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Results for “ELECTRIC DIPOLE”

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At least 145 records · Page 8

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NASA NTRS1983

Electron impact excitation from a 1 Delta g state of molecular oxygen

First measurements of electron impact excitation on the O2 a delta-one sub g metastable state to a higher bound state, pi-one sub u, is reported. The data were taken at an incident electron energy of 500 eV and scattering angles of 0 deg to 15 deg. A superelastic electron scattering experiment was performed on the pure oxygen target gas in order to establish the composition of the discharged oxygen and to confirm the existence of delta-one sub g molecules in the interaction region. The electron-impact energy loss spectrum obtained is shown. The electronic assignment of the upper state which produces the vibrational structure was determined to be pi-one sub u by examining the potential energy curves of O2 and applying the electric dipole selection rules. The relative line intensities were obtained and used to determine the Morse potential for the pi-one sub u state.

Khakoo, M. A.↗

NASA NTRS1983

CO 1-0 band isotopic lines as intensity standards

Fundamental band vibration-rotational line intensities are reported for the (C-12)(O-16), (C-13)(O-16), and (C-12)(O-18) molecules. The intensities were computed using numerically obtained matrix elements of a recently, determined electric dipole moment function. New intensity measurements for some of these lines obtained via high-resolution Fourier spectra are also reported. The overall consistency (approximately 2.2 percent) between calculations, which are based on recent experimental determinations of CO 1-0 band intensities, not including our own, those of the authors, and independent experimental results of the authors suggests that the lines of the fundamental band of CO can be used as absolute intensity standards.

Chackerian, C., Jr.↗

NASA NTRS1982

A theory of electrophoresis of emulsion drops in aqueous two-phase polymer systems

An electrophoresis study has been carried out in an emulsion formed from an electrically neutral aqueous mixture of dextran and polyethylene glycol equilibrated at sufficient concentrations in the presence of electrolytes. Electrophoresis of a drop of one phase suspended in the other is observed, and the direction of the drop's motion is reversed when the disperse phase and the continuous phase are interchanged. In the presence of sulfate, phosphate, or citrate ions, an electrostatic potential difference of the order of a few mV exists between the two phases. The potential implied by the direction of the electrophoretic motion is opposite to the Donnan potential observed between the two phases. The mobility of an emulsion drop increases with the drop radius and depends on ion concentration. These results are explained in terms of a model postulating an electric dipole layer associated with a mixture of oriented polymer molecules at the surface of a drop, with a potential difference between the interiors of the two phases resulting from the unequal ion distribution.

Levine, S.↗

NASA NTRS1984

Theory of collision-induced translation-rotation spectra: H2-He

An adiabatic quantal theory of spectral line shapes in collision-induced absorption and emission is presented which incorporates the induced translation-rotation and translation-vibration spectra. The generalization to account for the anisotropy of the scattering potential is given. Calculations are carried out of the collision-induced absorption spectra of He in collisions with H2 with ab initio electric dipole functions and realistic potentials. The anisotropy of the interaction potential is small and is not included in the calculations. The predicted spectra are in satisfactory agreement with experimental data though some deviations occur which may be significant. The rotational line shapes have exponential wings and are not Lorentzian. The connection between the quantal and classical theories is written out explicitly for the isotropic overlap induction.

Birnbaum, G.↗

NASA NTRS1984

The far-infrared laser magnetic resonance spectrum of the SiH radical and determination of ground state parameters

The far-infrared laser magnetic resonance spectrum of the SiH radical in the v = O level of its X2Pi state has been recorded. The signals are rather weak. The molecules were generated in the reaction between fluorine atoms and SiH4. Rotational transitions have been detected in both 2Pi1/2 and 2Pi3/2 spin components but no fine structure transitions between the spin components were observed. Proton hyperfine splittings were resolved on some lines. The measurements have been analyzed, subjected to a least-squares fit using an effective Hamiltonian, and the appropriate molecular parameters determined. The weakness of the spectrum and the failure of attempts to power saturate favorable lines are both consistent with a small value for the electric dipole moment for SiH.

