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Boron Abundances in A and B-type Stars

Boron abundances in A- and B-type stars may be a successful way to track evolutionary effects in these hot stars. The light elements - Li, Be, and B - are tracers of exposure to temperatures more moderate than those in which the H-burning CN-cycle operates. Thus, any exposure of surface stellar layers to deeper layers will affect these light element abundances. Li and Be are used in this role in investigations of evolutionary processes in cool stars, but are not observable in hotter stars. An investigation of boron, however, is possible through the B II 1362 A resonance line. We have gathered high resolution spectra from the IUE database of A- and B-type stars near 10 solar mass for which nitrogen abundances have been determined. The B II 1362 A line is blended throughout; the temperature range of this program, requiring spectrum syntheses to recover the boron abundances. For no star could we synthesize the 1362 A region using the meteoritic/solar boron abundance of log e (B) = 2.88; a lower boron abundance was necessary which may reflect evolutionary effects (e.g., mass loss or mixing near the main-sequence), the natal composition of the star forming regions, or a systematic error in the analyses (e.g., non-LTE effects). Regardless of the initial boron abundance, and despite the possibility of non-LTE effects, it seems clear that boron is severely depleted in some stars. It may be that the nitrogen and boron abundances are anticorrelated, as would be expected from mixing between the H-burning and outer stellar layers. If, as we suspect, a residue of boron is present in the A-type supergiants, we may exclude a scenario in which mixing occurs continuously between the surface and the deep layers operating the CN-cycle. Further exploitation of the B II 1362 A line as an indicator of the evolutionary status of A- and B-type stars will require a larger stellar sample to be observed with higher signal-to-noise as attainable with the Hubble Space Telescope.

Lambert, David L.↗

FUSE Observations of Galactic and LMC Novae in Outburst

This document is a collection of five abstracts from papers written on the 'FUSE Observations of Galactic and LMC Novae in Outburst'. The titles are the following: (1) Analyzing FUSE Observations of Galactic and LMC Novae; (2) Detailed NLTE Model Atmospheres for Novae during Outburst: Modeling Optical and Ultraviolet Observations for Nova LMC 1988; (3) Numerical Solution of the Expanding Stellar Atmosphere Problem; (4) A Non-LTE Line-Blanketed Expanding Atmosphere Model for A-supergiant Alpha Cygni; and (5) Non-LTE Model Atmosphere Analysis of the Early Ultraviolet Spectra of Nova Andromedae 1986. A list of journal publications is also included.

Huschildt, P. H.↗

Studying the MLT by a Combined Analysis of SABER/TIMED and Lidar Measurements

The SABER instrument on board the TIMED Satellite is a limb scanning infrared radiometer designed to measure temperature and minor constituent vertical profiles and energetics parameters in the mesosphere and lower thermosphere (MLT). The measurements have been performed continuously since January 25, 2002 to provide excellent coverage for both hemispheres. The Leibniz-Institute of Atmospheric Physics (LAP) at Kuehlungsborn, Germany (54N, 12E) operates two lidar instruments, using three different temperature measurement methods, optimized for three altitude ranges. The total altitude range of the lidar installation lies from 1 to 105 km. Another instrument used for intercomparison is the ALOMAR RMR lidar, located at Andoya, Norway (69N, 16E). We have searched the SABER and lidar datasets for coincidental common volume measurements within plus or minus 1 degree in latitude, plus or minus 2 degrees in longitude and approx. 1 hour in time for the sake of (a) comparison of measured temperatures; (b) validation of the models used in SABER data analysis; and (c) extracting new information about MLT parameters. In this work we applied the non-LTE ALI-ARMS code designed to calculate the nonequilibrium radiance in different viewing geometries to the analysis of measurements which satisfied these search criteria. The results of this analysis (a) support the application of higher value of CO2-O quenching rate (6e-12 cubic centimeters per second) by the non-LTE temperature retrievals from the SABER 15 micrometer limb radiance data, and (b) demonstrate the importance of accounting for the vibrational-vibrational energy exchange among the CO2 isotopes for accurate temperature retrievals. Using temperature profiles obtained in lidar measurements as inputs for the retrieval algorithm we also retrieved the nighttime CO2 densities from the SABER 15 micrometer limb radiances and compared them with the model and climatology CO2 data used in the SABER nighttime temperature retrievals.

