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At least 145 records · Page 8
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DOE OSTI2026

Photoabsorption and photoionization of N2 near the first ionization threshold

The photoabsorption and photoionization spectra of molecular nitrogen, N2, near the first ionisation threshold display numerous intense resonances that have not been satisfactorily assigned to date. Principal among these is a pair of broad resonances between 126,200 and 126,600 cm−1 commonly referred to as the ”cathedral” bands. Here, we present new double-resonance photoionization spectra in this region recorded via the 𝑎′′ 1Σ+ 𝑔,𝑣′=0 intermediate state as well as new high-resolution, vacuum-ultraviolet photoabsorption spectra of 14N2,14N15N, and 15N2 to provide additional insight into the assignment of these features. Progress towards a fully consistent interpretation of the existing data on these bands is discussed, and a route towards a comprehensive description of the N2 absorption spectrum up to the 𝐵 2Σ+ 𝑢 state of N+ 2 is proposed.

Nitrogen, vacuum ultraviolet absorption, photoioni↗
NASA NTRS1972

Excitation of the metastable E(3 Sigma g plus) state of N2 by electron impact

The contribution of the N2(E(3 Sigma g plus)) state to the total metastable excitation function of N2 assessed on the basis of time-of-flight studies of metastable nitrogen molecules. The cross section for electron impact excitation state was determined in the domain of the resonance form threshold (11.87 eV) to an energy of about 13 eV. The maximum value of the cross section was found to be (7.0 + or - 4.0) x 10 to the -18th power sq cm at an energy of 12.2 eV. The measurement was made absolute by using the previously determined yield of the metastable detector, the lifetime of the E state, and by eliminating the energy spread in the electron beam from the raw data. The half-width (FWHM) of the resonance-like excitation function near threshold was found to be about 0.4 eV. No substantial evidence was obtained from the present data for the presence of the nonresonant part of the excitation function for the state studied.

Borst, W. L.↗
NASA NTRS1972

Angular distribution of electrons elastically scattered from N2.

Measurement of the angular distribution of electrons elastically scattered from N2 as a function of energy, utilizing a crossed-beam technique. Measurements have been made of monoenergetic electrons with energies between 5 and 90 eV scattered from a collimated beam of N2 at angles from -114 to +160 deg. The wide angular range of the measurements has enabled the determination of the total elastic-scattering and momentum-transfer cross sections. The measurements are relative and have been normalized to Fisk's (1936) theoretical calculation at 5 eV. The results generally agree well with other published measurements and with theory.

Shyn, T. W.↗
NASA NTRS1972

The IR emission spectrum of N2 excited under auroral conditions.

Recently determined experimental and theoretical cross sections for electron impact excitation of six triplet states of N2 (A, B, W, C, E, D) have been utilized to predict the absolute IR volume emission rates from N2 under nighttime auroral conditions. Secondary electron fluxes appropriate to an IBC II normal aurora were used in the calculations. The cascade contributions coupling the various electronic states were included as well as the most important quenching processes. The results indicate that the B yields reversibly A and W yields reversibly B cascade processes, which are important in the population of the A, B, and W states, produce appreciable radiation in the 1- to 5-micron wavelength region.

Cartwright, D. C.↗
NASA NTRS1973

Valence resonance states of N2/-/

Resonant scattering observed in the transmission of electrons between 9 and 11 eV in collision with N2 has been attributed to the attachment of the scattered electron to an excited valence state. Resonance valence excited states of N2(-) are calculated that could support this hypothesis. Although calculated and observed resonance energies are in close agreement, the calculations do not reflect the observed complex angular behavior of the scattered electron.

Krauss, M.↗
NASA NTRS1974

Quadrupole moment of CO, N2, and NO/+/

Evaluation of quadrupole moments obtained for CO, N2, and NO(+) with multiconfiguration self-consistent-field wave functions chosen by the optimized valence configuration (OVC) approach of Wahl and Das (1972). The quadrupole moments thus obtained are compared with both experimental and Hartree-Fock values. The Hartree-Fock results are found to be not very accurate for N2, especially if vibrational averages over vibrational levels greater than 1 or 2 are to be taken. The agreement between the OVC quadrupole moment and the experimental values is found to be best for CO.

