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Low-density photodissociation regions

A theoretical parameter study of the temperature and chemical structure of photodissociation regions (PDRs) and their resultant spectrum is presented. The models, which solve for the chemical and thermal steady state of a one-dimensional slab exposed to an incident FUV flux, relate the observed line and continuum emission from these regions to physical parameters of interest. Intensities of numerous fine-structure lines, the molecular rotational transitions (C-12)O J = 1-0 and H2 0-0 S(0), and the dust continuum intensities at 60 and 100 microns are predicted, and the column density of FUV-pumped vibrationally excited H2 is estimated.

Hollenbach, David J.↗

Relative contributions of discrete and continuum absorption to the photodissociation of vibrationally excited O2 (v = 12-20)

In order to test the proposal that photodissociation of highly vibrationally excited O2 in the Schumann-Runge (SR) band is a source of upper stratospheric ozone, cross sections for the band and continuum absorption are calculated. Calculated maximum SR cross sections are in the 1-2 x 10 to the -18th sq cm range, with the O2(B) state contributing 2-3 orders of magnitude greater absorption than the 1 3Pi(u) state. For v-double prime = 12, it is shown that the SR band and continuum cross sections merge smoothly at 250 nm. It is shown that numerous processes, the most important of which is nonlinear photoabsorption, ultimately lead to the prediction that narrow laser line absorption in the 248-nm region should generate comparable O atom yields whether absorption is into the bands or the continuum. In the atmosphere, SR band absorption is the dominant process.

Saxon, R. P.↗

Far-infrared observations of M17SW - The clumpy structure of the photodissociation region

Forbidden O I 63-micron and forbidden Si II 35-micron fine-structure line emission in M17SW was mapped, and the intensities of the forbidden O I 63 and 146 microns, forbidden Si II 35 microns, and forbidden C II 158 microns were measured at four positions. New 50- and 100-micron continuum maps of the M17SW cloud at comparable resolution to the FIR line observations are presented. Analysis in terms of a homogeneous model yields an incident UV field of 56,000 habings, a density of 30,000 cu cm, and a temperature of about 300 K for the atomic gas. It is concluded that the M17SW photodissociation region is clumpy in nature. The observed forbidden Si II and high-J CO imply the presence of high-density clumps. The clumps dominate the emission in the forbidden O I, Si II, and high-level CO lines, while the forbidden C II, C I, and low-level CO arise mostly in the interclump gas. The extended (about 15 pc) forbidden C II and forbidden C I emission is attributed to the halo gas.

Meixner, Margaret↗

Models of clumpy photodissociation regions

FIR fine structure line and submillimeter line emissions important in the cooling of photodissociation regions (PDRs) as they would arise in clumpy regions are investigated with a simple two-component model for clumpy PDRs consisting of high-density clumps embedded in a lower density interclump medium. The effects of varying the densities of the clump and interclump material in a self-consistent manner are studied. It is found that, while the clump filling factor moderately affects the penetration of the UV field, the density of the interclump material is the most important factor in determining the penetration of the UV field. Observational evidence for the effects of clumpiness in PDRs is found in the spatially extended C II and C I forbidden line emissions which reveal the extent of the UV penetration, and in the observed high intensities of the high CO transitions which indicate the presence of high-density clumps.

Meixner, M.↗

Solar-pumped photodissociation iodine laser

The scientific feasibility of a solar-pumped iodine photodissociation laser for space applications is under investigation. Recently, a 2-W CW output for more than one hour was achieved using n-C3F7I vapor as the laser material and a vortex-stabilized argon arc as the light source.

Lee, J. H.↗

Anatomy of a Photodissociation Region: High angular resolution images of molecular emission in the Orion Bar

We present observations of the molecular component of the Orion Bar, a prototypical Photodissociation Region (PDR) illuminated by the Trapezium cluster. The high angular resolution (6 sec-10 sec) that we have achieved by combining single-dish and interferometric observations has allowed us to examine in detail the spatial and kinematic morphology of this region and to estimate the physical characteristics of the molecular gas it contains. Our observations indicate that this PDR can be essentially described as a homogeneously distributed slab of moderately dense material (approximately 5 x 10(exp 4)/cu cm), in which are embedded a small number of dense (greater than 10(exp 6)/cu cm) clumps. The latter play little or no role in determining the thickness and kinetic temperature structure of this PDR. This observational picture is largely supported by PDR model calculations for this region, which we describe in detail in this work. We also find our model predictions of the intensities of a variety of atomic and molecular lines to be in good general agreement with a number of previous observations.

