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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8

Production of fast-charge Zn-based aqueous batteries via interfacial adsorption of ion-oligomer complexes

Abstract Aqueous zinc batteries are attracting interest because of their potential for cost-effective and safe electricity storage. However, metallic zinc exhibits only moderate reversibility in aqueous electrolytes. To circumvent this issue, we study aqueous Zn batteries able to form nanometric interphases at the Zn metal/liquid electrolyte interface, composed of an ion-oligomer complex. In Zn||Zn symmetric cell studies, we report highly reversible cycling at high current densities and capacities (e.g., 160 mA cm −2 ; 2.6 mAh cm −2 ). By means of quartz-crystal microbalance, nuclear magnetic resonance, and voltammetry measurements we show that the interphase film exists in a dynamic equilibrium with oligomers dissolved in the electrolyte. The interphase strategy is applied to aqueous Zn||I 2 and Zn||MnO 2 cells that are charged/discharged for 12,000 cycles and 1000 cycles, respectively, at a current density of 160 mA cm −2 and capacity of approximately 0.85 mAh cm −2 . Finally, we demonstrate that Zn||I 2 -carbon pouch cells (9 cm 2 area) cycle stably and deliver a specific energy of 151 Wh/kg (based on the total mass of active materials in the electrode) at a charge current density of 56 mA cm −2 .

25 ENERGY STORAGE↗

Traction Inverter Integrated On-Board DC Fast Charging through Partial Power Processing

This paper introduces an innovative on-board integrated DC charging approach through partial power processing (PPP) in a traction inverter system. The proposed system, incorporating a series-connected partial power dual-active-bridge (DAB) converter, efficiently regulates the DC link voltage to achieve an optimal bus voltage for traction operation across a wide speed and torque range. Leveraging partial and bidirectional power processing, the battery current during charging is precisely regulated without the need for external DC-DC charging equipment, ensuring seamless integration to a DC hub with different voltage levels. This advanced integration also endows the system with bidirectional power exchange capability to/from the external DC hub, i.e., vehicle-to-DC (V2DC).

DAB↗

Multiport Control with Partial Power Processing in Solid-State Transformer for PV, Storage, and Fast-Charging Electric Vehicle Integration

This article proposes a multiport control method to enable partial power processing (PPP) in a medium-voltage (MV) multiport solid-state transformer (SST). MV multiport SSTs are promising in integrating low-voltage DC sources or loads such as solar photovoltaic, energy storage, and electric vehicles into smart grids without bulky line-frequency transformers. Compared to voltage-source SST, current-source (CS) SST features single-stage isolated bidirectional AC/AC, AC/DC, or DC/DC conversion using an inductive DC link. For a multiport CS SST, it is revealed in this article that the PPP capability can be enabled through the proposed control without extra hardware, different from the case of voltage-source converters where special hardware architecture is required for the PPP. With the PPP, most power exchange between LV ports is processed by only a fraction of the entire conversion stage, leading to reduced DC-link current, volume, loss, and improved efficiency. The proposed multiport PPP control scheme is analyzed to verify the advantages across a wide voltage and power range against conventional full power processing (FPP) multiport control, using the soft-switching solid-state transformer (S4T) with reduced conduction loss as an example. Comparative experimental results based on a SiC three-port S4T prototype verify the effectiveness of the proposed PPP scheme against the FPP scheme under both steady state and dynamic conditions. Here, the DC-link current reduction is measured to be more than 36%. Significantly, the proposed multiport PPP control scheme is generic and applicable to any hard-switching or soft-switching CS SSTs without extra hardware.

14 SOLAR ENERGY↗

DEPLOYING FAST CHARGING INFRASTRUCTURE FOR ELECTRIC VEHICLES IN URBAN NETWORKS: AN ACTIVITY-BASED APPROACH

This paper explores an important problem under the domain of network modeling, the optimal configuration of charging infrastructure for electric vehicles (EVs) in urban networks considering EV users' daily activities and charging behavior. This study proposes a charging behavior simulation model considering different initial state of charge (SOC), travel distance, availability of home chargers, and the daily schedule of trips for each traveler. The proposed charging behavior simulation model examines the complete chain of trips for EV users as well as the interdependency of trips traveled by each driver. The problem of finding the optimum charging configuration is then formulated as a mixed-integer nonlinear programming problem that considers the dynamics of travel time and travel distance, the interdependency of trips made by each driver, limited range of EVs, remaining battery capacity for recharging, waiting time in queue, and detour to access a charging station. This problem is solved using a metaheuristic approach for a large-scale case network. A series of examples are presented to demonstrate the model efficacy and explore the impact of energy consumption on the final SOC and the optimum charging infrastructure.

Chain of Trips↗

Enabling Extreme Fast Charging through Control of Li Deposition Overpotential on Graphite Electrodes

Currently produced electric vehicles (EVs) rely on the use of lithium ion battery technology due to its high energy and power density. However, a major barrier facing the adoption of electric vehicles is that currently utilized Li-ion batteries take significantly longer to recharge (~ 30 minutes) compared to the time necessary to refuel vehicles powered by internal combustion engines (< 10 minutes). Thus, the need to develop Li-ion batteries which can be charged in approximately 10 minutes (6 C rate) without sacrificing range, cost, or cycle life is critical for the widespread implementation of EVs.

