Application of trioxygen difluoride in liquid rocket propellant technology.
Trioxygen difluoride additive rendering LOX hypergolic, discussing environmental limits of reliable hypergolic ignition with liquid and gaseous hydrogen
Amster, A. B.↗
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Application of trioxygen difluoride in liquid- rocket-propellant technology.
Trioxygen difluoride additive rendering LOX hypergolic, discussing environmental limits of reliable hypergolic ignition with liquid and gaseous hydrogen
Amster, A. B.↗
Combustion characteristics in the transition region of liquid fuel sprays
A number of important effects have been observed in the droplet size transition region in spray combustion systems. In this region, where the mechanism of flame propagation is transformed from diffusive to premixed dominated combustion, the following effects have been observed: (1) maxima in burning velocity; (2) extension of flammability limits; (3) minima in ignition energy; and (4) minima in NOx formation. A monodisperse aerosol generator has been used to form and deliver a well controlled liquid fuel spray to the combustion test section where measurements of ignition energy have been made. The ignition studies were performed on monodisperse n-heptane sprays at atmospheric pressure over a range of equivalence ratios and droplet diameters. A capacitive discharge spark ignition system was used as the ignition source, providing independent control of spark energy and duration. Preliminary measurements were made to optimize spark duration and spark gap, optimum conditions being those at which the maximum frequency or probability of ignition was observed. Using the optimum electrode spacing and spark duration, the frequency of ignition was determined as a function of spark energy for three overall equivalence ratios (0.6, 0.8, and 1.0) and for initial droplet diameters of 25, 40, 50, 60, and 70 micro m.
Cernansky, N. P.↗
Microgravity combustion of dust suspensions
Unlike the combustion of homogeneous gas mixtures, there are practically no reliable fundamental data (i.e., laminar burning velocity, flammability limits, quenching distance, minimum ignition energy) for the combustion of heterogeneous dust suspensions. Even the equilibrium thermodynamic data such as the constant pressure volume combustion pressure and the constant pressure adiabatic flame temperature are not accurately known for dust mixtures. This is mainly due to the problem of gravity sedimentation. In normal gravity, turbulence, convective flow, electric and acoustic fields are required to maintain a dust in suspension. These external influences have a dominating effect on the combustion processes. Microgravity offers a unique environment where a quiescent dust cloud can in principle be maintained for a sufficiently long duration for almost all combustion experiments (dust suspensions are inherently unstable due to Brownian motion and particle aggregation). Thus, the microgravity duration provided by drop towers, parabolic flights, and the space shuttle, can all be exploited for different kinds of dust combustion experiments. The present paper describes some recent studies on microgravity combustion of dust suspension carried out on the KC-135 and the Caravelle aircraft. The results reported are obtained from three parabolic flight campaigns.
Lee, John H. S.↗
Theoretical Prediction of Microgravity Ignition Delay of Polymeric Fuels in Low Velocity Flows
A new flammability apparatus and protocol, FIST (Forced Flow Ignition and Flame Spread Test), is under development. Based on the LIFT (Lateral Ignition and Flame Spread Test) protocol, FIST better reflects the environments expected in spacebased facilities. The final objective of the FIST research is to provide NASA with a test methodology that complements the existing protocol and provides a more comprehensive assessment of material flammability of practical materials for space applications. Theoretical modeling, an extensive normal gravity data bank and a few validation space experiments will support the testing methodology. The objective of the work presented here is to predict the ignition delay and critical heat flux for ignition of solid fuels in microgravity at airflow velocities below those induced in normal gravity. This is achieved through the application of a numerical model previously developed of piloted ignition of solid polymeric materials exposed to an external radiant heat flux. The model predictions will provide quantitative results about ignition of practical materials in the limiting conditions expected in space facilities. Experimental data of surface temperature histories and ignition delay obtained in the KC-135 aircraft are used to determine the critical pyrolysate mass flux for ignition and this value is subsequently used to predict the ignition delay and the critical heat flux for ignition of the material. Surface temperature and piloted ignition delay calculations for Polymethylmethacrylate (PMMA) and a Polypropylene/Fiberglass (PP/GL) composite were conducted under both reduced and normal gravity conditions. It was found that ignition delay times are significantly shorter at velocities below those induced by natural convection.
