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All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

Transcriptomic Changes in Seedlings from Seeds Exposed to Simulated Space Radiation

Outside the protection of Earth’s magnetic field, living organisms are constantly exposed to space radiation that consists of energetic protons and other heavier charged particles. With the goal of manned Mars exploration, the production of fresh crop during long duration space missions can be beneficial for meeting astronauts’ nutritional and psychological needs. In our study, we not only evaluated plant/fruit morphometrics and edible fresh mass, but also analyzed transcriptomic changes in seedlings from seeds of three plant species (Arabidopsis, mizuna, and tomato) exposed to simulated Galactic Cosmic Rays(GCR) and solar particle events(SPE). The radiation experiments were performed in the NASA Space Radiation Laboratory (NSRL) facility at Brookhaven National Lab (BNL). 10-day Arabidopsis seedlings were exposed acutely (~240 cGy/hr) to simulated GCR scenarios of combined ions including protons, helium, oxygen, titanium, and/or iron ions at 40 or 80 cGy. Seeds of Arabidopsis, mizuna, and tomato were exposed to 40 or 80 cGy simulated GCR (dry seeds) or SPE (imbibed seeds) at lower dose rates(20-26 cGy/hr). Seedlings from control and irradiated seeds were then collected in RNAlater at similar growth stages with true leaves emerged. Total RNA was isolated and analyzed via Illumina whole transcriptome sequencing technology. Plant species-specific bioinformatics revealed transcriptional biomarkers and signaling pathways induced by simulated space radiation that were found to be dose, dose-rate, and species dependent. DNA damage response, stress signaling, and metabolic pathways are among the most significant changes. These data highlight some critical insights on the mechanisms of how plants respond and adapt to the space radiation environment and provide a molecular basis for crop selection and refinement in deep space exploration.

Anirudha Dixit↗
DOE OSTI2023

Community Centered Solar Development (CCSD) Case Study Interviews [Slides]

Large-scale solar (LSS, defined here as ground-mounted photovoltaic projects ≥1 MWDC) has grown rapidly in the U.S., accounting for nearly half of new electric generating capacity added to the U.S. grid in 2022. All sources of electricity bring positive and negative impacts to hosting communities and the rapid growth of LSS has increased the urgency to understand those impacts. Yet, information about the potential positive and negative impacts of LSS on host communities, and the factors or drivers leading to support or opposition to a project, is lacking. This information gap limits how project developers, municipalities, and local siting authorities can address community concerns and appropriately align proposed projects to best suit and benefit local communities. As part of Berkeley Lab’s Community-Centered Solar Development (CCSD) project, this research set out to explore deep insights and perceptions from LSS stakeholders that only qualitative data can provide to identify key factors driving project success or threatened failure. Case studies, such as those utilized in this research, are uniquely adept at capturing the subjective experience of individuals and at identifying variables, structures, and interactions between stakeholders. Our case studies included 54 semi-structured interviews across 7 different LSS sites, representing a diversity of geographies, project sizes (MW), site types (i.e., greenfield, agrivoltaic, and brownfield / contaminated sites), zoning jurisdiction types, and more (Table 1). In addition to local residents living in close proximity to these LSS sites, we interviewed other key stakeholders involved in the projects such as developers, decision-makers, utility representatives, landowners, and individuals from community-based organizations. The overarching aim of this case study research was two-fold: (1) to inform subsequent tasks in the CCSD research project (including an upcoming national survey of LSS neighbors), and (2) to provide insights into the following set of research questions: -What are the key positive and negative drivers leading to support and opposition to LSS projects? -To what extent do LSS projects exacerbate or mitigate perceived inequities and marginalization within hosting communities and how can those inequities be mitigated going forward? -What strategies can communities employ to align LSS development with local land-use plans and community needs and values? The research findings and next steps are described in this slide deck report.

