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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

IR heating of the cometary atmosphere

The transfer of radiation, solar and IR dust, in the cometary atmosphere is analyzed using a six-band radiative transfer model. The first five bands correlate with the strongest IR band of H2O and the sixth corresponds to the bulk of solar energy. The radiation field for each band is calculated as a function of the cometocentric distance using the three-stream approximation. It is observed that the mean intensity of the IR radiation field generated by the dust and the cometary nucleus drops from a very large value of about 40,000 erg/sq cm sec at the surface to 400 erg/sq cm sec at 7 km, rises to a peak value of 500 erg/sq cm sec at 100 km and then falls off monotonically. The causes of these changes in radiation field intensity are discussed. The effect of variation of the IR radiation field on the gas temperature is studied.

Marconi, M. L.↗
NASA NTRS1988

Comparison of satellite IR rain estimates with radar rain observations in hurricanes

Radar-observed rainrates and rain areas obtained for the Hurricanes Frederic (1979), Alicia (1983), and Diana (1984) were used in conjunction with GOES IR data to examine the validity of three satellite IR rain estimation techniques: the Arkin (1983) method, the Negri-Adler-Wetzel (1984) technique, and the convective-stratiform technique of Adler and Negri (1987). The Alicia hurricane was also monitored using the subjective manual technique of Spayd and Scofield (1984). It is shown that the success of IR techniques in identifying areas of rainfall depends on the hurricane feature being addressed. Thus, the three objective IR techniques were unable to identify the locations of radar-observed eyewall and inner band precipitation areas because of strong vertical wind shear in the eyewall and the lack of the vertical extent of stratiform precipitation beneath the central dense overcast.

Morris, K. Robert↗
NASA NTRS1988

Study of nonlinear optical sBs phenomena in mid IR fibers

This is the first reported attempt at investigation of the sBs phenomena in mid IR fibers using externally fed or laser self generated low frequency and microwave frequency phonon waves as diagnostic probes of such processes. The observation of laser excited phonon emissions in the mid IR fiber and direct modulation of CO2 laser pulse transmission by externally imposed low frequency radiation is the first indication of the predicted low sBs threshold in these fibers in the phonon rich mid IR spectral region. The prospect of wide applications of the sBs process in optical switching, phase conjugation and ultimately optical computing and possible deleterious effects in mid IR laser heterodyne spectroscopy, sideband modulation and transmitted power limitation is discussed.

Yu, Chung↗
NASA NTRS1990

Imaging and two-dimensional spectra of the IR-bright galaxy NGC 2146 - A recent low-energy merger?

New data are presented on the IR-luminous galaxy NGC 2146 from several sources: direct imaging in B, R, and H-alpha; IR imaging in the J, H, and K bands; long-slit spectroscopy at optical and IR wavelengths; and scanning etalon observations in H-alpha. The results allow measurement of the interstellar extinction in the dust lane, and estimation of the true luminosity of the galaxy and nuclear regions. The spectra indicate that there is no active nucleus, and measure the changing ratio of forbidden to permitted lines across the galaxy. IR images and colors indicate the existence of a significant population of hot young stars in the central regions of the system. The H-alpha velocity maps show the full radial-velocity pattern, and suggest that the system consists of a disturbed disk and a merging or interacting arm which connects to the inner dust and radio structures. Outer H-alpha and H I structures appear to be the earlier remnants of this spiraling merger.

Hutchings, J. B.↗
NASA NTRS1991

High-resolution CO observations of luminous infrared galaxies with large L(ir)/L(B) ratios - IRAS 10173 + 0828, Zw 049.057, IRAS 17208 - 0014

The Owens Valley mm-wave interferometer has been used for high-resolution (about 3-7 arcsec) mapping of CO emission in three luminous IRAS galaxies: IRAS 17208 - 0014, 15107 + 0724, and IRAS 10173 + 0828. These galaxies are among the most extreme, in terms of their L(ir)/L(B) ratio, for objects in the IRAS Bright Galaxy Surveys. The CO emission detected in the three galaxies originates from a single region centered on the IRAS emission peak. These observations have shown that these galaxies have similar values for the global L(ir)/M(H2) ratio, for the surface density of molecular gas in their central regions and for the extinction toward the nucleus (above 300 mag). A high L(ir)/L(B) ratio seems to be a good predictor for both a high global L(ir)/M(H2) ratio and very large central H2 surface densities.