Feofilov, A. G.↗

The Hottest Horizontal-Branch Stars in Omega Centauri: Late Hot Flasher vs. Helium Enrichment

UV observations of some massive globular clusters uncovered a significant population of very hot stars below the hot end of the horizontal branch (HB), the so-called blue hook stars. This feature might be explained either by the late hot flasher scenario here stars experience the helium flash while on the white dwarf cooling curve or by the helium-rich sub-population recently postulated to exist in some clusters. Spectroscopic analyses of blue hook stars in omega Cen and NGC 2808 support the late hot flasher scenario, but the stars contain much less helium than expected and the predicted C, N enrichment could not be verified from existing data. We want to determine effective temperatures, surface gravities and abundances of He, C, N in blue hook and canonical extreme horizontal branch (EHB) star candidates. Moderately high resolution spectra of stars at the hot end of the blue horizontal branch in the globular cluster omega Cen were analysed for atmospheric parameters (T(sub eff), log g) and abundances using LTE and Non-LTE model atmospheres. In the temperature range 30,000 K to 50,000 K we find that 37% of our stars are helium-poor (log nHe/nH less than -2), 49% have solar helium abundance within a factor of 3 (-1.5 less than or equal to log nHe/nH less than or equal to -0.5) and 14% are helium rich (log nHe/nH greater than -0.4). We also find carbon enrichment in step with helium enrichment, with a maximum carbon enrichment of 3% by mass. At least 30% of the hottest HB stars in omega Centauri show helium abundances well above the predictions from the helium enrichment scenario (Y = 0.42 corresponding to log nHe/nH approximately equal to -0.74). In addition the most helium-rich stars show strong carbon enrichment as predicted by the late hot flasher scenario. We conclude that the helium-rich HB stars in omega Cen cannot be explained solely by the helium-enrichment scenario invoked to explain the blue main sequence.

Moehler, S.↗

Mesospheric Water Vapor Retrieved from SABER/TIMED Measurements

The SABER instrument on board the TIMED satellite is a limb scanning infrared radiometer designed to measure temperature and minor constituent vertical profiles and energetics parameters in the mesosphere and lower thermosphere (MLT) The H2O concentrations are retrieved from 6.3 micron band radiances. The interpretation of this radiance requires developing a non-LTE H2O model that includes energy exchange processes with the system of O3 and O2 vibrational levels populated at the daytime through a number of photoabsorption and photodissociation processes. We developed a research model base on an extended H2O non-LTE model of Manuilova coupled with the novel model of the electronic kinetics of the O2 and O3 photolysis products suggested by Yankosvky and Manuilova. The performed study of this model helped u to develop and test an optimized operational model for interpretation of SABER 6.3 micron band radiances. The sensitivity of retrievals to the parameters of the model is discussed. The H2O retrievals are compared to other measurements for different seasons and locations.

Feofilov, Arte, G.↗

Assessment of the Quality of the Version 1.07 Temperature-Versus-Pressure Profiles of the Middle Atmosphere from TIMED/SABER

