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At least 145 records · Page 8

Dose and linear energy transfer spectral measurements for the supersonic transport program

The purpose of the package, called the high altitude radiation instrumentation system (HARIS), is to measure the radiation hazard to supersonic transport passengers from solar and galactic cosmic rays. The HARIS includes gaseous linear energy transfer spectrometer, a tissue equivalent ionization chamber, and a geiger meuller tube. The HARIS is flown on RB-57F aircraft at 60,000 feet. Data from the HARIS are reduced to give rad and rem dose rates measured by the package during the flights. Results presented include ambient data obtained on background flights, altitude comparison data, and solar flare data.

Philbrick, R. B.↗

Energy-transfer mechanisms in the CH3F-SF6 optically pumped laser

The power of an optically pumped CH3F laser operating on the 496-micron line has been doubled with the addition of SF6 without any corresponding increase in pump absorption. It is suggested that a near-resonant energy transfer between CH3F and SF6 followed by SF6 deactivation is the mechanism responsible for the enhancement.

Lawandy, N. M.↗

Intermode energy transfer in vibrationally excited O3

The laser-excited fluorescence method has been employed to determine the rate constants for vibrational relaxation of the O3 (010), O3 (100) and O3 (001) levels at 298 K. The fluorescence observations from the O3 (010) level provide direct measurements of the rate for intermode vibrational energy transfer from the coupled nu sub 1 and nu sub 3 modes to the nu sub 2 mode. The slowness of this process indicates the likelihood that the nu sub 1 and/or nu sub 3 modes (rather than the nu sub 2 mode) play a predominant role in the laser-enhanced reaction between vibrationally excited O3 and NO at 298 K.

Hui, K.-K.↗

Hybrid Reduced Order Model for N2-N2 Interactions for Application to Dissociation and Energy Transfer Processes

Recent work in the aerothermodynamics community has focused on the development of reduced-order models for thermo-chemical non-equilibrium which avoid the restrictive assumptions of multi-temperature models and the prohibitive cost associated with State-to-State (StS) models. In the present work, this is accomplished by lumping energy states together and assuming groups of states are roughly in equilibrium. As a result, the non-equilibrium behavior of a gas can be captured at a reduced computational cost from a full StS simulation. In this work, we present a hybrid grouping model for studying energy transfer and dissociation in a mixture of nitrogen molecules due to N2-N2 reactions. This is accomplished by making use of a grouping strategy informed by data from the N2-N StS kinetic data. However, due to the massive computational cost associated with constructing StS data for the N2-N2 system, the kinetic data for the hybrid grouping model are calculated using the quasi-classical trajectory (QCT) method by sampling states for trajectory within the groups. This general framework is called the Maximum-Entropy Quasi-Classical Trajectory (ME-QCT) method. The primary challenge associated with this method is that rates for reverse grouped reactions cannot be obtained through detailed balance at a group level, due to the variation of group internal temperatures. To construct the full model for N2-N2 grouped kinetics using the ME-QCT method, detailed balance is invoked at the microscopic level, allowing for the calculation of the full kinetic data from QCT. Results will be presented using the full ME-QCT model for the N2-N2 system in an isothermal and isochoric reactor simulation. In addition, simple CFD test cases for a one-dimensional standing shock and for a quasi-one-dimensional nozzle will be used for demonstration of the ME-QCT method. This method allows for the calculation of non-equilibrium behavior for the N2-N2 system without the prohibitive cost of a full StS simulation. Moreover, it enables the construction of a unified model for the dissociating and recombining non-equilibrium flows.

nonequilibrium modeling↗

Temperature dependence of electronic energy transfer and quenching in copolymer films of styrene and 2-(2'-hydroxy-5'-vinylphenyl)-2H-benzotriazole

Quenching of the emission of both the polystyrene monomer and the excimer for a series of varying composition copolymer films of styrene and 2-(2'-hydroxy-5'-vinylphenyl)-2H-benzotriazole is reported. The preponderance of quenching for both the monomer and excimer emissions is due to interception of the migrating excitation at the quencher site, although additional quenching results via long-range dipole-dipole energy transfer from the monomer and excimer traps to the quencher trap. The quenching of the monomer fluorescence and phosphorescence and that of the excimer fluorescence were found to be temperature independent over the ranges 14-58 and 191-296 K, respectively. Most significantly, it is concluded that the energy migration process is temperature independent over the range 14-296 K.

