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At least 145 records · Page 8

Mass analysis of neutral particles and ions released during electrical breakdowns on spacecraft surfaces

A specialized spectrometer was designed and developed to measure the mass and velocity distributions of neutral particles (molecules and molecular clusters) released from metal-backed Teflon and Kapton films. Promising results were obtained with an insulation breakdown initiation system based on a moveable contact touching the insulated surfaces. A variable energy, high voltage pulse is applied to the contact. The resulting surface damage sites can be made similar in size and shape to those produced by a high voltage electron beam system operating at similar discharge energies. The point discharge apparatus was used for final development of several high speed recording systems and for measurements of the composition of the materials given off by the discharge. Results with this apparatus show evolution of large amounts of fluorocarbon fragments from discharge through Teflon FEP, while discharges through Kapton produce mainly very light hydrocarbon fragments at masses below about 80 a.m.u.

Kendall, B. R. F.↗

Laser-Assisted Analysis of Aerosol Particles

Proposed instrument makes rapid mass-spectrometric analyses of individual particles in aerosols. Each particle vaporized and ionized by intense laser pulse, which creates ions of minimum complexity. Ability to analyze single aerosol particles continuously makes technique suitable for detection of toxic aerosol particles on real-time basis and for identification of their sources.

Sinha, M. P.↗

Mass analysis of neutral particles and ions released during electrical breakdowns on spacecraft surfaces

Charged-particle fluxes from breakdown events were studied. Methods to measure mass spectra and total emitted flux of neutral particles were developed. The design and construction of the specialized mass spectrometer was completed. Electrical breakdowns were initiated by a movable blunt contact touching the insulating surface. The contact discharge apparatus was used for final development of two different high-speed recording systems and for measurements of the composition of the materials given off by the discharge. It was shown that intense instantaneous fluxes of neutral particles were released from the sites of electrical breakdown events. A laser micropulse mass analyzer showed that visible discoloration at breakdown sites were correllated with the presence of iron on the polymer side of the film, presumably caused by punch-through to the Inconel backing. Kapton samples irradiated by an oxygen ion beam were tested. The irradiated samples were free of surface hydrocarbon contamination but otherwise behaved in the same way as the Kapton samples tested earlier. Only the two samples exposed to oxygen ion bombardment were relatively clean. This indicates an additional variable that should be considered when testing spacecraft materials in the laboratory.

Kendall, B. R. F.↗

3D Finite Element Analysis of Particle-Reinforced Aluminum

Deformation in particle-reinforced aluminum has been simulated using three distinct types of finite element model: a three-dimensional repeating unit cell, a three-dimensional multi-particle model, and two-dimensional multi-particle models. The repeating unit cell model represents a fictitious periodic cubic array of particles. The 3D multi-particle (3D-MP) model represents randomly placed and oriented particles. The 2D generalized plane strain multi-particle models were obtained from planar sections through the 3D-MP model. These models were used to study the tensile macroscopic stress-strain response and the associated stress and strain distributions in an elastoplastic matrix. The results indicate that the 2D model having a particle area fraction equal to the particle representative volume fraction of the 3D models predicted the same macroscopic stress-strain response as the 3D models. However, there are fluctuations in the particle area fraction in a representative volume element. As expected, predictions from 2D models having different particle area fractions do not agree with predictions from 3D models. More importantly, it was found that the microscopic stress and strain distributions from the 2D models do not agree with those from the 3D-MP model. Specifically, the plastic strain distribution predicted by the 2D model is banded along lines inclined at 45 deg from the loading axis while the 3D model prediction is not. Additionally, the triaxial stress and maximum principal stress distributions predicted by 2D and 3D models do not agree. Thus, it appears necessary to use a multi-particle 3D model to accurately predict material responses that depend on local effects, such as strain-to-failure, fracture toughness, and fatigue life.