The quality of the retrieved temperature-versus-pressure (or T(p)) profiles is described for the middle atmosphere for the publicly available Sounding of the Atmosphere using Broadband Emission Radiometry (SABER) Version 1.07 (V1.07) data set. The primary sources of systematic error for the SABER results below about 70 km are (1) errors in the measured radiances, (2) biases in the forward model, and (3) uncertainties in the corrections for ozone and in the determination of the reference pressure for the retrieved profiles. Comparisons with other correlative data sets indicate that SABER T(p) is too high by 1-3 K in the lower stratosphere but then too low by 1 K near the stratopause and by 2 K in the middle mesosphere. There is little difference between the local thermodynamic equilibrium (LTE) algorithm results below about 70 km from V1.07 and V1.06, but there are substantial improvements/differences for the non-LTE results of V1.07 for the upper mesosphere and lower thermosphere (UMLT) region. In particular, the V1.07 algorithm uses monthly, diurnally averaged CO2 profiles versus latitude from the Whole Atmosphere Community Climate Model. This change has improved the consistency of the character of the tides in its kinetic temperature (T(sub k)). The T(sub k) profiles agree with UMLT values obtained from ground-based measurements of column-averaged OH and O2 emissions and of the Na lidar returns, at least within their mutual uncertainties. SABER T(sub k) values obtained near the mesopause with its daytime algorithm also agree well with the falling sphere climatology at high northern latitudes in summer. It is concluded that the SABER data set can be the basis for improved, diurnal-to-interannual-scale temperatures for the middle atmosphere and especially for its UMLT region.

Remsberg, E. E.↗

Improved Determination of Surface and Atmospheric Temperatures Using Only Shortwave AIRS Channels

AIRS was launched on EOS Aqua on May 4, 2002, together with AMSU-A and HSB, to form a next generation polar orbiting infrared and microwave atmospheric sounding system. AIRS is a grating spectrometer with a number of linear arrays of detectors with each detector sensitive to outgoing radiation in a characteristic frequency v(sub i) with a spectral band pass delta v(sub i) of roughly v(sub i) /1200. AIRS contains 2378 spectral channels covering portions of the spectral region 650 cm(exp -1) (15.38 gm) - 2665 cm(exp -1)' (3.752 micrometers). These spectral regions contain significant absorption features from two CO2 absorption bands, the 15 micrometer (longwave) CO2 band, and the 4.3 micrometer (shortwave) CO, absorption band. There are also two atmospheric window regions, the 12 micrometerm - 8 micrometer (longwave) window, and the 4.17 micrometer - 3.75 micrometer (shortwave) window. Historically, determination of surface and atmospheric temperatures from satellite observations was performed using primarily observations in the longwave window and CO2 absorption regions. One reason for this was concerns about the effects, during the day, of reflected sunlight and non-Local Thermodynamic Equilibrium (non-LTE) on the observed radiances in the shortwave portion of the spectrum. According to cloud clearing theory, more accurate soundings of both surface skin and atmospheric temperatures can be obtained under partial cloud cover conditions if one uses the longwave channels to determine cloud cleared radiances R(sub i) for all channels, and uses R(sub i) only from shortwave channels in the determination of surface and atmospheric temperatures. This procedure is now being used by the AIRS Science Team in preparation for the AIRS Version 6 Retrieval Algorithm. This paper describes how the effects on the radiances of solar radiation reflected by clouds and the Earth's surface, and also of non-LTE, are accounted for in the analysis of the data. Results are presented for both daytime and nighttime conditions showing improved surface and atmospheric soundings under partial cloud cover resulted from not using R(sub i) in the retrieval process for any longwave channels sensitive to cloud effects. This improvement is made possible because AIRS NEDT in the shortwave portion of the spectrum is extremely low.

Susskind,Joel↗

The Hot Horizontal-Branch Stars in omega Centauri

Context. UV observations of some massive globular clusters have revealed a significant population of stars hotter and fainter than the hot end of the horizontal branch (HB), the so-called blue hook stars. This feature might be explained either by the late hot flasher scenario where stars experience the helium flash while on the white dwarf cooling curve or by the progeny of the helium-enriched sub-population recently postulated to exist in some clusters. Previous spectroscopic analyses of blue hook stars in co Cen and NGC 2808 support the late hot flasher scenario, but the stars contain much less helium than expected and the predicted C, N enrichment could not be verified. Aims. We compare observed effective temperatures, surface gravities, helium abundances, and carbon line strengths (where detectable) of our targets stars to the predictions of the two scenarios. Methods. Moderately high resolution spectra of hot HB stars in the globular cluster omega-Cen were analysed for radial velocity variations, atmospheric parameters and abundances using LTE and non-LTE model atmospheres. Results. We find no evidence for close binaries among our target stars. All stars below 30 000 K are helium-poor and very similar to HB stars observed in that temperature range in other globular clusters. In the temperature range 30000 K to 50000 K we find that 28% of our stars are helium-poor (log ((sup n)He/(sup n )H)< - 1.6), while 72% have roughly solar or super-solar helium abundance (log ((sup n)He/(sup n )H) >/= -1.5). We also find carbon enrichment strongly correlated with helium enrichment, with a maximum carbon enrichment of 3% by mass. Conclusions. The strong carbon enrichment in tandem with helium enrichment is predicted by the late hot flasher scenario, but not by the helium-enrichment scenario. We conclude that the helium-rich HB stars in omega-Cen cannot be explained solely by the helium-enrichment scenario invoked to explain the blue main sequence.

