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At least 145 records · Page 8

Solid state NMR Investigation of Structural Differences in Pelletized DEB Samples

Upon hydrogenation of DEB pellets, which are composed of 75% virgin DEB and 25% of nanometer scale Pd catalysts on activated carbon, the uptake rate is strong, and the hydrogenation process is fast. However, the last batch of DEB pellets from KCNSC uptakes 10 times slower than traditional DEB pellets after ~ 50% consumption. In addition, the last batch of DEB getter pellets also became partially molten/wet during the hydrogenation process. This molten/wet phase during hydrogenation has only been observed with DPB and never with DEB formulation. DRIFT (diffuse reflection infrared Fourier transform) and XRD (x-ray diffraction) confirm that the questionable batch of DEB pellets from KCNSC are truly 100% DEB and not a mixture of DEB and DPB. So, there must be something different in the composition (like concentration and distribution of Pd) or interaction between the DEB molecules with the surrounding environment (activated carbon spreading medium). The possibility of some chemical contamination in the processing of this batch of questionable DEB getter pellets also comes to mind. Due to the ability of NMR to detect intermolecular interaction and sensitivity to small chemical concentration, NMR investigation was requested for this questionable batch of DEB getter pellets from KCNSC.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

How does pelleting alter the enzymatic digestibility of corn stover?

Pelleting of lignocellulosic biomass facilitates its transportation, storage and handling and offers opportunities to improve the enzymatic digestibility of pelleted biomass. Here, we report the impact of pelleting on the enzymatic digestibility of corn stover prior to pretreatment and associated substrate characteristics. Pelleting almost doubles the digestibility of unpretreated corn stover, from 8.2 to 15.5% glucan conversion, at 5% solid loading using 1 FPU Cellic CTec2 per g solids. Compositional analysis indicates that loose and pelleted corn stover have similar non-dissolvable compositions, although their extractives are slightly different. Enzymatic hydrolysis of washed corn stover after size reduction to normalize particle sizes and removal of extractives confirms that pelleting improves corn stover digestibility. Such differences may be explained by the decreased particle size, increased specific surface area, improved cellulose accessibility, and reduction of the polymer length of cellulose induced by pelleting. These findings help to design processing schemes for sustainable and efficient use of lignocellulose.

Chen, Xueli↗

Assessing Edge Localized Mode (ELM) Mitigation by Pellet Triggering in Smallest-Possible Affordable Robust Compact (SPARC) Low-Collisionality Discharges

Simulations of pellet edge-localized mode (ELM) triggering with the M3D-C1 code confirmed experimentally observed pellet mass thresholds in low-collisionality DIII-D discharges and predicted extremely large thresholds in ITER. The linear (static) and nonlinear (dynamic) workflows developed in this previous work are now applied to the SPARC tokamak. Multiple synthetic equilibria for the high-performance H-mode scenario are tested for MHD stability without pellets using the linear workflow and ELITE simulations; a stable one is identified. Pellets of various mass are injected along an inboard, near-midplane trajectory in the M3D-C1 simulation. No pellet mass threshold for ELM triggering can be found for realistic pellet masses, concluding that fueling from this injection location would not trigger ELMs. A poloidal scan of possible injection locations shows very high thresholds on the high-field side and reasonable thresholds on the low-field-side (LFS). Based on results of this work the location for a LFS injection was finalized in the SPARC design. For this LFS injection the pellet mass threshold is determined using the linear workflow, aligning well with the poloidal scan.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

A centrifuge CO2 pellet cleaning system

An advanced turbine/CO2 pellet accelerator is being evaluated as a depaint technology at Oak Ridge National Laboratory (ORNL). The program, sponsored by Warner Robins Air Logistics Center (ALC), Robins Air Force Base, Georgia, has developed a robot-compatible apparatus that efficiently accelerates pellets of dry ice with a high-speed rotating wheel. In comparison to the more conventional compressed air 'sandblast' pellet accelerators, the turbine system can achieve higher pellet speeds, has precise speed control, and is more than ten times as efficient. A preliminary study of the apparatus as a depaint technology has been undertaken. Depaint rates of military epoxy/urethane paint systems on 2024 and 7075 aluminum panels as a function of pellet speed and throughput have been measured. In addition, methods of enhancing the strip rate by combining infra-red heat lamps with pellet blasting and by combining the use of environmentally benign solvents with the pellet blasting have also been studied. The design and operation of the apparatus will be discussed along with data obtained from the depaint studies.