Billingsley, F. P., II↗
NASA NTRS1975

Production of N2O/+/ by reaction of metastable O2/+/ ions with N2

Photoionization mass spectrometry examination of the production of N2O(+) was undertaken to determine whether N2(+) or O2(+) ions are responsible for onset of N2O(+). It appears that the N2(+) ion does not contribute significantly to the production of N2O(+) in this experiment. Therefore, it is clear that excited O2(+) is responsible for the formation of N2O(+) near the appearance potential of these ions.

Ajello, J. M.↗
NASA NTRS1975

Proton transfer reactions from H3/+/ ions to N2, O2, and CO molecules

The rate constants for proton transfer from H3(+) ions to N2, O2, and CO have been measured as function of hydrogen-buffer-gas partial pressure. The rate constant for proton transfer from H3(+) to N2 shows a very large pressure dependence, increasing from 1.0 by 10 to the -9th power cu cm/s at low H2 partial pressures to 1.7 by 10 to the -9th power cu cm/s at high H2 partial pressures. The rate constants for proton transfer from H3(+) to O2 and CO are constant with partial pressure of H2. The roles of excess vibrational energy in H3(+) ions and of equilibrium between forward and back reactions are discussed. Back reaction is observed only for the reaction of H3(+) ions with O2, and an equilibrium constant of 2.0 (plus or minus 0.4) at 298 K has been determined. From these data, the proton affinity of O2 is deduced to be 0.47 (plus or minus 0.11) kcal/mole higher than that of H2.

Kim, J. K.↗
NASA NTRS1976

Electron impact excitation of the Meinel band system of N2/+/

The emission spectrum of the Meinel band system of N2(+) was obtained in the region between 0.72 and 1.6 micrometers by electron impact excitation of N2. The relative excitation function is presented for the (0, 0) band from 22 to 120 eV. Cross sections of the Meinel bands that fall in this region were measured relative to the (2, 0) Meinel band. The results obtained are in good agreement with previously published values below 1.1 micrometers except for the (0, 0) band which is 30% higher. The electronic transition moment at large internuclear distances is found to agree with theoretical estimates.

Mandelbaum, D.↗
NASA NTRS1977

Measurements of the O+ plus N2 and O+ plus O2 reaction rates from 300 to 900 K

Rate coefficients for the O(+) + N2 atom transfer and O(+) + O2 charge transfer reactions are determined at thermal energies between 300 K and 900 K difference in a heated drift tube mass spectrometer apparatus. At 300 K the values K(O(+) + N2) = (1.2 plus or minus 0.1) x 10 to the negative 12 power cubic cm/sec and k(O(+) + O2) = (2.1 plus or minus 0.2) x 10 to the negative 11 power cubic cm/sec were obtained, with a 50% difference decrease in the reaction rates upon heating to 700 K. These results are in good agreement with heated flowing afterglow results, but the O(+) + O2 thermal rate coefficients are systematically lower than equivalent Maxwellian rates inferred by conversion of nonthermal drift tube and flow drift data.

Chen, A.↗
NASA NTRS1977

Charge exchange of metastable 2D oxygen ions with N2 in the thermosphere

The charge exchange of metastable 2D oxygen ions with N2 in the thermosphere is investigated through analysis of N2 (+) measurements and related data obtained by the Atmosphere Explorer-C satellite. The rate coefficient for the charge exchange process is found to be 5 + or - 1.7 times 10 to the negative 10th power cu cm per sec. A rate coefficient is also developed for atomic oxygen quenching of the metastable 2D oxygen ions.

Torr, D. G.↗
NASA NTRS1978

Internuclear dependence of the polarizability of N2

A study is made of the internuclear dependence of the polarizability of N2. Specifically, the dependencies of parallel and perpendicular polarizabilities on internuclear separation is found for the N2 molecule in its ground state. Results are presented for vibrationally elastic cross sections as functions of incident electron energy in an eight-state calculation and for the excitation of the first vibrational state.

Temkin, A.↗
NASA NTRS1979

Dissociative recombination of N2/+/ in the ionosphere

N2(+) ion measurements are examined which were made with the Atmospheric Explorer-C satellite during a phase of solar activity in 1978 that was significantly higher than near the earlier minimum. It is found that the major source of N2(+) is photoionization, rather than charge exchange with O(+) (2D), and that the major loss process above 300 km is dissociative recombination with electrons. A data sample for which the electron temperature (T sub e) covered the range from 1000 to 3400 K is used to evaluate the rate constant, alpha, for the dissociative-recombination process. The results show good agreement with laboratory measurements given by the expression: alpha = 1.8 x 10 to the -7th (T sub e/300) to the -0.39th cu cm/sec.