14 SOLAR ENERGY↗
NASA NTRS2021

Identifying Molecules as Biosignatures with Assembly Theory and Mass Spectrometry

The search for evidence of life elsewhere in the universe is hard because it is not obvious what signatures are unique to life. Here we postulate that complex molecules found in high abundance are universal biosignatures as they cannot form by chance. To explore this, we developed the first intrinsic measure of molecular complexity that can be experimentally determined, and this is based upon a new approach called assembly theory which gives the molecular assembly number (MA) of a given molecule. MA allows us to compare the intrinsic complexity of molecules using the minimum number of steps required to construct the molecular graph starting from basic objects, and a probabilistic model shows how the probability of any given molecule forming randomly drops dramatically as its MA increases. To map chemical space, we calculated the MA of ca. 2.5 million compounds, and collected data which showed the complexity of a molecule can be experimentally determined by using three independent techniques including infra-red spectroscopy, nuclear magnetic resonance, and by fragmentation in a mass spectrometer, and this data has an excellent corelation with the values predicted from our assembly theory. We then set out to see if this approach could allow us to identify molecular biosignatures with a set of diverse samples from around the world, outer space, and the laboratory including prebiotic soups. The results show that there is a non-living to living threshold in MA complexity and the higher the MA for a given molecule, the more likely that it had to be produced by a biological process. This work demonstrates it is possible to use this approach to build a life detection instrument that could be deployed on missions to extra-terrestrial locations to detect biosignatures, map the extent of life on Earth, and be used as a molecular complexity scale to quantify the constraints needed to direct prebiotically plausible processes in the laboratory. Such an approach is vital if we are going to find new life elsewhere in the universe or create de-novo life in the lab.

Stuart M Marshall↗
NASA NTRS2000

International Space Station: Expedition 2000

Live footage of the International Space Station (ISS) presents an inside look at the groundwork and assembly of the ISS. Footage includes both animation and live shots of a Space Shuttle liftoff. Phil West, Engineer; Dr. Catherine Clark, Chief Scientist ISS; and Joe Edwards, Astronaut, narrate the video. The first topic of discussion is People and Communications. Good communication is a key component in our ISS endeavor. Dr. Catherine Clark uses two soup cans attached by a string to demonstrate communication. Bill Nye the Science Guy talks briefly about science aboard the ISS. Charlie Spencer, Manager of Space Station Simulators, talks about communication aboard the ISS. The second topic of discussion is Engineering. Bonnie Dunbar, Astronaut at Johnson Space Flight Center, gives a tour of the Japanese Experiment Module (JEM). She takes us inside Node 2 and the U.S. Lab Destiny. She also shows where protein crystal growth experiments are performed. Audio terminal units are used for communication in the JEM. A demonstration of solar arrays and how they are tested is shown. Alan Bell, Project Manager MRMDF (Mobile Remote Manipulator Development Facility), describes the robot arm that is used on the ISS and how it maneuvers the Space Station. The third topic of discussion is Science and Technology. Dr. Catherine Clark, using a balloon attached to a weight, drops the apparatus to the ground to demonstrate Microgravity. The bursting of the balloon is observed. Sherri Dunnette, Imaging Technologist, describes the various cameras that are used in space. The types of still cameras used are: 1) 35 mm, 2) medium format cameras, 3) large format cameras, 4) video cameras, and 5) the DV camera. Kumar Krishen, Chief Technologist ISS, explains inframetrics, infrared vision cameras and how they perform. The Short Arm Centrifuge is shown by Dr. Millard Reske, Senior Life Scientist, to subject astronauts to forces greater than 1-g. Reske is interested in the physiological effects of the eyes and the muscular system after their exposure to forces greater than 1-g.