Moehler, S.↗

The Temperature and Distribution of Organic Molecules in the Inner Regions of T Tauri Disks

"High-resolution NIR spectroscopic observations of warm molecular gas emission from young circumstellar disks allow us to constrain the temperature and composition of material in the inner planet-forming region. By combining advanced data reduction algorithms with accurate modeling of the terrestrial atmospheric spectrum and a novel double-differencing data analysis technique, we have achieved very high-contrast measurements (S/N approx. 500-1000) of molecular emission at 3 microns. In disks around low-mass stars, we have achieved the first detections of emission from HCN and C2H2 at near-infrared wavelengths from several bright T Tauri stars using the CRIRES spectrograph on the Very Large Telescope and NIRSPEC spectrograph on the Keck Telescope. We spectrally resolve the line shape, showing that the emission has both a Keplerian and non-Keplerian component as observed previously for CO emission. We used a simplified single-temperature local thermal equilibrium (LTE) slab model with a Gaussian line profile to make line identifications and determine a best-fit temperature and initial abundance ratios, and we then compared these values with constraints derived from a detailed disk radiative transfer model assuming LTE excitation but utilizing a realistic temperature and density structure. Abundance ratios from both sets of models are consistent with each other and consistent with expected values from theoretical chemical models, and analysis of the line shapes suggests that the molecular emission originates from within a narrow region in the inner disk (R < 1 AU)."

Mandell, Avi↗

Modeling Circumstellar Disks of B-Type Stars with Observations from the Palomar Testbed Interferometer

Geometrical (uniform disk) and numerical models were calculated for a set of B-emission (Be) stars observed with the Palomar Testbed Interferometer (PTI). Physical extents have been estimated for the disks of a total of15 stars via uniform disk models. Our numerical non-LTE models used parameters for the B0, B2, B5, and B8spectral classes and following the framework laid by previous studies, we have compared them to infrared K-band interferometric observations taken at PTI. This is the first time such an extensive set of Be stars observed with long-baseline interferometry has been analyzed with self-consistent non-LTE numerical disk models.

Grzenia, B. J.↗

Stellar Laboratories: New GeV and Ge VI Oscillator Strengths and their Validation in the Hot White Dwarf RE0503-289

