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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS1975

Plasma polymerization of an ethylene-nitrogen gas mixture

A procedure has been developed whereby nitrogen can be incorporated into an organic film from an ethylene-nitrogen gas mixture using an internal electrode capacitively coupled radio frequency reactor. The presence of nitrogen has been shown directly by infrared transmittance spectra and electron spectroscopic chemical analysis data, and further indirect evidence was provided by dielectric measurements and by the reverse osmosis properties of the film. Preparation of a nitrogen containing film did not require vapor from an organic nitrogen containing liquid monomer. Some control over the bonding and stoichiometry of the polymer film was provided by the added degree of freedom of the nitrogen partial pressure in the gas mixture. This new parameter strongly affected the dielectric properties of the plasma polymerized film and could affect the reverse osmosis behavior.

Hudis, M.↗
NASA NTRS1979

A study of the mechanism of thigmomorphogenesis in plants, with special reference to the role of ethylene and its significance to research with plants in space

Because of the paucity of data concerning thigmomorphogenesis, all aspects of the phenomenon were under study, although the role of ethylene mediation was central to the approach. Although this report must necessarily point to a specific time in ongoing research, several aspects of the study reached at least temporary stopping points and were therefore written and submitted for publication. These are identified. Other papers which are currently in preparation, but not yet submitted, are also identified. The phenomenon of thigmomorphogenesis is divided into the sensory function, transduction step(s) and the response function.

Jaffe, M. J.↗
NASA NTRS1981

Ethylene in IRC +10216

Ethylene has been detected in the circumstellar gas surrounding the supergiant star IRC +10216. Two lines of the nu sub 7 vibration-rotation band near 28 THz (949/cm) have been seen in absorption at an expansion velocity of 14 km/sec relative to the central star. The line intensities indicate a rotational temperature of T greater than 400 K and a radial C2H4 column density of 10 to the 16th to 10 to the 17th per sq cm.

Betz, A. L.↗
NASA NTRS1982

A photochemical study of the kinetics of the reactions of NH2 with phosphine, ethylene, and acetylene using flash photolysis-laser induced fluorescence

The photochemistry of the reactions of NH2 was investigated in an attempt to explain the existence of an abundance of ammonia in the Jovian atmosphere. The production of ammonia reservoirs from the coupling of ammonia with other atmospheric constituents was considered. The rate constants for the reactions of NH2 radicals with phosphine, acetylene, and ethylene were measured. Flash photolysis was used for the production of NH2 radicals and laser induced fluorescence was employed for radical detection. It was determined that the rates of the reactions were too slow to be significant as a source of ammonia reservoirs in the Jovian atmosphere.

Bosco, S. R.↗
NASA NTRS1983

Applications of ethylene vinyl acetate as an encapsulation material for terrestrial photovoltaic modules

Terrestrial photovoltaic modules must undergo substantial reductions in cost in order to become economically attractive as practical devices for large scale production of electricity. Part of the cost reductions must be realized by the encapsulation materials that are used to package, protect, and support the solar cells, electrical interconnects, and other ancillary components. As many of the encapsulation materials are polymeric, cost reductions necessitate the use of low cost polymers. The performance and status of ethylene vinyl acetate, a low cost polymer that is being investigated as an encapsulation material for terrestrial photovoltaic modules, are described.

Cuddihy, E. F.↗
NASA NTRS1984

Temperature and pressure dependence of the absolute rate constant for the reactions of NH2 radicals with acetylene and ethylene

The absolute rate constants for the reaction between the NH2 free radical and acetylene and ethylene is measured experimentally using a flash photolysis technique. The constant is considered to be a function of temperature and pressure. At each temperature level of the experiment, the observed pseudo-first-order rate constants were assumed to be independent of flash intensity. The results of the experiment indicate that the bimolecular rate constant for the NH2 + C2H2 reaction increases with pressure at 373 K and 459 K but not at lower temperatures. Results near the pressure limit conform to an Arrhenius expression of 1.11 (+ or -) 0.36 x 10 to the -13th over the temperature range from 241 to 459 K. For the reaction NH2 + C2H4, a smaller rate of increase in the bimolecular rate constant was observed over the temperature range 250-465 K. The implications of these results for current theoretical models of NH2 + C2H2 (or H4) reactions in the atmospheres of Jupiter and Saturn are discussed.