Foster, C. A.↗

Microstructure studies of U3Si2 fuel pellets sintered in argon vs. vacuum environment

A comparison study on the effects of sintering U3Si2 pellets under vacuum (~1x10-6 Torr) vs in argon has been carried out as part of a pellet fabrication process for potential light water reactor fuel application. A cross section of pellets sintered in each environment was examined using scanning electron microscopy (SEM) equipped with Energy dispersive spectroscopy (EDS). The average density of pellets sintered under vacuum and argon was 11.90 g/cm3 (97.5% theoretical density (TD)) and 11.37 g/cm3 (93.2% TD), respectively. SEM micrographs and EDS revealed the grain structure of pellets sintered under vacuum (vacuum samples) to be angular with a Si rich phase, U5Si4, along the grain boundaries, while grain structure of pellets sintered in argon (argon samples) reveals smaller average grain size and higher porosity with two separate Si rich phase inclusions: U5Si4 and USi. EDS confirmed the main phase in each pellet to be U3Si2 with an O rich phase inclusion. The estimated area percent of U3Si2 and the O rich phase in the samples from SEM image analysis was: argon samples 83.9% and 5.9% and vacuum samples 81.8% and 4.6%, respectively.

fuel fabrication↗

Robust Immobilized Amine CO 2 Sorbent Pellets Utilizing a Poly(Chloroprene) Polymer Binder and Fly Ash Additive

Pelletization of ca. 50 wt % amine/silica carbon dioxide sorbents was achieved with the novel combination of fly ash (FA) as a strength additive and hydrophobic poly(chloroprene) (PC) as a binder. The PC content and overall synthesis procedure of these materials were optimized to produce pellets, labeled as FA/E100-S_(20/80)_12.2, with the highest ball-mill attrition resistance (<0.5 wt % by fines, 24 h) and maximum CO 2 capture capacity of 1.78 mmol CO 2 g -1 . The strength of the pellets was attributed to hydrogen-bonding of the relatively homogeneous PC network with the interlocked FA and BIAS particles (DRIFTS, SEM-EDS). The low degradation of 3–4 % in the pellet's CO 2 capture capacity under both dry TGA (7.5 h) and practical fixed-bed (6.5 h dry; 4.5 h humid,≈5 vol % H 2 O) CO 2 adsorption–desorption conditions highlights the pellet's excellent cyclic stability. These robust pellet characteristics make PC/FA/sorbent materials promising for commercial scale, point-source CO 2 capture.

01 COAL, LIGNITE, AND PEAT↗

Effect of pelleting on the enzymatic digestibility of corn stover

Pelleting of lignocellulosic biomass to improve its transportation, storage and handling impacts subsequent processing and conversion. Here, this work reports the role of high moisture pelleting in the enzymatic digestibility of corn stover prior to pretreatment, together with associated substrate characteristics. Pelleting increases the digestibility of unpretreated corn stover, from 8.2 to 15.5% glucan conversion, at 5% solid loading using 1 FPU Cellic® CTec2 per g solids. Compositional analysis indicates that loose and pelleted corn stover have similar non-dissolvable compositions, although their extractives are different. Enzymatic hydrolysis of corn stover after size reduction to normalize particle sizes and removal of extractives confirms that pelleting improves corn stover digestibility. Such differences may be explained by the decreased particle size, improved substrate accessibility, and hydrolysis of cross-linking structures induced by pelleting. These findings are useful for the development of processing schemes for sustainable and efficient use of lignocellulose.

09 BIOMASS FUELS↗

Deuterium pellet fueling in type-III ELMy H-mode plasmas on EAST superconducting tokamak

Type-III ELMy H-mode plasmas are a valuable operating scenario, as they may simultaneously achieve fusion power gain of Q = 10 and acceptable steady-state and peak power fluxes to the plasma-facing components. It is important to investigate cryogenic deuterium pellet injection fueling in this kind of H-mode plasma since it has been chosen as a main plasma fueling technique for ITER. Recently, pellet fueling experiments have been successfully carried out on EAST, an ITER-like tokamak. A maximum electron density of 0.73 × n GW has been obtained. It is found that ELM behavior was modified immediately and a string of small ELMs were induced when pellets were injected at a low velocity from ¯40 cm above the mid-plane on the low field side, which is different from the fact that pellets trigger signal ELMs in Type-I ELMy H-mode plasmas in other tokamaks. Furthermore, the decreased edge temperature caused by the cryogenic pellet was proposed as the reason for this ELM modification. These results will provide a useful reference for the pellet fueling in a Type-III ELMy H-mode plasma on ITER in the future.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Gas adsorption capacity of wood pellets