Shen, H.↗

A Preliminary Analysis of Calcifying Particles in the Serum and Prostates of Patients with Prostatic Inflammation

Chronic diseases of the prostate such as benign prostatic hyperplasia (BPH) & chronic pelvic pain syndrome (CPPS) have associated findings of chronic inflammation, despite a lack of causal relationship. Numerous attempts to define an infectious agent responsible for the clinical findings have been inconsistent. The possibility of an infectious agent, that has not been uncovered with routine culturing methods, forms the basis for this study. Serum from 940 healthy Finnish men were compared with serum from 40 Crohn's, 40 path dx prostatitis, & 40 with path dx carcinoma, using an enzyme-linked immunosorbant assay (ELISA), to detect antigens specific to Nanobacteria(NB) utilizing monoclonal antibodies (Ab) 5/3 and 8D10. This ELISA has not been validated for detecting NB-associated with clinical prostatic disease, yet cross-reactivity with other bacterial species is low. Immunohistochemistry was performed on de-paraffinized prostatic tissue slides, de-calcified with EDTA and stained with the DAKO Catalyzed Signal Amplification kit, employing 8D10 as the primary (target/antigen-detecting) Ab. The mean (plus or minus SD) & median concentrations of NB antigen (U/50 L) were 379.59 (plus or minus 219.28) & 640.00 for patients with prostatitis (BPH) vs 3.31 (plus or minus 3.55) & 2.94 for prostate adenocarcinoma, 1.88 (plus or minus 2.94) & 0.80 for Crohn's disease, & 7.43 (plus or minus 25.57) & 0.00 for patients with no clinical prostatic disease. Unpaired t-tests revealed statistically significant differences between the prostatitis (BPH) sera & each of the other groups with p less than 0.005, but no differences between the other groups themselves. Preliminary studies with immunohistochemistry & 3-D confocal microscopy reveal 16/24 tissue sections + for NB Ag in BPH vs. only 2/22 tissue sections with prostate cancer. The preliminary findings of this serum screening study suggest that NB antigen may be commonly found in the serum of patients with the pathological diagnosis of prostatitis. Preliminary immunohistologic studies, suggest that NB may be found within the gland itself at a higher rate in patients with BPH relative to patients with adenocarcinoma, however confirmatory studies with a more specific ELISA technique, primary cultures, & with larger numbers of patients in a prospective design are required to determine if 1) NB are a causative organism for clinical hyperplastic and inflammatory disease, & if 2) serological testing can be used to discriminate patients with nanobacterial-associated prostatic disease.

Jones, Jeffrey A.↗

Characterization and Analysis of Aerosol Particle Retention and Re-aerosolization from Hook-and-Loop Fasteners on the International Space Station

The extensive use of hook and loop fasteners aboard the International Space Station warrants careful examination of its contribution to indoor air pollution, as its fine fibers catch aerosol particles then re-aerosolize them upon being pulled apart, often within the breathing zone of astronauts. This problem is expanded by the lack of gravity because airborne particles larger than 1 micrometer do not settle. Instead these aerosols remain in the air until removed by filtration. Aerosol inhalation can have negative health effects, ranging from acute symptoms to long-term consequences, depending on particle sizes, mass and material composition. This study characterizes the size distribution, number concentration, and mass concentration of re-aerosolized debris generated by hook and loop fasteners taken from the stray light cover of the Microgravity Science Glovebox in the U.S. Laboratory of the ISS to understand the extent of its impact on air quality. Transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM), in conjunction with energy dispersive spectroscopy (EDS) were also used to characterize the morphology and composition of the particles.

Boyajian, Barbara↗

An alpha particle experiment for chemical analysis of the Martian surface and atmosphere.

