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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
DOE OSTI2014

Impulsive and long duration high-energy gamma-ray emission from the very bright 2012 March 7 solar flares

The Fermi Large Area Telescope (LAT) detected gamma-rays up to 4 GeV from two bright X-class solar flares on 2012 March 7, showing both an impulsive and temporally extended emission phases. The gamma-rays appear to originate from the same active region as the X-rays associated with these flares. The >100 MeV gamma-ray flux decreases monotonically during the first hour (impulsive phase) followed by a slower decrease for the next 20 hr. A power law with a high-energy exponential cutoff can adequately describe the photon spectrum. Assuming that the gamma rays result from the decay of pions produced by accelerated protons and ions with a power-law spectrum, we find that the index of that spectrum is ∼3, with minor variations during the impulsive phase. During the extended phase the photon spectrum softens monotonically, requiring the proton index varying from ∼4 to >5. The >30 MeV proton flux observed by the GOES satellites also shows a flux decrease and spectral softening, but with a harder spectrum (index ∼2-3). Based on these observations, we explore the relative merits of prompt or continuous acceleration scenarios, hadronic or leptonic emission processes, and acceleration at the solar corona or by the fast coronal mass ejections. We conclude that the most likely scenario is continuous acceleration of protons in the solar corona that penetrate the lower solar atmosphere and produce pions that decay into gamma rays. However, acceleration in the downstream of the shock cannot be definitely ruled out.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

Low-energy electro- and photo-emission spectroscopy of GaN materials and devices

In hot-electron semiconductor devices, carrier transport extends over a wide range of conduction states, which often includes multiple satellite valleys. Electrical measurements can hardly give access to the transport processes over such a wide range without resorting to models and simulations. An alternative experimental approach however exists which is based on low-energy electron spectroscopy and provides, in a number of cases, very direct and selective information on hot-electron transport mechanisms. Recent results obtained in GaN crystals and devices by electron emission spectroscopy are discussed. Using near-band-gap photoemission, the energy position of the first satellite valley in wurtzite GaN is directly determined. By electro-emission spectroscopy, we show that the measurement of the electron spectrum emitted from a GaN p-n junction and InGaN/GaN light-emitting diodes (LEDs) under electrical injection of carriers provides a direct observation of transport processes in these devices. In particular, at high injected current density, high-energy features appear in the electro-emission spectrum of the LEDs showing that Auger electrons are being generated in the active region. These measurements allow us identifying the microscopic mechanism responsible for droop which represents a major hurdle for widespread adoption of solid-state lighting.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2026

Tendencies of Soil Microbial NO Emissions During HI‐SCALE as Predicted by a Nitrification/Denitrification Scheme

Many atmospheric chemical processes, including the formation of secondary organic aerosol (SOA), are strongly modulated by the reactions of NO and NO 2 (NO x ). Though NO x is controlled by anthropogenic emissions near urban areas, in rural areas soil microbes can be a significant contribution to NO emission globally. The relative rates of emissions of different nitrogen-containing species (e.g., NO, N 2 O, HONO, and N 2 ) are strong functions of soil properties such as temperature, moisture content, pH, and soil carbon and nitrogen pools. However, typical large-scale biogeochemical models either express these emissions simplistically, or not at all. Here we investigate the potential impact of soil NO emissions on atmospheric chemistry and SOA formation over regional and monthly time scales, specifically the 2016 spring and summer Intensive Observational Periods (IOPs) of the Holistic Interactions of Shallow Clouds, Aerosols and Land Ecosystems (HI-SCALE) field campaign. We implement the soil NO nitrification/denitrification parameterization of Rasool et al. (2019) into the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem), supplemented by a 1-km soil moisture analysis. We then simulate both IOPs over the U.S. Great Plains, evaluating against ground stations and flight data. We show that soil NO emissions can account for a large fraction of total NO x and locally increase O 3 concentrations by up to 25%, while alleviating negative biases of gases and aerosols toward observations. Soil moisture and temperature changes between IOP1 and IOP2 lead to overall differences in emissions, but with large regional variability due to heterogeneous surface characteristics.