In this paper, temperature-programmed desorption (TPD) analysis was used to measure and analyze the adsorption of off-gases and oxygen by wood pellets during storage. Such information on how these gases interact with the material helps in the understanding of the purging/stripping behavior of off-gases to develop effective ventilation strategies for wood pellets. Steam-exploded pellets showed the lowest carbon dioxide (CO 2 ) uptake compared to the regular and torrefied pellets. The high CO 2 adsorption capacity of the torrefied pellets could be attributed to their porous structure and therefore greater available surface area. Quantifying the uptake of carbon monoxide by pellets was challenging due to chemical adsorption, which formed a strong bond between the material and carbon monoxide. The estimated energy of desorption for CO (97.8 kJ/mol) was very high relative to that for CO 2 (7.24 kJ/mol), demonstrating the mechanism of chemical adsorption and physical adsorption for CO and CO 2 , respectively. As for oxygen, the strong bonds that formed between the material and oxygen verified the existence of chemical adsorption and formation of an intermediate material.

09 BIOMASS FUELS↗

Coaxial pellets for metallic impurity injection on the large helical device

Two coaxial pellets with tungsten inserted into graphite carbon and polyethylene (PE) tubes are compared for tungsten spectroscopic study in the Large Helical Device. The tungsten pellet with carbon tube causes plasma collapse, while that with PE tube smoothly ablates without collapse. The deposition profile of the pellets is analyzed with a help of pellet ablation spectroscopy. It is found that the tungsten pellet with carbon tube can significantly penetrate into the core plasma and leads to the plasma collapse. A tungsten spectrum with radial profile is successfully observed when the tungsten pellet with PE tube is used.

36 MATERIALS SCIENCE↗

Enhanced energy confinement after series of pellets in Wendelstein 7-X

A series of ice pellets was injected into the advanced stellarator Wendelstein 7-X (W7-X). Although the pellets were small and slow, deep and efficient particle fueling could be observed experimentally. The most striking feature appearing after the injection of the pellets, however, was a transient increase in the energy confinement time. This transient phase resembled in several aspects modes of enhanced confinement after gas-puff or pellet injection, as observed in other fusion experiments. All experimental attempts, to prolong this phase, failed. In this paper, discharges are described that show the enhanced energy confinement, and some conditions are summarized which seem to be essential in order to generate it. The focus here is on deep particle fueling by pellets, and shaping of the density profiles during and after the series of pellets. During this time, neutral gas particle re-fueling at the plasma edge is reduced, while density profile peaking and low impurity radiation losses are present.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Ablation of solid pellets induced by supra-thermal ions in the far scrape-off layer of tokamak plasmas

Injection of solid pellets is a key element in several aspects of the operation of a magnetic confinement plasma reactor for fusion applications, including plasma fueling, control and diagnosis. This letter reports observations demonstrating that pellet ablation can begin outside the plasma boundary, by effect of supra-thermal ions, whose orbits, under appropriate conditions, can extend well into the vacuum region. The phenomenon was recorded during plasma discharges in the DIII-D tokamak, combining pulsed modulation of heating neutral beams, with high-frequency injection of sub-millimeter lithium pellets, and it is ascribed to the large fraction of trapped beam ions associated with counter current neutral beam injection. The effect was quantitatively evaluated by means of Monte-Carlo simulations of supra-thermal ion orbits, finding that the heat-deposition was of the order of 50-100 W/mm 2 , in the region traversed by the lithium pellets before reaching the plasma boundary, which is consistent with the severe pellet deterioration observed for low velocity pellets.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Self-consistent investigation of density fueling needs on ITER and CFETR utilizing the new Pellet Ablation Module

