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At least 145 records · Page 8

Hexagonal boron nitride (h-BN) irradiated with 140 MeV protons

Here, hexagonal boron nitride was irradiated with 140 MeV protons to a fluence of ~6 10 20 p/cm 2 at T irr ~200 °C. Isotropic graphite was also irradiated alongside h-BN under similar conditions and fluence to enable direct comparison of the two similar structures. The effects of proton irradiation on dimensional stability and microstructure were studied using precision dilatometry and energy dispersive Xray diffraction techniques revealing by direct comparison to graphite that h-BN can better resist radiation damage from bombardment when irradiated with protons impinging normal to the crystallographic planes or along the crystallographic c-axis. X-ray diffraction experiments also revealed a preferred orientation of the crystallites in bulk samples near the sample surface, an orientation influenced by irradiation. Thermal studies using differential scanning calorimetry and thermogravimetric analysis to 740 °C, augmented by precision dilatometry, provided evidence of subtle phase transitions attributed to residual w-BN in the matrix. Irradiation appears to induce shifting of such transitions.

36 MATERIALS SCIENCE↗

A tutorial on the micro-trench technique for incident ion angle, material erosion, and impurity deposition measurements at plasma-facing surfaces

The micro-trench method is a new technique to measure polar and azimuthal incident ion angles, material erosion, and impurity deposition at plasma-facing surfaces, and has been applied in the DIII-D divertor. This article gives a tutorial of the micro-trench technique consisting of six steps: (1) micro-trench fabrication, (2) pre-exposure measurement of the fabricated micro-trench geometry, (3) tracer material deposition, (4) plasma exposure, (5) post-exposure observation of the tracer material, and (6) post-exposure measurement of the micro-trench geometry. Two criteria need to be satisfied to apply the micro-trench method successfully: (i) uniform impurity deposition on the micro-trench floor, and (ii) erosion dominated by the physical sputtering induced by the impinging ions. Furthermore, when those two criteria are satisfied, post-exposure analysis of the impurity deposition patterns on the micro-trench floor may be used to determine the polar and azimuthal incident ion directions (mean values of the ion angle directions), erosion rate, and impurity deposition rate during plasma exposure without computational interpretation.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Performance evaluation of the SPES FEBIAD ion source

SPES (Selective Production of Exotic Species) is the Radioactive Ion Beam (RIB) facility that is currently in the installation phase at the Istituto Nazionale di Fisica Nucleare in the Laboratori Nazionali di Legnaro (LNL-INFN). The main purpose of the facility is to deliver neutron-rich radioactive beams with a range of mass between 60 and 160 amu produced as fission products originated within a Uranium Carbide (UC x ) target impinged by high energy protons (40–70 MeV). In the last few years, the SPES group and their collaborators have focused on multiple aspects: development of various ISOL targets, ion sources, a high-power beam dump, versatile Front-End designs, primary proton beam and RIB diagnostics, design of beam optic components, and remote target handling. The development and optimization of ionization sources represents one of the most important R&D activities. The collaboration between SPES and ISOLDE (CERN) groups has enabled the evaluation of the performances of a novel FEBIAD ion source taking advantage of the ISOLDE off-line Front-End. In this paper, the results of efficiency and transversal emittance measurements of the new SPES FEBIAD ion source are presented and discussed. Particular attention is dedicated to the description of the experimental setup and to the comparison of experimental data with simulation to promote the reproducibility of the experimental tests with other types of sources.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Experimental and computational investigation of interactive flow induced oscillations of two tandem rough cylinders at 3×10 4 ≤Re≤1.2×10 5

