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At least 145 records · Page 8

Lightweight engine containment

Kevlar fabric styles and weaves were studied, as well as methods of application for advanced gas turbine engines. The Kevlar material was subjected to high speed impacts by simple projectiles fired from a rifle, as well as more complex shapes such as fan blades released from gas turbine rotors in a spin pit. Just contained data was developed for a variety of weave and/or application techniques, and a comparative containment weight efficiency was established for Kevlar containment applications. The data generated during these tests is being incorporated into an analytical design system so that blade containment trade-off studies between Kevlar and metal case engine structures can be made. Laboratory tests and engine environment tests were performed to determine the survivability of Kevlar in a gas turbine environment.

Weaver, A. T.↗

Improved Fire-Resistant Resins for Laminates

Fire-resistant resins for fabricating laminates with inorganic fibers, especially graphite fibers, are formed from bisimides containing main-chain phosphorus and olefinic end groups. Bisimides are thermally polymerized to form resins and laminates virtually imcombustible in pure oxygen at 300 degrees C. New resins are suitable for many applications requiring good adhesion and excellent resistance to heat, fire, solvents and chemicals.

Fohlen, G. M.↗

Test Structures Applied to the Rapid Prototyping of Sensors

Recently, test structures were used to aid in the rapid development of a gas sensor and pressure sensor. These sensors were fabricated using co-fired ceramic technology and a multiproject approach. This talk will describe results obtained from a ceramic substrate which contained 36 chips with six variants including the sensors, process control monitors, and an interconnect chip. As far as the authors know, this is the first implementation of multi-projects in co-fired ceramic substrate. The gas sensor is being developed for the Space Shuttle and the pressure gage is being developed as a Martian barometer.

sensors ceramic substrate prototyping↗

STABILITY TESTS OF MONOPROPELLANTS EXPOSED TO FLAMES AND RIFLE FIRE

Tests of the stability of several monopropellants under the effects of impact and heat were conducted in order to assess the potential hazard in a propellant storage area from major fires and enemy attack. Hydrazine, hydrazine nitrate solution, n-propyl nitrate, and ethylene oxide were all tested in one-gallon aluminum containers (half of them filled to 25% and half to 95% capacity) by being subjected to oil bonfires and wood bonfires, and 20-mm incendiary, 20mm high explosive incendiary, and .30-caliber rifle fire. Aviation gasoline was tested in the same manner, for comparison. In the bonfire tests, all four monopropellants generally gave explosion intensities equivalent to one another regardless of the type of bonfire (oil or wood) or the amount of liquid in the test container. Occasionally, however, with hydrazine, hydrazine nitrate solution, and n-propyl nitrate, anomalous results occurred: there was either (a) no explosion or (b) an explosion of above average intensity. Ethylene oxide more nearly approximated the behavior of aviation gasoline than did the other monopropellants. In the rifle-fire tests, n-propyl nitrate appeared to be most shock- sensitive since it was exploded by all three types of ammunition. Hydrazine and hydrazine nitrate solution were exploded by the high-explosive ammunition, but not by the incendiary or .30-dber ammunition. Ethylene oxide was not exploded by any of the gunfire, but the liquid was ignited by both incendiary and high-explosive incendiary ammunition.

FIRING↗

Test data from solid propellant plume aerodynamics test program in Ames 6 x 6 foot supersonic wind tunnel (shuttle test FA7) (Ames test 033-66)

The aerodynamic effects of plumes from hot combustion gases in the presence of a transonic external flow field were measured to advance plumes simulation technology, extend a previously acquired data base, and provide data to compare with the effects observed using cold gas plumes. A variety of underexpanded plumes issuing from the base of a strut-mounted ogive-cylinder body were produced by combusting solid propellant gas generators. The gas generator fired in a short-duration mode (200 to 300 msec). Propellants containing 16 percent and 2 percent A1 were used, with chamber pressures from 400 to 1800 psia. Conical nozzles of 15 deg half-angle were tested with area ratios of 4 and 8. Pressures were measured in the gas generator combustion chamber, along the nozzle wall, on the base, and along the body rear exterior. Schlieren photographs were taken for all tests. Test data are presented along with a description of the test setup and procedures.

Hair, L. M.↗

Rubberized, Brominated Epoxies

Graphite/epoxy composite materials made with resins containing bromine and rubber additives. New composites tougher and more resistant to fire. Flame resistance increased by introducing bromine via commercial brominated flame-retartant polymeric additives.

