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Possible Quantum Paramagnetism in Compressed Sr 2 IrO 4

The result of compression on the magnetic ground state of Sr 2 IrO 4 is studied with x-ray resonant techniques in the diamond anvil cell. The weak interlayer exchange coupling between square-planar 2D IrO 2 layers is easily modified upon compression, with a crossover between magnetic structures around 7 GPa mimicking the effect of an applied magnetic field at ambient pressure. Higher pressures drive an order-disorder magnetic phase transition with no magnetic order detected above 17–20 GPa. The persistence of strong exchange interactions between J eff = 1 / 2 magnetic moments within the insulating IrO 2 layers up to at least 35 GPa points to a highly frustrated magnetic state in compressed Sr 2 IrO 4 , opening the door for realization of novel quantum paramagnetic phases driven by extended 5 d orbitals with entangled spin and orbital degrees of freedom.

36 MATERIALS SCIENCE↗

Magnetic moment collapse induced axial alternative compressibility of Cr 2 TiAlC 2 at 420 GPa from first principle

The electronic structure and thermo-dynamical properties of Cr 2 TiAlC 2 are studied by first principles under pressure. The obtained results observed that the ferromagnetic order is the most stable ground state and the magnetic moment will collapse at about 50GPa. As a result, the lattice a axis becomes stiffer above about 420GPa, ultimately presenting the same axial compressibility trends with those of nonmagnetic compounds Mo2TiAlC2 and hypothetical Cr2TiAlC2. The elastic constants and phonon dispersion curves demonstrate the structural stability during the disappearance of magnetic moment and occurrence of axial alternative compressibility. The density of states and energy band calculations confirmed the existence of magnetic moment of Cr2TiAlC2 at 0GPa and disappearance at high pressures above 50GPa. Evolutions of magnetic moment collapse with pressure are confirmed by a variety of properties. The obtained grüneisen parameter and thermal expansion coefficients show the maximum value among the known MAX phases, to date and to the author’s knowledge.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Enhanced detection of paramagnetic fluorine-19 magnetic resonance imaging agents using zero echo time sequence and compressed sensing

Fluorine-19 ( 19 F) magnetic resonance imaging (MRI) is an emerging technique offering specific detection of labeled cells in vivo. Lengthy acquisition times and modest signal-to-noise ratio (SNR) makes three-dimensional spin-density–weighted 19 F imaging challenging. Recent advances in tracer paramagnetic metallo-perfluorocarbon (MPFC) nanoemulsion probes have shown multifold SNR improvements due to an accelerated 19 F T 1 relaxation rate and a commensurate gain in imaging speed and averages. However, 19 F T 2 -reduction and increased linewidth limit the amount of metal additive in MPFC probes, thus constraining the ultimate SNR. To overcome these barriers, we describe a compressed sampling (CS) scheme, implemented using a “zero” echo time (ZTE) sequence, with data reconstructed via a sparsity-promoting algorithm. Our CS-ZTE scheme acquires k-space data using an undersampled spherical radial pattern and signal averaging. Image reconstruction employs off-the-shelf sparse solvers to solve a joint total variation and -norm regularized least square problem. To evaluate CS-ZTE, we performed simulations and acquired 19 F MRI data at 11.7 T in phantoms and mice receiving MPFC-labeled dendritic cells. For MPFC-labeled cells in vivo, we show SNR gains of ~6.3 × with 8-fold undersampling. We show that this enhancement is due to three mechanisms including undersampling and commensurate increase in signal averaging in a fixed scan time, denoising attributes from the CS algorithm, and paramagnetic reduction of T 1 . Importantly, 19 F image intensity analyses yield accurate estimates of absolute quantification of 19 F spins. Overall, the CS-ZTE method using MPFC probes achieves ultrafast imaging, a substantial boost in detection sensitivity, accurate 19 F spin quantification, and minimal image artifacts.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