Source record↗
DOE OSTI2020

Reducing the risks of wildfires

Anyone who has lived in New Mexico for at least a year realizes that the Land of Enchantment has six seasons. In addition to the four seasons everyone else has, we have a wildfire season, which typically comes during late spring and early summer. Wildfires sometimes even last through the monsoon season, when thunderstorms are lighter than usual. Wildfires, it seems, are inevitable in Los Alamos and the surrounding communities that make up part of northern New Mexico. In recent history, the 2000 Cerro Grande Fire destroyed 150,000 acres (including 7,500 acres of Laboratory property) and 235 Los Alamos homes. In 2011, the Las Conchas Fire burned more than 156,000 acres and threatened Los Alamos and the Lab. To minimize the chances of wildfires and to strengthen defenses against wildfires, the Laboratory every year carries out various fire-mitigation strategies throughout its 42 square miles.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Transport and Retention of Particulate Organic Matter in Sand: Lab Experiments and Modelling

Flow-through reactor (FTR) experiments were conducted at three different downward vertical flow rates to study the transport and retention of particulate organic matter (Chlorella powder) in riverbed sediments. This data package includes data files (.csv) regarding effluent collected from the FTRs during the experiments (time, duration, volume of each sample collection; concentration of nonreactive bromide tracer; concentration of suspended Chlorella determined by absorbance measurements) and sediment (sand) slices collected from the FTRs after the experiments (mass of Chlorella retained in 1 cm depth intervals determined by loss-on-ignition method). More detailed descriptions of data are provided in the data dictionary, and detailed methods are available in the associated MSc thesis listed in ‘Related References.’ The data dictionary and file level meta data (FLMD) are included in the data package as both .csv and .xlsx files. This data package also includes timelapse videos (.mp4) of the experiments, and modelling scripts associated with the experiments. The modelling scripts are included as MATLAB ‘live scripts’ (.mlx, which can be run using MATLAB), and are also included as .pdf and .html files with output plots included (which can be viewed without a MATLAB license and installation). The data files and modelling scripts are organized into a .zip folder for each of the three FTR experiments (three flow rates).

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1997

Gene Regions Responding to Skeletal Muscle Atrophy

Our stated specific aims for this project were: 1) Identify the region(s) of the mouse IIb myosin heavy chain (MHC) promoter necessary for in vivo expression in mouse fast-twitch muscle, and 2) Identify the region(s) of the mouse IIb MHC promoter responsive to immobilization in mouse slow-twitch muscle in vivo. We sought to address these specific aims by introducing various MHC IIb promoter/reporter gene constructs directly into the tibialis anterior and gastrocnemius muscles of living mice. Although the method of somatic gene transfer into skeletal muscle by direct injection has been successfully used in our laboratory to study the regulation of the skeletal alpha actin gene in chicken skeletal muscle, we had many difficulties utilizing this procedure in the mouse. Because of the small size of the mouse soleus and the difficulty in obtaining consistent results, we elected not to study this muscle as first proposed. Rather, our MHC IIb promoter deletion experiments were performed in the gastrocnemius. Further, we decided to use hindlimb unloading via tail suspension to induce an upregulation of the MHC IIb gene, rather than immobilization of the hindlimbs via plaster casts. This change was made because tail suspension more closely mimics spaceflight, and this procedure in our lab results in a smaller loss of overall body mass than the mouse hindlimb immobilization procedure. This suggests that the stress level during tail suspension is less than during immobilization. This research has provided an important beginning point towards understanding the molecular regulation of the MHC lIb gene in response to unweighting of skeletal muscle Future work will focus on the regulation of MHC IIb mRNA stability in response to altered loading of skeletal muscle

Booth, Frank W.↗
DOE OSTI2024

Searching for Strongly-Interacting Dark Matter with the Heavy Photon Search Experiment

