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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS1988

Solidification-Rate Effects In MAR-M-246+Hf Alloy

Under slower solidification, primary-dendrite-arm spacing increases. Report discusses experiments on influence of solidification rates on crystallographic orientation and mechanical properties of superalloy MAR-M-246+Hf. Specimens grown in directional-solidification furnace, visually examined for microstructure, and stretched to failure in tensile-testing machine. Back-reflection Laue x-ray photographs taken to determine growth orientations.

Hamilton, David↗
NASA NTRS1987

Theoretical studies of the potential surface for the F - H2 greater than HF + H reaction

The F + H2 yields HF + H potential energy hypersurface was studied in the saddle point and entrance channel regions. Using a large (5s 5p 3d 2f 1g/4s 3p 2d) atomic natural orbital basis set, a classical barrier height of 1.86 kcal/mole was obtained at the CASSCF/multireference CI level (MRCI) after correcting for basis set superposition error and including a Davidson correction (+Q) for higher excitations. Based upon an analysis of the computed results, the true classical barrier is estimated to be about 1.4 kcal/mole. The location of the bottleneck on the lowest vibrationally adiabatic potential curve was also computed and the translational energy threshold determined from a one-dimensional tunneling calculation. Using the difference between the calculated and experimental threshold to adjust the classical barrier height on the computed surface yields a classical barrier in the range of 1.0 to 1.5 kcal/mole. Combining the results of the direct estimates of the classical barrier height with the empirical values obtained from the approximation calculations of the dynamical threshold, it is predicted that the true classical barrier height is 1.4 + or - 0.4 kcal/mole. Arguments are presented in favor of including the relatively large +Q correction obtained when nine electrons are correlated at the CASSCF/MRCI level.

Bauschlicher, Charles W., Jr.↗
NASA NTRS1988

Nonlinear structural analysis of a turbine airfoil using the Walker viscoplastic material model for B1900 + Hf

A viscoplastic material model for the high temperature turbine airfoil material B1900 + Hf was developed and was demonstrated in a three dimensional finite element analysis of a typical turbine airfoil. The demonstration problem is a simulated flight cycle and includes the appropriate transient thermal and mechanical loads typically experienced by these components. The Walker viscoplastic material model was shown to be efficient, stable and easily used. The demonstration is summarized and the performance of the material model is evaluated.

Meyer, T. G.↗
NASA NTRS1988

Theoretical studies of the potential surface for the F + H2 - HF + H reaction

Several aspects of the F + H2 - HF + H potential energy hypersurface are considered. The classical barrier height is studied as a function of improvements to both the one-particle and n-particle treatments, approaching the one-particle basis set limit. The externally contracted CI (CCI) method is used to compute bending potentials in the collinear saddle point region. The calculated CCI surface is used to locate the bottleneck on the vibrationally adiabatic potential curve, and the reaction threshold is deduced from a one-dimensinal tunneling calculation. The true classical barrier height is estimated by adjusting the CCI barrier height for the difference in the calculated and experimental thresholds.

Bauschlicher, Charles W., Jr.↗
NASA NTRS1988

U-Th-Pb, Sm-Nd, Rb-Sr, and Lu-Hf systematics of returned Mars samples

The advantage of studying returned planetary samples cannot be overstated. A wider range of analytical techniques with higher sensitivities and accuracies can be applied to returned samples. Measurement of U-Th-Pb, Sm-Nd, Rb-Sr, and Lu-Hf isotopic systematics for chronology and isotopic tracer studies of planetary specimens cannot be done in situ with desirable precision. Returned Mars samples will be examined using all the physical, chemical, and geologic methods necessary to gain information on the origin and evolution of Mars. A returned Martian sample would provide ample information regarding the accretionary and evolutionary history of the Martian planetary body and possibly other planets of our solar system.

Tatsumoto, M.↗
NASA NTRS1989

The effects of temperature gradient and growth rate on the morphology and fatigue properties of MAR-M246(Hf)

MAR-M246(Hf) is a nickel based superalloy used in the turbopump blades of the Space Shuttle main engines. The effects are considered of temperature gradient (G) and growth rate (R) on the microstructure and fatigue properties of this superalloy. The primary dendrite arm spacings were found to be inversely proportional to both temperature gradient and growth rate. Carbide and gamma - gamma prime morphology trends were related to G/R ratios. Weibull analysis of fatigue results shows the characteristic life to be larger by a factor of 10 for the low gradient/fast rate pairing of G and R, while the reliability (beta) was lower.