State-of-the-art spectral analysis of hot stars by means of non-LTE model-atmosphere techniques has arrived at a high level of sophistication. The analysis of high-resolution and high-S/N spectra, however, is strongly restricted by the lack of reliable atomic data for highly ionized species from intermediate-mass metals to trans-iron elements. Especially data for the latter has only been sparsely calculated. Many of their lines are identified in spectra of extremely hot, hydrogen-deficient post-AGB stars. A reliable determination of their abundances establishes crucial constraints for AGB nucleosynthesis simulations and, thus, for stellar evolutionary theory. Aims. In a previous analysis of the UV spectrum of RE 0503-289, spectral lines of highly ionized Ga, Ge, As, Se, Kr, Mo, Sn, Te, I, and Xe were identified. Individual abundance determinations are hampered by the lack of reliable oscillator strengths. Most of these identified lines stem from Ge V. In addition, we identified Ge VI lines for the first time. We calculated Ge V and Ge VI oscillator strengths in order to reproduce the observed spectrum. Methods. We newly calculated Ge V and Ge VI oscillator strengths to consider their radiative and collisional bound-bound transitions in detail in our non-LTE stellar-atmosphere models for the analysis of the Ge IV-VI spectrum exhibited in high-resolution and high-S/N FUV (FUSE) and UV (ORFEUS/BEFS, IUE) observations of RE 0503-289. Results. In the UV spectrum of RE 0503-289, we identify four Ge IV, 37 Ge V, and seven Ge VI lines. Most of these lines are identified for the first time in any star. We can reproduce almost all Ge IV, GeV, and Ge VI lines in the observed spectrum of RE 0503-289 (T(sub eff) = 70 kK, log g = 7.5) at log Ge = -3.8 +/- 0.3 (mass fraction, about 650 times solar). The Ge IV/V/VI ionization equilibrium, that is a very sensitive T(sub eff) indicator, is reproduced well. Conclusions. Reliable measurements and calculations of atomic data are a prerequisite for stellar-atmosphere modeling. Our oscillator-strength calculations have allowed, for the first time, Ge V and Ge VI lines to be successfully reproduced in a white dwarf s (RE 0503-289) spectrum and to determine its photospheric Ge abundance.

Rauch, T.↗

THz Limb Sounder (TLS) for Lower Thermospheric Wind, Oxygen Density, and Temperature

Neutral winds are one of the most critical measurements in the lower thermosphere and E region ionosphere (LTEI) for understanding complex electrodynamic processes and ion-neutral interactions. We are developing a high-sensitivity, low-power, noncryogenic 2.06 THz Schottky receiver to measure wind profiles at 100-140 km. The new technique, THz limb sounder (TLS), aims to measure LTEI winds by resolving the wind-induced Doppler shift of 2.06 THz atomic oxygen (OI) emissions. As a transition between fine structure levels in the ground electronic state, the OI emission is in local thermodynamic equilibrium(LTE) at altitudes up to 350km. This LTE property, together with day-and-night capability and small line-of-sight gradient, makes the OI limb sounding a very attractive technique for neutral wind observations. In addition to the wind measurement, TLS can also retrieve [OI] density and neutral temperature in the LTEI region. TLS leverages rapid advances in THz receiver technologies including subharmonically pumped (SHP)mixers and Schottky-diode-based power multipliers. Current SHP Schottky receivers have produced good sensitivity for THz frequencies at ambient environment temperatures (120-150 K), which are achievable through passively cooling in spaceflight. As an emerging technique, TLS can fill the critical data gaps in the LTEI neutral wind observations to enable detailed studies on the coupling and dynamo processes between charged and neutral molecules.

wind profiles↗

Formation of the UV Spectrum of Molecular Hydrogen in the Sun

Ultraviolet (UV) lines of molecular hydrogen have been observed in solar spectra for almost four decades, but the behavior of the molecular spectrum and its implications for solar atmospheric structure are not fully understood. Data from the High-Resolution Telescope Spectrometer (HRTS) instrument revealed that H2 emission forms in particular regions, selectively excited by a bright UV transition region and chromospheric lines. We test the conditions under which H2 emission can originate by studying non-LTE models, sampling a broad range of temperature stratifications and radiation conditions. Stratification plays the dominant role in determining the population densities of H2, which forms in greatest abundance near the continuum photosphere. However, opacity due to the photoionization of Si and other neutrals determines the depth to which UV radiation can penetrate to excite the H2. Thus the majority of H2 emission forms in a narrow region, at about 650 km in standard one dimensional (1D) models of the quiet Sun, near the tau = 1 opacity surface for the exciting UV radiation, generally coming from above. When irradiated from above using observed intensities of bright UV emission lines, detailed non-LTE calculations show that the spectrum of H2 seen in the quiet-Sun Solar Ultraviolet Measurement of Emitted Radiation atlas spectrum and HRTS light-bridge spectrum can be satisfactorily reproduced in 1D stratified atmospheres, without including three-dimensional or time-dependent thermal structures. A detailed comparison to observations from 1205 to 1550 Angstroms is presented, and the success of this 1D approach to modeling solar UV H2 emission is illustrated by the identification of previously unidentified lines and upper levels in HRTS spectra.