The Heavy Photon Search Experiment (HPS) is a fixed-target experiment at Jefferson Lab’s Hall B, designed to explore a hidden sector (HS) of particles containing dark matter and a new force mediator known as the “heavy photon” (A'). The A' is a massive spin-1 gauge boson associated with a new U (1)D symmetry in the HS that kinetically mixes with the Standard Model () photon with a weak coupling strength parameterized by ¿, with ¿2 ~ 10-2 -10-10. HPS utilizes a high-intensity electron beam on a thin tungsten target to produce heavy photons in the MeV-GeV mass range via “dark bremsstrahlung,” a process analogous to SM bremsstrahlung but suppressed by ¿2. The A' can decay resonantly to SM leptons, allowing HPS to conduct both mass resonance searches for prompt decays (large ¿) and displaced vertex searches for long-lived particles (small ¿). In addition to the minimal A' model, HPS probes more complex extensions such as the QCD-like strongly-interacting massive particles (SIMPs) HS containing “dark” pions (pD) and vector mesons (VD), with pD as dark matter candidates. These particles introduce new thermal dark matter freeze- out scenarios and visible signals through long-lived VD decays to SM leptons, which are accessible to HPS. This analysis conducted a displaced vertex search for VD ¿ e-e+ in the mass range 30 MeV to 124 MeV and ¿ between 10-6 < ¿ < 10-2 using data from the 2016 Engineering Run (10.753 nb-1) at 2.3 GeV. Unlike the minimal A' search, SIMP signal kinematics required new approaches to signal normalization and SM background rejection. The strongest signal evidence was a local p-value of 0.01317 for mVD = 119 MeV, corresponding to a global significance of 0.9s. Although no signal was found, this search excluded a region of the SIMP parameter space at 90 % confidence. This work demonstrates HPS’s competitive capability to probe SIMP sectors within cosmologically significant parameters and introduces a new method for HPS displaced vertex searches using track vertical impact parameter cuts

Spellman, Alic [Univ. of California, Santa Cruz, C↗
NASA NTRS2013

A New Population of High-z, Dusty Lyman-alpha Emitters and Blobs Discovered by WISE: Feedback Caught in the Act?

By combining data from the NASA Wide-field Infrared Survey Explorer (WISE) mission with optical spectroscopy from the W. M. Keck telescope, we discover a mid-IR color criterion that yields a 78% success rate in identifying rare, typically radio-quiet, 1.6 approx. < z approx. < 4.6 dusty Ly-alpha emitters (LAEs). Of these, at least 37% have emission extended on scales of 30-100 kpc and are considered Ly-alpha "blobs" (LABs). The objects have a surface density of only approx.. 0.1 deg(exp -2), making them rare enough that they have been largely missed in deep, small area surveys. We measured spectroscopic redshifts for 92 of these galaxies, and find that the LAEs (LABs) have a median redshift of 2.3 (2.5). The WISE photometry coupled with data from Herschel (Herschel is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA) reveals that these galaxies are in the Hyper Luminous IR galaxy regime (L(sub IR) approx. > 10(exp 13)-10(exp 14) Solar L) and have warm colors. They are typically more luminous and warmer than other dusty, z approx.. 2 populations such as submillimeter-selected galaxies and dust-obscured galaxies. These traits are commonly associated with the dust being illuminated by intense active galactic nucleus activity. We hypothesize that the combination of spatially extended Ly-alpha, large amounts of warm IR-luminous dust, and rarity (implying a short-lived phase) can be explained if the galaxies are undergoing brief, intense "feedback" transforming them from an extreme dusty starburst/QSO into a mature galaxy.