Atmoshpheric Chemistry↗
DOE OSTI2015

Annual Fossil-Fuel CO2 Emissions: Mass of Emissions Gridded by One Degree Latitude by One Degree Longitude (NDP-058.2015)

The 2015 version of this database presents a time series recording 1° latitude by 1° longitude CO2 emissions in units of million metric tons of carbon per year from anthropogenic sources for 1751-2011. Detailed geographic information on CO2 emissions can be critical in understanding the pattern of the atmospheric and biospheric response to these emissions. Global, regional, and national annual estimates for 1751 through 2011 were published earlier (Boden et al. 2015). Those national, annual CO2 emission estimates were based on statistics about fossil-fuel burning, cement manufacturing and gas flaring in oil fields as well as energy production, consumption, and trade data, using the methods of Marland and Rotty (1984). The national annual estimates were combined with gridded 1° data on political units and 1984 human populations to create the new gridded CO2 emission time series. The same population distribution was used for each of the years as proxy for the emission distribution within each country. The implied assumption for that procedure was that per capita energy use and fuel mixes are uniform over a political unit. The consequence of this first-order procedure is that the spatial changes observed over time are solely due to changes in national energy consumption and nation-based fuel mix. Increases in fossil-fuel CO2 emissions over time are apparent for most areas.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Spinning Dust Emission from Circumstellar Disks and Its Role In Excess Microwave Emission

Electric dipole emission from rapidly spinning polycyclic aromatic hydrocarbons (PAHs) is widely believed to be an origin of anomalous microwave emission (AME), but recently it has encountered a setback owing to the noncorrelation of AME with PAH abundance seen in a full-sky analysis. Microwave observations for specific regions with well-constrained PAH features would be crucial to test the spinning dust hypothesis. In this paper, we present physical modeling of microwave emission from spinning PAHs from protoplanetary disks (PPDs) around Herbig Ae/Be stars and T Tauri stars where PAH features are well observed. Guided by the presence of 10 μm silicate features in some PPDs, we also model microwave emission from spinning nanosilicates. Thermal emission from big dust grains is computed using the Monte Carlo radiative transfer code (radmc-3d). Our numerical results reflect that microwave emission from either spinning PAHs or spinning nanosilicates dominates over thermal dust at frequencies ν < 60 GHz, even in the presence of significant grain growth. Lastly, we attempt to fit millimeter–centimeter observational data with both thermal dust and spinning dust for several disks around Herbig Ae/Be stars that exhibit PAH features and find that spinning dust can successfully reproduce the observed excess microwave emission (EME). Future radio observations with ngVLA, SKA, and ALMA Band 1 would be valuable for elucidating the origin of EME and potentially open a new window for probing nanoparticles in circumstellar disks.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Probing the Diffuse Ly α Emission on Cosmological Scales: Ly α Emission Intensity Mapping Using the Complete SDSS-IV eBOSS

Based on Sloan Digital Sky Survey Data Release 16, we have detected the large-scale structure of Lyα emission in the universe at redshifts z = 2–3.5 by cross-correlating quasar positions and Lyα emission imprinted in the residual spectra of luminous red galaxies. We apply an analytical model to fit the corresponding Lyα surface brightness profile and multipoles of the redshift-space quasar–Lyα emission cross-correlation function. The model suggests an average cosmic Lyα luminosity density of $6.6^{+3.3}_{-3.1}$ x 10 40 erg s -1 cMpc -3 , a ~2σ detection with a median value about 8–9 times those estimated from deep narrowband surveys of Lyα emitters at similar redshifts. Although the low signal-to-noise ratio prevents us from a significant detection of the Lyα forest–Lyα emission cross-correlation, the measurement is consistent with the prediction of our best-fit model from quasar–Lyα emission cross-correlation within current uncertainties. We rule out the scenario where the Lyα photons mainly originate from quasars. We find that Lyα emission from star-forming galaxies, including contributions from that concentrated around the galaxy centers and that in diffuse Lyα-emitting halos, is able to explain the bulk of the Lyα luminosity density inferred from our measurements. Ongoing and future surveys can further improve the measurements and advance our understanding of the cosmic Lyα emission field.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1995

