Multivariate chemometric methods and Vis-NIR spectrophotometry for monitoring plutonium-238 anion exchange column effluent in a radiochemical hot cell
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Fluorescent immunoconjugate cetuximab-IRDye800 bypasses the blood-brain-barrier to afford visualization of patient-derived GBM39 brain tumor tissue for facilitating its fluorescence-guided resection.
We determined the dielectric function of the alloy system (In{sub x}Ga{sub 1−x}){sub 2}O{sub 3} by spectroscopic ellipsometry in the wide spectral range from 0.5 eV to 8.5 eV and for In contents ranging from x = 0.02 to x = 0.61. The predicted optical transitions for binary, monoclinic β-Ga{sub 2}O{sub 3}, and cubic bcc-In{sub 2}O{sub 3} are well reflected by the change of the dielectric functions' lineshape as a function of the In content. In an intermediate composition range with phase-separated material (x ≈ 0.3…0.4), the lineshape differs considerably, which we assign to the presence of the high-pressure rhombohedral InGaO{sub 3}-II phase, which we also observe in Raman experiments in this range. By model analysis of the dielectric function, we derived spectra of the refractive index and the absorption coefficient and energy parameters of electronic band-band transitions. We discuss the sub-band gap absorption tail in relation to the influence of the In 4d orbitals on the valence bands. The data presented here provide a basis for a deeper understanding of the electronic properties of this technologically important material system and may be useful for device engineering.
Sol-gel silica thin films embedding an ytterbium quinolinolato complex (YbClQ{sub 4}) have been obtained using different alkoxides. Homogeneous, crack- and defect-free thin films of optical quality have been successfully deposited on glass substrate by dip-coating. The silica thin films have been characterized by time-resolved photoluminescence. The luminescence properties of the YbClQ{sub 4} are preserved in silica films prepared through an optimized sol-gel approach. The excited state lifetime of the lanthanide is comparable to those observed in bulk and longer than the corresponding ones in solution.
Tm{sup 3+} ions doped Na{sub 2}Y{sub 2}B{sub 2}O{sub 7} powder phosphor has been synthesized through combustion method. Crystal structure and phase of the prepared sample have been investigated by powder X-ray diffraction (XRD) analysis. Upconversion emission bands in the 400-900 nm range under the excitation of 980nm diode laser have been acquired, and involved upconversion mechanism has been discussed with the help of a suitable energy level diagram. The colour coordinate of developed phosphor has been calculated by CIE chromaticity diagram. Present phosphor can be used in fabrication of upconverting LEDs.
Mg{sub 2}Si thin film was embedded in amorphous silicon matrix by solid phase epitaxy. The structure and optical properties were investigated by electron energy loss, X-ray photoelectron, Raman, and photo thermal deflection spectroscopy measurements. It was found that in the photon energy range of 0.8–1.7 eV, the light absorption of the structure with magnesium silicide (Mg{sub 2}Si) film embedded in a-Si(i) matrix is 1.5 times higher than that for the same structure without Mg{sub 2}Si.
The science goals for ground-based large-area surveys, such as the Dark Energy Survey, Pan-STARRS, and the Large Synoptic Survey Telescope, require calibration of broadband photometry that is stable in time and uniform over the sky to precisions of a percent or better. This performance will need to be achieved with data taken over the course of many years, and often in less than ideal conditions. This paper describes a strategy to achieve precise internal calibration of imaging survey data taken in less than 'photometric' conditions, and reports results of an observational study of the techniques needed to implement this strategy. We find that images of celestial fields used in this case study with stellar densities ∼1 arcmin{sup –2} and taken through cloudless skies can be calibrated with relative precision ∼0.5% (reproducibility). We report measurements of spatial structure functions of cloud absorption observed over a range of atmospheric conditions, and find it possible to achieve photometric measurements that are reproducible to 1% in images that were taken through cloud layers that transmit as little as 25% of the incident optical flux (1.5 magnitudes of extinction). We find, however, that photometric precision below 1% is impeded by the thinnest detectable cloud layers. We comment on implications of these results for the observing strategies of future surveys.