Fernandez-Pello, A. C.↗
Performance of a Laser Ignited Multicylinder Lean Burn Natural Gas Engine
Market demands for lower fueling costs and higher specific powers in stationary natural gas engines has engine designs trending towards higher in-cylinder pressures and leaner combustion operation. However, Ignition remains as the main limiting factor in achieving further performance improvements in these engines. Addressing this concern, while incorporating various recent advances in optics and laser technologies, laser igniters were designed and developed through numerous iterations. Final designs incorporated water-cooled, passively Q-switched, Nd:YAG micro-lasers that were optimized for stable operation under harsh engine conditions. Subsequently, the micro-lasers were installed in the individual cylinders of a lean-burn, 350 kW, inline 6-cylinder, open-chamber, spark ignited engine and tests were conducted. To the best of our knowledge, this is the world’s first demonstration of a laser ignited multi-cylinder natural gas engine. The engine was operated at high-load (298 kW) and rated speed (1800 rpm) conditions. Ignition timing sweeps and excess-air ratio (λ) sweeps were performed while keeping the NOx emissions below the USEPA regulated value (BSNOx < 1.34 g/kW-hr), and while maintaining ignition stability at industry acceptable values (COV_IMEP <5 %). Through such engine tests, the relative merits of (i) standard electrical ignition system, and (ii) laser ignition system were determined. In conclusion, a rigorous combustion data analysis was performed and the main reasons leading to improved performance in the case of laser ignition were identified.
33 ADVANCED PROPULSION SYSTEMS↗
Assessment of Turbulent Combustion Models for Simulating Prechamber Ignition in a Natural Gas Engine
Lean combustion is a promising strategy to increase thermal efficiency in an internal combustion engine, by exploiting a favorable specific heat ratio of the fresh mixture while simultaneously suppressing the heat losses to the cylinder wall. However, unstable ignition and slow flame propagation at fuel-lean conditions lead to large cycle-to-cycle variability and limit the high-efficiency engine operating range. Prechamber ignition is considered an effective concept to extend the lean operating limit, by providing spatially distributed ignition with multiple turbulent flame-jets and enabling a faster combustion rate compared to the conventional spark ignition approach. From a numerical modeling standpoint to date science base and available simulation tools are inadequate to properly understand and predict the combustion processes in prechamber ignited engines. In this paper, conceptually different Reynolds-averaged Navier–Stokes (RANS) combustion models widely adopted in the engine modeling community are used to simulate the ignition and combustion processes in a medium-duty natural gas engine with a prechamber spark-ignition system. Here, a flamelet-based turbulent combustion model, i.e., G-equation, and a multizone well-stirred reactor model are employed for this modeling study. Simulation results are compared with experimental data in terms of in-cylinder pressure and heat release rate. Finally, the analysis of the performance of the two models is carried out to highlight the strengths and limitations of the two evaluated approaches.
42 ENGINEERING↗
Investigation of cleanliness verification techniques for rocket engine hardware
Oxidizer propellant systems for liquid-fueled rocket engines must meet stringent cleanliness requirements for particulate and nonvolatile residue. These requirements were established to limit residual contaminants which could block small orifices or ignite in the oxidizer system during engine operation. Limiting organic residues in high pressure oxygen systems is particularly important. The current method of cleanliness verification used by Rocketdyne requires an organic solvent flush of the critical hardware surfaces. The solvent is filtered and analyzed for particulate matter, followed by gravimetric determination of the nonvolatile residue (NVR) content of the filtered solvent. The organic solvents currently specified for use (1,1,1-trichloroethane and CFC-113) are ozone-depleting chemicals slated for elimination by December 1995. A test program is in progress to evaluate alternative methods for cleanliness verification that do not require the use of ozone-depleting chemicals and that minimize or eliminate the use of solvents regulated as hazardous air pollutants or smog precursors. Initial results from the laboratory test program to evaluate aqueous-based methods and organic solvent flush methods for NVR verification are provided and compared with results obtained using the current method. Evaluation of the alternative methods was conducted using a range of contaminants encountered in the manufacture of rocket engine hardware.