Brown, J. M.↗

NASA NTRS1985

Plasma-depleted holes, waves, and energized particles from high-altitude explosive plasma perturbation experiments

The results of high-explosive shaped charge experiments King Crab and Bubble Machines I and II, intended to perturb the ambient plasma and magnetic field, are discussed. The instrumentation was flown above an altitude of 460 km in March 1980 and 1981 and comprised a single-axis dipole electric field detector, a fixed bias cylindrical Langmuir probe, a three-axis attitude magnetometer, and curved plated energetic ion and electron electrostatic analyzer. Among the effects of the explosion which are detailed, emphasis is placed on the creation of an ion-depleted dark hole during the Bubble Machine II experiment; mechanisms explaining the phenomenon are outlined. The auroral intensity ion beams with energies of up to 6.8 keV, observed following the explosion in the field-aligned ion electrostatic analyzer, are suggested to represent an existing ion conic population pitch angle scattered by the released barium into the view of the detector.

Wescott, E. M.↗

NASA NTRS1985

DE-1 measurements of AKR wave directions

In addition to its wave rotation sense, the direction of auroral kilometric radiation (AKR) can also be measured with the plasma wave instrument on Dynamics Explorer 1, from the relative phase of the signals received by its orthogonal electric dipole antennas. By this method, which differs in principle from the previous spin-null method for measuring wave directions, it has been found possible to pinpoint the AKR source by triangulation, using measurements from different points along the DE-1 orbit. The resulting apparent source, in one instance, seemed to occupy a well-defined auroral-zone invariant magnetic latitude and showed the expected increase of altitude with decreasing frequency. An analysis of the method also confirmed the validity of the previous rotation sense measurements.

Calvert, W.↗

NASA NTRS1986

Natural ELF noise evaluation for TSS emissions detection on the Earth's surface. The electric field component approach

The preliminary estimate of the local noise structure in the proximity of a receiver is essential to establishing the detectability of a given signal in presence of such noise. The possibility of detecting the Electric Field Component of the background noise by means of electric dipoles horizontally placed on the sea bed in shallow water is outlined, in order to find its spectral and statistical characteristics for the definition of the optimal receiving system.

Tacconi, G.↗

NASA NTRS1985

Radiative relaxation of molecular vibration of the nitric oxide molecule as a possible source of the infrared Shuttle glow

A model calculation to predict infrared Shuttle flow due to the radiative relaxation of vibration of the NO molecule is presented. Space Shuttles hit atmospheric NO molecules at a very high speed and excite vibrational and rotational motions up to the temperature of 54,000 K. With the electric dipole radiation of delta v = 1, 2, 3, and particularly 4 (v is the vibrational quantum number), the excited NO molecules emit infrared radiation before they collide with other molecules. The total radiation power is estimated to be 170 A micro-W, where A is the cross-section area of the Shuttle in sq m if no adsorption of the NO molecule takes place on the Shuttle surface. The intensity of each infrared line is calculated as a function of time, including all vibrational states up to v = 35.

Mizushima, M.↗

NASA NTRS1986

Macroscopic T nonconservation - Prospects for a new experiment

Breakdown of time-reversal invariance can be detected in macroscopic samples as a magnetic alignment along an electric field. It is shown that both fundamental and practical limits to the detection of this effect in paramagnets correspond to measurement of electron electric dipole moments down to d(e) of about 10 to the -28th e cm on 50-g quantities of EuS near its Curie point; this compares to the current limit of d(e) not greater than 10 to the -24th e cm. Strategies for still greater sensitivity are outlined.

Bialek, W.↗

NASA NTRS1986

Theoretical transition probabilities for the OH Meinel system

An electric dipole moment function (EDMF) for the X 2Pi ground state of OH, based on the complete active-space self-consistent field plus a multireference singles-plus-double excitation configuration-interaction procedure (using an extended Slater basis) is reported. Two theoretical EDMFS are considered: the MCSCF (7)-SCEP EDMF of Werner et al., (1983) and a previously unpublished EDMF based on the MCSCF multireference CI(SD) procedure using a large Slater basis. The theoretical treatment follows that of Mies (1974), except that the Hill and Van Vleck (1928) approximation to intermediate coupling is used. This approximation is shown to be accurate to better than 5 percent for the six principal branches of the OH Meinel system.