Torr, M. R.↗
NASA NTRS1980

The ultraviolet dayglow. I - Far UV emissions of N and N2

Far ultraviolet rocket spectra of N I and N2 dayglow emissions have been analyzed by using AE-E photoelectron spectra, laboratory-measured excitation cross sections, and photochemical models of atomic nitrogen. A self-consistent picture of both optically thick and thin emission features is found by using a model in which the principal production mechanism for N I 1200-A and 1493-A photons is photodissociative excitation of N2. The aeronomic data require that 50-70% of the excited 4 P atoms produced dissociatively have velocities within the Doppler core of the ambient nitrogen atoms, contrary to the expectation that those atoms are produced with large excess kinetic energy. The derived atomic nitrogen density has a maximum density of 2.7 x 10 to the 7th per cu cm at 170 km, a value that is within 40% of that from recent models of odd nitrogen photochemistry.

Meier, R. R.↗
NASA NTRS1980

Laboratory measurements of the O+/2D/ + N2 and O+/2D/ + O2 reaction rate coefficients and their ionospheric implications

Rate coefficients which have been measured at thermal energies for the charge transfer reactions of metastable O+/2D/ ions with N2 and O2 are reported. It is found that at an effective temperature of about 550 K, k(n2) = (8 + or - 2) x 10 to the -10 cu cm/sec and k(O2) = (7 + or - 2) x 10 to the -10 cu cm/sec. Drift tube-mass spectrometer measurements employ the reaction He(+) + O2 as the source of metastable O+ ions, showing that the ions produced in this manner are in the 2D state rather than the 2P state, a possible alternative identification. Finally, consideration is given to the ionospheric implications of the laboratory measurements.

Johnsen, R.↗
NASA NTRS1980

Kinetic inhibition of CO and N2 reduction in the solar nebula

It is shown that the conversion of CO to methane and of N2 to ammonia in the primitive solar nebula was probably so slow relative to radial mixing rates or nebula evolutionary rates that only small amounts of NH3 and CH4 could have been present. Thus most of the nitrogen was present as N2 and most of the carbon as CO and CO2 throughout the nebula. The consequences of this kinetic effect upon the composition of cometary ices and of the Jovian planets, the melting and outgassing behavior of ice rich planetary satellites, and the abundance of carbon in the terrestrial planets are briefly discussed.

Lewis, J. S.↗
NASA NTRS1980

Electron-impact excitation of the singlet states of N2. I - The Birge-Hopfield system /b 1 pi u - X 1 Sigma g +/

Results of a study of the electron-impact excitation of the b 1 pi u state of N2, one of the singlet states thought to be excited by precipitating electrons in the auroral zones, and of its predissociation and radiative relaxation through the emission of the Birge-Hopfield band system (b 1 pi u - X 1 Sigma g +) are presented. A collimated electron beam was passed through N2 gas producing a variety of atomic states through dissociative excitation, and the radiation resulting from relaxation of these states was observed by VUV and visible-IR monochromators. Absolute emission cross sections for 11 Birge-Hopfield bands are obtained for energies from threshold to 500 eV, and used to calculate the absolute transition probabilities for BH(1, v-prime) bands and the variation of the electric dipole moment with internuclear distance. With the exception of the v-prime equals 1, 5 and 6 vibrational levels, all b 1 pi u levels are found to predissociate with a specific predissociation branching ratio greater than 0.99, representing a major source of nitrogen atoms.

Zipf, E. C.↗
NASA NTRS1981

Electron-temperature dependence of dissociative recombination of electrons with N2/+/.N2 dimer ions

The variation with electron temperature of the dissociative recombination of electrons with N2(+).N2 dimer ions is investigated in light of the importance of such ions in the lower ionosphere and in laser plasmas. Dissociative recombination coefficients were determined by means of a microwave afterglow mass spectrometer technique for electron temperatures from 300-5600 K and an ion and neutral temperature of 300 K. The recombination coefficient is found to be proportional to the -0.41 power of the electron temperature in this range, similar to that observed for the CO(+).CO dimer ion and consistent with the expected energy dependence for a fast dissociative process.

Whitaker, M.↗