Fritzemeier, Marilyn L.↗
Investigation of Cleanliness Verification Techniques for Rocket Engine Hardware
Oxidizer propellant systems for liquid-fueled rocket engines must meet stringent cleanliness requirements for particulate and nonvolatile residue. These requirements were established to limit residual contaminants which could block small orifices or ignite in the oxidizer system during engine operation. Limiting organic residues in high pressure oxygen systems, such as in the Space Shuttle Main Engine (SSME), is particularly important. The current method of cleanliness verification for the SSME uses an organic solvent flush of the critical hardware surfaces. The solvent is filtered and analyzed for particulate matter followed by gravimetric determination of the nonvolatile residue (NVR) content of the filtered solvent. The organic solvents currently specified for use (1, 1, 1-trichloroethane and CFC-113) are ozone-depleting chemicals slated for elimination by December 1995. A test program is in progress to evaluate alternative methods for cleanliness verification that do not require the use of ozone-depleting chemicals and that minimize or eliminate the use of solvents regulated as hazardous air pollutants or smog precursors. Initial results from the laboratory test program to evaluate aqueous-based methods and organic solvent flush methods for NVR verification are provided and compared with results obtained using the current method. Evaluation of the alternative methods was conducted using a range of contaminants encountered in the manufacture of rocket engine hardware.
Fritzemeier, Marilyn L.↗
Evaluation of an Interferometric Sensor for In-Space Detection of Gas Leaks
Space mission planning often involves long-term storage of volatile liquids or high-pressure gases. These may include cryogenic fuels and oxidizers, high-pressure gases, and life-support-critical consumables. The risk associated with the storage of fluids and gases in space systems has long been an issue and the ability to retain these fluids is often tied to mission success. A leak in the storage or distribution system can cause many different problems, including a simple, but mission endangering, loss of inventory or, in severe cases, unbalanced thrust loads on a flight vehicle. Cryogenic propellants are especially difficult to store, especially over a long duration. The propellant can boil off and be lost through the insulating walls of the tank or simple thermal cycling of the fittings, valves, and propellant feed lines may unseat seals allowing the fluid to escape. Current NASA missions call for long-duration in-space storage of propellants, oxidizers, and life support supplies. Leaks of a scale detectable through a pressure drop in the storage tank are often catastrophic and have long been the focus of ground-based mitigation efforts where redundant systems are often employed. However, there is presently no technology available for detecting and monitoring low-level, but still mission-endangering, gas leaks in space. Standard in-space gas detection methods either have a very limited pressure range over which they operate effectively or are limited to certain gases. Mass spectrometer systems are able to perform the detection tasks, but their size, mass and use of high voltage, which could potentially lead to an arc that ignites a combustible propellent, severely limit their usefulness in a space system. In this paper, we present results from testing of the light-based interferometric gas monitoring and leak detection sensor shown in Fig. 1. The output of the sensor is an interference fringe pattern that is a function of the gas density, and commensurate index of refraction, in the sample region. Changes in the density of gas cause the interference fringes to move across a photodiode detector, providing a temporal history of the leak. The sensor is fiber coupled and constructed from solid optics, allowing for placement almost anywhere on the spacecraft. It is also advantageous in that it consumes very little power and does not introduce an ignition source. Data are presented demonstrating the capability of the sensor to measure density variations in different gas species. In addition, the transient response of the sensor in vacuum is demonstrated. These data extend and improve upon the results previously presented by the authors in Ref. [1].