CRADA Final Report: CRADA Number NFE-22-09330 with General Fusion

General Fusion is developing a magnetized target fusion (MTF) approach that involves compressing an initial magnetically confined plasma inside a cavity formed in liquid metal. This approach builds from concepts initially developed under the Linus program at the U.S. Naval Research Laboratory and combines it with advances from compact toroid experiment (CTX) and sustained spheromak plasma experiment (SSPX) in compact toroid plasmas and coaxial Marshall gun systems. Modeling the tokamak during compression is central to designing a successful MTF device. The plasma is formed by coaxial helicity injection in the General Fusion device. Immediately after formation, the plasma has a diverted tokamak configuration with a single null. As the wall moves inwards, the plasma is repelled from the conducting surface and driven inwards by currents induced by its magnetic field in the liquid metal wall. As the liquid metal closes (or bridges) the opening of the coaxial plasma injector, the magnetic field topology alters to remove the null. Due to this, the plasma moves from a diverted to a wall-limited configuration. The liquid metal liner continues to close in and change shape, reducing in radius by a factor of ten at the peak of plasma compression. A model of the MTF plasma must be able to handle this continually varying geometry, and to be predictive, it must faithfully include the real imperfections arising in the process. In this project, we pursued a Monte Carlo approach to closures for MHD by computing kinetic electron trajectories in an MHD plasma background from simulations of GF devices. This requires enhancing the capabilities of the KORC-T code for running large ensembles of kinetic trajectories by porting it to GPU architectures and enabling workflows for large ensembles on OLCF machines. With these capabilities, it is possible to produce a large library of kinetic calculations of electron orbits evolving in plasma configurations spanning the magnetic configurations and plasma density profiles, including non-axisymmetry, arising in the General Fusion’s existing PI3 spherical tokamak device. Using ensembles will capture particles passing a single point in space in a given magnetic configuration, and the entire dataset will cover a range of global magnetic field geometries. By sampling around many starting points, this dataset will capture the spatial dependence of the plasma parameters. From this large dataset, it is possible to produce a reduced model for the kinetic effects not captured in MHD.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Scalable Multiphysics Block Preconditioning for Low Mach Number Compressible Resistive MHD with Application to Magnetic Confinement Fusion

This study investigates multiphysics block preconditioners that are critical in devising scalable Newton–Krylov iterative solvers for longer time-scale fully implicit fluid plasma models. The specific model of interest is the visco-resistive, low Mach number, compressible magnetohydrodynamics (MHD) model. This model describes the dynamics of conducting fluids in the presence of electromagnetic fields and can be used to study aspects of astrophysical phenomena, important science and technology applications, and basic plasma physics. The specific application of interest that motivates this study is the macroscopic simulation of longer time-scale stability and disruptions of magnetic confinement fusion devices, specifically the ITER Tokamak. The computational solution of the governing balance equations for mass, momentum, heat transfer, and magnetic induction for resistive MHD systems can be extremely challenging. These difficulties arise from both the strong nonlinear, nonsymmetric coupling of fluid and electromagnetic phenomena as well as the significant range of time and length scales that the interactions of these physical mechanisms produce. To handle the range of time and spatial scales of interest, a fully implicit unstructured variational multiscale finite element formulation is employed. For the scalable solution of the Newton linearized systems, fully coupled block preconditioners are designed to leverage algebraic multigrid subsolves. In conclusion, results are presented for the strong and weak scaling of the method as well as the robustness of these techniques for a large range of Lundquist numbers.