Abstract Self-consistent modeling using the stability, transport, equilibrium, and pedestal (STEP) workflow in the OMFIT integrated modeling framework (predicting pedestal with EPED, core profiles with TGYRO, current profile with ONETWO, and EFIT for equilibrium) suggests ITER and future devices such as China Fusion Engineering Test Reactor (CFETR) Zhuang et al (2019 Nucl. Fusion 59 112010) will benefit from high-density operation (Greenwald limit fraction f g w ≈ 0.7−1.3). Regimes with an operational density near the Greenwald limit will likely need peaked density profiles so that the pedestal density remains below the Greenwald limit. Peaked density profiles can be achieved with the help of pellet injection. A flexible Pellet Ablation Module (PAM), which predicts the density source based on a comprehensive analytical pellet ablation model, has been developed for predicting pellet fueling for transport studies, and has been incorporated into the STEP workflow for predictive modeling. This workflow is applied to DIII-D and finds good agreement with experiments. On ITER the effect of pellet fueling is examined in an advanced inductive scenario, where a fusion gain of up to Q = 9 is predicted with strong central pellet fueling. On CFETR, with a mid-radius density source, an average of 1.5 × 10 22 electrons s −1 are required to achieve the density and temperature profiles necessary for the 1000 MW advanced scenario with a tritium burn-up fraction of ∼ 3 % .

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Simulation of triggering and evolution of ELM by pellet injection in EAST under BOUT++ framework

A BOUT ++ three-field magnetohydrodynamic model is employed to study the triggering and evolution of edge localized mode (ELM) by Li pellets injected along the outer mid-plane in the EAST configuration. The linear simulation shows that compared with a large deposition on the pedestal top (scenario I), a smaller deposition within the steep-gradient pedestal region (scenario II) can stimulate much larger linear growth rates of all-n peeling-ballooning modes (PBMs). The nonlinear simulation shows that there exists a pellet size threshold for ELM triggering for two deposition locations; the threshold for scenario I predicted in the present study matches the EAST observation well. Comparison of the two scenarios reveals that a smaller deposition is sufficient to trigger an ELM in a much shorter time in scenario II, whose ELM size is comparable to that in scenario I. This conclusion confirms previous DIII-D and ASDEX-Upgrade observations, suggesting that the steep-gradient pedestal region is a favorable deposition location for ELM triggering with minimum pellet size. Simulation analyses also find that the positive radial gradient of the hump-like pressure profile in the outer mid-plane induced by the pellet deposition plays a different role in the two scenarios. In scenario I, the force resulting from the gradient hinders the outflow of core plasmas and in return, the perturbation is suppressed from spreading inwards after ELM crashes. In scenario II, with a sizable deposition, the gradient results in another competitive perturbation growth region during the linear phase, thus dispersing the free energy and reducing the efficiency of destabilizing PBMs by pellet injection. The suppressing effect of saturated zonal flow on other modes, the short ELM fast crash phase, and the restricting transport effect of the positive radial pressure gradient work together to constrain the pedestal energy loss, especially when the pellet deposition amount is high.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Core Fueling of DEMO by Direct Line Injection of High-Speed Pellets From the HFS

Pellet injection represents to date the most realistic candidate technology for core fueling of a demonstration fusion power reactor tokamak fusion reactor. Modeling of both pellet penetration and fuel deposition profiles, for different injection locations, indicates that effective core fuelling can be achieved launching pellets from the inboard high field side at speeds not less than ~ 1 km/s. Inboard pellet fueling is commonly achieved in present tokamaks, using curved guide tubes; however, this technology might be hampered at velocities ≥ 1 km/s. An innovative approach, aimed at identifying suitable inboard "direct line'' paths, to inject high-speed pellets (in the 3 to 4 km/s range), has recently been proposed as a potential complementary solution. The fuel deposition profiles achievable by this approach have been explored using the HPI2 simulation code. The results presented here show that there are possible geometrical schemes providing good fueling performance. The problem of neutron flux in a direct line-of-sight injection path is being investigated, though preliminary analyses indicate that, perhaps, this is not a serious problem. The identification and integration of straight injection paths suitably tilted may be a rather difficult task due to the many constraints and to interference with existing structures. The suitability of straight guide tubes to reduce the scatter cone of high-speed pellets is, therefore, of main interest. A preliminary investigation, aimed at addressing these technological issues, has recently been started. As a result, a possible implementation plan, using an existing Italian National Agency for New Technologies, Energy and Sustainable Economic Development-Oak Ridge National Laboratory facility is shortly outlined.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Status and prospects for renewable energy using wood pellets from the southeastern United States

