA GRC. From the viewpoint of an early-career engineer, lessons learned about modal pretest analysis, modal testing, and finite element model correlation of the MVF Table expander head will be presented and discussed. This will include the importance of understanding the limitations of using uncorrelated finite element models in the modal pretest analysis and planning, the importance of orthogonality metrics in judging adequacy and accuracy of test mode shapes, and the importance of having the FEM match the as built hardware in the model correlation effort.

Emma L Pierson↗

NASA NTRS2021

Chapter 3: Petrologic Evolution of Martian Volcanism and Clues from Meteorites

The formation and evolution of the Martian surface, and ultimately the fate of its various volcanic regions, are revealed in the chemistry of Martian meteorites, and the mineralogy of the crust. The interpretation of the chemistry from remote sensing instrumentation from orbiters and landers/rovers has been strongly influenced by our knowledge of geochemical processes on Earth, the Moon, and other asteroidal, rocky bodies [1]. The composition, and thus evolution, of the Martian crust has been resultant from SNC (shergottite –nakhlite –chassignite) meteorites, which are the igneous counterpart of rocks of Martian origin [2, 3, 4]. These meteorites are chemically similar to terrestrial basalts and cumulates, with the exception of higher concentrations of iron and other volatile elements (i.e., phosphorous, chlorine, chalcophile) [5]. From Tuff et al. [2], most Martian meteorites have relatively young crystallization ages ranging from 1.4 billion years to 180 million years ago [6]. These are considered to be derived from young, usually lightly-cratered volcanic regions, such as the Tharsis volcanic region [6, 7]. Though mainly basaltic in composition, surface rocks are richer in nickel and sulfur with lower manganese/iron ratios than Martian meteorites [2], which can be explained by the differences in oxygen fugacity during melting of the sulfur-rich mantle [2, 8]. From this difference, Martian meteorites are tied to surface rocks through an early (3.7 billion years ago) oxidation of the uppermost mantle, producing the more recent volcanic rocks [2]. The variety of compositions from basaltic, olivine volcanic rocks through pyroxene-cumulate nakhlites and peridotite chassignites, enable the hypothetical reconstructions of the silicic evolution of Mars similar to techniques used on Earth [2, 5, 9]. In this chapter, we will explore the basic Martian composition of the crust and mantle in regards to volcanic regions, the crustal components of the North-South dichotomy, and more detail of the SNC meteorites in relation to the evolution of the mantle for volcanism.

C Ahrens↗

NASA NTRS1983

Regolith breccia Allan Hills A81005 - Evidence of lunar origin, and petrography of pristine and nonpristine clasts

It is shown that the ratios of MnO/FeO in pyroxene, texture (abundant brown and swirly glass, which are typical of lunar regolith breccias) and overall composition (approximately 75 percent plagioclase) indicate a lunar origin for the regolith breccia Allan Hills A81005, presumably from an unsampled region of the moon. The rock is found to differ in detail from other regolith samples; for example, it has exceptionally low contents of Na and KREEP. In addition, a pristine clast is found to contain exceptionally coarse augite in comparison with similar Apollo samples. It is found that ALHA81005 is not perceptibly more shocked than typical Apollo regolith breccias. It is concluded that the discovery of this rock on earth strengthens the suggestion that SNC achondrites were derived by impact ejection from Mars.

Warren, P. H.↗

NASA NTRS1983

Siderophile, lithophile and mobile trace elements in the lunar meteorite Allan Hills 81005

The content of trace elements (siderophile Co, Au, As, Sb, Ga; chalcophile/mobile Se, Te, Bi, In, Ag, Zn, Tl, Cd; lithophile Rb, Cs, U) is investigated to ascertain whether the meteorite is of lunar origin. Five elements reflect lunar crustal processes, whereas the remaining 11 siderophile and mobile elements suggest 1.4 + or - 0.5 percent micrometeorite admixture or enrichment by thermal redistribution on the moon. It is found that the impact launching of ALH A81005 to the earth was not attended by substantial shock loading. A Martian origin for severely shocked SNC meteorites is therefore considered plausible.

Verkouteren, R. M.↗

NASA NTRS1983

Brachina - A new type of meteorite, not a Chassignite

The results of a study of the small achondrite found in 1974 near Brachina, Australia are presented and discussed. Trace element data for Brachina were found to be quite different from that for Chassigny. The major differences are higher FeO/MnO, Ge/Al, and K/La ratios, W depletion, high siderophile content, near-horizontal REE pattern at about 1 x chondrite level, high refractory/nonrefractory metal ratios (e.g., Ir/Au), and chalcophile element depletion. Brachina's 4.5 billion year age and oxygen isotropic signature within the eucritic field further suggest that it is not related to Chassigny or SNC meteorites, though it may be related to primitive meteorites, such as silicate inclusions in IAB irons and winonaites.

Nehru, C. E.↗

NASA NTRS1984

Lunar and Planetary Science Conference, 14th, Houston, TX, March 14-18, 1983, Proceedings. Part 2

Various topics on the geology and evolution of the moon, planets, and meteorites are addressed. Some of the subjects considered include: Venusian rocks, impact cratering rate in recent time, ice and debris in Martian fretted terrain, geological evolution of Ganymede's Galileo Regio, and Lu-Hf and Sm-Nd evolution in lunar mare basalts. Also discussed are: ages and cosmic ray exposure history of moon rocks, U-Pb geochronology of zircons from lunar breccia, petrologic comparisons of Cayley and Descartes, chemistry and origin of chondrites and condrules, and the petrogenesis of SNC meteorites.

Boynton, W. V.↗

NASA NTRS1985

Impact Cratering Calculations

Impact cratering, both normal and oblique, on planetary surfaces is discussed and energy partitioning, ejecta distribution, (both with regard to size, velocity, energy content, and size sorting), the condensation physics of impact induced vapor, and the loss of planetary atmospheres during accretion of terrestrial and icy planets are considered. The possible origin of SNC meteorites, impact into porous regolith, equation of state of water and ice, and a possible model for the accretion of the Jovian and Saturnian satellites are examined.

Ahrens, T. J.↗