97 MATHEMATICS AND COMPUTING↗

Extrusion compression molded critical rare earth free bonded permanent magnets

Samarium iron nitride (Sm-Fe-N) bonded magnets have emerged as promising candidates for various industrial applications due to their exceptional magnetic properties. Compounds with magnetic material 95 wt fraction (wt.%) (∼74 vol%) and 97 wt.% (∼81 vol%) of SmFeN in a polyamide (PA12) polymer binder are manufactured using a batch mixer followed by compression molding. A maximum energy product ( BH ) max of 186.21 kJ.m -3 (23.4 MGOe) is achieved in the 95 wt.% bonded magnets; 97 wt.% magnets had a ( BH ) max of 165.52 kJ.m -3 (20.8 MGOe). It is found that the degree of alignment (DoA) of 99 % is achieved in the 95 wt.% magnets, whereas the 97 wt.% magnets are limited to a DoA of 90 % respectively. The high DoA can be attributed to low particle-particle interaction during the post-magnetic field alignment process. Finally, this research provides a useful insight of binder-particle interactions at very high magnet weight fractions and their effect on magnetic strength and performance.

36 MATERIALS SCIENCE↗

Effect of Magnetization on the Tunneling Anomaly in Compressible Quantum Hall States

Tunneling of electrons into a two-dimensional electron system is known to exhibit an anomaly at low bias, in which the tunneling conductance vanishes due to a many-body interaction effect. Recent experiments have measured this anomaly between two copies of the half-filled Landau level as a function of in-plane magnetic field, and they suggest that increasing spin polarization drives a deeper suppression of tunneling. Here, we present a theory of the tunneling anomaly between two copies of the partially spin-polarized Halperin-Lee-Read state, and we show that the conventional description of the tunneling anomaly, based on the Coulomb self-energy of the injected charge packet, is inconsistent with the experimental observation. We propose that the experiment is operating in a different regime, not previously considered, in which the charge-spreading action is determined by the compressibility of the composite fermions.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Large-Scale Compressibility in Rotating Flows of Astrophysical Plasma in the Shallow Water Approximation

Two systems of magnetohydrodynamic equations in the shallow water approximation are proposed as a basis for studies in the field of plasma astrophysics: the system of equations with a full allowance for the Coriolis force and the system of equations on the β-plane in which the changes of the Coriolis parameter are linear in coordinate. Both systems of equations take into account such fundamentally important phenomena in plasma astrophysics as the compressibility and external magnetic field effects, increasing significantly the potential for applying these equations to study astrophysical objects. Compressibility in plasma astrophysics is shown to change significantly the dispersion laws for magneto-Poincare, magnetostrophic, and magneto-Rossby waves. The same nonlinear interactions as those in the absence of compressibility have been found to be realized in the case of a compressible rotating plasma. Three-wave equations in the weak nonlinearity approximation, in which the interaction coefficients depend on plasma large-scale compressibility and thermodynamic characteristics, have been derived by the method of multiscale expansions. Expressions for the growth rates of the parametric instabilities of three-wave interactions with large-scale compressibility have been derived.

79 ASTRONOMY AND ASTROPHYSICS↗

Analysis of fusion fuel conditions and instability development in shocklessly compressed MagLIF implosion simulations

Magnetized liner inertial fusion (MagLIF) implosions on the Z accelerator have almost exclusively been driven by ∼100-ns rise time current pulses. The rise time is selected to be as short as achievable on Z partially to minimize the time during which deleterious implosion instabilities can develop. Modifying the shape of the current pulse could provide benefits for MagLIF, including more efficient compression of the fusion fuel and the magnetic flux inside the liner cavity. Quasi-isentropic compression of the liner prevents formation of shocks in the liner material and reduces the amount of entropy generation within the liner. This allows for more final compression of the liner and fuel assembly. We present results from one-dimensional (1D) radiation-magnetohydrodynamic (rad-MHD) simulations comparing thermonuclear fuel conditions in MagLIF implosions driven with two different current pulses: a ∼100-ns rise time, ∼21.5 MA peak current “short pulse” and a ∼200-ns rise time, ∼21.5 MA peak current “shockless” pulse. We also quantify and compare the instability development in three-dimensional (3D) MHD implosion simulations driven by these two different pulse shapes. Our 1D simulations indicate that the shocklessly compressed MagLIF implosion performs better than the short pulse driven implosion with a >50% higher thermonuclear neutron yield, and 3D simulations indicate comparable implosion instability development, suggesting that pulse shaping could enable improvements to MagLIF performance on Z without compromising implosion stability.