Tauber, Jan A.↗

Relative emission-line strengths for the 146 and 63 micron transitions in O I and a comparison with far-infrared observations of photodissociation regions

Theoretical O I density-sensitive emission-line ratios R = I(2s(sup 2))(2p(sup 4))((sup 3)P(sub 0))-((2s(sup 2))(2p(sup 4))((sup 3)P(sub 1)))/I((2s(sup 2))(2p(sup 4))((sup 3)P(sub 1))-(2s(sup 2))(2p(sup 4))((sup 3)P(sub 2))) = I(146 micrometers)/I(63 micrometers) are presented for a range of temperatures (T = 100-10,000 K), neutral hydrogen densities (N(sub H) = 10(exp -2) to 10(exp 7)/cu cm) and radiation fields (G(sub 0) = 1-10(exp 6)) applicable to both photodissociation regions (PDRs) and H II regions and the diffuse ionized medium (DIM). The observed values of R for several PDRs, measured from far-infrared spectra obtained with the Kuiper Airborne Observatory (KAO), imply hydrogen densities which are in good agreement with those determined using other methods. This provides observational support for the validity of the theoretical O I line ratios, and hence the atomic data used in their derivation.

Keenan, F. P.↗

HCN and HCO(+) images of the photodissociation region in the Orion Bar

We present preliminary millimeter-wavelength images of the photodissociation region (PDR) in the Orion Bar, observed with the Berkeley- Illinois-Maryland array (BIMA). These new BIMA observations have attained 5 arc sec resolution in the J=l-O emission lines of HCO+ (formyl ion) and HCN (hydrogen cyanide). The results are compared with previous observations of the J=1-0 transition lines of (13)CO. We find that the HCO+ and HCN have different spatial distributions. HCN appears to lie primarily inside dense clumps of gas, which are defined by areas of intense (13)CO emission. However, the HCO+ emission appears to be only loosely associated with the surfaces of the gas clumps. We suggest that HCO+ abundance is enhanced by the presence of vibrationally excited H2 on the surfaces of dense clumps, and that the HCN abundance is attenuated by photo destruction outside the cores of dense clumps of gas.

Youngowl, Rolaine C.↗

Anatomy of the Photodissociation Region in the Orion Bar

Much of the interstellar gas resides in photodissociation regions whose chemistry and energy balance is controlled by the flux of far-ultraviolet radiation upon them. These photons can ionize and dissociate molecules and heat the gas through the photoelectric effect working on dust grains. These regions have been extensively modeled theoretically, but detailed observational studies are few. Mapping of the prominent Orion Bar photo-dissociation region at wavelengths corresponding to the carbon-hydrogen stretching mode of polycyclic aromatic hydrocarbons, the 1-0 S(l) line of molecular hydrogen, and the J = 1-0 rotational line of carbon monoxide allows the penetration of the far-ultraviolet radiation into the cloud to be traced. The results strongly support the theoretical models and show conclusively that the incident far-ultraviolet radiation field, not shocks as has sometimes been proposed, is responsible for the emission in the Orion Bar.

Tielens, A. G. G. M.↗

Far Infrared Line Profiles from Photodissociation Regions and Warm Molecular Clouds

This report summarizes the work done under NASA Grant NAG2-1056 awarded to the University of Colorado. The aim of the project was to analyze data obtained over the past several years with the University of Colorado far-infrared heterodyne spectrometer (Betz Boreiko 1993) aboard the Kuiper Airborne Observatory. Of particular interest were observations of CO and ionized carbon (C II) in photodissociation regions (PDRS) at the interface between UV-ionized H II regions and the neutral molecular clouds supporting star formation. These data, obtained with a heterodyne spectrometer having a resolution of 3.2 MHz, which is equivalent to a velocity resolution of 0.2 km/s at 60 microns and 1.0 km/s at 300 microns, were analyzed to obtain physical parameters such as density and temperature in the observed PDR. The publication resulting from the work reported here is appended. No inventions were made nor was any federally owned property acquired as a result of the activities under this grant.

