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At least 145 records · Page 8

Magnetic optical activity in intense laser fields. I - Self-rotation and Verdet constant

The paper is concerned with the Faraday rotation and circular dichroism of dilute gases in longitudinal magnetic fields subject to strong radiation fields. In particular, magnetic fields are considered which produce Zeeman shifts much smaller than inverse collision times but which may be greater or smaller then the multipole relaxation times. Doppler broadening is considered, and explicit expressions are given for dipole transitions in a two-level system with arbitrary angular momentum for strong and weak magnetic fields. The same system is then studied as a function of the external magnetic-field strength with a fixed laser frequency. It is shown that this experimental arrangement, referred to as forward scattering, has certain advantages that are not present in the more usual magnetic rotation spectroscopy.

Giraud-Cotton, S.↗

Techniques and Tools for Estimating Ionospheric Effects in Interferometric and Polarimetric SAR Data

The InSAR Scientific Computing Environment (ISCE) is a flexible, extensible software tool designed for the end-to-end processing and analysis of synthetic aperture radar data. ISCE inherits the core of the ROI_PAC interferometric tool, but contains improvements at all levels of the radar processing chain, including a modular and extensible architecture, new focusing approach, better geocoding of the data, handling of multi-polarization data, radiometric calibration, and estimation and correction of ionospheric effects. In this paper we describe the characteristics of ISCE with emphasis on the ionospheric modules. To detect ionospheric anomalies, ISCE implements the Faraday rotation method using quadpolarimetric images, and the split-spectrum technique using interferometric single-, dual- and quad-polarimetric images. The ability to generate co-registered time series of quad-polarimetric images makes ISCE also an ideal tool to be used for polarimetric-interferometric radar applications.

Ionosphere↗

The Faraday Effect Tracker of Coronal and Heliospheric Structure (FETCH) Instrument

There continue to be open questions regarding the solar wind and coronal mass ejections (CMEs). For example: how do magnetic fields within CMEs and corotating/stream interaction regions (CIRs/SIRs) evolve in the inner heliosphere? What is the radially distributed magnetic profile of shock-driving CMEs? What is the internal magnetic structure of CMEs that cause magnetic storms? It is clear that these questions involve the magnetic configurations of solar wind and transient interplanetary plasma structures, for which we have limited knowledge. In order to better understand the origin of the magnetic field variability in steady-state structures and transient events, it is necessary to probe the magnetic field in Earth-directed structures/disturbances. This is the goal of the Multiview Observatory for Solar Terrestrial Science (MOST) mission (Gopalswamy et al., 2022). For MOST to answer the aforementioned questions, we propose the instrument concept of the Faraday Effect Tracker of Coronal and Heliospheric structures (FETCH), a simultaneous quad-line-of-sight polarization radio remote-sensing instrument. With FETCH, spacecraft radio beams passing through the Sun–Earth line offer the possibility of obtaining information of plasma conditions via analysis of radio propagation effects such as Faraday rotation and wave dispersion, which provide information of the magnetic field and total electron content (TEC). This is the goal of the FETCH instrument, one of ten instruments proposed to be hosted on the MOST mission. The MOST mission will provide an unprecedented opportunity to achieve NASA’s heliophysics science goal to “explore and characterize the physical processes in the space environment from the Sun” (Gopalswamy et al., 2022).