O'Connor, Donald B.↗

Electronic energy transfer and quenching in copolymers of styrene and 2-(2-prime-hydroxy -5-prime-vinylphenyl)-2H-benzotriazole Photochemical processes in polymeric systems. X

Intensity and lifetime quenching of the polystyrene monomer and excimer fluorescence emission by a pendant quencher have been studied in the solid state and in solution for a series of copolymers of styrene and 2-(2-prime-hydroxy-5-prime-vinylphenyl)-2H-benzotriazole. Two mechanisms of quenching have been identified. One involves interception of the migrating monomer excitation by the quencher, and the other involves a single-step Foerster energy-transfer process from the excimer traps to a quencher. The relative efficiencies of these two quenching mechanisms in the solid state and in solution have been compared and related to the efficiency of electronic energy migration. An estimate of the excimer trap concentration in solid polystyrene is also reported.

Coulter, D. R.↗

Energy transfer in NH3-He collisions

The paper presents a new electron gas intermolecular NH3-He potential determined by the Hartree-Fock results of Davis, Boggs, and Mehrotra (1979) with semiempirical long-range induction and dispersion terms. The resulting potential agrees with beam scattering and pressure broadening measurements; it was also found that the quadrupole induced dipole interaction is not as effective as the short range anisotropy. It was concluded that discrepancies remain in the quantitative description of energy transfer in the NH3-He system; discrepancies result from improper consideration of the dependence of cross-sections on degenerate magnetic quantum levels in the experimental investigation.

Green, S.↗

NO(gamma) emission by energy transfer from NO(+) (a) to NO

Ultraviolet emission produced by photoexcitation of NO at 50-80 nm is observed using synchrotron radiation as a light source. The emission increases at an excitation wavelength corresponding to the ionization potential of the NO(+) (a) state. The emission spectra at several excitation wavelengths are dispersed and identified to be mainly the NO(gamma) band. The dependence of emission intensity on gas pressure and delay time indicates that the emission is produced by a secondary reaction, which is attributed to the energy transfer from NO(+) (a) to NO.

Ma, Guang↗

A digital computer simulation and study of a direct-energy-transfer power-conditioning system

An investigation of the behavior of the power-conditioning system as a whole is a necessity to ensure the integrity of the aggregate system in the case of space applications. An approach for conducting such an investigation is considered. A description is given of the application of a general digital analog simulator program to the study of an aggregate power-conditioning system which is being developed for use on the International Ultraviolet Explorer spacecraft. The function of the direct energy transfer system studied involves a coupling of a solar array through a main distribution bus to the spacecraft electrical loads.

Burns, W. W., III↗

Energy transfer by radiation in non-grey atomic gases in isothermal and non-isothermal slabs

A multiband model for the absorption coefficient of atomic hydrogen-helium plasmas is constructed which includes continuum and line contributions. Emission from 28 stronger lines of 106 that have been screened is considered, of which 21 are from hydrogen and 7 belong to helium, with reabsorption due to line-line, line-continuum overlap accurately accounted for. The model is utilized in the computation of intensities and fluxes from shock-heated slabs of 85% H2-15% He mixtures for slab thicknesses from 1 to 30 cm, temperature from 10,000 to 20,000 K, and for different densities. In conjunction with the multiband model, simple numerical schemes have been devised which provide a quick and comprehensive way of computing radiative energy transfer in nonisothermal and nongrey gases.

Poon, P. T. Y.↗

Cellular effects of individual high-linear energy transfer particles and implications for tissue response at low doses

The energy deposition patterns produced by the radiation environment in space can be quite different from those in conventional radiation environments. Furthermore, conventional radiation biological experiments, using randomly distributed particle tracks, cannot access some variables which may be important in determining the health effects of irradiation. Controlled microbeam irradiation provides the means to investigate the effects and unique energy deposition patterns and cell environment for a variety of end points.

Non-NASA Center↗

RADIATIVE ENERGY TRANSFER ON ENTRY INTO MARS AND VENUSQUARTERLY REPORT NO. 4

The emissivity of carbon dioxide in the 2.7 4 µ region has been measured at temperatures from 2000°K to 3500°K, for optical densities less than 5 atm-cm. The high temperatures were obtained by passing a shock wave through the test gas. A total gas pressure of one atm was maintained by varying the carbon dioxide concentration in an inert gas. Emissivities obtained from absorption and emission measurements are in agreement. results are compared to an approximate method for calculating emissivity, The which considers the molecular population concentrated in a single band whose center is temperature dependent. A comparison with previous results suggests that this single band model will overestimate the peak and underestimate the width of the observed values. The observed and calculated emissivities are in agreement if the intensities of the (n 1 +1,n 2 , n 3 + 1 → n 1 , n 2 , n 3 ) and (n 1 ,n 2 +2, n 3 + 1 → n 1 , n 2 , n 3 ) transitions are assumed proportional to (n 1 +1) (n 3 +1) and (n 2 +1)(n 3 +1)/2. The use of this single band model which was originally intended to provide a rough prediction of emissivity, indicates that the use of the appropriate terms of the electric dipole expansion is satisfactory for the (n 1 +1,n 2 , n 3 + 1 → n 1 , n 2 , n 3 ) transition, but is not for (n 1 ,n 2 +2, n 3 + 1 → n 1 , n 2 , n 3 ) transition.