The RCW41 star-forming region is embedded within the Vela Molecular Ridge, hosting a massive stellar cluster surrounded by a conspicuous H II region. Understanding the role of interstellar magnetic fields and studying the newborn stellar population is crucial to building a consistent picture of the physical processes acting on this kind of environment. We carried out a detailed study of the interstellar polarization toward RCW41 with data from an optical and near-infrared polarimetric survey. Additionally, deep near-infrared images from the 3.5 meter New Technology Telescope were used to study the photometric properties of the embedded young stellar cluster, revealing several YSO candidates. By using a set of pre-main-sequence isochrones, a mean cluster age in the range 2.5-5.0 million years was determined, and evidence of sequential star formation was revealed. An abrupt decrease in R-band polarization degree was noticed toward the central ionized area, probably due to low grain alignment efficiency caused by the turbulent environment and/or the weak intensity of magnetic fields. The distortion of magnetic field lines exhibits dual behavior, with the mean orientation outside the area approximately following the borders of the star-forming region and directed radially toward the cluster inside the ionized area, in agreement with simulations of expanding H II regions. The spectral dependence of polarization allowed a meaningful determination of the total-to-selective extinction ratio by fittings of the Serkowski relation. Furthermore, a large rotation of polarization angle as a function of wavelength was detected toward several embedded stars.
We calculate the intensity and photon spectrum of the intergalactic background light (IBL) as a function of redshift using an approach based on observational data obtained in many different wavelength bands from local to deep galaxy surveys. This allows us to obtain an empirical determination of the IBL and to quantify its observationally based uncertainties. Using our results on the IBL, we then place 68% confidence upper and lower limits on the opacity of the universe to {gamma}-rays, free of the theoretical assumptions that were needed for past calculations. We compare our results with measurements of the extragalactic background light and upper limits obtained from observations made by the Fermi Gamma-ray Space Telescope.
We present the results of near-infrared spectroscopic observations of the K-band-selected candidate galaxies in the protocluster at z = 3.09 in the SSA22 field. We observed 67 candidates with K {sub AB} < 24 and confirmed redshifts of the 39 galaxies at 2.0 < z {sub spec} < 3.4. Of the 67 candidates, 24 are certainly protocluster members with 3.04 ≤ z {sub spec} ≤ 3.12, which are massive red galaxies that have been unidentified in previous optical observations of the SSA22 protocluster. Many distant red galaxies (J – K {sub AB} > 1.4), hyper extremely red objects (J – K {sub AB} > 2.1), Spitzer MIPS 24 μm sources, active galactic nuclei (AGNs) as well as the counterparts of Lyα blobs and the AzTEC/ASTE 1.1 mm sources in the SSA22 field are also found to be protocluster members. The mass of the SSA22 protocluster is estimated to be ∼2-5 × 10{sup 14} M {sub ☉}, and this system is plausibly a progenitor of the most massive clusters of galaxies in the current universe. The reddest (J – K {sub AB} ≥ 2.4) protocluster galaxies are massive galaxies with M {sub star} ∼ 10{sup 11} M {sub ☉} showing quiescent star formation activities and plausibly dominated by old stellar populations. Most of these massive quiescent galaxies host moderately luminous AGNs detected by X-ray. There are no significant differences in the [O III] λ5007/Hβ emission line ratios and [O III] λ5007 line widths and spatial extents of the protocluster galaxies from those of massive galaxies at z ∼ 2-3 in the general field.
We present the results of high resolution (R ≥ 30,000) optical and near-IR spectroscopic monitoring observations of HBC 722, a recent FU Orionis object that underwent an accretion burst in 2010. We observed HBC 722 in the optical/near-IR with the Bohyunsan Optical Echelle Spectrograph, Hobby–Eberly Telescope-HRS, and Immersion Grating Infrared Spectrograph, at various points in the outburst. We found atomic lines with strongly blueshifted absorption features or P Cygni profiles, both evidence of a wind driven by the accretion. Some lines show a broad double-peaked absorption feature, evidence of disk rotation. However, the wind-driven and disk-driven spectroscopic features are anti-correlated in time; the disk features became strong as the wind features disappeared. This anti-correlation might indicate that the rebuilding of the inner disk was interrupted by the wind pressure during the first 2 years. The half-width at half-depth of the double-peaked profiles decreases with wavelength, indicative of the Keplerian rotation; the optical spectra with the disk feature are fitted by a G5 template stellar spectrum convolved with a rotation velocity of 70 km s{sup −1} while the near-IR disk features are fitted by a K5 template stellar spectrum convolved with a rotation velocity of 50 km s{sup −1}. Therefore, the optical and near-IR spectra seem to trace the disk at 39 and 76 R{sub ⊙}, respectively. We fit a power-law temperature distribution in the disk, finding an index of 0.8, comparable to optically thick accretion disk models.