The interactive flow induced oscillations (FIO) of two adjacent, elastically mounted, rigid, tandem, locally-rough cylinders in transverse flow direction are analyzed utilizing two-dimensional Unsteady Reynolds-Averaged Navier-Stokes (2-D URANS) equations and verified experimentally in the proximity-wake region. Three sets of experiments and simulations (K = 600N/m, ζ = 0.14; K = 600N/m, ζ = 0.26; K = 1,200N/m, ζ = 0.26; K is spring stiffness, ζ is damping ratio) of two tandem cylinders with turbulence stimulation are tested and simulated for Reynolds number in the range of 30,000 = Re ≤ 120,000. The reduced velocity range is U* = 2.48–14.22, the mass ratio is m* = 1.343, and the center-to-center in-flow spacing to diameter ratio is d/D = 2.57. The characteristics of amplitude response, frequency response, lift force, and interactive wake patterns are presented and discussed. The trends of the amplitude and frequency responses from numerical simulations are in good agreement with experimental results. The main conclusions of Reynolds number effect on interactive flow induced oscillations are: (1) Five significant flow patterns between two tandem locally-rough cylinders for different Reynolds numbers are observed through analyzing the complex but stable interactions between vortices and cylinders. (2) In the initial and upper VIV branches, the downstream cylinder's FIO is seriously interfered by the wake of the upstream cylinder. (3) The downstream cylinder is strongly impinged by the vortices shed from the upstream cylinder resulting in nearly 180O out-of-phase oscillations in transition from VIV to galloping and in-phase oscillations in galloping.

42 ENGINEERING↗

The characterization of wear-causing particles and silica sand in particular

Erodants and abradants are two types of wear-causing particles (WCP). Despite their effects on the severity and rate of wear, WCP are inadequately characterized in a surprising number of publications, especially those involving impingement erosion and three-body abrasion. That shortfall makes it difficult to correlate features of WCP with the details of worn surfaces, or to develop wear models that account for those features. It is argued that the documentation of WCP should go beyond simply reporting their composition and mean particle size. In late 1985, ASTM Committee G2 on Wear and Erosion established a task group on the characterization of WCP. At that time, image analysis was slower and less sophisticated than it is today. While that ASTM task group failed to produce a consensus standard, computerized particle characterization methods were developing in fields other than tribology, fields like geoscience, heavy sand mining, materials processing, and pharmaceuticals. A notable exception to this is ferrography, which is a widely-used diagnostic for lubricated tribosystems. In the context of dry wear, it is useful to identify which features of WCP would be beneficial to document, and to identify some techniques and scales of detail appropriate to particular tribosystems. In this paper, examples are presented for the morphological and mechanical characterization of silica sand grains, as prompted by a triboanalysis of the abrasive and erosive wear of biomass pre-processing equipment. The authors propose a minimum level of documentation for WCP, one that can enrich tribosystem analysis both in laboratory tests and field studies.

36 MATERIALS SCIENCE↗

Dynamics of an inertially collapsing gas bubble between two parallel, rigid walls

The collapse of cavitation bubbles in channel flows can give rise to structural damage along neighbouring walls. Although the collapse of a bubble near a single wall has been studied extensively, less is known about bubble collapse between two walls, e.g. as in a channel. We conduct highly resolved, direct simulations of the Navier–Stokes equations to investigate the bubble dynamics and pressures produced by the collapse of a bubble between two parallel rigid walls. We examine the dependence of the dynamics and pressures on the initial bubble location, confinement and driving pressure. For a fixed initial stand-off distance, as the channel width increases the bubble volume, migration distance and re-entrant jet speed approach their single-wall counterparts. We obtain an expression for the minimum channel width at which the confinement does not affect the bubble dynamics depending on the driving pressure difference and initial stand-off distance. For a fixed channel width, varying stand-off distance reduced the maximum wall pressures in the channel relative to the single wall; the trend was consistent for three different driving pressures. Two different jetting behaviours are seen when the bubble is centred in the channel, depending on the channel width. Under significant confinement, wall-parallel re-entrant jets impinge upon each other and further intensify the collapse of the vortex ring.

Rodriguez, Jr, Mauro (ORCID:0000000305450265)↗

Inertial collapse of a gas bubble in a shear flow near a rigid wall

Despite the extensive research on bubble collapse near rigid walls, the bubble collapse dynamics in the presence of shear flow near a rigid wall is poorly understood. We conduct direct simulations of the Navier–Stokes equations to explore the bubble dynamics and pressures during bubble collapse near a rigid, flat wall under linear shear flow conditions. We examine the dependence of the bubble collapse morphology and wall pressures on the initial bubble location and shear rate. We find that shear distorts the bubble, generating two re-entrant jets – one developing from the side opposite to the mean flow and the other from the far end toward the wall. Upon impact of the jet on the opposite side of the bubble, water-hammer shocks are produced, which propagate outward and interact with the convoluted bubble shape. The shock stretches the bubble towards the wall, resulting in a closer impact location for the jet originating from the far end compared with the case with no shear flow. The water-hammer pressure location can be approximated as the theoretical distance travelled by a particle initialised at the bubble centre with the corresponding constant shear flow velocity. The maximum wall pressures can thus be predicted by considering the distance between the far jet impingement location and the wall along the wall-normal direction. As the shear rate is increased, the maximum wall pressure increases, although only marginally. We determine the critical initial stand-off distance from the wall at which the bubble morphology is shear dominated, i.e. characterised by converging re-entrant jets.