Boreiko, R. T.↗

Far Infrared Line Profiles from Photodissociation Regions and Warm Molecular Clouds

This report summarizes the work done under NASA Grant NAG2-1056 awarded to the University of Colorado. The aim of the project was to analyze data obtained over the past several years with the University of Colorado far-infrared heterodyne spectrometer (Betz & Boreiko 1993) aboard the Kuiper Airborne Observatory. Of particular interest were observations of CO and ionized carbon (C II) in photodissociation regions (PDRs) at the interface between UV-ionized H II regions and the neutral molecular clouds supporting star formation. These data, obtained with a heterodyne spectrometer having a resolution of 3.2 MHz, which is equivalent to a velocity resolution of 0.2 km/s at 60 microns and 1.0 km/s at 300 microns, were analyzed to obtain physical parameters such as density and temperature in the observed PDR. The publication resulting from the work reported here is appended. No inventions were made nor was any federally owned property acquired as a result of the activities under this grant.

Boreiko, R. T.↗

Far Infrared Line Profiles from Photodissociation Regions and Warm Molecular Clouds

This report summarizes the work done under NASA Grant NAG2-1056 awarded to the University of Colorado. The aim of the project was to analyze data obtained over the past several years with the University of Colorado far-infrared heterodyne spectrometer aboard the Kuiper Airborne Observatory. Of particular interest were observations of CO and ionized carbon (C II) in photodissociation regions (PDRS) at the interface between UV-ionized H II regions and the neutral molecular clouds supporting star formation. These data, obtained with a heterodyne spectrometer having a resolution of 3.2 MHz, which is equivalent to a velocity resolution of 0.2 km s(exp -1) at 60 microns and 1.0 km s(exp -1) at 300 microns, were analyzed to obtain physical parameters such as density and temperature in the observed PDR.

Boreiko, R. T.↗

The Ratio of Ortho- to Para-H2 in Photodissociation Regions

We discuss the ratio of ortho- to para-H2 in photodissociation regions (PDRs). We draw attention to an apparent confusion in the literature between the ortho-to-para ratio of molecules in FUV-pumped vibrationally excited states and the total H2 ortho-to-para abundance ratio. These ratios are not the same because the process of FUV pumping of fluorescent H2 emission in PDRs occurs via optically thick absorption lines. Thus gas with an equilibrium ratio of ortho- to para-H2 equal to 3 will yield FUV-pumped vibrationally excited ortho-to-para ratios smaller than 3, because the ortho-H2 pumping rates are preferentially reduced by optical depth effects. Indeed, if the ortho and para pumping lines are on the "square root" part of the curve of growth, then the expected ratio of ortho and para vibrational line strengths is 3(sup 1/2) approximately 1.7, close to the typically observed value. Thus, contrary to what has sometimes been stated in the literature, most previous measurements of the ratio of ortho- to para-H2 in vibrationally excited states are entirely consistent with a total ortho-to-para ratio of 3, the equilibrium value for temperatures greater than 200 K. We present an analysis and several detailed models that illustrate the relationship between the total ratios of ortho- to para-H2 and the vibrationally excited ortho-to-para ratios in PDRs. Recent Infrared Space Observatory measurements of pure rotational and vibrational H2 emissions from the PDR in the star-forming region S140 provide strong observational support for our conclusions.

Sternberg, Amiel↗

Global Analysis of the Effects of Dust on the Photodissociation Rates

Aerosols scatter and absorb UV radiation and consequently either enhance or reduce the actinic fluxes and photolysis rates. Mineral dust particles are known to absorb UV radiation, but the impact on the photolysis rates is complicated by the optical properties dependency on the particle size, composition and wavelength. The high spatial and temporal variabilities of the dust size distribution add difficulties to the global analysis. The Georgia Tech/Goddard Global Ozone Chemistry Aerosol Radiation and Transport (GOCART) model has been used to simulate several years of the global distribution of mineral dust in the troposphere. The optical parameters (extinction efficiency, single scattering albedo and asymmetry parameter) of the seven particle sizes (from 0.1 to 5 microns), transported by the model, have been inserted in the Tropospheric Ultraviolet-Visible (TUV) radiation model version 4. The photodissociation rates of J(N02) and J(03 to O(1D)) have been calculated with TUV-4 with and without dust particles on the global scale. The effects of dust on J(N02) and J(03) will be analyzed with an emphasis on the difference between major dust sources in Africa and Asia.