An alpha particle experiment similar to the one performed successfully on the Surveyor lunar missions is described. It is designed to provide a chemical analysis of the Martian surface and atmosphere. Analyses of rocks of known and unknown compositions have been made under simulated Martian conditions. The accuracies attained are generally comparable to those of the Surveyor lunar analyses. Improvements have been achieved in determining carbon and oxygen, so that a few per cent of water or carbonates in rocks can be detected. Some aspects of the integration of such an experiment with the spacecraft, a possible mission profile, and some other problems associated with a soft-landing mission to Mars are discussed. The importance of such a chemical analysis experiment in answering current questions about the nature and history of Martian surface material and its suitability for life processes is presented.

Economou, T. E.↗

Development of test methods for scale model simulation of aerial applications in the NASA Langley Vortex Research Facility

As part of basic research to improve aerial applications technology, methods were developed at the Langley Vortex Research Facility to simulate and measure deposition patterns of aerially-applied sprays and granular materials by means of tests with small-scale models of agricultural aircraft and dynamically-scaled test particles. Interactions between the aircraft wake and the dispersed particles are being studied with the objective of modifying wake characteristics and dispersal techniques to increase swath width, improve deposition pattern uniformity, and minimize drift. The particle scaling analysis, test methods for particle dispersal from the model aircraft, visualization of particle trajectories, and measurement and computer analysis of test deposition patterns are described. An experimental validation of the scaling analysis and test results that indicate improved control of chemical drift by use of winglets are presented to demonstrate test methods.

Jordan, F. L., Jr.↗

Effect of including variable gas properties and entrained particles in the flow analysis of the ASRM nozzle

The objective of this study is to determine the effect of using constant gas properties for the analysis of the Advanced Solid Rocket Motor (ASRM) nozzle and to gain more understanding concerning those types of analysis which might require this additional complexity. Kinetics data for viscosity, thermal conductivity, specific heat, and specific heat ratio are extracted from the Solid Propellant Rocket Motor Performance Prediction Computer Program (SPP) and tabulated as a function of temperature. These tables are added to the Aerovisc computational fluid dynamics (CFD) code in place of the constant gas property values. The results of a CFD analysis of the ASRM 48 inch motor with constant gas properties will be compared with an analysis which uses variable gas properties. Mach number, surface pressure, and torque plots are presented. A full scale ASRM analysis using SPP with and without particle flow is presented.

Clayton, Curtis D.↗

The signature of parallel electric fields in a collisionless plasma

The presence of a parallel electric field in the magnetosphere should be apparent through its effect on particles. An analysis is made of particle trajectories in phase space for a steady state collisionless plasma. The analysis utilizes the concepts of distribution function, total energy, and magnetic moment because all three quantities are conserved in a steady state situation in the absence of collisions. Two methods are presented for using particle data to gain information on the potential distribution. The first method involves the use of measurements of both ion and electron distribution functions and invokes the principle of quasi-neutrality. The second method involves the observation of discontinuities in velocity space which can be interpreted in terms of the effect of the electric field on the apparent loss or source cone.

Whipple, E. C., Jr.↗

Utilization of the LS-APGD microplasma/orbitrap-FTMS booster system for detection and isotopic analysis of neodymium nanoparticles

Detection and isotopic analysis of particle populations has seen rapid growth across several application areas, including environmental analysis, nuclear forensics, and food safety. The ability to characterize the particles' unique elemental and isotopic fingerprints could provide information related to formation, processing history, and transport. Regarding nuclear forensics, isotopic analysis of particles derived from diverse materials is often used as a tool to trace the origin and processing history. Mass spectrometric-based techniques currently used for particle population analysis often suffer from limited mass resolution, particularly when dealing with real-world samples that are affected by isobaric and polyatomic interferences from the matrix. To address these analytical challenges, we propose a novel method utilizing the liquid sampling-atmospheric pressure glow discharge (LS-APGD) microplasma ionization source coupled to an ultrahigh resolution Orbitrap mass spectrometer, further enhanced with the FTMS X2T Booster data acquisition and processing unit. The FTMS Booster enables acquisition of extended transient times of up to 3 s, significantly improving mass resolution, thereby reducing or even eliminating the need for prior separation of isobaric or polyatomic interferences. Additionally, the detection of low-abundance isotopes was improved by increasing the signal-to-noise (S/N) ratio. As proof of concept, this study demonstrates the feasibility of the LS-APGD/Orbitrap-FTMS X2T Booster platform for direct analysis using a suspension of well-characterized ∼120 nm neodymium particles. The quality of the isotope ratios values obtained from a few hundred particles were in good agreement with those obtained from homogeneous ionic solutions. These results highlight the potential of the LS-APGD/Orbitrap platform for rapid, accurate, and interference-resilient isotope ratio analysis of particle populations without the need for dissolution and subsequent chemical separations, offering significant advantages for nuclear forensics, safeguards, and environmental applications. The effort here also points to further paths forward, hopefully towards single particle (SP) analysis using microplasma ionization and the ultrahigh resolving power of the Orbitrap mass analyzer.