Shipley, G. A. (ORCID:0000000205364001)↗

Pressure-Driven Sequential Lattice Collapse and Magnetic Collapse in Transition-Metal-Intercalated Compounds Fe x NbS 2

Volume collapse under high pressure is an intriguing phenomenon involving subtle interplay between lattice, spin, and charge. The two most important causes of volume collapse are lattice collapse (low-density to high-density) and magnetic collapse (high-spin to low-spin). Herein we report the pressure-driven sequential volume collapses in partially intercalated Fe x NbS 2 (x = 1/4, 1/3, 1/2, 2/3). Because of the distinct interlayer atomic occupancy, the low-iron-content samples exhibit both lattice and magnetic collapses under compression, whereas the high-iron-content samples exhibit only one magnetic collapse. Therefore, theoretical calculations indicate that the low-pressure volume collapses for x = 1/4 and x = 1/3 are lattice collapses, and the high-pressure volume collapses for all four samples are magnetic collapses. The magnetic collapse involving the high-spin to low-spin crossover of Fe2+ has also been verified by in situ X-ray emission measurements. Integrating two distinct volume collapses into one material provides a rare playground of lattice, spin, and charge.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Fast ignition realization experiment with high-contrast kilo-joule peta-watt LFEX laser and strong external magnetic field

A petawatt laser for fast ignition experiments (LFEX) laser system [N. Miyanaga et al., J. Phys. IV France 133, 81 (2006)], which is currently capable of delivering 2 kJ in a 1.5 ps pulse using 4 laser beams, has been constructed beside the GEKKO-XII laser facility for demonstrating efficient fast heating of a dense plasma up to the ignition temperature under the auspices of the Fast Ignition Realization EXperiment (FIREX) project [H. Azechi et al., Nucl. Fusion 49, 104024 (2009)]. In the FIREX experiment, a cone is attached to a spherical target containing a fuel to prevent a corona plasma from entering the path of the intense heating LFEX laser beams. The LFEX laser beams are focused at the tip of the cone to generate a relativistic electron beam (REB), which heats a dense fuel core generated by compression of a spherical deuterized plastic target induced by the GEKKO-XII laser beams. Recent studies indicate that the current heating efficiency is only 0.4%, and three requirements to achieve higher efficiency of the fast ignition (FI) scheme with the current GEKKO and LFEX systems have been identified: (i) reduction of the high energy tail of the REB; (ii) formation of a fuel core with high areal density using a limited number (twelve) of GEKKO-XII laser beams as well as a limited energy (4 kJ of 0.53-μm light in a 1.3 ns pulse); (iii) guiding and focusing of the REB to the fuel core. Laser–plasma interactions in a long-scale plasma generate electrons that are too energetic to efficiently heat the fuel core. Three actions were taken to meet the first requirement. First, the intensity contrast of the foot pulses to the main pulses of the LFEX was improved to >10{sup 9}. Second, a 5.5-mm-long cone was introduced to reduce pre-heating of the inner cone wall caused by illumination of the unconverted 1.053-μm light of implosion beam (GEKKO-XII). Third, the outside of the cone wall was coated with a 40-μm plastic layer to protect it from the pressure caused by imploding plasma. Following the above improvements, conversion of 13% of the LFEX laser energy to a low energy portion of the REB, whose slope temperature is 0.7 MeV, which is close to the ponderomotive scaling value, was achieved. To meet the second requirement, the compression of a solid spherical ball with a diameter of 200-μm to form a dense core with an areal density of ∼0.07 g/cm{sup 2} was induced by a laser-driven spherically converging shock wave. Converging shock compression is more hydrodynamically stable compared to shell implosion, while a hot spot cannot be generated with a solid ball target. Solid ball compression is preferable also for compressing an external magnetic field to collimate the REB to the fuel core, due to the relatively small magnetic Reynolds number of the shock compressed region. To meet the third requirement, we have generated a strong kilo-tesla magnetic field using a laser-driven capacitor-coil target. The strength and time history of the magnetic field were characterized with proton deflectometry and a B-dot probe. Guidance of the REB using a 0.6-kT field in a planar geometry has been demonstrated at the LULI 2000 laser facility. In a realistic FI scenario, a magnetic mirror is formed between the REB generation point and the fuel core. The effects of the strong magnetic field on not only REB transport but also plasma compression were studied using numerical simulations. According to the transport calculations, the heating efficiency can be improved from 0.4% to 4% by the GEKKO and LFEX laser system by meeting the three requirements described above. This efficiency is scalable to 10% of the heating efficiency by increasing the areal density of the fuel core.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Results from new multi-megabar shockless compression experiments at the Z machine