Gamma-ray emission from globular clusters. Shock high energy emission from the Be-Star/Pulsar System PSR 1259-63. Echoes in x-ray novae

This grant covers work on the Compton phase 3 investigation, 'Shock High Energy Emission from the Be- Star/Pulsar System PSR 1259-63' and cycle 4 investigations 'Diffuse Gamma-Ray Emission at High Latitudes' and 'Echoes in X-Ray Novae'. Work under the investigation 'Diffuse Gamma-Ray Emission at High Latitudes' has lead to the publication of a paper (attached), describing gamma-ray emissivity variations in the northern galactic hemisphere. Using archival EGRET data, we have found a large irregular region of enhanced gamma-ray emissivity at energies greater 100 MeV. This is the first observation of local structure in the gamma-ray emissivity. Work under the investigation 'Echoes in X-Ray Novae' is proceeding with analysis of data from OSSE from the transient source GRO J1655-40. The outburst of this source last fall triggered this Target of Opportunity investigation. Preliminary spectral analysis shows emission out to 600 keV and a pure power low spectrum with no evidence of an exponential cutoff. Work is complete on the analysis of BATSE data from the Be-Star/Pulsar Sustem PSR 1259-63.

Kaaret, Philip↗
NASA NTRS2017

Emissions Relationships Among Western Forest Fire Plumes: I. Emission Factors Free from Mixing Errors

Previous studies of emission factors from biomass burning are prone to largeerrors since they ignore the interplay of mixing and varying pre-fire backgroundCO2 levels. Such complications severely affected our studies of 446 forest fireplume samples measured in the Western US by the science teams of NASAsSEAC4RS and ARCTAS airborne missions. Consequently we propose a MixedEffects Regression Emission Technique (MERET) to check techniques like theNormalized Emission Ratio Method (NERM), where use of sequentialobservations cannot disentangle emissions and mixing. We also evaluate asimpler consensus technique. All techniques relate emissions to fuel burnedusing C burn = Δ Ctot added to the fire plume, where ≈ Ctot (CO2 + CO). Mixed-effectsregression can estimate pre-fire background values of Ctot (indexed byobservation j) simultaneously with emissions factors indexed by individual species i, δέλτα-xi (Cburn )i,j., MERET and consensus require more than twoemissions indicators. Our studies excluded samples where exogenous CO orCH4 might have been fed into a fire plume, mimicking emission.We sought to let the data on 13 gases and particulate properties suggest clustersof variables and plume types, using non-negative matrix factorization (NMF).While samples were mixtures, the NMF unmixing suggested purer burn types.Particulate properties (bscat, babs, SSA, AÅE) and gas-phase emissions were interrelated.Finally, we sought a simple categorization useful for modeling ozone productionin plumes. Two kinds of fires produced high ozone: those with large fuel nitrogenas evidenced by remnant CH3CN in the plumes, and also those from veryintense large burns. Fire types with optimal ratios of delta-NOydelta-HCHO associate with the highest additional ozone per unit Cburn, Perhaps theseplumes exhibit limited NOx binding to reactive organics. Perhaps these plumesexhibit limited NOx binding to reactive organics.

plumes↗
DOE OSTI2016

Energy and emissions saving potential of additive manufacturing: the case of lightweight aircraft components