Jaeggli, S. A.↗

Chemical Complexity Induced by Efficient Ice Evaporation in the Barnard 5 Molecular Cloud

Cold gas-phase water has recently been detected in a cold dark cloud, Barnard 5 located in the Perseus complex, by targeting methanol peaks as signposts for ice mantle evaporation. Observed morphology and abundances of methanol and water are consistent with a transient non-thermal evaporation process only affecting the outermost ice mantle layers, possibly triggering a more complex chemistry. Here we present the detection of the complex organic molecules (COMs) acetaldehyde (CH3CHO) and methyl formate (CH3OCHO), as well as formic acid (HCOOH) and ketene (CH2CO), and the tentative detection of di-methyl ether (CH3OCH3) towards the ''methanol hotspot'' of Barnard 5 located between two dense cores using the single dish OSO 20 m, IRAM 30 m, and NRO 45 m telescopes. The high energy cis-conformer of formic acid is detected, suggesting that formic acid is mostly formed at the surface of interstellar grains and then evaporated. The detection of multiple transitions for each species allows us to constrain their abundances through LTE and non-LTE methods. All the considered COMs show similar abundances between approx. 1 and approx. 10% relative to methanol depending on the assumed excitation temperature. The non-detection of glycolaldehyde, an isomer of methyl formate, with a [glycolaldehyde]/[methyl formate] abundance ratio lower than 6%, favours gas phase formation pathways triggered by methanol evaporation. According to their excitation temperatures derived in massive hot cores, formic acid, ketene, and acetaldehyde have been designated as ''lukewarm'' COMs whereas methyl formate and di-methyl ether were defined as ''warm'' species. Comparison with previous observations of other types of sources confirms that lukewarm and warm COMs show similar abundances in low-density cold gas whereas the warm COMs tend to be more abundant than the lukewarm species in warm protostellar cores. This abundance evolution suggests either that warm COMs are indeed mostly formed in protostellar environments and/or that lukewarm COMs are efficiently depleted by increased hydrogenation efficiency around protostars.

ISM: molecules↗

Planetary Spectrum Generator: An Accurate Online Radiative Transfer Suite for Atmospheres, Comets, Small Bodies and Exoplanets

We have developed an online radiative-transfer suite (https://psg.gsfc.nasa.gov) applicable to a broad range of planetary objects (e.g., planets, moons, comets, asteroids, TNOs, KBOs, exoplanets). The Planetary Spectrum Generator (PSG) can synthesize planetary spectra (atmospheres and surfaces) for a broad range of wavelengths (UV/Vis/near-IR/IR/far-IR/THz/sub-mm/Radio) from any observatory (e.g., JWST, ALMA, Keck, SOFIA), any orbiter (e.g., ExoMars, Juno), or any lander (e.g., MSL). This is achieved by combining several state-of-the-art radiative transfer models, spectroscopic databases and planetary databases (i.e., climatological and orbital). PSG has a 3D (three-dimensional) orbital calculator for most bodies in the solar system, and all confirmed exoplanets, while the radiative-transfer models can ingest billions of spectral signatures for hundreds of species from several spectroscopic repositories. It integrates the latest radiative-transfer and scattering methods in order to compute high resolution spectra via line-by-line calculations, and utilizes the efficient correlated-k method at moderate resolutions, while for computing cometary spectra, PSG handles non-LTE and LTE excitation processes. PSG includes a realistic noise calculator that integrates several telescope/instrument configurations (e.g., interferometry, coronagraphs) and detector technologies (e.g., CCD, heterodyne detectors, bolometers). Such an integration of advanced spectroscopic methods into an online tool can greatly serve the planetary community, ultimately enabling the retrieval of planetary parameters from remote sensing data, efficient mission planning strategies, interpretation of current and future planetary data, calibration of spectroscopic data, and development of new instrument/spacecraft concepts.

