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Expectation values and kinetic energy for vibrational-rotational levels of ground states of H2, HD, and D2
The purpose of this document is to provide a performance assessment (PA) of the 200 West Area Low‑Level Burial Grounds (LLBGs), under the requirements of DOE O 435.1, Radioactive Waste Management1. The objective is to ensure that the radioactive waste is managed in a manner that is protective of human health and the environment. Figure ES-1 shows the location of the LLBGs in the 200 West and 200 East Areas of the Hanford Site.
Groundwater data around the Utah FORGE site has been collected to determine the piezometric levels and compositional variability. Field measurements in 2020 are designed to obtain and survey new groundwater wells that have been drilled on the distal periphery of the Utah FORGE project area. The spreadsheet included in this submission contains ground water level data from the Utah FORGE site as monitored from wells WOW-2 and WOW-3. The well locations are also provided as UTM, Zone 12, NAD83 coordinates.
This model package report (MPR) documents the development of the integrated vadose and saturated zone flow and transport model developed for the performance assessment of Trenches 31 and 34 in the low-level burial grounds (LLBGs). This modeling capability is intended for use in addressing the analysis requirements outlined in DOE O 435.1, Chg 1, Radioactive Waste Management1. The overall objective of the modeling effort is to provide a basis for making informed disposal decisions pertinent to Trenches 31 and 34. The purpose of the MPR is to document the development of the three-dimensional numerical vadose zone and saturated flow and transport model test case and evaluate its adequacy to support the LLBG performance assessment. The purpose is not to present results for DOE 435.1 decision making. The use of the model to perform base case and sensitivity analysis for the LLBG performance assessment, including inputs and results, is documented separately in subsequent environmental calculation files. This report discusses the development and translation of the conceptual model for flow and contaminant transport into the LLBG performance assessment three-dimensional numerical flow and transport model evaluated using the Subsurface Transport Over Multiple Phases (STOMP©) simulator. The development of representative geologic framework is described along with the implementation of waste release models used to represent contaminant release from waste disposed in the trenches. The report also provides the technical basis for specific model parameters and boundary conditions, along with description of modeling assumptions. This MPR includes certain calculations that are necessary to demonstrate the soundness of the model. Results provided by the model include vadose zone and saturated zone flow fields, and estimates of the possible future concentration in groundwater of technetium-99 and iodine-129 as example test cases. As an evaluation of the test cases, the model estimates of current vadose conditions are compared to available and analogous field and laboratory data, and compared to the results from the original performance assessment model (WHC-EP-0645, Performance Assessment for the Disposal of Low-Level Waste in the 200 West Area Burial Grounds 2 ). The features, events, and processes applicable to vadose zone and saturated zone flow and transport model are identified, and representative initial estimates for various parameters are documented. Note that the parameter estimates presented in this MPR are for illustration purposes, and may or may not reflect values selected for eventual performance assessment. Several key topical discussions (i.e., basis for recharge estimates, basis for vadose zone modeling, basis for saturated zone model development, and calibration) are included, which serve as the groundwork for confidence building for the groundwater pathway modeling and results. Numerical simulation results based on an example test case are included to illustrate the use of the combined saturated-unsaturated model in performance assessment calculations. Sensitivity and uncertainty results are not included in this MPR. Those results will be included in future environmental calculation files. The inclusion of the trapezoidal trench geometry and construction details in the finite difference grid introduces some gross simplifications regarding the trench and liner systems. The model test case presented in this MPR includes the assumption that the trench liner system does not affect flow through or around the trenches after the liner system is assumed to fail. This MPR also includes results of other test cases that involve alternate assumptions about how to incorporate the hydraulic effects of the trenches into the vadose zone of the model. These alternate cases do not attempt to account for the presence of the liner system after its assumed failure either. None of these cases is considered to be the base case at this time. Analysis and alternate cases that attempt to account for the presence of the liner system in greater detail, and its effect on flow through and around it, are to be documented in subsequent environmental calculation files. Depending on the results of those analyses and alternate cases, the eventual base case may involve more detailed inclusion of the effects of the liner system hydraulics.