FTMS X2T booster↗

Development of test methods for scale model simulation of aerial applications in the NASA Langley Vortex Facility

Methods have been developed at the Langley Vortex Research Facility to simulate and measure the deposition patterns of aerially applied sprays and granular materials by means of tests with small-scale models of agricultural and dynamically scaled test particles. Interactions between the aircraft wake and the dispersed particles are studied with the aim of modifying wake characteristics and dispersal techniques in order to increase swath width, improve deposition pattern uniformity, and minimize drift. This paper examines the particle sizing analysis, test methods for particle dispersal from the model aircraft, and measurement and computer analysis of test deposition patterns. Results that indicate improved control of chemical drift by winglets are presented to demonstrate test methods.

Jordan, F. L., Jr.↗

Chemical components of the Apollo 15 regolith

The lunar regolith is a complex mixture of many components. Compositional data is used to identify and estimate the relative importance of the various chemical components of the regolith. The results and conclusions of four methods that were applied to Apollo 15 regolith data were reviewed to determine the important chemical components: graphical techniques, analysis of individual soil particles, factor analysis, and multicomponent mixing models. This synthesis relies heavily on data and conclusions from the literature as well as new analyses on 28 regolith breccia samples, 28 soil samples, and 50 individual 1 to 2 mm particles from soil 15272.

Korotev, R. L.↗

Irreducible Bhabha background in the detection of muonium-antimuonium conversion

Experiments such as MACS and the proposed MACE study muonium-antimuonium conversion by the energies of the final state 𝑒 ± . The 𝑒 + and 𝑒 − from an antimuonium decay tend to be nonrelativistic and relativistic, respectively, and vice versa for muonium. However, these 𝑒 ± can exchange their energies by hard Bhabha scattering, causing muonium to fake an antimuonium decay signal. We compute the rate for this background and find that, while negligible for MACE, it will become larger than the signal for conversion probabilities less than 10 −18 .

muonium↗

Search for the production of Higgs-portal scalar bosons in the NuMI beam using the MicroBooNE detector

We present the strongest experimental limits to date on the mixing angle, 𝜃, with which a new scalar particle, 𝑆, mixes with the Higgs field in the mass range 110 MeV < 𝑚 𝑆 <155 MeV. This result uses the MicroBooNE liquid argon time projection chamber to search for decays of these Higgs-portal scalar particles through the 𝑆 → 𝑒 + ⁢𝑒 − channel with the decays of kaons in the NuMI neutrino beam acting as the source of the scalar particles. The analysis uses an exposure of 2.01 × 10 21 protons on target of NuMI beam data including periods when the beam focusing system was configured to focus positively charged hadrons and separate periods when negatively charged hadrons were focused. The analysis searches for scalar particles produced from kaons decaying in flight in the beam’s decay volume and at rest in the target and absorber. At 𝑚 𝑆 =125 MeV (𝑚 𝑆 =150 MeV) we set a limit of 𝜃 < 3.19 ×10 −4 (𝜃 < 2.79 ×10 −4 ) at the 95% confidence level.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