Gilwee, W.↗

Synthesis and Review: African Environmental Processes and Water-Cycle Dynamics

Africa's vast landmass harbors a variety of physical processes that affect the environment and the water cycle. This focus issue on the "African Environmental Processes and Water-Cycle Dynamics" contains eight articles that address these phenomena from different but complementary perspectives. Fires used for agricultural and related purposes play a major role in land-cover change, surface albedo modifications, and smoke emission; all of which affect the environment and the water cycle in different ways. However, emissions of aerosols and trace gases are not restricted to fires, but also emanate from other natural and human activities. The African water cycle undergoes significant perturbations that are attributable to several factors, including the aforesaid environmental processes. These changes in the water cycle have produced severe drought and flooding events in recent decades that affect societal wellbeing across sub-Saharan Africa. The combined effects of the environmental processes and water-cycle dynamics affect and are affected by climate variability and can be propagated beyond the continent. Future studies should utilize the wealth of observations and modeling tools that are constantly improving to clearly elucidate the interrelationships between all of these phenomena for the benefit of society.

Water cycle dynamics↗

Production and application of chemical fibers with special properties for manufacturing composite materials and goods of different usage

The development of modern technologies demands the creation of new nonmetallic, fibrous materials with specific properties. The fibers and materials developed by NII 'Chimvolokno', St. Petersburg, can be divided into two groups. The first group includes heat-resistant fibers, fire-resistant fibers, thermotropic fibers, fibers for medical application, and textile structures. The second group contains refractory fibers, chemoresistant and antifriction fibers, fibers on the basis of polyvinyl alcohol, microfiltering films, and paperlike and nonwoven materials. In cooperation with NPO 'Chimvolokno' MYTITSHI, we developed and started producing heat-resistant high-strength fibers on the base of polyhetarearilin and aromatic polyimides (SVM and terlon); heat-resistant fibers on the base of polyemede (aramid); fire-retardant fibers (togilen); chemoresistant and antifriction fibers on the basis of homo and copolymers of polytetrafluoroethylene (polyfen and ftorin); and water soluble, acetylated, and high-modulus fibers from polyvinyl alcohol (vylen). Separate reports will deal with textile structures and thermotropic fibers, as well as with medical fibers. One of the groups of refractory fibers carbon fibers (CF) and the corresponding paperlike nonwoven materials are discussed in detail. Also, composite materials (CM) and their base, which is the subject of the author's research since 1968, is discussed.

Levit, R.↗

Valve Health Monitoring System Utilizing Smart Instrumentation

The valve monitoring system is a stand alone unit with network capabilities for integration into a higher level health management system. The system is designed for aiding in failure predictions of high-geared ball valves and linearly actuated valves. It performs data tracking and archiving for identifying degraded performance. The data collection types are cryogenic cycles, total cycles, inlet temperature, body temperature torsional strain, linear bonnet strain, preload position, total travel and total directional changes. Events are recorded and time stamped in accordance with the IRIG B True Time. The monitoring system is designed for use in a Class 1 Division II explosive environment. The basic configuration consists of several instrumentation sensor units and a base station. The sensor units are self contained microprocessor controlled and remotely mountable in three by three by two inches. Each unit is potted in a fire retardant substance without any cavities and limited to low operating power for maintaining safe operation in a hydrogen environment. The units are temperature monitored to safeguard against operation outside temperature limitations. Each contains 902-928 MHz band digital transmitters which meet Federal Communication Commission's requirements and are limited to a 35 foot transmission radius for preserving data security. The base-station controller correlates data from the sensor units and generates data event logs on a compact flash memory module for database uploading. The entries are also broadcast over an Ethernet network. Nitrogen purged National Electrical Manufactures Association (NEMA) Class 4 enclosures are used to house the base-station

Jensen, Scott L.↗

Animal Exposure During Burn Tests

An animal exposure test system (AETS) was designed and fabricated for the purpose of collecting physiological and environmental (temperature) data from animal subjects exposed to combustion gases in large scale fire tests. The AETS consisted of an open wire mesh, two-compartment cage, one containing an exercise wheel for small rodents, and the other containing one rat instrumented externally for electrocardiogram (ECG) and respiration. Cage temperature is measured by a thermistor located in the upper portion of the rat compartment. Animal activity is monitored by the ECG and the records indicate an increase in EMG (electromyograph) noise super-imposed by the increased activity of the torso musculature. Examples of the recordings are presented and discussed as to their significance regarding toxicity of fire gases and specific events occurring during the test. The AETS was shown to be a useful tool in screening materials for the relative toxicity of their outgassing products during pyrolysis and combustion.