We present OH observation results during the NACHTT-11 field campaign at the Boulder Atmospheric Observatory in Weld County, Colorado. The observed OH levels during the daytime (at noon) were ~ 2.7 × 106 molecules cm-3 at the ground level (2 m above ground level, AGL). HONO and ozone photolysis were the two dominant photochemical OH production pathways during the field campaign. However, alkene ozonolysis, found an important source for OH by two previous winter season OH observations, was a minor contribution to OH primary production (~5 %). To evaluate recycling sources of OH from HO2 and RO2, an observation constrained University of Washington Chemical Mechanism (UWCM) box model is employed to simulated ambient OH levels with different model scenarios. For the base run without constraining observed HONO, the model simulated OH significantly underestimates the observed OH level (20.8 times in the morning and 7.2 times in the daytime). This indicates that the known HONO sources incorporated in the UWCM model cannot explain the observed HONO level. Once HONO is constrained by the observation, the discrepancy between observation and model simulation improves (5.1 times in the morning and 2.1 times in the daytime) but still out of the measurement uncertainty range (35 %). We explore two possible reasons for the observed unexplainably high wintertime OH levels. First, potential roles of Cl atoms produce organic peroxy radicals from the reactions between Cl atmos and alkane compounds. However, the Cl levels during the observation period are estimated very low (~ 103 atoms cm-3) to explain the enhanced OH levels. Second, Impacts of higher HONO levels on the ground was evaluated. Strong HONO gradient towards ground was observed especially during the early morning (6 am to 8 am) was observed and the lowest level available for the HONO observation during the campaign is 5 m AGL. Once we assume the twice of the observed HONO levels averaged between 5 m to 15 m at 2 m AGL, model predicted OH levels agree well within the observation uncertainty range. Wintertime photochemistry has not been investigated as much as the summer season. The results of this study along with a limited number of winter OH observations clearly urge further investigation on tropospheric oxidation capacity in the winter season considering implications of tropospheric oxidation capacity to the short-lived climate forcers especially methane.
Ice-nucleating particles (INPs) influence the formation of ice crystals in clouds and many types of precipitation. This study reports unique properties of INPs collected from 42 precipitation samples in the Texas Panhandle region from June 2018 to July 2019. We used a cold stage instrument called the West Texas Cryogenic Refrigerator Applied to Freezing Test system to estimate INP concentrations per unit volume of air (nINP) through immersion freezing in our precipitation samples with our detection capability of >0.006 INP L -1 . A disdrometer was used for two purposes: (1) to characterize the ground-level precipitation type and (2) to measure the precipitation intensity as well as size of precipitating particles at the ground level during each precipitation event. While no clear seasonal variations of n INP values were apparent, the analysis of yearlong ground-level precipitation observation as well as INPs in the precipitation samples showed some INP variations, e.g., the highest and lowest n INP values at -25°C both in the summer for hail-involved severe thunderstorm samples (3.0 to 1130 INP L -1 ), followed by the second lowest at the same temperature from one of our snow samples collected during the winter (3.2 INP L -1 ). Furthermore, we conducted bacteria community analyses using a subset of our precipitation samples to examine the presence of known biological INPs. In parallel, we also performed metagenomics characterization of the bacterial microbiome in suspended ambient dust samples collected at commercial open-lot livestock facilities (cattle feedyards hereafter) in the Texas Panhandle (i.e., the northernmost counties of Texas, also known as “West Texas”) to ascertain whether local cattle feedyards can act as a source of bioaerosol particles and/or INPs found in the precipitation samples. Some key bacterial phyla present in cattle feedyard samples appeared in precipitation samples. However, no known ice nucleation active species were detected in our samples. Overall, our results showed that cumulative n INP in our precipitation samples below -20°C could be high in the samples collected while observing > 10 mm h -1 precipitation with notably large hydrometeor sizes and an implication of cattle feedyard bacteria inclusion.
The Titan-Centaur was launched from Kennedy Space Center on February 11, 1974 at 0948 eastern daylight time. Ground level effluent measurements were obtained from the solid rocket motors for comparison with NASA diffusion models for predicting effluent ground level concentrations and cloud behavior. The results obtained provide a basis for an evaluation of such key model inputs such as cloud rise rate, stabilization altitude, crosswind growth, volume expansion, and cloud trajectory. Ground level effluent measurements were limited because of changing meteorological conditions, incorrect instrument location, and operational problems. Based on the measurement results, operational changes are defined. Photographs of the ground exhaust clouds are shown. The chemical composition of the exhaust gases was analyzed and is given.