Planesas, P.↗
NASA NTRS1991

A windswept cometary tail on the Galactic center supergiant IRS 7

High-resolution VLA observations provide evidence of optically thick radio emission from IRS 7, a cool red supergiant star, located at a projected distance of roughly 1 1t-yr from the Galactic center. IRS 7 shows a remarkable tail of ionized gas pointing directly away from the compact nonthermal radio source at the Galactic center, Sgr A(asterisk). Given previous evidence for a strong source of UV emission and for a strong circumnuclear wind emanating from the Galactic center, the free-free emission from IRS 7 and its associated tail are interpreted in terms of the ionization and removal of the circumstellar envelope of the red supergiant either by the ram pressure of the nuclear wind or by the pressure of radiation arising from the immediate vicinity of Sgr A(asterisk). The wind mechanism is preferred because: (1) the force it can potentially exert is much greater; and (2) Sgr A(asterisk) is clearly not a known source of luminous energy in the near-IR, whereas it remains a plausible source of a hot, high-velocity wind. Also considered is the potential effect of a nuclear wind upon the atmospheres of red giants in the inner parsec.

Yusef-Zadeh, F.↗
NASA NTRS1993

Estimation of monthly rainfall over Japan and surrounding waters from a combination of low-orbit microwave and geosynchronous IR data

A method is described for estimating the mean monthly rainfall data for climate studies by combining the geosynchronous IR and low-orbit microwave data. The microwave technique uses the brightness temperature at 37 and 86 GHz from the Special Sensor Microwave/Imager instrument on board the DMSP satellite to define raining areas over water and land, and the 86-GHz scattering signal to assign rain rate based on cloud model-microwave calculations. The IR estimates are initially computed separately, using hourly data from the Japanese Geostationary Meteorological Satellite. Results show that, in areas where the microwave technique performs well, the combined microwave-IR monthly total estimates have better error statistics than either the microwave of the IR techniques individually.

Adler, Robert F.↗
NASA NTRS1991

Need for active structures in future large IR and sub-mm telescopes

The potential of active structures technology for future IR and sub-mm telescopes deployed in space is discussed. A space infrared telescope with an aperture of at least 8 m, operating at about 50 k with surface precision better that 0.5 microns is required for future work in space IR and sub-mm astronomy. Telescope parameters, noise, and sensitivity are discussed. The effects of large scale figure errors are examined and conceptual designs of future space IR and sub-mm telescopes are presented. Possible uses of active structures technology and feedback control in future IR and sub-mm space observatories are suggested.

Rapp, Donald↗
NASA NTRS1994

The structure and nature of NGC 2017 IRS. 1: High-resolution radio continuum maps

We have observed the star formation cluster NGC 2071 IRS 1, 2, and 3, with 0.14 sec spatial resolution at 2 cm. The strong source IRS 1 breaks up into a bright peak sitting on a narrow line emission extending over about 400 AU, with three much weaker peaks. This ridge, which has a p.a. = 100 deg, is not aligned with any of the other structures that have previously been seen around IRS 1: its orientation is about 55 deg from the CO outflow direction, and 35 deg from a hypothetical disk direction. The spectral and spatial results, combined with earlier radio and infrared observations, indicate that most likely the radio and infrared emission from the exciting source, IRS 1, is produced by a dense wind hidden by at least 100 visual magnitudes of extinction; the extended ridge of emission comes from an optically thin H II region with characteristic dimensions of approximately AU and which may result from a clumpy distribution of local gas and dust.

Smith, Howard A.↗
NASA NTRS1992

Development of IR radiation simulator for spacecraft thermal testing

The aim was to simulate, in a ground test, the solar radiation environment to which the Ofeq satellite would be exposed in orbit. The solar simulator usually used is very expensive, as are its operation and maintenance, therefore an infrared (IR) simulator was used; its development involved the creation of uniform IR fluxes onto the irregular geometry of a spacecraft. The tests were carried out on a thermal model of the satellite and the model was verified in a solar simulator test at a European space center. Heat flux mapping software was developed to plan the positioning of the heating elements which generated the IR fluxes and a system was built for heat flux and temperature monitoring and control. A special heat flux sensor was developed to measure the energy absorbed by the satellite surfaces; its calibration had to be independent of wavelength, so that the measurements obtained at IR wavelengths would be equivalent to the actual solar radiation effects. The results of the verification experiment are presented; their conformity with predicted values indicates that the technique developed is a suitable tool for satellite design verification.