Gaume, J. G.↗

The global Cretaceous-Tertiary fire: Biomass or fossil carbon

The global soot layer at the K-T boundary indicates a major fire triggered by meteorite impact. However, it is not clear whether the principal fuel was biomass or fossil carbon. Forests are favored by delta value of C-13, which is close to the average for trees, but the total amount of elemental C is approximately 10 percent of the present living carbon, and thus requires very efficient conversion to soot. The PAH was analyzed at Woodside Creek, in the hope of finding a diagnostic molecular marker. A promising candidate is 1-methyl-7-isopropyl phenanthrene (retene,), which is probably derived by low temperature degradation of abietic acid. Unlike other PAH that form by pyrosynthesis at higher temperatures, retene has retained the characteristic side chains of its parent molecule. A total of 11 PAH compounds were identified in the boundary clay. Retene is present in substantial abundance. The identification was confirmed by analysis of a retene standard. Retene is characteristic of the combustion of resinous higher plants. Its formation depends on both temperature and oxygen access, and is apparently highest in oxygen-poor fires. Such fires would also produce soot more efficiently which may explain the high soot abundance. The relatively high level of coronene is not typical of a wood combustion source, however, though it can be produced during high temperature pyrolysis of methane, and presumably other H, C-containing materials. This would require large, hot, low O2 zones, which may occur only in very large fires. The presence of retene indicates that biomass was a significant fuel source for the soot at the Cretaceous-Tertiary boundary. The total amount of elemental C produced requires a greater than 3 percent soot yield, which is higher than typically observed for wildfires. However, retene and presumably coronene imply limited access of O2 and hence high soot yield.

Gilmour, Iain↗

Fire-retardant decorative inks for aircraft interiors

Commercial and experimental fire retardants were screened as potential fire retardants for acrylic printing inks used on aircraft interior sandwich panels. The fire retardants are selected according to their physical properties and their thermostabilities. A criterion for selecting a more stable fire retardant is established. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) are used to determine thermostabilities. Results show that the fire retardant formulations are more thermally stable than the acrylic ink control. It is determined that an ink formulation containing a brominated phenol and carboxy-terminated butadiene acrylonitrile which has been modified with a brominated polymeric additive (BPA), yields the highest limiting oxygen index (LOI) of all the compounds tested. All of the fire-retardant formulations have a higher oxygen index than the baseline acrylic ink.

Kourtides, D. A.↗

Development of phosphorylated adhesives

The synthesis of epoxy prepolymers containing phosphorus was carried out in such a manner as to provide adhesives containing at least 5 percent of this element. The purpose of this was to impart fire retardant properties to the adhesive. The two epoxy derivatives, bis(4-glycidyl-oxyphenyl)phenylphosphine oxide and bis(4-glycidyl-2-methoxyphenyl)phenylphosphonate, and a curing agent, bis(3-aminophenyl)methylphosphine oxide, were used in conjunction with one another and along with conventional epoxy resins and curing agents to bond Tedlar and Polyphenylethersulfone films to Kerimid-glass syntactic foam-filled honeycomb structures. Elevated temperatures are required to cure the epoxy resins with the phosphorus-contaning diamine; however, when Tedlar is being bonded, lower curing temperatures must be used to avoid shrinkage and the concomitant formation of surface defects. Thus, the phosphorus-containing aromatic amine curing agent cannot be used alone, although it is possible to use it in conjunction with an aliphatic amine which would allow lower cure temperatures to be used. The experimental epoxy resins have not provided adhesive bonds quite as strong as those provided by Epon 828 when compared in peel tests, but the differences are not very significant. It should be noted, if optimum properties are to be realized. In any case the fire retardant characteristics of the neat resin systems obtained are quite pronounced, since in most cases the self-extinguishing properties are evident almost instantly when specimens are removed from a flame.

Bilow, N.↗

ISCCP results for the FIRE IFO regions and times

The ISCCP analysis of cloud conditions during and in the vicinity of the FIRE cirrus and marine stratus Intensive Field Observations (IFOs) is presented in two forms: the standard climatology product, which is averaged to a nominal 250 km resolution and a pixel-by-pixel version that samples the original data at about 30 km spacing every three hours. These results are based on NOAA-9 and GOES-6 images covering October to November 1986 and July 1987 for the FIRE Extended Area. Comparisons of these results with other FIRE observations will serve to check the accuracy of the clear sky radiances inferred by the ISCCP analysis, which determines the accuracy of the cloud detections. Of more interest is the exploration of the dependence of the inferred cloud properties for direct evaluation of the role of small scale variability of cloud properties on the radiation field. This is illustrated by preliminary results obtained for the scales contained in the ISCCP data. The ISCCP analysis also sets the larger scale context of the FIRE data: (1) comparisons of the clouds occurring in the FIRE IFOs with nearby locations and times are presented, and (2) comparisons of the cloud conditions for the same month in other years are shown.