Polzin, Kurt A.↗
Counterflow ignition of n-butanol at atmospheric and elevated pressures
Vital to the development of predictive combustion models is a robust understanding of the coupled effects of chemical kinetics and convective–diffusive transport at both atmospheric and elevated pressures. The current study describes a new variable-pressure non-premixed counterflow ignition experiment designed to address the need for well-characterized reference data to validate such models under conditions sensitive to both chemical and transport processes. A comprehensive characterization of system behavior is provided to demonstrate boundary condition and ignition quality as well as adherence to the assumption of quasi-one-dimensionality, and suggest limitations and best practices for counterflow ignition experiments. This effort reveals that the counterflow ignition experiment requires special attention to ignition location in order to ensure that the assumption of quasi-one-dimensionality is valid, particularly at elevated pressures. This experimental tool is then applied to the investigation of n-butanol for pressures of 1–4 atm, pressure-weighted strain rates of 200–400 s -1 , and fuel mole fractions of 0.05–0.25. Results are simulated using two n-butanol models available in the literature and used to validate and assess model performance. Comparison of experimental and numerical ignition results for n-butanol demonstrates that while existing models largely capture the trends observed with varying pressure, strain rate, and fuel loading, the models universally over-predict experimental ignition temperatures. While several transport coefficients are found to exhibit order-of-magnitude or greater sensitivities relative to reaction rates, variation of transport parameters is not able to account for the large deviations observed between experimental and numerical results. Additional comparison of ignition kernel structure and fuel breakdown pathways between two literature models suggests that an under-prediction in the radical pool growth with respect to temperature variation may be responsible for both the deviation from the experimental results and the discrepancy in ignition temperature results observed between models.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Modeling Nanosecond-Pulsed Spark Discharge and Flame Kernel Evolution
Dilute combustion, either using exhaust gas recirculation or with excess air, is considered a promising strategy to improve the thermal efficiency of internal combustion engines. However, the dilute air-fuel mixture, especially under intensified turbulence and high-pressure conditions, poses significant challenges for ignitability and combustion stability, which may limit the attainable efficiency benefits. In-depth knowledge of the flame kernel evolution to stabilize ignition and combustion in a challenging environment is crucial for effective engine development and optimization. To date, a comprehensive understanding of ignition processes that result in the development of fully predictive ignition models usable by the automotive industry does not yet exist. Spark-ignition consists of a wide range of physics that includes electrical discharge, plasma evolution, joule-heating of gas, and flame kernel initiation and growth into a self-sustainable flame. In this study, an advanced approach is proposed to model spark-ignition energy deposition and flame kernel growth. To decouple the flame kernel growth from the electrical discharge, a nanosecond-pulsed high-voltage discharge is used to trigger spark-ignition in an optically accessible small ignition test vessel with a quiescent mixture of air and methane. Initial conditions for the flame kernel, including its thermodynamic state and species composition, are derived from a plasma-chemical equilibrium calculation. The geometric shape and dimension of the kernel are characterized using a multi-dimensional thermal plasma solver. Here, the proposed modeling approach is evaluated using a high-fidelity computational fluid dynamics procedure to compare the simulated flame kernel evolution against flame boundaries from companion Schlieren images.
42 ENGINEERING↗
Plasma stopping-power measurements reveal transition from non-degenerate to degenerate plasmas
Physically realized electron gas systems usually reside in either the quantum non-degenerate or fully degenerate limit, where the average de Broglie wavelength of the thermal electrons becomes comparable with the interparticle distance between electrons. A few systems, such as young brown dwarfs and the cold dense fuels created in imploded cryogenic capsules at the National Ignition Facility, lie between these two limits and are partially degenerate. The National Ignition Facility has the unique capability of varying the electron quantum degeneracy by adjusting the laser drive used to implode the capsules. This allows experimental studies of the effects of the degeneracy level on plasma transport properties. By measuring rare nuclear reactions in these cold dense fuels, we show that the electron stopping power, which is the rate of energy loss per unit distance travelled by a charged particle, changes with increasing electron density. We observe a quantum-induced shift in the peak of the stopping power using diagnostics that measure above and below this peak. The observed changes in the stopping power are shown to be unique to the transition region between non-degenerate and degenerate plasmas. Furthermore, our results support the screening models applied to partially degenerate astrophysical systems such as young brown dwarfs.