Abstract The ongoing debate about costs and benefits of wood‐pellet based bioenergy production in the southeastern United States ( SE USA ) requires an understanding of the science and context influencing market decisions associated with its sustainability. Production of pellets has garnered much attention as US exports have grown from negligible amounts in the early 2000s to 4.6 million metric tonnes in 2015. Currently, 98% of these pellet exports are shipped to Europe to displace coal in power plants. We ask, ‘How is the production of wood pellets in the SE USA affecting forest systems and the ecosystem services they provide?’ To address this question, we review current forest conditions and the status of the wood products industry, how pellet production affects ecosystem services and biodiversity, and what methods are in place to monitor changes and protect vulnerable systems. Scientific studies provide evidence that wood pellets in the SE USA are a fraction of total forestry operations and can be produced while maintaining or improving forest ecosystem services. Ecosystem services are protected by the requirement to utilize loggers trained to apply scientifically based best management practices in planning and implementing harvest for the export market. Bioenergy markets supplement incomes to private rural landholders and provide an incentive for forest management practices that simultaneously benefit water quality and wildlife and reduce risk of fire and insect outbreaks. Bioenergy also increases the value of forest land to landowners, thereby decreasing likelihood of conversion to nonforest uses. Monitoring and evaluation are essential to verify that regulations and good practices are achieving goals and to enable timely responses if problems arise. Conducting rigorous research to understand how conditions change in response to management choices requires baseline data, monitoring, and appropriate reference scenarios. Long‐term monitoring data on forest conditions should be publicly accessible and utilized to inform adaptive management.

09 BIOMASS FUELS↗

Infrared Optical Constants from Pressed Pellets of Powders: I. Improved n and k Values of (NH4)(2)SO(4)from Single-Angle Reflectance

In combination with other parameters, the real, n(?), and imaginary, k(?), components of the complex refractive index, = n + ik, can be used to simulate the optical properties of a material in different forms, e.g. its infrared spectra. But obtaining reliable values of the optical constants n/k for solid materials is challenging due to the lack of optical quality specimens, usually crystals, large enough to measure. An alternative to crystals is to press the powder into a uniform disk. We have produced pellets from ammonium sulfate, (NH4)2SO4, powder and derived the pellets’ n and k values via single-angle reflectance using a specular reflectance device in combination with a Fourier transform infrared spectrometer. The single-angle technique measures amplitude of light reflected from the material as a function of wavelength over a wide spectral domain; the optical constants are determined from the reflectance data using the Kramers-Kronig relationship. We investigate several parameters associated with the pellets and pellet formation and their effects upon delivering the most reliable n/k values. Parameters studied include pellet diameter, mass and density (void space), drying, grinding, sieving and particle size in the pellet formation, as well as pressing pressure and duration. Of these parameters, using size-selected mixtures of dried, small (< 100 µm) particles and pressing at = 10 tons for at least 30 minutes were found key to forming highly reflective samples. Comparison to two sets of previous literature n(?) and k(?) values obtained from crystalline (NH4)2SO4 both as crystal reflectance as well as extinction spectra of aerosols measured in a flow tube show reasonable agreement, but suggests the present values, as confirmed from two independent techniques, represent a substantial improvement for n/k values for (NH4)2SO4, also demonstrating promise to measure the optical constants of other materials.

Optical constants, index of refraction, single-ang↗

GLOBAL WOOD PELLET INDUSTRY AND MARKET – CURRENT DEVELOPMENTS AND OUTLOOK

The wood pellet use in the heating and electricity sector has recorded a steady growth in the last years. IEA bioenergy task 40 carried out an update of the situation on the national pellet markets in the most relevant pellet producing countries and the global development as well. Various country specific data is collected and compiled for more than 30 countries, containing updated information about regulatory framework, production, consumption, price trends, quality standards and trade aspects. The analysis confirmed the positive development in terms of production and consumption of wood pellets in almost all countries. In 2015 more than 26 Mt of wood pellets have been produced and consumed worldwide. Technologies and markets become more mature. Increased international pellet trade needs to be supported by adequate frame condition not only for commerce, but also with regard to sustainability issues.

09 BIOMASS FUELS↗