Galaxies: ISM↗
NASA NTRS2016

The Impact of New Trends in Satellite Launches on Orbital Debris Environment

The main goal of this study is to examine the impact of new trends in satellite launch activities on the orbital debris environment and collision risk. Starting from the launch of the first artificial satellite in 1957, space borne technology has become an indispensable part of our lives. More than 6,000 satellites have been launched into Earth orbit. Though the annual number of satellites launched stayed flat for many decades, the trend has recently changed. The satellite market has been undergoing a major evolution with new space companies replacing the traditional approach of deploying a few large, complex and costly satellites with an approach to use a multitude of smaller, less complex and cheaper satellites. This new approach creates a sharp increase in the number of satellites and so the historic trends are no longer representative. As a foundation for this study, a scenario for satellite deployments based on the publicly announced future satellite missions has been developed. These constellation-deploying companies include, but are not limited to, Blacksky, CICERO, EROS, Landmapper, Leosat, Northstar, O3b, OmniEarth, OneWeb, Orbcomm, OuterNet, PlanetIQ, Planet Labs, Radarsat, RapidEye Next Generation, Sentinel, Skybox, SpaceX, and Spire. Information such as the annual number of launches, the number of orbital planes to be used by the constellation, as well as apogee, perigee, inclination, spacecraft mass and area were included or approximated. Besides the production of satellites, a widespread ongoing effort to enhance orbital injection capabilities will allow delivery of more spacecraft more accurately into Earth orbits. A long list of companies such as Microcosm, Rocket Lab, Firefly Space Systems, Sierra Nevada Corporation and Arca Space Corporation are developing new launch vehicles dedicated for small satellites. There are other projects which intend to develop interstages with propulsive capabilities which will allow the deployment of satellites into their desired orbits beyond the restrictions of the launch vehicle used. These near future orbital injection technologies are also covered in the developed scenario. Using the above-mentioned background information, this study aims to examine how the orbital debris environment will be affected from the new dynamics of the emerging space markets. We developed a simulation tool that is capable of propagating the objects in a given deployment scenario with variable-sized time-steps as small as one second. Over the course of the run, the software also detects collisions; additional debris objects are then created according to the NASA breakup model and are fed back into the simulation framework. Examining the simulation results, the total number of particles to accumulate in different orbits can be monitored and the number of conjunctions can be tracked to assess the collision risks. The simulation makes it possible to follow the short- and long-term effects of a particular satellite or constellation on the space environment. Likewise, the effects of changes in the debris environment on a particular satellite or constellation can be evaluated. It is authors hope that the results of this paper and further utilization of the developed simulation tool will assist in the investigation of more accurate deorbiting metrics to replace the generic 25-year disposal guidelines, as well as to guide future launches toward more sustainable and safe orbits.

New Space↗
NASA NTRSDate not supplied

NASA Kennedy Space Center Swamp Works 10th Anniversary: Innovative Research & Technology Development Summary

Kennedy Space Center’s (KSC) Swamp Works, provides government and commercial space ventures with the technologies required for working and living on the surfaces of the Moon or other planets and bodies in our solar system. The Swamp Works team establishes rapid, innovative and cost-effective exploration mission solutions through leveraging of partnerships across NASA, industry and academia. Concepts start small and build up fast, with lean development processes and a hands-on approach. Testing is performed in early stages to drive design improvements and progressively increase Technology Readiness Levels (TRL). Swamp Works provides concepts, architecture studies and trades, designs, data, technology development, technology demonstration hardware, flight hardware, testing, flight support and knowledge in support of the development of surface systems. It consists of several teams with associated laboratories and test capabilities. The Granular Mechanics and Regolith Operations (GMRO) Laboratory and the Electrostatics and Surface Physics Laboratory (ESPL) are co-located in the Engineering Development Lab (EDL) facility high bay. The Applied Chemistry Lab (ACL) is in an adjacent facility and other KSC labs are being influenced by the innovation methods pioneered at the Swamp Works. The Swamp Works was founded in January 2013 by a group of scientists and engineers at KSC with the over-arching vision of expanding humanity and civilization into the solar system by the use of space resources via advanced technology. Ultimately, this will create a solar system economy that will improve the human condition due to the abundance of energy and resources. This paper will summarize the projects and technology development that have been performed by the Swamp Works to celebrate its 10th Anniversary of innovation success.