Shimrony, Yoram↗
NASA NTRS2016

Comparison of Heat Flux Gages for High Enthalpy Flows - NASA Ames and IRS

This article is a companion to a paper on heat flux measurements as initiated under a Space Act Agreement in 2011. The current focus of this collaboration between the Institute of Space Systems (IRS) of the University of Stuttgart and NASA Ames Research Center is the comparison and refinement of diagnostic measurements. A first experimental campaign to test different heat flux gages in the NASA Interaction Heating Facility (IHF) and the Plasmawindkanaele (PWK) at IRS was established. This paper focuses on the results of the measurements conducted at IRS. The tested gages included a at face and hemispherical probe head, a 4" hemispherical slug calorimeter, a null-point calorimeter from Ames and a null-point calorimeter developed for this purpose at IRS. The Ames null-point calorimeter was unfortunately defective upon arrival. The measured heat fluxes agree fairly well with each other. The reason for discrepancies can be attributed to signal-to-noise levels and the probe geometry.

spacecraft reentry↗
NASA NTRS2016

The Spectacular Radio-Near-IR-X-Ray Jet of 3C 111: the X-Ray Emission Mechanism and Jet Kinematics

Relativistic jets are the most energetic manifestation of the active galactic nucleus (AGN) phenomenon. AGN jets are observed from the radio through gamma-rays and carry copious amounts of matter and energy from the subparsec central regions out to the kiloparsec and often megaparsec scale galaxy and cluster environs. While most spatially resolved jets are seen in the radio, an increasing number have been discovered to emit in the optical/near- IR and/or X-ray bands. Here we discuss a spectacular example of this class, the 3C 111 jet, housed in one of the nearest, double-lobed FR II radio galaxies known. We discuss new, deep Chandra and Hubble Space Telescope (HST) observations that reveal both near-IR and X-ray emission from several components of the 3C 111 jet, as well as both the northern and southern hotspots. Important differences are seen between the morphologies in the radio, X-ray, and near-IR bands. The long (over 100 kpc on each side), straight nature of this jet makes it an excellent prototype for future, deep observations, as it is one of the longest such features seen in the radio, near-IR/optical, and X-ray bands. Several independent lines of evidence, including the X-ray and broadband spectral shape as well as the implied velocity of the approaching hotspot, lead us to strongly disfavor the EC/CMB model and instead favor a two-component synchrotron model to explain the observed X-ray emission for several jet components. Future observations with NuSTAR, HST, and Chandra will allow us to further constrain the emission mechanisms.

galaxies: active – galaxies: jets – radio cont↗
NASA NTRS2017

Composite Reflective Absorptive IR-Blocking Filters Embedded in Metamaterial Antireflection Coated Silicon

Infrared (IR)-blocking filters are crucial for controlling the radiative loading on cryogenic systems and for optimizing the sensitivity of bolometric detectors in the far-IR. We present a new IR filter approach based on a combination of patterned frequency-selective structures on silicon and a thin (2575 micron thick) absorptive composite based on powdered reststrahlen absorbing materials. For a 300 K blackbody, this combination reflects approximately 50% of the incoming light and blocks greater than.99.8% of the total power with negligible thermal gradients and excellent low-frequency transmission. This allows a reduction in the IR thermal loading to negligible levels in a single cold filter. These composite filters are fabricated on silicon substrates, which provide excellent thermal transport laterally through the filter and ensure that the entire area of the absorptive filter stays near the bath temperature. A metamaterial antireflection coating cut into these substrates reduces in-band reflections to below 1%, and the in-band absorption of the powder mix is below 1% for signal bands below 750 GHz. This type of filter can be directly incorporated into silicon refractive optical elements.