Bhola, Sahil (ORCID:0000000236766302)↗

Detecting shearless phase-space transport barriers in global gyrokinetic turbulence simulations with test particle map models

In magnetically confined fusion plasmas, the role played by zonal 𝐸 x 𝐵 flow shear layers in the suppression of turbulent transport is relatively well understood. However, less is understood about the role played by the weak shear regions that arise in the non-monotonic radial electric field profiles often associated with these shear layers. In electrostatic simulations from the global total-𝑓 gyrokinetic particle-in-cell code XGC, we demonstrate how shearless regions with non-zero flow curvature form zonal ‘jets’ that, in conjunction with neighbouring regions of shear, can act as robust barriers to particle transport and turbulence spreading. By isolating quasi-coherent fluctuations radially localised to the zonal jets, we construct a map model for the Lagrangian dynamics of gyrokinetic test particles in the presence of drift waves. We identify the presence of shearless invariant tori in this model and verify that these tori act as partial phase-space transport barriers in the simulations. We also demonstrate how avalanches impinging on these shearless tori cause eddy detachment events that form ‘cold/warm core ring’ structures analogous to those found in oceanic jets, facilitating transport across the barriers without destroying them completely. We discuss how shearless tori may generically arise from tertiary instabilities or other types of discrete eigenmodes, suggesting their potential relevance to broader classes of turbulent fluctuations.

fusion plasma↗

Damage to Polystyrene Polymer Film by Shock Wave Induced Bubble Collapse

Metallic surfaces that are in contact with solutions are commonly used in numerous applications where these surfaces can be damaged by shock wave induced bubble collapse. Use of polymer films that coat such surfaces to prevent them from damage requires a better understanding of how much harm collapsing bubbles produce in the films. In this study, we report the results from coarse-grained molecular dynamics simulations to study the damage to polystyrene (PS) films coating a hard surface. The damage was caused by a collapsing nanobubble located in the proximity of the film and interacting with an impinging shock wave. This collapse produces a high-speed water jet that impacts the PS film with a greater force than the shock front and creates cavities/pits in the PS film. We observed that polymer molecules located in the jet vicinity undergo conformational extension in the direction perpendicular to the jet motion, while chain molecules in the rest of the film undergo compression. Furthermore, we also observed that damage to the film is sensitive to the strength of the shock wave.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Low Energy Implantation into Transition-Metal Dichalcogenide Monolayers to Form Janus Structures

Atomically-thin two-dimensional (2D) materials face significant energy barriers for synthesis and processing into functional metastable phases such as Janus structures. Here, in this study, the controllable implantation of hyperthermal species from pulsed laser deposition (PLD) plasmas is introduced as a top-down method to compositionally engineer 2D monolayers. The kinetic energies of Se clusters impinging on suspended monolayer WS 2 crystals were controlled in the <10 eV/atom range with in situ plasma diagnostics to determine the thresholds for selective top layer replacement of sulfur by selenium for the formation of high quality WSSe Janus monolayers at low (300 °C) temperatures, and bottom layer replacement for complete conversion to WSe 2 . Atomic-resolution electron microscopy and spectroscopy in tilted geometry confirm the WSSe Janus monolayer. Molecular dynamics simulations reveal that Se clusters implant to form disordered metastable alloy regions, which then recrystallize to form highly ordered structures, opening the door for low-energy implantation by PLD as a novel method to explore the synthesis of 2D Janus layers and alloys of variable composition.