Sandia’s Z Machine has been used to magnetically drive shockless compression of materials in a planar configuration to multi-megabar pressure levels, allowing accurate measurements of quasi-isentropic mechanical response at relatively low temperatures in the solid phase. This work details recent improvements to design and analysis of such experiments, including the use of new data on the mechanical and optical response of lithium fluoride windows. Comparison of windowed and free-surface data on copper to 350 GPa lends confidence to the window correction method. Preliminary results are presented on gold to 500 GPa and platinum to 450 GPa; both appear stiffer than existing models.

36 MATERIALS SCIENCE↗

Solar wind compressible turbulence near proton scales: Cluster observations

The solar wind compressible turbulence attracts more attention recently due to its possible role in plasma heating. Using the plasma density and magnetic field measured simultaneously by the Cluster C1 probe, we statistically investigate the wave characteristics of the proton-scale compressible turbulence. In most cases, the density and magnetic field strength fluctuations almost show no positive correlation, suggesting the absence of fast mode waves. Moreover, the magnetic compressibility C{sub b} as measured by the level of magnetic fluctuations parallel to the background field, is enhanced continuously around proton scales and is consistent with kinetic Alfvén wave (KAW) prediction. Interestingly, kinetic slow mode waves (KSW) are identified in a few cases through large values of C{sub b} and plasma compressibility C{sub p}, together with the the anti-correlation between n and B. We suggest that both KAW and KSW can account for the compressible fluctuations energy, while their relative proportions under certain plasma condition require further studies.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Applied axial magnetic field effects on laboratory plasma jets: Density hollowing, field compression, and azimuthal rotation

We experimentally measure the effects of an applied axial magnetic field (B z ) on laboratory plasma jets and compare experimental results with numerical simulations using an extended magnetohydrodynamics code. A 1 MA peak current, 100 ns rise time pulse power machine is used to generate the plasma jet. On application of the axial field, we observe on-axis density hollowing and a conical formation of the jet using interferometry, compression of the applied B z using magnetic B-dot probes, and azimuthal rotation of the jet using Thomson scattering. Experimentally, we find densities ≤ 5×10 17 cm -3 on-axis relative to jet densities of ≥ 3×10 18 cm -3 . For aluminum jets, 6.5 ± 0.5 mm above the foil, we find on-axis compression of the applied 1.0 ± 0.1 T B z to a total 2.4 ± 0.3 T, while simulations predict a peak compression to a total 3.4 T at the same location. On the aluminum jet boundary, we find ion azimuthal rotation velocities of 15-20 km/s, while simulations predict 14 km/s at the density peak. We discuss possible sources of discrepancy between the experiments and simulations, including: surface plasma on B-dot probes, optical fiber spatial resolution, simulation density floors, and 2D vs. 3D simulation effects. Lastly, this quantitative comparison between experiments and numerical simulations helps elucidate the underlying physics that determine the plasma dynamics of magnetized plasma jets.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Semi-analytic model of plasma-jet-driven magneto-inertial fusion