Additive manufacturing (AM) holds great potential for improving materials efficiency, reducing life-cycle impacts, and enabling greater engineering functionality compared to conventional manufacturing (CM), and AM has been increasingly adopted by aircraft component manufacturers for lightweight, cost-effective designs. This study estimates the net changes in life-cycle primary energy and greenhouse gas emissions associated with AM technologies for lightweight metallic aircraft components through the year 2050, to shed light on the environmental benefits of a shift from CM to AM processes in the U.S. aircraft industry. A systems modeling framework is presented, with integrates engineering criteria, life-cycle environmental data, aircraft fleet stock and fuel use models under different AM adoption scenarios. Estimated fleet-wide life-cycle primary energy savings at most reach 70-173 million GJ/year in 2050, with cumulative savings of 1.2–2.8 billion GJ. Associated cumulative GHG emission reductions were estimated at 92.1–215.0 million metric tons. In addition, thousands of tons of aluminum, titanium and nickel alloys could be potentially saved per year in 2050. The results indicate a significant role of AM technologies in helping society meet its long-term energy use and GHG emissions reduction goals, and highlight barriers and opportunities for AM adoption for the aircraft industry.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2014

Doping-tunable thermal emission from plasmon polaritons in semiconductor epsilon-near-zero thin films

We utilize the unique dispersion properties of leaky plasmon polaritons in epsilon-near-zero (ENZ) thin films to demonstrate thermal radiation control. Owing to its highly flat dispersion above the light line, a thermally excited leaky wave at the ENZ frequency out-couples into free space without any scattering structures, resulting in a narrowband, wide-angle, p-polarized thermal emission spectrum. We demonstrate this idea by measuring angle- and polarization-resolved thermal emission spectra from a single layer of unpatterned, doped semiconductors with deep-subwavelength film thickness (d/λ{sub 0} ∼ 6×10{sup −3}, where d is the film thickness and λ{sub 0} is the free space wavelength). We show that this semiconductor ENZ film effectively works as a leaky wave thermal radiation antenna, which generates far-field radiation from a thermally excited mode. The use of semiconductors makes the radiation frequency highly tunable by controlling doping densities and also facilitates device integration with other components. Therefore, this leaky plasmon polariton emission from semiconductor ENZ films provides an avenue for on-chip control of thermal radiation.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

Outstanding field emission properties of wet-processed titanium dioxide coated carbon nanotube based field emission devices

Field emission devices using a wet-processed composite cathode of carbon nanotube films coated with titanium dioxide exhibit outstanding field emission characteristics, including ultralow turn on field of 0.383 V μm{sup −1} and threshold field of 0.657 V μm{sup −1} corresponding with a very high field enhancement factor of 20 000, exceptional current stability, and excellent emission uniformity. The improved field emission properties are attributed to the enhanced edge effect simultaneously with the reduced screening effect, and the lowered work function of the composite cathode. In addition, the highly stable electron emission is found due to the presence of titanium dioxide nanoparticles on the carbon nanotubes, which prohibits the cathode from the influence of ions and free radical created in the emission process as well as residual oxygen gas in the device. The high-performance solution-processed composite cathode demonstrates great potential application in vacuum electronic devices.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2016

Construction of a quartz spherical analyzer: application to high-resolution analysis of the Ni K α emission spectrum

The construction and characterization of a focusing X-ray spherical analyzer based on α-quartz 4$\bar{4}$04 are presented. The performance of the analyzer was demonstrated by applying it to a high-resolution X-ray spectroscopy study of the K α 1,2 emission spectrum of Ni. An analytical representation based on physical grounds was assumed to model the shape of the X-ray emission lines. Satellite structures assigned to 3 d spectator hole transitions were resolved and determined as well as their relative contribution to the emission spectrum. The present results on 1 s -1 3 d -1 shake probabilities support a recently proposed calculation framework based on a multi-configuration atomic model.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