Properties of exact density functionals provide useful constraints for the development of new approximate functionals. This paper focuses on convex sums of ground-level densities. It is observed that the electronic kinetic energy of a convex sum of degenerate ground-level densities is equal to the convex sum of the kinetic energies of the individual degenerate densities. (The same type of relationship holds also for the electron-electron repulsion energy.) This extends a known property of the Levy-Valone Ensemble Constrained-Search and the Lieb Legendre-Transform refomulations of the Hohenberg-Kohn functional to the individual components of the functional. Moreover, we observe that the kinetic and electron-repulsion results also apply to densities with fractional electron number (even if there are no degeneracies), and we close with an analogous point-wise property involving the external potential. Examples where different degenerate states have different kinetic energy and electron-nuclear attraction energy are given; consequently, individual components of the ground state electronic energy can change abruptly when the molecular geometry changes. These discontinuities are predicted to be ubiquitous at conical intersections, complicating the development of universally applicable density-functional approximations.
Nitrogen dioxide (NO2) is an important contributor to air pollution and can adversely affect human health(1–9) . A decrease in NO2 concentrations has been reported as a result of lockdown measures to reduce the spread of COVID-19(10–20). Questions remain, however, regarding the relationship of satellite-derived atmospheric column NO2 data with health-relevant ambient ground-level concentrations, and the representativeness of limited ground-based monitoring data for global assessment. Here we derive spatially resolved, global ground-level NO2 concentrations from NO2 column densities observed by the TROPOMI satellite instrument at sufficiently fine resolution (approximately one kilometre) to allow assessment of individual cities during COVID-19 lockdowns in 2020 compared to 2019. We apply these estimates to quantify NO2 changes in more than 200 cities, including 65 cities without available ground monitoring, largely in lower-income regions. Mean country-level population-weighted NO2 concentrations are 29% ± 3% lower in countries with strict lockdown conditions than in those without. Relative to long-term trends, NO2 decreases during COVID-19 lockdowns exceed recent Ozone Monitoring Instrument (OMI)-derived year-to-year decreases from emission controls, comparable to 15 ± 4 years of reductions globally. Our case studies indicate that the sensitivity of NO2 to lockdowns varies by country and emissions sector, demonstrating the critical need for spatially resolved observational information provided by these satellite-derived surface concentration estimates.
This paper describes ground-level measurements of sonic boom signatures made as part of the SR-71 sonic boom propagation experiment recently completed at NASA Dryden Flight Research Center, Edwards, California. Ground level measurements were the final stage of this experiment which also included airborne measurements at near and intermediate distances from an SR-71 research aircraft. Three types of sensors were deployed to three station locations near the aircraft ground track. Pressure data were collected for flight conditions from Mach 1.25 to Mach 1.60 at altitudes from 30,000 to 48,000 ft. Ground-level measurement techniques, comparisons of data sets from different ground sensors, and sensor system strengths and weaknesses are discussed. The well-known N-wave structure dominated the sonic boom signatures generated by the SR-71 aircraft at most of these conditions. Variations in boom shape caused by atmospheric turbulence, focusing effects, or both were observed for several flights. Peak pressure and boom event duration showed some dependence on aircraft gross weight. The sonic boom signatures collected in this experiment are being compiled in a data base for distribution in support of the High Speed Research Program.
This document summarizes the available information regarding the natural system (vadose zone and saturated zone) at the active trenches of the 200 West Area and 200 East Area Low-Level Burial Grounds (LLBGs). This information is relevant for developing the natural system fate and transport model for the update of the active trenches performance assessment. This document presents a description of the major features, events, and processes of the natural system at the active trenches of the 200 West Area and 200 East Area LLBGs that involves the geologic features or framework, and the vadose zone and groundwater flow and transport system. The description of the geologic features includes the following items: geologic setting, major structural features, major hydrostratigraphic units, and geologic framework. The discussion concerning vadose zone flow and transport at the active trenches of the 200 West Area and 200 East Area LLBGs includes the following topics: vadose zone features, events, and processes relevant to the development of the vadose zone conceptual model; hydrogeologic units and conditions; factors affecting moisture movement; and flow and transport properties of major units. The discussion concerning the groundwater flow and transport system in the vicinity of the active trenches of the 200 West Area and 200 East Area LLBGs includes the following topics: saturated zone features, events, and processes relevant to the saturated zone conceptual model; hydrogeologic units; groundwater flow conditions; and flow and transport properties.