A semi-analytic model for plasma-jet-driven magneto-inertial fusion is presented here. Compressions of a magnetized plasma target by a spherically imploding plasma liner are calculated in one dimension (1D), accounting for compressible hydrodynamics and ionization of the liner material, energy losses due to conduction and radiation, fusion burn and alpha deposition, separate ion and electron temperatures in the target, magnetic pressure, and fuel burn-up. Results show 1D gains of 3–30 at spherical convergence ratio <15 and 20–40 MJ of liner energy, for cases in which the liner thickness is 1 cm and the initial radius of a preheated magnetized target is 4 cm. Some exploration of parameter space and physics settings is presented. The yields observed suggest that there is a possibility of igniting additional dense fuel layers to reach high gain.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Nonlinear ablative Rayleigh-Taylor instability: Increased growth due to self-generated magnetic fields

The growth rate of the nonlinear ablative Rayleigh-Taylor (RT) instability is enhanced by magnetic fields self-generated by the Biermann battery mechanism; a scaling for this effect with perturbation height and wavelength is proposed and validated with extended-magnetohydrodynamic simulations. The magnetic flux generation rate around a single RT spike is found to scale with the spike height. The Hall parameter, which quantifies electron magnetization, is found to be strongly enhanced for short-wavelength spikes due to Nernst compression of the magnetic field at the spike tip. Furthermore, the impact of the magnetic field on spike growth is through both the suppressed thermal conduction into the unstable spike and the Righi-Leduc heat flow deflecting heat from the spike tip to the base. Righi-Leduc is found to be the dominant effect for small Hall parameters, while suppressed thermal conduction dominates for large Hall parameters. These results demonstrate the importance of considering magnetic fields in all perturbed inertial confinement fusion hot spots.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

SHOCK STRENGTH IN SPACE AND ASTROPHYSICAL PLASMAS

The Rankine–Hugoniot (R–H) jump conditions are the most important and frequently used equations in studies of the properties of space and astrophysical plasmas during their passage through shock discontinuities. This paper revisits the R–H conditions for shocks, develops the formulation of the compression ratio, and examines its range of values and properties. The analysis expresses the downstream thermodynamic variables and the compression ratio as functions of the upstream thermodynamic variables, either for equal or different polytropic indices upstream and downstream of the shock. In the general case of space plasmas with an oblique magnetic field, the compression ratio is given by a quartic polynomial, which is reduced to a cubic trinomial when the upstream/downstream polytropic indices are equal. The special cases of magnetic fields that are perpendicular or parallel to the shock normal are also examined. In any case, the compression ratio polynomial has one degree larger order, when the upstream/downstream polytropic indices are different. Emphasis is placed on the maximum value of the compression ratio, which is known to be ∼4 for adiabatic polytropic index ∼5/3. However, the compression ratio can be much larger if the upstream/downstream polytropic indices are not equal to each other and less than one. Several other issues are investigated: (i) the entropic condition, showing that statistical mechanics and thermodynamics lead to the same relation of entropy variation; (ii) the effect of kappa distributions on jump conditions; and (iii) the upper limit of the upstream temperature for a shock to exist.

79 ASTRONOMY AND ASTROPHYSICS↗

Effect of Strain on Magnetic Coupling in Ga-Doped WS{sub 2} Monolayer: Ab Initio Study

Magnetic properties of Ga-doped WS{sub 2} monolayer under strain are investigated by ab initio methods. Without strain, the Ga-doped WS{sub 2} monolayer is a magnetic nanomaterial, and the total magnetic moment is about 0.82 μ{sub B}. We applied strain to Ga-doped WS{sub 2} monolayer from − 10 to 10%. The magnetic properties are modified under different strains, and a maximum magnetic moment reaches 3.09 μ{sub B} at − 3% compressive strain. However, the magnetic moment of system decreases to zero sharply when compressive strain arrived at − 10%. The coupling among Ga 3d, W 5d, and S 3p states is responsible for the strong strain effect on the magnetic properties. Our studies predict Ga-doped WS{sub 2} monolayer under strain to be candidates for application in spintronics.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