Robotic Mining↗
NASA NTRSDate not supplied

Swamp Works Technology Development 10th Anniversary: 2013-2023

Kennedy Space Center’s (KSC) Swamp Works, provides government and commercial space ventures with the technologies required for working and living on the surfaces of the Moon or other planets and bodies in our solar system. The Swamp Works team establishes efficient, innovative and cost-effective exploration mission solutions through leveraging of partnerships across NASA, industry and academia. Concepts start small and build up momentum, with lean development processes and a hands-on approach. Testing is performed in early stages to drive design improvements and progressively increase Technology Readiness Levels (TRL). Swamp Works provides concepts, architecture studies and trades, designs, data, technology development, technology demonstration hardware, flight hardware, testing, flight support and knowledge in support of the development of surface systems. It consists of several teams with associated laboratories and test capabilities. The Granular Mechanics and Regolith Operations (GMRO) Laboratory and the Electrostatics and Surface Physics Laboratory (ESPL) are co-located in the Engineering Development Lab (EDL) facility high bay. The Applied Chemistry Lab (ACL) is in an adjacent facility and other KSC labs are being influenced by the innovation methods pioneered at the Swamp Works. The Swamp Works was founded in January 2013 by a group of scientists and engineers at KSC with the over-arching vision of expanding humanity and civilization into the solar system by the use of space resources via advanced technology. Ultimately, this will create a solar system economy that will improve the human condition due to the abundance of energy and resources. This presentation will summarize the projects and technology development that have been performed by the Swamp Works to celebrate its 10th Anniversary of innovation success.

Swamp Works↗
NASA NTRS2023

Swamp Works Technology Development 10th Anniversary: 2013-2023 - Innovative Research & Technology Development Summary

Kennedy Space Center’s (KSC) Swamp Works, provides government and commercial space ventures with the technologies required for working and living on the surfaces of the Moon or other planets and bodies in our solar system. The Swamp Works team establishes rapid, innovative and cost-effective exploration mission solutions through leveraging of partnerships across NASA, industry and academia. Concepts start small and build up efficiently, with lean development processes and a hands-on approach. Testing is performed in early stages to drive design improvements and progressively increase Technology Readiness Levels (TRL). Swamp Works provides concepts, architecture studies and trades, designs, data, technology development, technology demonstration hardware, flight hardware, testing, flight support and knowledge in support of the development of surface systems. It consists of several teams with associated laboratories and test capabilities. The Granular Mechanics and Regolith Operations (GMRO) Laboratory and the Electrostatics and Surface Physics Laboratory (ESPL) are co-located in the Engineering Development Lab (EDL) facility high bay. The Applied Chemistry Lab (ACL) is in an adjacent facility and other KSC labs are being influenced by the innovation methods pioneered at the Swamp Works. The Swamp Works was founded in January 2013 by a group of scientists and engineers at KSC with the over-arching vision of expanding humanity and civilization into the solar system by the use of space resources via advanced technology. Ultimately, this will create a solar system economy that will improve the human condition due to the abundance of energy and resources. This presentation will summarize the projects and technology development that have been performed by the Swamp Works to celebrate its 10th Anniversary of innovation success.

Swamp Works↗
NASA NTRS2009

Connecting Research and Practice: An Experience Report on Research Infusion with SAVE

NASA systems need to be highly dependable to avoid catastrophic mission failures. This calls for rigorous engineering processes including meticulous validation and verification. However, NASA systems are often highly distributed and overwhelmingly complex, making the software portion of these systems challenging to understand, maintain, change, reuse, and test. NASA's systems are long-lived and the software maintenance process typically constitutes 60-80% of the total cost of the entire lifecycle. Thus, in addition to the technical challenges of ensuring high life-time quality of NASA's systems, the post-development phase also presents a significant financial burden. Some of NASA's software-related challenges could potentially be addressed by some of the many powerful technologies that are being developed in software research laboratories. Many of these research technologies seek to facilitate maintenance and evolution by for example architecting, designing and modeling for quality, flexibility, and reuse. Other technologies attempt to detect and remove defects and other quality issues by various forms of automated defect detection, architecture analysis, and various forms of sophisticated simulation and testing. However promising, most such research technologies nevertheless do not make the transition from the research lab to the software lab. One reason the transition from research to practice seldom occurs is that research infusion and technology transfer is difficult. For example, factors related to the technology are sometimes overshadowed by other types of factors such as reluctance to change and therefore prohibits the technology from sticking. Successful infusion might also take very long time. One famous study showed that the discrepancy between the conception of the idea and its practical use was 18 years plus or minus three. Nevertheless, infusing new technology is possible. We have found that it takes special circumstances for such research infusion to succeed: 1) there must be evidence that the technology works in the practitioner's particular domain, 2) there must be a potential for great improvements and enhanced competitive edge for the practitioner, 3) the practitioner has to have strong individual curiosity and continuous interest in trying out new technologies, 4) the practitioner has to have support on multiple levels (i.e. from the researchers, from management, from sponsors etc), and 5) to remain infused, the new technology has to be integrated into the practitioner's processes so that it becomes a natural part of the daily work. NASA IV&V's Research Infusion initiative sponsored by NASA's Office of Safety & Mission Assurance (OSMA) through the Software Assurance Research Program (SARP), strives to overcome some of the problems related to research infusion.