Villanueva, G. L.↗

Chemical Complexity Induced by Efficient Ice Evaporation in the Barnard 5 Molecular Cloud

Cold gas-phase water has recently been detected in a cold dark cloud, Barnard 5 located in the Perseus complex, by targeting methanol peaks as signposts for ice mantle evaporation. Observed morphology and abundances of methanol and water are consistent with a transient non-thermal evaporation process only affecting the outermost ice mantle layers, possibly triggering a more complex chemistry. Here we present the detection of the complex organic molecules (COMs) acetaldehyde (CH3CHO) and methyl formate (CH3OCHO), as well as formic acid (HCOOH) and ketene (CH2CO), and the tentative detection of di-methyl ether (CH3OCH3) towards the ‘methanol hotspot’ of Barnard 5 located between two dense cores using the single dish OSO 20m, IRAM 30m, and NRO 45m telescopes. The high energy cis- conformer of formic acid is detected, suggesting that formic acid is mostly formed at the surface of interstellar grains and then evaporated. The detection of multiple transitions for each species allows us to constrain their abundances through LTE and non-LTE methods. All the considered COMs show similar abundances between ∼ 1 and ∼ 10 % relative to methanol depending on the assumed excitation temperature. The non-detection of glycolaldehyde, an isomer of methyl formate, with a [glycolaldehyde]/[methyl formate] abundance ratio lower than 6 %, favours gas phase formation pathways triggered by methanol evaporation. According to their excitation temperatures derived in massive hot cores, formic acid, ketene, and acetaldehyde have been designated as ‘lukewarm’ COMs whereas methyl formate and di-methyl ether were defined as ‘warm’ species. Comparison with previous observations of other types of sources confirms that lukewarm and warm COMs show similar abundances in low-density cold gas whereas the warm COMs tend to be more abundant than the lukewarm species in warm protostellar cores. This abundance evolution suggests either that warm COMs are indeed mostly formed in protostellar environments and/or that lukewarm COMs are efficiently depleted by increased hydrogenation efficiency around protostars.

astrochemistry – ISM: abundances – ISM: clouds – I↗

HydroGEN: Low Temperature Electrolysis

In low temperature electrolysis (LTE), it is imperative to both enhance and explore durability and demonstrate the opportunities for anion exchange membrane-based water electrolysis (AEMWE). The advantage of alkaline-based systems is primarily reduced capital cost: high pH enabling platinum group metal (PGM)-free catalysts and coatings, and the enhanced stability of those components compared to proton exchange membrane (PEM) -based systems. Compared to the water-only fed AEMWE in previous LTE 2.0 work, supporting electrolytes can allow for a significant improvement in performance through higher site-access and stability by reducing utilization and overpotential stresses that lead to catalyst layer delamination.

HYDROGEN↗

Modeling and Simulation of Radiative Compressible Flows in Aerodynamic Heating Arc-Jet Facility

Numerical simulations of an arc heated flow inside NASA's 20 [MW] Aerodynamics heating facility (AHF) are performed in order to investigate the three-dimensional swirling flow and the current distribution inside the wind tunnel. The plasma is considered in Local Thermodynamics Equilibrium(LTE) and is composed of Air-Argon gas mixture. The governing equations are the Navier-Stokes equations that include source terms corresponding to Joule heating and radiative cooling. The former is obtained by solving an electric potential equation, while the latter is calculated using an innovative massively parallel ray-tracing algorithm. The fully coupled system is closed by the thermodynamics relations and transport properties which are obtained from Chapman-Enskog method. A novel strategy was developed in order to enable the flow solver and the radiation calculation to be preformed independently and simultaneously using a different number of processors. Drastic reduction in the computational cost was achieved using this strategy. Details on the numerical methods used for space discretization, time integration and ray-tracing algorithm will be presented. The effect of the radiative cooling on the dynamics of the flow will be investigated. The complete set of equations were implemented within the COOLFluiD Framework. Fig. 1 shows the geometry of the Anode and part of the constrictor of the Aerodynamics heating facility (AHF). Fig. 2 shows the velocity field distribution along (x-y) plane and the streamline in (z-y) plane.

Pasma flows↗