Bosco, S. R.↗
NASA NTRS1986

Heat Bonding of Irradiated Ethylene Vinyl Acetate

Reliable method now available for joining parts of this difficult-tobond material. Heating fixture encircles ethylene vinyl acetate multiplesocket part, providing heat to it and to tubes inserted in it. Fixtures specially designed to match parts to be bonded. Tube-and-socket bonds made with this technique subjected to tensile tests. Bond strengths of 50 percent that of base material obtained consistently.

Slack, D. H.↗
NASA NTRS1985

Stress-relaxation and stress-strain behavior of poly(ethylene-co-vinylacetate) at varying crosslink density

The stress-relaxation modulus of an unfilled ethylene vinyl acetate polymer at three different degrees of crosslinking was measured at 15 temperatures over a temperature span of about 160 C. At each temperature, the time response was measured for at least three decades of time. From these data it was possible to construct a master curve for each degree of crosslinking. The time-temperature shift factors, alpha(T), were found to be related to temperature by the relation log alpha(T) = -A(T - 273), where the parameter A has an average value of 0.234 for the three materials.

Fedors, R. F.↗
NASA NTRS1987

New lines of ethylene and a search for methylene in IRC + 10216

Seven new lines in the 10 micron nu7 band of C2H4 have been detected in the highly obscured carbon star IRC + 10216. The line intensities cannot be well described by a single rotational temperature, in contrast to the lines of CH4 and SiH4 previously observed in this source. There are at least three interpretations: the line intensities are variable on a time scale of months and years, C2H4 lines are formed over a region less homogeneous than that of CH4 and SiH4, or ethylene is somewhat nonthermally excited. Regardless, the line intensities indicate an average rotational temperature of 100 K and a column density of about 4 x 10 to the 15th/sq cm, which is approximately 2 x 10 to the -5th times the CO abundance. A search was also made for infrared transitions of CH2, the methylene radical. No lines were detected, but the observational limits are compared with the abundance and radial distribution for CH2 predicted by a model invoking the photodissociation of CH4.

Goldhaber, D. M.↗
NASA NTRS1992

Vacuum Ultraviolet (VUV) radiation-induced degradation of Fluorinated Ethylene Propylene (FEP) Teflon aboard the Long Duration Exposure Facility (LDEF)

Examination of fluorinated ethylene propylene (FEP) copolymer specimens recovered from the Long Duration Exposure Facility (LDEF) provides evidence for degradation attributed to extended solar vacuum ultraviolet (VUV) irradiation. Scanning electron microscope (SEM) images of sheared FEP film edges reveal the presence of a highly embrittled layer on the exposed surface of specimens obtained from the trailing edge of the LDEF. Similar images obtained for leading edge and control FEP films do not exhibit evidence for such an embrittled layer. Laboratory VUV irradiation of FEP films is found to produce a damage layer similar to that witnessed in the LDEF trailing edge films. Spectroscopic analyses of irradiated films provide data to advance a photochemical mechanism for degradation.

Brinza, David E.↗
NASA NTRS1992

Vacuum ultraviolet radiation/atomic oxygen synergism in fluorinated ethylene propylene Teflon erosion

A micrographic investigation is reported of samples of the fluorinated ethylene propylene (FEP) Teflon thermal-blanketing materials recovered from the Long-Duration Exposure Facility (LDEF) satellite. The samples are taken from the trailing edge and row 8 which correspond to exposures to vacuum UV (VUV) and VUV + atomic O, respectively. Data are taken from SEM and IR-spectra observations, and the LDEF leading-edge FEP shows a high degree of erosion, roughening, and sharp peaks angled in the direction of the flow of atomic O. The trailing edge sample influenced primarily by VUV shows a hard brittle layer and some cracked mosaic patterns. Comparisons to a reference sample suggest that the brittle layer is related to exposure to VUV and is removed by atomic-O impingement. Polymers that are stable to VUV radiation appear to be more stable in terms of atomic oxygen.