Munson, C. D.↗
NASA NTRS2020

Exploring the Limits of the Data-Model-Theory Synergy: “Hot” MW Transitions for Rovibrational IR Studies

In order to further improve the accuracy of rovibrational IR line lists generated from the “Best Theory +Reliable High-resolution Experiment” (BTRHE) strategy from 0.01-0.05 cm-1, or 300-1500 MHz, to ~10 MHz, we explore the current limits of the Data-Model-Theory synergy by examining the accuracy and consistency of existing data, then propose that “hot” bands in microwave (MW) spectra is the solution we need for future enhancements. The Ames SO2 J=0-20 rovibrational energy levels computed on the semi-empirically refined Ames-2 potential energy surface (PES) are fit to the Effective Hamiltonian (EH) model regularly used in the experimental infrared (IR) analysis for SO2 isotopologues. In the fitted EH(Ames) model, the rotational constants A/B/C and all 5 quartic centrifugal distortion constants display clear, systematic, and consistent patterns along the vibrational state energy or quanta. Such consistent patterns may facilitate the vibrational assignments for MW hot bands and extract more information from high temperature MW spectra. Some EH(Expt) analyses were carried out with the lowest order Coriolis Coupling term, C1. Their constants should not be directly compared with other EH(Expt) and EH(Ames) results. After excluding them, our  = EH(Ames)- EH(Expt) analyses for 5 isotopologues (626, 636, 646, 628 and 828) indicates some loss of accuracy and consistency starting from vibrational states as low as 22 or 1000 cm-1. Some EH parameters, e.g. K, may have relative deviations as large as 50-100% and totally lose any recognizable patterns. This simply means that current EH(Expt) models do not have the system-wide consistency we need to further refine the EH(Ames) and Ames rovibrational IR line lists. A large part of such defects are probably inherited from the limited precision of experimental line positions, i.e. 1E-3 ~ 1E-4 cm-1, or 3-30 MHz. This is confirmed in a series of truncation tests using the Ames data. Although the EH(Ames) consistency may help identify unreliable rovibrational EH(Expt) parameters, and make reliable predictions for minor isotopologues and unobserved vibrational bands, we believe only the highly accurate “hot” MW transitions can provide real enhancements for EH(Expt) accuracy and consistency. “Hot” MW spectra should play a more significant role in the future synergy of Data, Model, and Theory in the field of rovibrational IR studies.

Xinchuan Huang↗
NASA NTRS2018

Quantitative validation of Ames IR intensity and new line lists for (32/33/34)S(16)O2, (32)S(18)O2 and (16)O(32)S(18)O

The quality of Ames-296K SO2 Infrared (IR) line list intensities is first validated by quantitative exploration of several dipole moment surfaces (DMSs) and partition sum convergence. The DMSs are computed with several of Dunning’s correlation-consistent basis sets and their vibrational dependence are compared to the empirical model derived from Stark effect experiments reported by D. Patel, D. Margolese, and T.R. Dykea [J.Chem.Phys. 70, 2740 (1979)]. The effective dipole deviations from the DMS adopted in the Ames IR lists is 0.2-0.4% for vibrational states up to 3v3. The vibrational dependence of the dipole moment is also in good agreement, except for nv1. Partition sum convergence at 296K is confirmed by new calculations with rotational quantum number J up to 150 and upper state E’ up to 8000 cm-1. The isotopologue consistency of the Ames IR line lists is superior relative to the regular Effective Hamiltonian (EH) models and Effective Dipole Moment (EDM) models. The v1+v2 and v2+v3 intensity consistency check reveals the recently reported experimental intensities need significant improvement or re-analysis. After the accuracy, convergence, and isotopologue consistency have been confirmed, the theoretical Ames-296K intensities are combined with the experimental line positions or EH models that experimental spectroscopists published after 2009. Three high-resolution IR line sets are reported for the (32/33/34)S(16)O2, (32)S(18)O2 and (16)O(32)S(18)O isotopologues: (1) the “New Lines Sets” include experimentally measured line positions; (2) the “Expanded Line Sets” include possible transitions among new rovibrational levels assigned in experiments and ground state (GS) levels predicted by reliable EH models; (3) the “Ames + MARVEL Sets” include possible transitions among all those levels reported in a recent MARVEL analysis. [Tóbiás et al, JQSRT 208, 152 (2018)]. Compared to the limited data in High-resolution TRANsmission molecular absorption database (HITRAN), these line sets have significantly improved the data coverage up to 4000 cm-1. Some missing bands can be traced to the unpublished experimental data. The isotopologue consistency of these line sets will help identify the uncertainties and defects in the experimental EH and EDM models. These line sets are good candidates for the next HITRAN update, if line shape parameters are available. The line sets can be downloaded from supplementary files or from the Ames Molecular Spectroscopic Database at http://huang.seti.org.