Rossow, William B.↗

Graphite fiber surface treatment to improve char retention and increase fiber clumping

Composites containing carbon and graphite fibers can release fibers into the atmosphere during a fire. This release can potentially cause failure in some types of electrical equipment. Reduced fiber dispersion during and after combustion will reduce risks. Epoxidized char forming systems were synthesized which will react with commercially available surface treated carbon fiber. Fibers modified with these char formers retained adhesion in a specific epoxy matrix resin. Small scale combustion testing indicates that using these char former modified fibers in laminates will help to reduce the dispersement of fibers resulting from exposure to fire without sacrificing resin to fiber adhesion.

Paul, J. T., Jr.↗

Medical Lessons Learned from the Exploration Atmospheres Study

Background: The National Aeronautics and Space Administration’s (NASA) Exploration Atmospheres study (EA) was done to evaluate alternative cabin atmospheres for future spacecraft designs and planetary surface exploration of the Moon, Mars and beyond. Deep space exploration involves creating habitats and environments safe for human occupancy and means to explore the outside environment (extravehicular activities, EVA). In order to validate alternative atmospheres and pre-spacewalk procedures, the EA study was conducted to evaluate factors such as hypoxia risks, denitrogenation protocols, food limitations, medications, and the impact of other factors on human performance. Overview: Space travel is constrained by mass, volume, power and the cost of vehicle development, which creates tradeoffs in various capabilities, including breathing gasses. Higher atmospheric pressure in a vehicle means more gas, and a stronger containment vessel/habitat; while lower pressure requires higher oxygen partial pressure, which may increase fire risk. NASA’s EA study evaluated a proposed alternative cabin environment (8.2 psia, 34% Oxygen), for future spacecraft habitat, and planetary EVAs. EA included both a 3-day and a 11-day trial. These trials included a depressurization and saturation to 8.2psi at 34% O2 with additional depresses to 4.3 psia at 85% O2 for simulated EVAs, (1 EVA during the 3-day and 5 during the 11-day trials). Discussion: Planning for and executing the medical monitoring and response plan for a trial of this scope was a huge undertaking with no prior practice to fall back on. Food obstacles, sleeping issues, medications, joint injury, equipment limitations, medical privacy, multiple cases of decompression sickness, and even a COVID outbreak among the support team proved challenging. Conclusion: Testing of this nature is an essential part NASA’s preparation for the upcoming Lunar Artemis missions. As spaceflight transitions beyond low earth orbit, to planetary, even more trials of this nature will be required to learn what are the optimal atmospheric and associated operational constraints to maintain the optimal health of the crew and achieve mission objectives.

R Sanders↗

Animal exposure during burn tests

An animal exposure test system has been designed and fabricated for the purpose of collecting physiological and environmental (temperature) data from animal subjects exposed to combustion gases in large scale fire tests. The AETS consists of an open wire mesh, two-compartment cage, one containing an exercise wheel for small rodents, and the other containing one rat instrumented externally for electrocardiogram and respiration. The ECG and respiration sensors are located in a belt placed around the torso of the subject, electrode wires forming an umbilical to a connector in the top of the compartment. A cable extends from the connector to the power supply and signal conditioning electronics. These are connected to a dual-beam oscilloscope for real time monitoring and a magnetic tape recorder having three or more channels. Endpoints observed are bradycardia, cardiac arrhythmias, changes in respiratory pattern, respiratory arrest and cardiac arrest. The ECG record also appears to be a good method of monitoring animal activity as indicated by an increase in EMG noise superimposed on the record during increased activity of the torso musculature. Examples of the recordings are presented and discussed as to their significance regarding toxicity of fire gases.

Gaume, J. G.↗

Aerosol characterization in smoke plumes from a wetlands fire

Results are presented from airborne measurements of aerosol mass loading, size distribution, and elemental composition obtained in a smoke plume from a fire at a Florida wildlife refuge. It is found that there was a high concentration of carbon-containing aerosols and salt crystals in the 0.1-0.2 micron size range; the composition and morphology of the aerosols differed with size. Aerosol mass concentrations are used in conjunction with those obtained for CO2 in order to calculate ratios of aerosol and CO2. The ratios are noted to be higher for the smoldering phase of the fire than for its flaming phase.

Woods, David C.↗