Schmidt, D. D.↗
NASA NTRS1988

Coherent HF radar backscatter from small-scale irregularities in the dusk sector of the subauroral ionosphere

This paper describes the characteristics of backscatter from decameter-scale ionospheric plasma density irregualarities, observed with an impressive regularity by the Goose Bay (Labrador) high-frequency (HF) radar in the dusk sector of the winter ionosphere, and discusses the relation of the scatter to the midlatitude trough. It is shown that this dusk scatter can be readily distinguished from other types of late afternoon/early evening scatter by the extreme equatorward position of its source region and by the low values of its associated radar Doppler velocities (not above 200 m/s) and spectral widths (not more than 200 m/s). A comparison of the radar observations with nearly simultaneous particle precipitation data obtained with the DMSP F6 satellite demonstrated that the source region of the backscatter lies within the subauroral ionosphere. It is shown that the characteristics of dusk scatter are compatible with the Spiro et al. (1978) model of the electrodynamics of the midlatitude trough.

Ruohoniemi, J. M.↗
NASA NTRS1989

Mapping high-latitude plasma convection with coherent HF radars

Several methods developed for mapping high-latitude plasma convection with a high-latitude HF radar are described, which utilize coherent backscatter from electron density irregularities at F-region altitudes to observe convective plasma motion. Several examples of two-dimensional convection-velocity maps are presented, showing instances of L-shell-aligned flow in the dusk sector, the reversal of convection near magnetic midnight, and counterstreaming in the dayside cleft.

Ruohoniemi, J. M.↗
NASA NTRS1989

Atmospheric density remote sensing of mesosphere and thermosphere to be used for spacecraft design by adopting VHF radar and HF Doppler sounder at low latitude west Pacific site during winter time

Simultaneous observations of VHF radar and HF Doppler array systems located at Chung Li (Taiwan) are used to observe three-dimensional wind speeds and gravity waves. The density perturbations are determined at different altitudes of the mesosphere and thermosphere during weak convective motions of the cold front in the winter. The present observations are believed to be valuable for space projects dealing with the low-latitude atmosphere.

Hung, R. J.↗
NASA NTRS1989

SC- and SI-associated ULF and HF-Doppler oscillations during the great magnetic storm of February 1986

Results are presented of an investigation of SC- and SI-associated ULF and HF-Doppler pulsations observed during the great geomagnetic storm of February 1986, which began with a sudden commmencement on February 6 at about 13:12 UT, developed slowly over the next two days, and, after a rapid intensification late on February 8, reached a minimum. It is shown that these ULF and geomagnetic pulsations can be explained by the dynamo-motor mechanism of ionospheric electric fields and by global compressional oscillations in the magnetosphere and ionosphere, respectively.

Yumoto, K.↗
NASA NTRS1990

High temperature inelastic deformation of the B1900 + Hf alloy under multiaxial loading - Theory and experiment

The multiaxial deformation behavior of the Ni-based alloy B1900 + Hf has been studied at elevated temperatures in the range of 649-982 C. Combined tension/torsion cyclic tests were performed on thin-wall tubular specimens under both in-phase and out-of-phase strain-controlled loading cycles. Both straining conditions resulted in stress loci of comparable magnitude, exhibiting no difference in cyclic hardening response. A phase angle was observed between the deviatoric stress and the incremental plastic strain vectors during 90-deg out-of-phase strain cycling, and nonproportional stress relaxation occurred under biaxial strain hold. The overall results have been used to assess the flow law, the hardening equations, and the applicability of the J2-based, elastic-viscoplastic model of Bodner-Partom (1979) for multiaxial loading conditions. The overall agreement between theory and experiment is good. Discrepancies are discussed in relation to micromechanical considerations.

Chan, K. S.↗
NASA NTRS1990

Implications for the evolution of continental crust from Hf isotope systematics of Archean detrital zircons

Results from the fractionation of zircon by sedimentary processes into continental margin sandstone yield information on the preservation of preexisting continental crust in the form of zircon, making it possible to distinguish between the contrasting theories of gradual growth versus constant volume of continental crust over geologic time. In this work, Hf-176/Hf-177 ratios were determined for detrital zircon fractions from 2.0-2.5, 2.6-3.0, and pre-3.0 Gyr old sandstones from the Canadian-Shield, the North-Atlantic, the Wyoming, and the Kaapvaal Cratons. Results pointed to small amounts of continental crust prior to 3.0 Gyr ago and a rapid addition of continental crust between 2.5 and 3.0 Gyr ago, consistent with the gradual growth of continental crust, and giving evidence against no-growth histories.