Xinchuan Huang↗
NASA NTRSDate not supplied

Pushing the Application Limit of Hyperspectral IR Sounder Remote Sensing for Frontiers of Weather and Climate Studies

Since the launch of AQUA Atmospheric Infrared Sounder (AIRS) in 2002, space-borne hyperspectral infrared (IR) sounders have provided information-rich, climate quality, and time-continuous spectral radiance measurements at the top of the atmosphere for more than two decades. Satellite based hyperspectral IR sensors, including AIRS, Cross-track Infrared Sounder (CrIS), and Infrared Atmospheric Sounding Interferometer (IASI), have demonstrated their critical roles for various weather applications and climate related studies. New use of hyperspectral IR sounder data will focus on underexplored areas. Current use of those data is generally limited by the capability of fully exploring and exploiting high spectral resolution information content, achieving radiometric accuracy and stability defined by the instruments, and merging data from different sensors to build a consistent, long-term climate data record. We will present the on-going research efforts at NASA Langley Research Center (LaRC) to develop novel hyperspectral IR sounder data products to address those potentials yet to be fully realized. Some applications of these products, including the study of Planetary Boundary Layer (PBL), the construction of climate data record over polar region, and the fusion of AIRS and CrIS data via the radiometric consistent climate fingerprinting method will be discussed.

Wan Wu↗
DOE OSTI2026

Complete Phase Transformation of Ir Nanowire Network into Defect-Rich Oxide Catalyst for High-Performance PEM Water Electrolysis

Iridium-based catalysts remain the most reliable option for the oxygen evolution reaction (OER) in proton exchange membrane water electrolyzers (PEMWEs). However, their high cost and limited performance represent critical barriers to the commercialization of this green hydrogen production technology. Herein, we report the creation of a metallic Ir nanowire network (IrNWN), which exhibits superior OER performance through its in-situ transition into an oxide structure with high intrinsic activity. At a low loading of 0.25 mgIr/cm2 in PEMWEs, IrNWN achieved a current density of 3.13 A/cm2 at a cell voltage of 1.8 V, outperforming the commercial Ir-based catalyst and surpassing the Department of Energy (DOE) 2026 technical target. Moreover, the high activity of IrNWN was maintained for 900 hours in a durability test at 2 A/cm2, showing a low degradation rate of 0.042 mV/hour. Structural analysis of the electrochemically oxidized IrNWN revealed the presence of mixed Ir oxidation states and a high density of surface terminal oxygen groups (μ1-O), which contributed to a reduced energy barrier for the rate-determining O-O coupling step.

oxygen evolution reaction↗
DOE OSTI2024

Carbon Nanospheres Loaded with Ir Single Atoms: Enhancing the Activity toward Formic Acid Oxidation by Increasing the Porosity

Theoretically, single-atom catalysts (SACs) offer 100 % atom utilization, making them strong candidates to replace expensive nanoparticles for catalysis. However, the structural supports used to anchor the SACs dramatically reduce the utilization efficiency of atoms ( i. e ., the percent of atoms actually accessible by reactants) by either encapsulating the SACs completely or creating severe diffusion limitation. Either of which leads to an overall low atom utilization and thus poor electrocatalytic activity similar to that of nanoparticles. In addressing this issue, we systematically investigated how the porous structure of carbon nanospheres affects the activity of Ir-SACs toward formic acid oxidation (FAO). Specifically, we utilized a kinetically-controlled growth strategy to produce uniform carbon nanospheres featuring yolk-shell, mesoporous, and hollow structures with Ir-SACs loaded throughout the structure. At a high specific surface area of 441 m 2 g -1 and exposed metal content of 1.82 wt %, the Ir-SACs based on mesoporous carbon nanospheres showed a remarkable FAO peak current density of 30.6 mA cm -2 , which was 283 and 46 times greater when benchmarked against the catalysts based on solid carbon nanospheres and 20 wt % Ir/C, respectively.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