Langhoff, S. R.↗

NASA NTRS1986

Theoretical study of the X1Sigma(+) states of the alkali hydrides NaH-CsH

By means of near Hartree-Fock quality Slater basis sets, and the incorporation of electron correlation through the coupled-pair formalism, theoretical potentials are obtained for the X1Sigma(+) states of NaH, KH, and RbH. Electric dipole moment functions are given for NaH-RbH, as well as vibrationally averaged dipole moments, Einstein coefficients, and radiative lifetimes for the first 10 vibrational levels; an extensive study is made of the computational requirements for an accurate permanent dipole moment of KH.

Langhoff, Stephen R.↗

NASA NTRS1986

Oscillator strengths for Ar VII, Ca IX and Fe XV

The excitation energies and oscillator strengths are calculated for electric-dipole-allowed and intercombination transitions between 3s2 1S, 3s3p(1,3)P0, 3p2 3P, 1D, 1S and 3s3d(1,3)D states in Ar VII, Ca IX, and Fe XV ions of the magnesium sequence. These states are represented by the fairly large configuration-interaction expansions. The calculations have been carried out in both LS and intermediate coupling schemes. The relativistic corrections have been included through the Breit-Pauli Hamiltonian. The results are compared with previous theoretical calculations and with measurements.

Tayal, S. S.↗

NASA NTRS1987

Atomic parameters for carbon-like S XI

Calculations of radiative rates and collision strengths of S XI for 46 levels of the six configurations 2s2 2p2, 2s 2p3, 2p4, 2s2 2p 3s, 2s2 2p 3p, and 2s2 2p 3d are presented concurrently so that all the atomic data are self-consistent. Collision strengths are calculated at an incident electron energy of 25 Rydbergs above the ground level 2p2(3P0) in order to include collisional excitation to the highest level considered. Good agreement with previous results is found, and it is suggested that the given electric dipole rates are accurate to within at least 20 percent.

Bhatia, A. K.↗

NASA NTRS1987

Diatomic molecules in the solar infrared spectrum from ATMOS-SL 3 high resolution observations

The ATMOS Fourier Transform Spectrometer has observed, for the first time, the solar infrared spectrum, from 2 to 16 microns, free of any telluric absorption. A very large number of molecular lines are present on these high quality spectra: vibration-rotation lines of CO (Delta-v = 1 and 2; including the isotopic species C-13, O-18 and O-17), CH, NH, OH and pure rotation lines of OH. The analysis of these lines will allow to derive accurate values for the solar abundances of C, N and O and the isotopic ratios C-13/C-12, O-18/O-16, and O-17/O-16, to test the photospheric model from high to deep layers, to test the electric dipole moment functions of the different molecules and to derive much better molecular constants for CH.

Grevesse, Nicolas↗

NASA NTRS1988

Mapping of auroral kilometric radiation sources to the aurora

Auroral kilometric radiation (AKR) and optical auroral emissions are observed simultaneously using plasma wave instrumentation and auroral imaging photometers carried on the DE 1 spacecraft. The DE 1 plasma wave instrument measures the relative phase of signals from orthogonal electric dipole antennas, and from these measurements, apparent source directions can be determined with a high degree of precision. Wave data are analyzed for several strong AKR events, and source directions are determined for several emission frequencies. By assuming that the AKR originates at cyclotron resonant altitudes, a candidate source field line is identified. When the selected source field line is traced down to auroral altitudes on the concurrent DE 1 auroral image, a striking correspondece between the AKR source field line and localized auroral features is produced. The magnetic mapping study provides strong evidence that AKR sources occur on field lines associated with discrete auroral arcs, and it provides confirmation that AKR is generated near the electron cyclotron frequency.

Huff, R. L.↗

NASA NTRS1988

Nonadiabatic corrections to the van der Waals potential

Closed-form expressions are derived for the finite-mass nonadiabatic corrections to the van der Waals potential in the electric-dipole approximations in terms of London-analog two-center atomic spectral sums. The nonadiabatic corrections to all orders at threshold energy and also those with first-order energy dependence are given.

Au, C. K.↗

NASA NTRS1988

The determination of absolute ro-vibrational intensities for radical diatomic molecules

Ro-vibrational transition intensities of radical and/or chemically reactive molecular species are difficult to determine. A number of methods which might be used to provide information on matrix elements of the electric dipole moment function and the construction of the dipole moment function from the information these methods provide are discussed. The derived dipole moment function represents an optimum choice and allows a calculation (with estimable errors) of the line intensities for a large number of ro-vibrational transitions.

Chackerian, C., Jr.↗