A spectral-based correction adapted from ISO 11204 [1] is investigated here to mitigate the effects of ambient noise contamination of sonic booms recorded by noise monitors during field tests. The algorithm from sections 5.4.2 and 7 of ISO 11204 is customized using six nonstandard correction grades in addition to implementing the two standardized grades described in ISO 11204. The six nonstandard grades allow for more aggressive correction of the levels of the sonic boom spectrum when they are proximate to the ambient spectrum. Of the eight correction grades, the most aggressive custom correction grade, termed “Custom F” here, performed best under the conditions that were studied. Consequently, “Custom F” is recommended for use when processing in-field recordings of X-59 sonic booms. To evaluate the eight correction grades, mock X-59 acoustic recordings were generated using predicted ground-level X-59 sonic booms. These ground-level waveforms were created by Doebler [2] by propagating nearfield CFD solutions of the X-59 C612A configuration to the ground using PCBoom [3] (please see Acknowledgements and Refs. [4, 5, 2, 6]). To generate the mock acoustic recordings from those ground-level waveforms, they were further modified using turbulence filters developed during the NASA SonicBAT effort [7], post boom noise audio clips from the NASA SonicBAT tests [7], and ambient noise from the NASA QSF18 test [8, 9]. These mock acoustic recordings enabled evaluation of the ambient noise mitigation methods since the proper loudness levels of the X-59 waveforms in absence of ambient noise are known. Specifically, these known levels provide a benchmark against which the corrected loudness levels are compared, where the corrected loudness levels are computed when ambient noise is present within the waveforms. Importantly, similar analyses using in-field recordings are not possible since the proper loudness levels of the sonic boom waveforms in absence of ambient noise are unknowable when analyzing in-field recordings. Consequently, if additional analyses of ambient noise mitigation methods are needed, then use of mock recordings like those used here is recommended.
This paper describes ground-level measurements of sonic boom signatures made as part of the SR-71 sonic boom propagation experiment recently completed at NASA Dryden Flight Research Center, Edwards, California. Ground-level measurements were the final stage of this experiment which also included airborne measurements at near and intermediate distances from an SR-71 research aircraft. The types of sensors were deployed to three station locations near the aircraft ground track. Pressure data collected for flight conditions from Mach 1.25 to Mach 1.60 at altitudes from 30,000 to 48,000 ft. Ground-level measurement techniques, comparisons of data sets from different ground sensors, and sensor system strengths and weaknesses are discussed. The well-known N-wave structure dominated r sonic boom signatures generated by the SR-71 aircraft at most of these conditions. Variations in boom shape caused by atmospheric turbulence, focusing effects, or both, were observed for several flights. Peak pressure and boom event duration showed some dependence on aircraft gross weight. The sonic boom signatures collected in this experiment are being compiled in a data base for distribution in support of the High Speed Research Program.
The purpose of this document is to provide the assessment of the long-term human health and environmental risk associated with the continued disposal of radioactive wastes in the active trenches of the 200 East and 200 West Area Low-Level Burial Grounds (LLBGs) at the Hanford Site (Figure ES-1), as required by DOE O 435.1, Radioactive Waste Management1. Since July 1, 2004, the only active trenches in the 200 West Area LLBGs are the lined Trenches 31 and 34 used for the disposal of containerized low-level waste and mixed low-level waste (Figure ES-2). The only active trench in the 200 East Area LLBGs is the unlined Trench 94 that was used for the disposal of naval reactor compartments (Figure ES-3). Trenches 31 and 34 are intended to be used until they reach their disposal capacity while Trench 94 will be used and expanded as necessary to meet the needs of the U.S. Navy.