Solar corona↗

Kinetic studies of excited singlet oxygen atom O( 1 D) reactions with ethanol

In this work, themultichannel reaction of excited singlet oxygen atom with ethanol, O( 1 D) + C 2 H 5 OH (1), was studied in a photolysis flow reactor coupled with mid-infrared Faraday rotation spectroscopy (FRS) and UV-IR direct absorption spectroscopy (DAS) at 297 K with reactor pressures of 60, 120, and 150 Torr (bath He). The excited singlet oxygen atom was generated through the photolysis of O 3 at 266 nm. The photon flux and O( 1 D) concentrations were determined by in situ actinometry based on O 3 depletion. Temporal profiles of OH and H 2 O were monitored via DAS signals at ca. 3568.62 and 3568.29 cm –1 , while temporal profiles of HO 2 were measured via FRS signals at ca. 1396.90 cm –1 . The branching ratios of the target reaction (1) were determined by fitting temporal profiles to simulations from an in-house reaction mechanism. Two major reaction channels were identified as CH 3 CHOH + OH and CH 3 O + CH 2 OH, and their branching ratios were determined as 0.46 ± 0.12 and 0.42 ± 0.11, respectively. A specific HO 2 + RO 2 reaction between HO 2 and O 2 CH 2 CH 2 OH (β-RO 2 ) at the low-temperature range is estimated in this work as HO 2 + O 2 CH 2 CH 2 OH → products with a rate constant of 7 × 10 –12 cm 3 molecule –1 s –1 .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Global Magneto-ionic Medium Survey: A Faraday Depth Survey of the Northern Sky Covering 1280–1750 MHz

The Galactic interstellar medium hosts a significant magnetic field, which can be probed through the synchrotron emission produced from its interaction with relativistic electrons. Linearly polarized synchrotron emission is generated throughout the Galaxy and, at longer wavelengths, modified along nearly every path by Faraday rotation in the intervening magneto-ionic medium. Full characterization of the polarized emission requires wideband observations with many frequency channels. We have surveyed polarized radio emission from the Northern sky over the range 1280–1750 MHz, with channel width 236.8 kHz, using the John A. Galt Telescope (diameter 25.6 m) at the Dominion Radio Astrophysical Observatory, as part of the Global Magneto-Ionic Medium Survey. The survey covered 72% of the sky, decl. −30° to +87° at all R.A. The intensity scale was absolutely calibrated, based on the flux density and spectral index of Cygnus A. Polarization angle was calibrated using the extended polarized emission of the Fan Region. Data are presented as brightness temperatures with angular resolution 40′. Sensitivity in Stokes Q and U is 45 mK rms in a 1.18 MHz band. We have applied rotation measure synthesis to the data to obtain a Faraday depth cube of resolution 150 rad m{sup −2} and sensitivity 3 mK rms of polarized intensity. Features in Faraday depth up to a width of 110 rad m{sup −2} are represented. The maximum detectable Faraday depth is ±2 × 10{sup 4} rad m{sup −2}. The survey data are available at the Canadian Astronomy Data Centre.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Rotation measures of low-latitude extragalactic sources and the magnetoionic structure of the Galaxy

Faraday rotation measurements of 56 extragalactic sources obtained predominantly in the range 45-93 deg, /b/ less than 5 deg are reported. Within the longitude range sampled in the present study, RM(l) = 1600 sin (l0 - l) rad/sq m, with a null in RM occurring at 62 deg. Under the assumption of a uniform circular geometry for the magnetic field lines, it is argued that the magnetoionic medium must exist to a Galactocentric radius of about 25 kpc to produce the observed magnitudes of the RMs, where it is assumed that ne and /B/ equal their local values of 0.03/cu cm and 2.1 micro-G out to Rm. The medium must exist to an even greater radius if ne and/or /B/ decrease with R, as is likely. Comparison of extragalactic and pulsar RMs along nearly coincident lines of sight is consistent with at least one field reversal exterior to the radius of the solar orbit about the Galactic center.

Clegg, Andrew W.↗

Enhanced tuneable rotatory power in a rotating plasma

We report that the gyrotropic properties of a rotating magnetized plasma are derived analytically. Mechanical rotation leads to a new cutoff for wave propagation along the magnetic field, and polarization rotation above this cutoff is the sum of the classical magneto-optical Faraday effect and the mechanico-optical polarization drag. Exploiting the very large effective group index near the cutoff, we expose here that polarization drag can be 10 4 larger than Faraday rotation at GHz frequency. The rotation leads to weak absorption while allowing direct frequency control, demonstrating the unique potential of rotating plasmas for nonreciprocal elements. The very large rotation frequency of a dense non-neutral plasma could enable unprecedented gyrotropy in the THz regime.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Low-loss, high-isolation, fiber-optic isolator

A low-loss, high-isolation, fiber-optic isolator for use in single-mode fiber systems utilizes a Faraday rotator and two polarizers, one at each end angularly oriented from each other at the angle of rotation for isolation, and two aspheric lens connectors to couple optical fibers to the Faraday isolator to reduce forward loss to about 2.5 dB and improve isolation to greater than 70 dB.