2D materials↗

Global Prompt Proton Sensor Network: Monitoring Solar Energetic Protons Based on GPS Satellite Constellation

Energetic particle instruments on board Global Positioning System (GPS) satellites form a powerful global prompt proton sensor network (GPPSn) that provides an unprecedented opportunity to monitor and characterize solar energetic protons targeting the Earth. The medium-Earth orbits of the GPS constellation have the unique advantage of allowing solar energetic protons to be simultaneously measured from multiple points in both open- and closed-field line regions. Examining two example intervals of solar proton events, we showcase in this study how GPS proton data are prepared, calibrated, and utilized to reveal important features of solar protons, including their source, acceleration/scattering by interplanetary shocks, the relative position of Earth when impinged by these shocks, the shape of solar particle fronts, the access of solar protons inside the dynamic geomagnetic field, and temporally varying proton distributions in both energy and space. By comparing to Van Allen Probes data, GPS proton observations are further demonstrated not only to be useful for qualitatively monitoring the dynamics of solar protons but also for quantitative scientific research including determining cutoff L-shells. Finally, our results establish that this GPPSn can join forces with other existing solar proton monitors and contribute to observing, warning, understanding, and ultimately forecasting the incoming solar energetic proton events.

47 OTHER INSTRUMENTATION↗

On the Regionality of Moist Kelvin Waves and the MJO: The Critical Role of the Background Zonal Flow

Abstract A global model with superparameterized physics is used to shed light on the observed regionality of convectively coupled Kelvin waves and the Madden‐Julian Oscillation (MJO). A series of aquaplanet simulations over zonally uniform sea‐surface temperatures is performed, in which the axisymmetric structure of the background zonal flow is altered through nudging, while maintaining a quasi‐fixed rainfall climatology. Results show that nudging at the equator to match profiles typical of the Indo‐Pacific or eastern Pacific sectors yields eastward‐moving tropical rain spectra typical of those sectors. Two different mechanistic pathways are identified as being responsible for this mean‐flow dependence, in addition to Doppler shifting effects. The first is through shifts of the Rossby wave critical line in the subtropical upper troposphere that affect the lateral forcing of Kelvin‐mode circulations at the equator by eastward and equatorward‐propagating eddies impinging on the tropics from higher latitudes. The second is through changes in the strength of the mean cyclonic shear in the lower tropical troposphere that affect the degree to which intraseasonal fluctuations in Kelvin‐mode zonal winds modulate the activity of higher‐frequency equatorial Rossby‐type eddies. In cases where the mean low‐level cyclonic shear is enhanced, the strength of this modulation, referred to as “shear‐induced eddy modulation” or SIEM, is also seen to be enhanced, such that MJO‐like modes of variability are rendered either unstable or near neutral, depending on the strength of the shear.

Tulich, S. N.↗

Massive, long-lived electrostatic potentials in a rotating mirror plasma

Abstract Hot plasma is highly conductive in the direction parallel to a magnetic field. This often means that the electrical potential will be nearly constant along any given field line. When this is the case, the cross-field voltage drops in open-field-line magnetic confinement devices are limited by the tolerances of the solid materials wherever the field lines impinge on the plasma-facing components. To circumvent this voltage limitation, it is proposed to arrange large voltage drops in the interior of a device, but coexist with much smaller drops on the boundaries. To avoid prohibitively large dissipation requires both preventing substantial drift-flow shear within flux surfaces and preventing large parallel electric fields from driving large parallel currents. It is demonstrated here that both requirements can be met simultaneously, which opens up the possibility for magnetized plasma tolerating steady-state voltage drops far larger than what might be tolerated in material media.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Earth-abundant Li-ion cathode materials with nanoengineered microstructures

Manganese-based materials have tremendous potential to become the next-generation lithium-ion cathode as they are Earth abundant, low cost and stable. Here we show how the mobility of manganese cations can be used to obtain a unique nanosized microstructure in large-particle-sized cathode materials with enhanced electrochemical properties. By combining atomic-resolution scanning transmission electron microscopy, four-dimensional scanning electron nanodiffraction and in situ X-ray diffraction, we show that when a partially delithiated, high-manganese-content, disordered rocksalt cathode is slightly heated, it forms a nanomosaic of partially ordered spinel domains of 3–7 nm in size, which impinge on each other at antiphase boundaries. The short coherence length of these domains removes the detrimental two-phase lithiation reaction present near 3 V in a regular spinel and turns it into a solid solution. This nanodomain structure enables good rate performance and delivers 200 mAh g –1 discharge capacity in a (partially) disordered material with an average primary particle size of ~5 µm. The work not only expands the synthesis strategies available for developing high-performance Earth-abundant manganese-based cathodes but also offers structural insights into the ability to nanoengineer spinel-like phases.