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
Analysis of operator splitting errors for near-limit flame simulations
High-fidelity simulations of ignition, extinction and oscillatory combustion processes are of practical interest in a broad range of combustion applications. Splitting schemes, widely employed in reactive flow simulations, could fail for stiff reaction–diffusion systems exhibiting near-limit flame phenomena. The present work first employs a model perfectly stirred reactor (PSR) problem with an Arrhenius reaction term and a linear mixing term to study the effects of splitting errors on the near-limit combustion phenomena. Analysis shows that the errors induced by decoupling of the fractional steps may result in unphysical extinction or ignition. The analysis is then extended to the prediction of ignition, extinction and oscillatory combustion in unsteady PSRs of various fuel/air mixtures with a 9-species detailed mechanism for hydrogen oxidation and an 88-species skeletal mechanism for n-heptane oxidation, together with a Jacobian-based analysis for the time scales. The tested schemes include the Strang splitting, the balanced splitting, and a newly developed semi-implicit midpoint method. Results show that the semi-implicit midpoint method can accurately reproduce the dynamics of the near-limit flame phenomena and it is second-order accurate over a wide range of time step size. For the extinction and ignition processes, both the balanced splitting and midpoint method can yield accurate predictions, whereas the Strang splitting can lead to significant shifts on the ignition/extinction processes or even unphysical results. With an enriched H radical source in the inflow stream, a delay of the ignition process and the deviation on the equilibrium temperature are observed for the Strang splitting. On the contrary, the midpoint method that solves reaction and diffusion together matches the fully implicit accurate solution. The balanced splitting predicts the temperature rise correctly but with an over-predicted peak. For the sustainable and decaying oscillatory combustion from cool flames, both the Strang splitting and the midpoint method can successfully capture the dynamic behavior, whereas the balanced splitting scheme results in significant errors.
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
Investigation of the fundamentals of low-energy nanosecond pulse ignition: Final CRADA Report
A detailed investigation of the fundamentals of low-energy nanosecond pulse ignition was performed with the objective to overcome the barrier presented by limited knowledge and characterization of nonequilibrium plasma ignition for realistic internal combustion engine applications (be it in the automotive or power generation field) and shed light on the mechanisms which improve the performance of the advanced TPS ignition system compared to conventional state-of-the-art hardware. Three main tasks of the research included experimental evaluation on a single-cylinder automotive gasoline engine, experimental evaluation on a single-cylinder stationary natural gas engine and energy quantification using x-ray diagnostics.
33 ADVANCED PROPULSION SYSTEMS↗
Performance of a hardened x-ray streak camera at Lawrence Livermore National Laboratory’s National Ignition Facility
Electron tubes continue to provide the highest speeds possible for recording dynamics of hot high-energy density plasmas. Standard streak camera drive electronics and CCD readout are not compatible with the radiation environment associated with high DT fusion yield inertial confinement fusion experiments >10 13 14 MeV DT neutrons or >10 9 n cm -2 ns -1 . Here, we describe a hardened x-ray streak camera developed for the National Ignition Facility and present preliminary results from the first experiment on which it has participated, recording the time-resolved bremsstrahlung spectrum from the core of an inertial confinement fusion implosion at more than 40× the operational neutron yield limit of the previous National Ignition Facility x-ray streak cameras.