Stevenson, Ross K.↗
NASA NTRS1990

Simultaneous HF-radar and DMSP observations of the cusp

The Geospace Environment Modeling (GEM) Program is directed toward modeling the coupled solar wind/magnetosphere/ionosphere system. The inter-calibration of ground-based observations of the ionosphere and satellite observations has been identified as an essential step in tying together the data to produce a global picture of geospace. On October 10, 1988 the DMSP-F9 satellite passed through the Southern Hemisphere cusp while a coheret scatter HF-radar was observing 10-m scale irregularities present in the ionosphere. The combined data indicate that these irregularities were being generated in the cusp, and that the cusp was a region of greater than normal electric field turbulence. The radar data indicate that the cusp was colocated with the region where the ionospheric convection rotated from sunward to anti-sunward with increasing latitude. These observations provide an unambiguous case where simultaneous satellite and ground-based observations of the cusp can be compared.

Baker, K. B.↗
NASA NTRS1991

HF radar observations of Pc 5 field line resonances in the midnight/early morning MLT sector

The technique of F region sounding by HF coherent radar is applied to the study of field line resonances equatorward of a region of shear flow in the early morning sector. The motions were predominantly in the geomagnetic east-west direction, indicating north-south electric fields. These oscillations had pronounced peaks in their latitudinal power distribution. For the pulsation at 1.95 mHz, a latitudinal phase shift of 180 deg was observed across the peaks in all the look directions of the radar, and a longitudinal wavelength corresponding to an m value of 3 was obtained. For the 2.6-mHz pulsation, the phase shifts across the peaks had a variation with a look direction that indicated a significant longitudinal as well as latitudinal variation; for this activity, an m value of about 16 is estimated. These features are interpreted in terms of the field line resonance theory, and the possible sources of the pulsation energy are discussed.

Ruohoniemi, J. M.↗
NASA NTRS1991

Total integral reactive cross sections for F + H2 yielding HF + H - Comparison of converged quantum, quasiclassical trajectory and experimental results

The paper reports converged quantum total integral reactive cross sections for the reaction F + H2 yielding HF + H, for initial rotational states j sub i = 0 and 1, using a time-dependent method. The results are compared to classical results and to the experimental results of Neumark et al. (1985). Strong quantum effects are found in the threshold region for both initial states (i.e., in the dependence of the reaction on initial state for low energies). The classical results agree better with experiment than do the quantum results; this appears to be due to errors in the potential used.

Neuhauser, Daniel↗
NASA NTRS1991

Microstructure and mechanical properties of a single crystal NiAl alloy with Zr or Hf rich G-phase precipitates

The possibility of producing NiAl reinforced with the G-phase (Ni16X6Si7), where X is Zr or Hf, has been investigated. The microstructure of these NiAl alloys have been characterized in the as-cast and annealed conditions. The G-phases are present as fine cuboidal precipitates (10 to 40 nm) and have lattice parameters almost four times that of NiAl. They are coherent with the matrix and fairly resistant to coarsening during annealing heat treatments. Segregation and nonuniform precipitate distribution observed in as-cast materials were eliminated by homogenization at temperatures near 1600 K. Slow cooling from these temperatures resulted in large plate shaped precipitates, denuded zones, and a loss of coherency in some of the large particles. Faster cooling produced a homogeneous fine distribution of cuboidal G-phase particles in the matrix. Preliminary mechanical properties for the Zr-doped alloy are presented and compared to binary single crystal NiAl. The presence of these precipitates appears to have an important strengthening effect at temperatures not less than 1000 K compared to binary NiAl single crystals.

Locci, I. E.↗
NASA NTRS1992

Spatial and temporal behavior of ULF pulsations observed by the Goose Bay HF radar

Techniques which allow the instantaneous amplitude and phase to be determined as functions of geomagnetic lattitude, longitude, and time are employed to carry out a detailed analysis of HF radar data of a ULF pulsation event in the postmidnight sector on January 11, 1989. Field line resonances with several different frequencies occur simultaneously at different latitudes. These can be associated with cavity mode frequencies of 1.3 mHz, 1.9 mHz, 2.7 mGz, and 3.3 mHz. These frequencies are constant to better than 10 percent over a local time period of nearly 4 hr. The field-aligned currents driven by the resonances can be as large as 5 micro-A/sq m at ionospheric heights. The data support a picture of modes driven by solar wind impulses.

Walker, A. D. M.↗
NASA NTRS1993

Direct observation of porous SiC formed by anodization in HF

A process for forming porous SiC from single-crystal SiC wafers has been demonstrated. Porous SiC can be fabricated by anodizing n-type 6H-SiC in HF under UV illumination. TEM reveals pores of sizes 10-30 nm with interpore spacings ranging from roughly 5 to 150 nm. This is the first reported direct observation of porous SiC formation.

Shor, Joseph S.↗