Abstract. Most prior field studies of new particle formation (NPF) have been performed at or near ground level, leaving many unanswered questions regarding the vertical extent of NPF. To address this, we measured concentrations of 11–16 nm diameter particles from ground level to 1000 m during the 2013 New Particle Formation Study at the Atmospheric Radiation Measurement Southern Great Plains site in Lamont, Oklahoma. The measurements were performed using a tethered balloon carrying two condensation particle counters that were configured for two different particle cut-off diameters. These observations were compared to data from three scanning mobility particle sizers at the ground level. We observed that 11–16 nm diameter particles were generated at the top region of the boundary layer, and were then rapidly mixed throughout the boundary layer. We also estimate liquid water content of nanoparticles using ground-based measurements of particle hygroscopicity obtained with a Humidified Tandem Differential Mobility Analyzer and vertically resolved relative humidity (RH) and temperature measured with a Raman lidar. Our analyses of these observations lead to the following conclusions regarding nanoparticles formed during NPF events at this site: (1) ground-based observations may not always accurately represent the timing, distribution, and meteorological conditions associated with the onset of NPF; (2) nanoparticles are highly hygroscopic and typically contain up to 50 % water by volume, and during conditions of high RH combined with high particle hygroscopicity, particles can be up to 95 % water by volume; (3) increased liquid water content of nanoparticles at high RH greatly enhances the partitioning of water-soluble species like organic acids into ambient nanoparticles.
The hook method is used to measure the absolute gf values of the following lines: the first 13 members of the principal series, the ground-level transition at 2275.46 A, and the intercombination line at 6572.78 A in Ca I; the first 22 members of the principal series, the ground-level transitions at 2428.1 and 2680.08 A, and the intercombination line at 6892.6 A in Sr I; and the members from principal quantum numbers 12 to 21, inclusive, as well as the ground-level transitions at 2432.5, 2444.6, and 2454.06 A in Ba I. The results are compared with those of previous measurements, and the quantum-defect method is applied to plot the oscillator strengths of the discrete transitions in the principal series of Mg I, Ca I, and Sr I in order to obtain estimates of the photoionization cross sections at the first ionization limit. The resulting cross sections are found to be about twice as large as previous values based on vapor-pressure data.
The purposes of this study are: Calculate the radiological dose due to a potential accident for the Transportation Safety Document (TSD). The calculation is based on the DOE Tool Box code MACCS2 Version 1.13.1 and FGR-13 dose conversion factor. Calculate the dilution factor X/Q which will be used to determine the consequence of a potential toxic chemical release. The calculation is based on the DOE Tool Box code MACCS2 Version 1.13.1. Calculate the Equivalent Source Term Mass Multiplier (ESTMM) relative to the 30-year aged fuel grade Pu for the 30-year aged weapon grade Pu, natural Uranium, enriched uranium, plutonium isotopes, uranium isotopes, and several other isotopes. The dose and X/Q are calculated based on the following two TSD potential accident scenarios for the release of 1 Ci of Pu-239 and 1 g of fuel grade plutonium: a ground level spill without building wake and a ground level fire with 5 MW sensible heat and with 20'W x 30'H building wake. The Equivalent Source Term Mass Multiplier (ESTMM) is calculated for various isotope materials. The dose and X/Q at 90 m are also calculated by extrapolation which shows that the dose and X/Q calculated by MACCS2 based on a spatial interval (0, 180 m) could be very conservative.
Abstract. The interplay of momentum surrounding wind farms significantly influences wake recovery, affecting the speed at which wakes return to their freestream velocities. Under stable atmospheric conditions, wind farm wakes can extend over considerable distances, leading to sustained vertical momentum flux downstream, with variations observed throughout the diurnal cycle. Particularly in regions such as the US Great Plains, stable conditions can induce low-level jets (LLJs), impacting wind farm performance and power output. This study examines the implications of wake recovery using long-term observations of vertical momentum flux profiles across diverse atmospheric conditions. In these observations, several key findings were observed, such as (a) LLJ heights being altered downstream of a wind farm, especially when the LLJs are below 250 m above ground level; (b) a notable impact of LLJ height on wake recovery being observed using momentum flux profiles at upwind and downwind locations, wherein LLJs between 250 and 500 m above ground level resulted in larger momentum transfer within the wake (i.e., smaller velocity deficit) compared to LLJs below 250 m above ground level; (c) the largest momentum flux variability being observed during stable atmospheric conditions, with non-negligible variability observed during neutral and unstable atmospheric conditions; (d) detection of wake effects almost always being observed throughout the atmospheric boundary layer height; and finally (e) enhancement of wake recovery being observed in the presence of propagating gravity waves. These insights deepen our understanding of the intricate dynamics governing wake recovery in wind farms, advancing efforts to model and predict their behavior across varying atmospheric contexts. In addition, the performance of large-eddy-simulation-based semi-empirical internal boundary layer height model estimates incorporating real-world atmospheric and turbine inputs was evaluated using observations during LLJ conditions.