POLARIZATION OF MAGNETIC DIPOLE EMISSION AND SPINNING DUST EMISSION FROM MAGNETIC NANOPARTICLES

Magnetic dipole emission (MDE) from interstellar magnetic nanoparticles is potentially an important Galactic foreground in the microwave frequencies, and its polarization level may pose great challenges for achieving reliable measurements of cosmic microwave background B-mode signal. To obtain realistic predictions for the polarization of MDE, we first compute the degree of alignment of big silicate grains incorporated with magnetic inclusions. We find that thermally rotating big grains with magnetic inclusions are weakly aligned and can achieve alignment saturation when the magnetic alignment rate becomes much faster than the rotational damping rate. We then compute the degree of alignment for free-flying magnetic nanoparticles, taking into account various interaction processes of grains with the ambient gas and radiation field, including neutral collisions, ion collisions, and infrared emission. We find that the rotational damping by infrared emission can significantly decrease the degree of alignment of small particles from the saturation level, whereas the excitation by ion collisions can enhance the alignment of ultrasmall particles. Using the computed degrees of alignment, we predict the polarization level of MDE from free-flying magnetic nanoparticles to be rather low. Such a polarization level is within the upper limits measured for anomalous microwave emission (AME), which indicates that MDE from free-flying iron particles may not be ruled out as a source of AME. We also quantify rotational emission from free-flying iron nanoparticles with permanent magnetic moments and find that its emissivity is about one order of magnitude lower than that from spinning polycyclic aromatic hydrocarbons.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

Evaluation of fuel-borne sodium effects on a DOC-DPF-SCR heavy-duty engine emission control system: Simulation of full-useful life

Here we report that for renewable fuels to displace petroleum, they must be compatible with emissions control devices. Pure biodiesel contains up to 5 ppm Na + K and 5 ppm Ca + Mg metals, which have the potential to degrade diesel emissions control systems. This study aims to address these concerns, identify deactivation mechanisms, and determine if a lower limit is needed. Accelerated aging of a production exhaust system was conducted on an engine test stand over 1001 h using 20% biodiesel blended into ultra-low sulfur diesel (B20) doped with 14 ppm Na. This Na level is equivalent to exposure to Na at the uppermost expected B100 value in a B20 blend for the system full-useful life. During the study, NOx emissions exceeded the engine certification limit of 0.33 g/bhp-hr before the 435,000-mile requirement. Replacing aged diesel oxidation catalyst (DOC), diesel particulate filter (DPF), and selective catalytic reduction (SCR) devices with new degreened parts showed that each device contributed equally to the NOx increase. Following this systems-based evaluation, a detailed investigation of the individual components was completed. Na was determined to have minimal impact on DOC activity. For this system, it is estimated that B20-Na resulted in 50% more ash into the DPF. However, the Na did not diffuse into the cordierite DPF nor degrade its mechanical properties. The SCR degradation was found to be caused by a small amount of precious group metals (PGM) contamination that increased NH3 oxidation, and lowered NOx reduction. Therefore, we determined that the primary effect of Na in this study is through increased ash in the DPF rather than deactivation of the catalytic activity.

42 ENGINEERING↗
DOE OSTI2015

Optical emission diagnostics of plasmas in chemical vapor deposition of single-crystal diamond

A key aspect of single crystal diamond growth via microwave plasma chemical vapor deposition is in-process control of the local plasma–substrate environment, that is, plasma gas phase concentrations of activated species at the plasma boundary layer near the substrate surface. Emission spectra of the plasma relative to the diamond substrate inside the microwave plasma reactor chamber have been analyzed via optical emission spectroscopy. The spectra of radical species such as CH, C{sub 2}, and H (Balmer series) important for diamond growth were identified and analyzed. The emission intensities of these electronically excited species were found to be more dependent on operating pressure than on microwave power. Plasma gas temperatures were calculated from measurements of the C{sub 2} Swan band (d{sup 3}Π → a{sup 3}Π transition) system. The plasma gas temperature ranges from 2800 to 3400 K depending on the spatial location of the plasma ball, microwave power and operating pressure. Addition of Ar into CH{sub 4}+H{sub 2} plasma input gas mixture has little influence on the Hα, Hβ, and Hγ intensities and single-crystal diamond growth rates.

36 MATERIALS SCIENCE↗