47 OTHER INSTRUMENTATION↗
Compact Augmented Spark Igniters for Liquid Rocket Engines
The objective of this dissertation is to characterize augmented spark impinging (torch) igniters. Torch igniters inject propellants into a small prechamber where a spark igniter imparts the activation energy to initiate combustion. The flame stabilizes within the prechamber and exits into the main combustion chamber where it ignites the main flow directly or by mixing with a coaxial flow to create a secondary flame. The underlying phenomena that promote reliable ignition are multifaceted and required a broad scope of investigations. Initial efforts focused on spark discharges across an annular geometry. Gaseous propellent projects the electrical arc toward the prechamber, where the arc and the thermal energy is imparted to the surrounding fluid then meets with a combustible mixture. Discharges are parametrically examined against pressure, spark-gap size, and exciter types to emulate transient engine startup. The energy imparted to the flow, approximate velocity, and distance traveled by the exhaust plume are determined. Spark quenching (no energy deposition) and its effects on perceived versus actual measurements are shown. Results outline the prechamber target zone where a combustible mixture is necessary for ignition. Next, three-dimensional, time-accurate, and nonreacting computational fluid dynamics simulations assess effects of geometric and mass flow differences on the size, location, and composition of a combustible mixture. Fluid dynamic phenomena are elucidated. Correlations between nondimensional variables are found. Results are coupled with a conservation-law analysis to produce novel objective functions. Lastly, a full-scale, modular torch igniter is tested. Injector sizes, mixture ratios, and injector momentum ratios are systematically varied to map ignition probability and ignition delay. Results show the importance of local mixture ratios, provide injector momentum ratios guidelines, and demonstrate reliable ignition of core mixture ratios typically outside flammability limits. The deliverable of this project is not a torch igniter or derivative thereof. Instead, this dissertation produces novel objective-functions for igniter design. These equations are functions of variables that may be constrained by engine-level requirements, physics, and experimental results from this work. They provide a foundation for future igniter design and will minimize iterative processes from the design cycle for next-generation ignition hardware.
Torch Igniter↗
Modeling of Transient Flow Mixing of Streams Injected into a Mixing Chamber
Ignition is recognized as one the critical drivers in the reliability of multiple-start rocket engines. Residual combustion products from previous engine operation can condense on valves and related structures thereby creating difficulties for subsequent starting procedures. Alternative ignition methods that require fewer valves can mitigate the valve reliability problem, but require improved understanding of the spatial and temporal propellant distribution in the pre-ignition chamber. Current design tools based mainly on one-dimensional analysis and empirical models cannot predict local details of the injection and ignition processes. The goal of this work is to evaluate the capability of the modern computational fluid dynamics (CFD) tools in predicting the transient flow mixing in pre-ignition environment by comparing the results with the experimental data. This study is a part of a program to improve analytical methods and methodologies to analyze reliability and durability of combustion devices. In the present paper we describe a series of detailed computational simulations of the unsteady mixing events as the cold propellants are first introduced into the chamber as a first step in providing this necessary environmental description. The present computational modeling represents a complement to parallel experimental simulations' and includes comparisons with experimental results from that effort. A large number of rocket engine ignition studies has been previously reported. Here we limit our discussion to the work discussed in Refs. 2, 3 and 4 which is both similar to and different from the present approach. The similarities arise from the fact that both efforts involve detailed experimental/computational simulations of the ignition problem. The differences arise from the underlying philosophy of the two endeavors. The approach in Refs. 2 to 4 is a classical ignition study in which the focus is on the response of a propellant mixture to an ignition source, with emphasis on the level of energy needed for ignition and the ensuing flame propagation issues. Our focus in the present paper is on identifying the unsteady mixing processes that provide the propellant mixture in which the ignition source is to be placed. In particular, we wish to characterize the spatial and temporal mixture distribution with a view toward identifying preferred spatial and temporal locations for the ignition source. As such, the present work is limited to cold flow (pre-ignition) conditions
Voytovych, Dmytro M.↗