36 MATERIALS SCIENCE↗

Cross sections of 147–149 Sm( 6 Li,x) reactions for the production of 149 Tb for targeted alpha therapy

Terbium-149g (t 1/2 = 4.12 h) is of particular interest for targeted alpha therapy cancer treatment due to its ability to decay via both alpha and positron emission, making it a potential theranostic nuclide. Due to many challenges facing its production, there are limited facilities worldwide that have demonstrated the ability to produce this nuclide in quantities sufficient for medical research. Since the Cyclotron Institute at Texas A&M University is a specialized accelerator facility capable of accelerating a wide variety of ions, we are investigating production pathway options. One of the major challenges facing its production is the known co-production of the excited isomeric state, 149m Tb (t 1/2 = 4.1 min). However, this state does not decay to the ground state of 149g Tb, negating any potential contribution to its yield. Due to its short-half life, the cross section for the population of this state has never been measured. After calculating several potential reaction yields using predictive models, the reactions of 147–149 Sm( 6 Li,xn) 149 Tb were identified as candidates. Lithium-6 beams of varied energies between 45-65 MeV were impinged on enriched 147 Sm, 148 Sm, and 149 Sm targets at the Cyclotron Institute at Texas A&M University, and the reaction products were measured immediately following irradiation using high-purity germanium detectors, enabling detection of both 149m Tb and 149g Tb. Cross sections for all nuclides produced in sufficient activity in these reactions were also measured and reported here. We conclude that the population of 149m Tb is much preferred over population of the ground state for these 6 Li-induced reactions, and it is necessary to explore other options for 149g Tb production.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Probing strong-field QED in beam-plasma collisions

Ongoing progress in laser and accelerator technology opens new possibilities in high-field science, notably to investigate the largely unexplored strong-field quantum electrodynamics (SFQED) regime where electron-positron pairs can be created directly from light-matter or even light-vacuum interactions. Laserless strategies such as beam-beam collisions have also been proposed to access the nonperturbative limit of SFQED. Here we report on a concept to probe SFQED by harnessing the interaction between a high-charge, ultrarelativistic electron beam and a solid conducting target. When impinging onto the target surface, the beam self fields are reflected, partly or fully, depending on the beam shape; in the rest frame of the beam electrons, these fields can exceed the Schwinger field, thus triggering SFQED effects such as quantum nonlinear inverse Compton scattering and nonlinear Breit-Wheeler electron-positron pair creation. Through reduced modeling and kinetic numerical simulations, we show that this single-beam setup can achieve interaction conditions similar to those envisioned in beam-beam collisions, but in a simpler and more controllable way owing to the automatic overlap of the beam and driving fields. This scheme thus eases the way to precision studies of SFQED and is also a promising milestone towards laserless studies of nonperturbative SFQED.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Anomalously abrupt switching of wurtzite-structured ferroelectrics: simultaneous non-linear nucleation and growth model

Ferroelectric polarization switching is one common example of a process that occurs via nucleation and growth, and understanding switching kinetics is crucial for applications such as ferroelectric memory. Here we describe and interpret anomalous switching dynamics in the wurtzite-structured nitride thin film ferroelectrics Al 0.7 Sc 0.3 N and Al 0.94 B 0.06 N using a general model that can be directly applied to other abrupt transitions that proceed via nucleation and growth. When substantial growth and impingement occur while nucleation rate is increasing, such as in these wurtzite-structured ferroelectrics under high electric fields, abrupt polarization reversal leads to very large Avrami coefficients ( e.g., n = 11), inspiring an extension of the KAI (Kolmogorov–Avrami–Ishibashi) model. We apply this extended model to two related but distinct scenarios that crossover between (typical) behavior described by sequential nucleation and growth and a more abrupt transition arising from significant growth prior to peak nucleation rate. This work therefore provides a more complete description of general nucleation and growth kinetics applicable to any system while specifically addressing the anomalously abrupt polarization reversal behavior in new wurtzite-structured ferroelectrics.

36 MATERIALS SCIENCE↗