25 ENERGY STORAGE↗

High-Power Oak Ridge Converter (ORC) for Extreme Fast Charging Applications

This project report presents a novel power converter system called Oak Ridge Converter (ORC), a patented technology developed by the Oak Ridge National Laboratory (ORNL) for XFC wireless EV charging systems. ORC integrates the grid interface converter (also known as the active front-end rectifier with power factor correction) with the high-frequency inverter stage, promoting size and cost-effective charging technology with reduced infrastructure costs. The integration of the front-end rectifier with the high-frequency inverter truly eliminates one power conversion stage and achieves more than 33% size, weight, volume, and cost reduction on the wireless charging systems. Furthermore, ORC eliminates the primary side direct current (DC) bus bulk capacitors that are usually aluminum electrolytic capacitors and replaces them with very small, cost-effective, highly reliable, and high-temperature operation-capable alternate current (AC) film capacitors. ORC is also applicable to both single-phase and poly-phase couplers. When used with polyphase couplers, ORC further improves the power density of the overall system with higher power density power electronics. Moreover, ORC is inherently bidirectional and allows the system to provide power back to the grid for grid ancillary or grid support services. The ORC, based on a patented ORNL technology, is an excellent approach to resolving the high-power charging problems as described above, which directly converts the 60 hertz (Hz) line frequency into high frequency (i.e., 85 kilohertz (kHz)) to use with a high-frequency isolation transformer or wireless charging coils while eliminating the primary side number of power conversion stages from two to one. The result of the project is a prototype and reference design for a high-power wireless charging system—including power electronics, magnetics, and thermal—serving as a baseline for product development. The proposed system results are demonstrated for 270 kW of output power, with the system's overall efficiency of 92% from the AC grid, achieving less than 3% current total harmonic distortion (THD) and around 0.99 power factor (PF).

33 ADVANCED PROPULSION SYSTEMS↗

Misalignment Tolerant Three-phase Wireless Fast Charging System for Electric Vehicles

This project proposes improving the technology level of the three-phase wireless charging technology developed at Oak Ridge National Laboratory (ORNL). Successful commercialization of wireless charging systems require that they meet strict safety standards for electromagnetic field emissions and interoperability with other wireless charging technology. ORNL has previously demonstrated a 50kW three-phase wireless power transfer system with 95% efficiency. This prototype system weighed less than 50% of similar high-power wireless charging system while simultaneously exhibiting better safety characteristics. Due to better material utilization, the reduction in mass is expected to translate into similar cost reduction for the magnetic coupler. Additionally, the smaller footprint of the system can ease vehicle integration difficulties that would be encountered using other technology. Furthermore, the three-phase design can be made to operate with existing single-phase coupler design more easily and without intentional physical misalignment which would otherwise pose safety issues.This project developed ORNL’s WPT technology to satisfy the specifications and requirements for electric vehicle (EV) charging. The result of the project will be a prototype and reference design for a high-power wireless charging system—including magnetics, power electronics, and controls—serving as a baseline for product development.

33 ADVANCED PROPULSION SYSTEMS↗

Misalignment Tolerant Three-phase Wireless Fast Charging System for Electric Vehicles

This project proposes improving the technology level of the three-phase wireless charging technology developed at Oak Ridge National Laboratory (ORNL). Successful commercialization of wireless charging systems require that they meet strict safety standards for electromagnetic field emissions and interoperability with other wireless charging technology. ORNL has previously demonstrated a 50kW three-phase wireless power transfer system with 95% efficiency. This prototype system weighed less than 50% of similar high-power wireless charging system while simultaneously exhibiting better safety characteristics. Due to better material utilization, the reduction in mass is expected to translate into similar cost reduction for the magnetic coupler. Additionally, the smaller footprint of the system can ease vehicle integration difficulties that would be encountered using other technology. Furthermore, the three-phase design can be made to operate with existing single-phase coupler design more easily and without intentional physical misalignment which would otherwise pose safety issues. This project developed ORNL’s WPT technology to satisfy the specifications and requirements for electric vehicle (EV) charging. The result of the project will be a prototype and reference design for a high-power wireless charging system—including magnetics, power electronics, and controls—serving as a baseline for product development.

33 ADVANCED PROPULSION SYSTEMS↗

DC Fast Charging Test Procedures

This report has been drafted as an initial effort to develop a standardized test procedure for DCFC for LD EVs. The proposed test procedures are designed to be time-efficient, aligned with EV discharge tests, and practical to implement, thereby minimizing the testing and computational efforts required by OEMs and testing authorities.

33 ADVANCED PROPULSION SYSTEMS↗

Ionization of multielectron atoms by fast charged particles.

Using plane waves to describe the incident and scattered particles, and screened hydrogenic and Coulomb functions to describe the atomic electrons before and after ejections, we have calculated the differential and total ionization cross sections of 11 atoms and one ion by electron impact, and ionization of helium by proton impact. The effective charges of the screened hydrogenic functions are fixed by the Hartree-Fock calculations. Calculations have been carried out for the atomic s, p, and d electrons. For low atomic numbers, we find reasonable agreement with the experimental data. For intermediate atomic numbers, we expect our results to overestimate the actual cross sections, since our choice of a unit charge for the Coulomb function of the ejected electrons will overestimate the atomic dipole potential strength, and in turn the high-energy cross sections. The advantage of the method presented here is that the ionization amplitude is given in analytic form. This may allow further analysis on this amplitude, and facilitates extension of the numerical integration for the cross section to high impact energies.

Omidvar, K.↗