Ginoux, Paul↗

Photodissociation Regions

The interstellar medium of galaxies is the reservoir out of which stars are born and into which stars inject newly created elements as they age. The physical properties of the interstellar medium are governed in part by the radiation emitted by these stars. Far-ultraviolet (6 eV< hNu < 13.6 eV) photons from massive stars dominate the heating and influence the chemistry of the neutral atomic gas and much of the molecular gas in galaxies. Predominantly neutral regions of the interstellar medium in which the heating and chemistry are regulated by far ultraviolet photons are termed Photodissociation Regions (PDRs). These regions are the origin of most of the non-stellar infrared (IR) and the millimeter and submillimeter CO emission from galaxies. The importance of PDRs has become increasingly apparent with the advances in IR and submillimeter astronomy. The IR emission from PDRs includes fine structure lines of C, C(+) and O; rovibrational lines of H2; rotational lines of CO; broad mid-IR features of polycyclic aromatic hydrocarbons; and a luminous underlying IR continuum from interstellar dust. The transition of H to H2 and C(+) to CO occurs within PDRs. Comparison of observations with theoretical models of PDRs enables one to determine the density and temperature structure, the elemental abundances, the level of ionization, and the radiation field. PDR models have been applied to interstellar clouds near massive stars, planetary nebulae, red giant outflows, photoevaporating planetary disks around newly formed stars, diffuse clouds, the neutral intercloud medium, and molecular clouds in the interstellar radiation field-in summary, much of the interstellar medium in galaxies. Theoretical PDR models explain the observed correlations of the [CII] 158, micrometers with the CO J=1-0 emission, the CO J=1-0 luminosity with the interstellar molecular mass, and the [CII] 158 micrometers plus [OI] 63 micrometers luminosity with the IR continuum luminosity. On a more global scale, PDR models predict the existence of two stable neutral phases of the interstellar medium, elucidate the formation and destruction of star-forming molecular clouds, and suggest radiation-induced feedback mechanisms that may regulate star formation rates and the column density of gas through giant molecular clouds.

Hollenbach, David J.↗

PAHs as Probes of Photodissociation Regions in M17 and the Orion Bar

We have obtained narrow-band images of M17 SW and the Orion Bar in the PAH emission bands and pedestal (3.29, 3. 36, 3. 42 microns) The emission bands at 3.3 and 3.4 microns arise from the photodissociation regions (PDRs) between ionized gas and molecular clouds. In both M17 SW and the Orion Bar, the PDRs are nearly edge-on, providing excellent opportunities for comparing models of PDRs with observations. We observe an exponential drop in the strength of the 3.3 micron emission with a 1/e distance of 9 arcsec in Orion and 5 arcsec in M17 SW, in good agreement with previous observations. These results show that the two regions are very similar, and they imply that the mean density is 2.4 times higher in the Orion Bar than in the M17 SW PDR. However, we also find that in the Orion Bar, the ratio of the 3.4 micron emission to the 3.3 micron emission is consistent with the 1/e distance of 3 arcsec determined from PDR models fit to the molecular H and CO in the Orion Bar. We are presently investigating how the main band can imply that the UV field is dropping with a 1/e distance of 9 arcsec while the model PDR predicts a 1/e distance of 3 arcsec.

Sloan, G. C.↗

Probing the Photodissociation Region Toward HD200775

The illuminating source of the photodissociation region associated with the reflection nebula NGC7023 is HD200775. We probed the foreground atomic and molecular material through diagnostics observed in absorption against the background star.

abundance-ISM molecules reflection nebulae stars↗

Hydrogen Migration and Vinylidene Pathway for Formation of Methane in the 193 nm Photodissociation of Propene: CH3CH=CH2 and CD3CD=CD2

Photodissociation channels and the final product yields from the 193 nm photolysis of propene-h6 (CH2=CHCH3) and propene-d6 (CD2=CDCD3) have been investigated, employing gas chromatography, mass spectroscopy, and flame ionization (GC/MS/FID) detection methods. The yields of methane as well as butadiene relative to ethane show considerable variations when propene-h6 or propene-d6 are photolyzed. This suggests significant variances in the relative importance of primary photolytic processes and/or secondary radical reactions, occurring subsequent to the photolysis. Theoretical calculations suggest the potential occurrence of an intramolecular dissociation through a mechanism involving vinylidene formation, accompanied by an ethylenic H-migration through the pi-orbitals. This process affects the final yields of methane-h4 versus methane-d4 with respect to other products. The product yields from previous studies of the 193 nm photolysis of methyl vinyl ketone-h6 and -d6 (CH2=CHCOCH3, CD2=CDCOCD3), alternative precursors for generating methyl and vinyl radicals, are compared with the current results for propene.

Zhao, Yi-Lei↗