Lutes, George F.↗

The Invariant Twist of Magnetic Fields in the Relativistic Jets of Active Galactic Nuclei

The origin of cosmic magnetic (B) fields remains an open question. It is generally believed that very weak primordial B fields are amplified by dynamo processes, but it appears unlikely that the amplification proceeds fast enough to account for the fields presently observed in galaxies and galaxy clusters. In an alternative scenario, cosmic B fields are generated near the inner edges of accretion disks in Active Galactic Nuclei (AGNs) by azimuthal electric currents due to the difference between the plasma electron and ion velocities that arises when the electrons are retarded by interactions with photons. While dynamo processes show no preference for the polarity of the (presumably random) seed field that they amplify, this alternative mechanism uniquely relates the polarity of the poloidal B field to the angular velocity of the accretion disk, resulting in a unique direction for the toroidal B field induced by disk rotation. Observations of the toroidal fields of 29 AGN jets revealed by parsec-scale Faraday rotation measurements show a clear asymmetry that is consistent with this model, with the probability that this asymmetry came about by chance being less than 1 %. This lends support to the hypothesis that the Universe is seeded by B fields that are generated in AGN via this mechanism

Contopoulos, Ioannis↗

Poynting Robertson Battery and the Chiral Magnetic Fields of AGN Jets

We propose that the magnetic fields in the accretion disks of active galactic nuclei (AGNs) are generated by azimuthal electric currents due to the difference between the plasma electron and ion velocities that arises when the electrons are retarded by interactions with the AGN photons (the Poynting Robertson battery). This process provides a unique relation between the polarity of the poloidal B field to the angular velocity Omega of the accretion disk (B is parallel to Omega), a relation absent in the more popular dynamo B-field generation. This then leads to a unique direction for the toroidal B field induced by disk rotation. Observations of the toroidal fields of 29 AGN jets revealed by parsec-scale Faraday rotation measurements show a clear asymmetry that is consistent with this model, with the probability that this asymmetry comes about by chance being approx.0.06 %. This lends support to the hypothesis that the universe is seeded by B fields that are generated in AGNs via this mechanism and subsequently injected into intergalactic space by the jet outflows.