Stiegman, A. E.↗
NASA NTRS1981

Interpreting plant responses to clinostating. I - Mechanical stresses and ethylene

The possibility that the clinostat mechanical stresses (leaf flopping) induces ethylene production and, thus, the development of epinasty was tested by stressing vertical plants by constant gentle horizontal or vertical shaking or by a quick back-and-forth rotation (twisting). Clinostat leaf flopping was closely approximated by turning plants so that their stems were horizontal, rotating them quickly about the stem axis, and returning them to the vertical, with the treatment repeated every four minutes. It was found that horizontal and vertical shaking, twisting, intermittent horizontal rotating, and gentle hand shaking failed to induce epinasties that approached those observed on the slow clinostat. Minor epinasties were generated by vigorous hand-shaking (120 sec/day) and by daily application of Ag(+). Reducing leaf displacements by inverting plants did not significantly reduce the minor epinasty generated by vigorous hand-shaking.

Salisbury, Frank B.↗
NASA NTRS1991

An investigation of the degradation of Fluorinated Ethylene Propylene (FEP) copolymer thermal blanketing materials aboard LDEF in the laboratory

Samples of fluorinated ethylene propylene copolymer thermal blanketing material, recovered from the Long Duration Exposure Facility (LDEF), were investigated to determine the nature and the extent of degradation due to exposure to the low-Earth-orbit environment. Samples recovered from the ram-facing direction of LDEF, which received vacuum-ultraviolet (VUV) radiation and atomic-oxygen impingement, and samples from the trailing edge, which received almost exclusively VUV exposure, were investigated by scanning electron microscopy and atomic force microscopy. The most significant result of this investigation was found on samples that received only VUV exposure. These samples possessed a hard, embrittled surface layer that was absent from the atomic-oxygen exposed sample and from unexposed control samples. This surface layer is believed to be responsible for the 'synergistic' effect between VUV and atomic oxygen. Overall, the investigation revealed dramatically different morphologies for the two samples. The sample receiving both atomic-oxygen and VUV exposure was deeply eroded and had a characteristic 'rolling' surface morphology, while the sample that received only VUV exposure showed mild erosion and a surface morphology characterized by sharp high-frequency peaks. The morphologies observed in the LDEF samples, including the embrittled surface layer, were successfully duplicated in the laboratory.

Stiegman, A. E.↗
NASA NTRS1992

Plasma copolymerization of ethylene and tetrafluoroethylene

An IR and XPS study of the low-pressure, radiofrequency, glow-discharge plasma copolymerization of ethylene (ET) and tetrafluoroethylene (TFE) is presented. The potential for creating Tefzel- or Teflon-like coatings on various polymeric substrates for use in advanced life support systems is examined.

Golub, Morton A.↗
NASA NTRS1994

Observations of Methane and Ethylene Diffusion Flames Stabilized Around a Blowing Porous Sphere Under Microgravity Conditions

This paper presents the experimental and theoretical results for expanding methane and ethylene diffusion flames in microgravity. A small porous sphere made from a low-density and low-heat-capacity insulating material was used to uniformly supply fuel at a constant rate to the expanding diffusion flame. A theoretical model which includes soot and gas radiation is formulated but only the problem pertaining to the transient expansion of the flame is solved by assuming constant pressure infinitely fast one-step ideal gas reaction and unity Lewis number. This is a first step toward quantifying the effect of soot and gas radiation on these flames. The theoretically calculated expansion rate is in good agreement with the experimental results. Both experimental and theoretical results show that as the flame radius increases, the flame expansion process becomes diffusion controlled and the flame radius grows as gamma t. Theoretical calculations also show that for a constant fuel mass injection rate a quasi-steady state is developed in the region surrounded by the flame and the mass flow rate at any location inside this region equals the mass injection rate.

Atreya, Arvind↗
NASA NTRS1994

Quasiglobal reaction model for ethylene combustion

The objective of this study is to develop a reduced mechanism for ethylene oxidation. The authors are interested in a model with a minimum number of species and reactions that still models the chemistry with reasonable accuracy for the expected combustor conditions. The model will be validated by comparing the results to those calculated with a detailed kinetic model that has been validated against the experimental data.

Singh, D. J.↗