radiative heat transfer↗

Surprisal analysis of rotational-translational energy transfer - Non-linear versus linear rotors

Surprisal versus energy gap analyses of state-to-state cross sections are presented for a number of linear rigid rotors excited by collisions with atoms for H2-H, H2-He, HCl-He, HCl-Ar, CO-He, CS-H2 (j=0) OCS-H2 (j=0) and HN2(+)-He, where (j=0) indicates that the hydrogen molecule was constrained to remain in its lowest level. Different systems exhibit wide variations in the slope of the surprisal plot and in certain cases, enough to indicate that the energy gap may not be the static dynamical constraint. Similar analyses are presented for nonlinear rotors excited by atoms for H2CO-He and H2O-He. For these, the data show a great deal of scatter, indicating that the reduced energy gap is probably not the appropriate independent variable.

Green, S.↗

Rates of mass, momentum, and energy transfer at the magnetopause

Empirical estimates of the global rates of transfer of solar wind mass, tangential momentum, and energy at the Earth's magnetopause are presented for comparison against model estimates based on the four principal mechanisms that have been proposed to explain such transfer. The comparisons, although not quite conclusive, strongly favor a model that incorporates some combination of direct magnetic connection and anomalous cross field diffusion. An additional global constraint, the rate at which magnetic flux is cycled through the magnetospheric convection system, strongly suggests that direct magnetic connection plays a significant if not dominant role in the solar wind/magnetosphere interaction.

Hill, T. W.↗

Joining of correct and incorrect DNA ends at double-strand breaks produced by high-linear energy transfer radiation in human fibroblasts

DNA double-strand breaks (DSBs) were measured within a 3.2-Mbp NotI fragment on chromosome 21 of cells of a normal human fibroblast cell line. Correct rejoining of DSBs was followed by measuring reconstitution of the original-size NotI fragment, and this was compared to total rejoining as measured by a conventional pulsed-field gel electrophoresis technique (FAR assay). After 80 Gy of particle irradiations with LETs in the range of 7-150 keV/microm, it was found that the repair kinetics was generally slower after irradiation with high-LET particles compared to X irradiation and that a larger proportion of the breaks remained unrepaired after 24 h. On the other hand, the misrejoining frequency as measured by the difference between correct and total rejoining after 24 h did not change with LET, but was approximately the same for all radiations at this dose, equal to 25-30% of the initial breaks. This result is discussed in relation to formation of chromosomal aberrations, deletion mutations and other biological end points.

NASA Discipline Radiation Health↗

Solar-pumped electronic-to-vibrational energy transfer lasers

The possibility of using solar-pumped lasers as solar energy converters is examined. The absorbing media considered are halogens or halogen compounds, which are dissociated to yield excited atoms, which then hand over energy to a molecular lasing medium. Estimates of the temperature effects for a Br2-CO2-He system with He as the cooling gas are given. High temperatures can cause the lower energy levels of the CO2 laser transition to be filled. The inverted populations are calculated and lasing should be possible. However, the efficiency is less than 0.001. Examination of other halogen-molecular lasant combinations (where the rate coefficients are known) indicate efficiencies in all cases of less than 0.005.

Harries, W. L.↗

Estimating three-demensional energy transfer in isotropic turbulence

To obtain an estimate of the spectral transfer function that indicates the rate of decay of energy, an x-wire probe was set at a fixed position, and two single wire probes were set at a number of locations in the same plane perpendicular to the mean flow in the wind tunnel. The locations of the single wire probes are determined by pseudo-random numbers (Monte Carlo). Second order spectra and cross spectra are estimated. The assumption of isotropy relative to second order spectra is examined. Third order spectra are also estimated corresponding to the positions specified. A Monte Carlo Fourier transformation of the downstream bispectra corresponding to integration across the plane perpendicular to the flow is carried out assuming isotropy. Further integration is carried out over spherical energy shells.

Li, K. S.↗