Kazanas, Demosthenes↗

Synthesis and Single Crystals of Refractory Oxides of Lanthanides and Thorium

At the completion of this program, we can report that we developed a considerable degree of technical improvements in our ability to perform hydrothermal reactions at high temperatures and pressures. We can now routinely perform reactions at 700-750°C and 200 MPa. Currently we are in the process of exploiting this new technology synthesizing a range of exotic new materials investigating relatively poorly understood materials. Our initial efforts focused on the chemistry of rare earth oxides with tetravalent and pentavalent oxides. We recently published a study of the lanthanides with Nb 5+ and Ta 5+ ions, where we grew oxides such as RENdO 4 and RETaO 4 as high quality single crystals. These compounds were targeted as potential hosts for luminescent and scintillation materials, particularly given that they are among the densest oxide hosts and hence have good potential as absorbers for high energy radiation like X-rays and gamma rays. We also isolated a range of unusual new rare earth tantalates with very complex structures. indicating that the chemistry is very sensitive to conditions. We performed some fairly comprehensive examinations of the solid-state chemistry of rare earth ions with various tetravalent metal ions especially Si 4+ , Ge 4+ , Sn 4+ and Ti 4+ . Given the potential role of rare earth silicates in immobilizing radioactive waste elements in long-term storage, and the similarity of our hydrothermal fluids with known geological conditions, this chemistry continues to be relevant. We prepared an extensive series of new lanthanide germanates (e.g. RE 13 Ge 6 O 31 (OH), BaRE 10 (GeO 4 ) 4 O 8 ). and found that there is there is almost no overlap between the chemistry of the rare earth silicates. Stannic oxide (SnO 2 ) is much more refractory and requires higher temperatures and of mineralizer concentrations. One significant result is the growth of RE 2 Sn 2 O 7 pyrochlore single crystals. These are of interest because the rare earth stannate pyrochlores are known to display a wide range of magnetic frustration such as spin ice behavior. We grew high quality single crystals of rare earth germanate and stannate pyrochlores and this led to a collaboration with Professor Kate Ross at Colorado State. Preliminary measurements, indicate that the crystals contain no detectable defects or site disorder. Initial neutron diffraction on single crystals was performed at Oak Ridge, and more detailed experiments involving the Ross group are underway at both NIST and ORNL. This particular chemistry has turned out to be the most potentially significant work on this project and the collaborative effort with Prof. Ross is the topic of a DoE renewal project on quantum materials. Our initial foray into the hydrothermal chemistry of rare earth titanates has also been very promising and a range of cubic and polar ferroic phases of the light rare earths RE 2 Ti 2 O 7 (RE = La - Pr) in the P2 1 phase. We also discovered an interesting new phase Ce 2 Ti 4 O 11 that can have implications in heavy metal immobilization and storage. along with a series of new rare earth titanates (La 5 Ti 4 O 15 (OH) Sm 3 TiO 5 (OH) 3 and Lu 5 Ti 2 O 11 (OH) with exceptionally complex structures. One interesting sidelight has been high temperature hydrothermal chemistry terbium, including the growth of large crystals of TbO(OH). This is not a new compound but it is the first time it has been grown as large single crystals. The Tb atom density is almost as high as that in Tb 2 O 3 and has a very high Verdet constant (ca. 70), making it a very attractive candidate as a Faraday rotator. Unfortunately it is not in a cubic structure but he material is hard, stable, pure and inexpensive, so should still be an attractive Faraday oscillator. We recently received a patent on this material. We also synthesized K 2 Tb(Ge 2 O 7 ) containing stable octahedral Tb 4+ ions, which appears to be the first example of a well-characterized Tb 4+ complex. Given that Tb 4+ has been proposed as a benign surrogate for more treacherous tetravalent ions such as Cf 4+ and Bk 4+ , we think that Tb 4+ silicates can be a particularly useful study for actinide immobilization and related work. We also began reaction studies with rare earths and both ReO 2 and RuO 2 . These resulted in large single crystals of species like RE 5 Ru 2 O 12 , RE 4 Re 2 O 11 , REReO 4 and RE 2 ReO 5 . Several of these samples have already been sent to ORNL for magnetic and neutron diffraction studies.

36 MATERIALS SCIENCE↗

Determination of travelling ionospheric disturbances

A total of 35 days of Faraday rotation data was obtained from the ATS-6 radio beacon experiment operating with the closely spaced network of Elbert, Table Mountain, and Fort Morgan. The 140-MHz Faraday bandpass data are uncorrelated in the transmission range from 8 to 45 minutes. There are distinct, well correlated, and time-displaced maxima and minima that allow the calculation of the speed and direction of horizontal motions of plane fronts of disturbances in the ionosphere. For some selected events, velocities between 88 and 278 m/sec were obtained.

Degenhardt, W.↗

Polarization-Rotating Sensors Connected To Optical Fibers

Proposed optoelectronic sensor system includes polarization-rotating sensing elements interrogated by polarized light transmitted to and from sensing elements along optical fibers. Polarization of light altered by combinations of inherent birefringence, stress-induced birefrigence, and Faraday rotation. Advantages include: light weight, fast response, immunity to electromagnetic interference at radio and lower frequencies, and no need to supply electrical power to sensing elements.

Frazer, Robert E.↗