Lindvall, Mikael↗
DOE OSTI2026

Balancing moisture and oxygen can match the crystallization dynamics of inert halide perovskite processing

Understanding crystallization in ambient environments is essential for scaling the fabrication of halide perovskite solar cells. Antisolvent-free perovskite deposition offers improved compatibility with high-throughput processing but introduces distinct crystallization dynamics relative to the more ubiquitous use of antisolvents in lab-scale perovskite fabrication. These dynamics are driven by interactions between solutes, solvent and the deposition environment. Using in situ wide-angle X-ray scattering during spin-coating and annealing, we demonstrate how relative humidity (RH) and oxygen, can be tuned to drive polytype evolution during ambient crystallization of formamidinium lead iodide to match that of inert synthesis and achieve comparable film and device quality. In an inert (N 2 ) environment, we find that perovskite films follow a well-established 2H → 3C phase transformation with a short period of coexistence of the 4H and 6H phase during heating. During crystallization in dry air (RH 0%), the added presence of oxygen leads to the dominance of 4H intermediate for an extended duration, establishing a 2H → 4H → 3C pathway. Introducing low humidity (RH 10%) suppresses the 4H phase to a short-lived intermediate above 100 °C, facilitating a more direct transition to the desired 3C phase and almost replicating the crystallization behavior observed under inert conditions. Interestingly, films crystallized under RH 10% show a lower onset temperature for the perovskite 3C phase than under N 2 . At higher humidity (RH 40%), the strong interaction of oxygen and moisture with iodoplumbates appears to stabilize higher order polytypes (4H and 6H). Devices fabricated under RH 10% achieve higher efficiency and enhanced stability compared to those produced under inert atmosphere. These findings provide mechanistic insight into crystallization pathways in different environments and provide a framework to transfer processes from inert to ambient conditions. The results highlight the critical role of controlled humidity in tuning antisolvent-free perovskite crystallization for scalable processing.

Hossain, Maimur [Univ. of California, San Diego, C↗
DOE OSTI2021

Characterization of Americium and Curium Complexes with the Protein Lanmodulin: A Potential Macromolecular Mechanism for Actinide Mobility in the Environment

Anthropogenic radionuclides, including long-lived heavy actinides such as americium and curium, represent the primary long-term challenge for management of nuclear waste. The potential release of these wastes into the environment necessitates understanding their interactions with biogeochemical compounds present in nature. Here, we characterize the interactions between the heavy actinides, Am 3+ and Cm 3+ , and the natural lanthanide-binding protein, lanmodulin (LanM). LanM is produced abundantly by methylotrophic bacteria, including Methylorubrum extorquens, that are widespread in the environment. We determine the first stability constant for an Am 3+ -protein complex (Am 3 LanM) and confirm the results with Cm 3 LanM, indicating a ~5-fold higher affinity than that for lanthanides with most similar ionic radius, Nd 3+ and Sm 3+ , and making LanM the strongest known heavy actinide-binding protein. The protein’s high selectivity over 243 Am’s daughter nuclide 239 Np enables lab-scale actinide-actinide separations as well as provides insight into potential protein-driven mobilization for these actinides in the environment. The luminescence properties of the Cm 3+ -LanM complex, and NMR studies of Gd 3+ -LanM, reveal that lanmodulin-bound f-elements possess two coordinated solvent molecules across a range of metal ionic radii. Finally, we show under a wide range of environmentally relevant conditions that lanmodulin effectively outcompetes desferrioxamine B, a hydroxamate siderophore previously proposed to be important in trivalent actinide mobility. Overall, these results suggest that natural lanthanide-binding proteins such as lanmodulin may play important roles in speciation and mobility of actinides in the environment; it also suggests that protein-based biotechnologies may provide a new frontier in actinide remediation, detection, and separations.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2023

A New Era of Discovery: The 2023 Long-Range Plan for Nuclear Science (V.1.2)

Nuclear science is the investigation of how protons and neutrons are formed from elementary particles and how the forces between those particles produce both nuclei and the vast variety of nuclear phenomena that occur in the universe. It has evolved into a broad field that addresses profound scientific questions: Where does the mass of visible matter come from? How do stars ignite, live, and die? How do nuclei illuminate the search for new laws of nature? This science points the way to using nuclei to build new technologies that benefit society. The 2015 Nobel Prize in physics was shared by nuclear physicists Art McDonald and Takaaki Kajita for the discovery of neutrino oscillations, which confirmed that neutrinos have mass. Our progress on big questions like this one since 2015 has been remarkable owing to new experimental tools, theoretical breakthroughs, powerful computational techniques, and the talented people who make these innovations possible. Focusing on these new tools, the Facility for Rare Isotope Beams (FRIB) at Michigan State University is already producing exciting results on decays of never-before-produced isotopes a year after it was completed on time and on budget. The energy upgrade of the Continuous Electron Beam Accelerator Facility (CEBAF) at the Thomas Jefferson National Accelerator Facility (Jefferson Lab) was also completed on schedule and on budget—new data from this facility are revealing the spectrum, structure, and dynamics of protons, neutrons, nuclei, and mesons. On the theory front, we can now calculate the distribution of quarks inside the proton from first principles. The implementation of artificial intelligence (AI) and machine learning (ML) techniques has led to improved data analysis and increased efficiency in running experiments and theoretical calculations. The impact of nuclear science goes beyond expanding the frontiers of knowledge about matter in the universe. We simultaneously develop a STEM work force that advances the security, technology, health, and wealth of our nation. Some connections are obvious. Expert scientists trained to work with radioactive nuclei are in demand in nuclear security arenas and are highly sought after by various government agencies and private industries. Graduate students and postdoctoral fellows (postdocs) obtain extensive computational, modeling, and data science skills that are similarly in high demand. Less obvious but equally important is the connection between these trained scientists and success in other professions, including medicine, energy, and entrepreneurial pursuits. The workforce that enables discovery in nuclear science also makes breakthroughs in technologies with tremendous impact on the nation’s economic advancement.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2025

Final Report for CSP Tower Public Opinion and Education Project

As part of the CSP Plant Optimization Study for the California Power Market (DE-EE0009809) the project wanted to understand the public’s opinion of the technology and and explore the types of community engagement that is needed to support such development. The initial objectives for the public perception activities were twofold. The primary objective was to gather public opinion and feedback from the communities living near the two operating solar power tower plants, Ivanpah and Crescent Dunes, and to distill lessons learned from the community engagement conducted before, during, and after the plants were developed to inform future development. This included outreach to nearby airports. The other objective was to gauge public opinion about large-scale solar, specifically CSP towers, to start educating the public on the benefits and to begin building relationships with communities of interest, initially targeting the Kingman, Arizona area. The objectives shifted after the first exploratory trip to Ivanpah and Kingman, however, as it became apparent that it would be challenging to gather public opinion from the community surrounding Ivanpah that could be useful for other community profiles, and the company wasn’t ready to address the concerns in Kingman. Another area was chosen, therefore, to represent those where future development is possible. The recently published Lawrence Berkeley National Lab Perceptions of Large-Scale Solar Project Neighbors Study exemplified public perception polling based on social science and served as the foundation for the survey questions taken to the field. The intent was to ensure that people knew their input was valued and that the time they spent was valuable for the participant as well. It has been noted in the literature that in-person interaction has greater benefits than activities online or via mail, as well as limits the expense.

14 SOLAR ENERGY↗