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At least 145 records · Page 8

Diffusion of Redox-Sensitive Elements in Basalt at Different Oxygen Fugacities

The terrestrial planets and moons of our solar system have differentiated over a range of oxygen fugacity conditions. Basalts formed from magmas on the Earth cover a range of more oxidized states (from approximately IW (iron wustite) plus 2 to approximately FMQ (fayalite-magnetite-quartz) plus 3) than crustal rocks from Mars (IW to approximately IW plus 3), and basalts from the Moon are more reduced than both, ranging from IW to IW minus 2. The small body Vesta differentiated around IW minus 4. Characterization of redox sensitive elements' diffusivities will offer insight into behavior of these elements as a function of f (fugacity of) O2 for these planetary bodies. Here, we report a systematic study of the diffusion of redox-sensitive elements in basaltic melts with varying oxygen fugacities (fO2) for trace elements, V, Nb, W, Mo, La, Ce, Pr, Sm, Eu, Gd, Ta, and W. Since fO2 is an intensive variable that is different for the reservoirs of various planets and moons in our solar system, it is important to characterize how changes in redox states will affect diffusion. We conducted experiments in a piston cylinder device at 1300 degrees Centigrade and 1 gigapascal, at the University of Rochester and NASA Johnson Space Center. We buffered some experiments at Ru-RuO2 (FMQ plus 6.00), and conducted other experiments within either a graphite or Mo capsule, which corresponds to fO2s of either FMQ minus1.2, or FMQ minus 3.00, respectively. Characterizing the diffusivities of redox sensitive elements at different fO2s is important because some elements, like Eu, have varying valence states, such as Eu (sup 2 plus) and Eu (sup 3 plus). Differences in charge and ion radii may lead to differences in diffusivities within silicate melts. This could, lead to formation of a Eu anomaly by diffusion, the magnitude of which may be controlled by the fO2. Characterization of trace element diffusion is also important in understanding trace element fractionation. We found, during the course of our investigation, that not only did the diffusivities of the redox sensitive elements change with fO2, but that the diffusivities of all other analyzed elements also changed. This indicates that not only do changes in valence influence trace elements diffusivities but that the structure of melt may have changed with varying oxygen fugacity, probably due to changes in the speciation of the major element Fe.

Szumila, I.↗

Influence of strong Coulomb coupling on diffusion in atmospheric pressure plasmas

Ion diffusion in atmospheric pressure plasmas is examined and particular attention is paid to the fact that ion–ion interactions can be influenced by strong Coulomb coupling. Three regimes are identified. At low ionization fractions (x i ≲ 10 —6 ), standard weakly correlated ion-neutral interactions set the diffusion rate. At moderate ionization fractions (10 —6 ≲ x i ≲ 10 —2 ) there is a transition from ion-neutral to ion–ion collisions setting the diffusion rate. In this regime, the effect of strong Coulomb coupling in ion–ion collisions is accounted for by applying the mean force kinetic theory. Since both ion-neutral and ion–ion interactions contribute a comparable amount to the total diffusion rate, models (such as particle-in-cell or fluid) must account for both contributions. At high ionization fractions (x i ≳ 10 —2 ), strongly correlated ion–ion collisions dominate and the plasma is heated substantially by a disorder-induced heating (DIH) process associated with strong correlations. The temperature increase due to DIH strongly influences the ion diffusion rate. This effect becomes even more important, and occurs at lower ionization fractions, as the pressure increases above atmospheric pressure. In addition to ion diffusion, DIH affects the neutral gas temperature, therefore influencing the neutral diffusion rate. Model predictions are tested using molecular dynamics simulations, which included a Monte Carlo collision routine to simulate the effect of ion-neutral collisions at the lowest ionization fractions. The model and simulations show good agreement over a broad range of ionization fractions. Importantly, the results provide a model for ion diffusion, on a wide range of ionization fractions and pressures, solely considering the elastic contribution to the diffusion coefficient—as an illustration of how strong Coulomb coupling influences diffusion processes in general.

fast neutral gas heating↗

Effects of Flame Structure and Hydrodynamics on Soot Particle Inception and Flame Extinction in Diffusion Flames

This paper summarizes recent studies of the effects of stoichiometric mixture fraction (structure) and hydrodynamics on soot particle inception and flame extinction in diffusion flames. Microgravity experiments are uniquely suited for these studies because, unlike normal gravity experiments, they allow structural and hydrodynamic effects to be independently studied. As part of this recent flight definition program, microgravity studies have been performed in the 2.2 second drop tower. Normal gravity counterflow studies also have been employed and analytical and numerical models have been developed. A goal of this program is to develop sufficient understanding of the effects of flame structure that flames can be "designed" to specifications - consequently, the program name Flame Design. In other words, if a soot-free, strong, low temperature flame is required, can one produce such a flame by designing its structure? Certainly, as in any design, there will be constraints imposed by the properties of the available "materials." For hydrocarbon combustion, the base materials are fuel and air. Additives could be considered, but for this work only fuel, oxygen and nitrogen are considered. Also, the structure of these flames is "designed" by varying the stoichiometric mixture fraction. Following this line of reasoning, the studies described are aimed at developing the understanding of flame structure that is needed to allow for optimum design.

Axelbaum, R. L.↗

Ebullition dominates methane fluxes from the water surface across different ecohydrological patches in a temperate freshwater marsh at the end of the growing season

Measurements of the spatial heterogeneity of methane fluxes in wetlands are critical to better understand and predict methane emissions at the ecosystem scale. However, the within-wetland spatial heterogeneity of fluxes is rarely assessed. Here, we use a spatially balanced rapid chamber-based survey of methane at different ecohydrological patches within a temperate freshwater marsh. We measured fluxes exclusively from the water surface without including vegetation. We further used the data from chamber measurements to partition diffusive and ebullitive fluxes. Three ecohydrological patches were distinguishable in the marsh, defined by the type and presence/absence of vegetation. Here, these patches were emergent vegetation, floating-leaved, and open water. Net methane fluxes from the water surface (diffusion plus ebullition) in emergent vegetation patches were larger than in the floating-leaved vegetation and open water patches (p < 0.05). Diffusive fluxes, representing a sizable smaller fraction of net fluxes, were larger in vegetated than in unvegetated patches (p < 0.05), while ebullitive fluxes mirrored the magnitude and differences observed in the net fluxes.Moreover, pooled net and ebullitive fluxes across patches (but not diffusive fluxes) were negatively correlated with water levels, the primary variable affecting patch distribution. Altogether, our results indicate that the differences among ecohydrological patches are driven by ebullition, ultimately highlighting challenges faced by scientists and practitioners in the field and modelers seeking to improve the predictability and resolution of wetland biogeochemical models.

54 ENVIRONMENTAL SCIENCES↗

Diffusion and phase change characterization by mass spectrometry

The high temperature diffusion of trace elements in metals and alloys was investigated. Measurements were made by high sensitivity mass spectrometry in which individual atoms were detected, and quantitative data was obtained for zircaloy-2, 304 stainless steel, and tantalum. Additionally, a mass spectrometer was also an analytical tool for determining an allotropic phase change for stainless steel at 955 C, and a phase transition region between 772 C and 1072 C existing for zircaloy-2. Diffusion rates were measured in thin (0.001" (0.0025 cm) and 0.0005" (0.0013 cm)) ribbons which were designed as high temperature thermal ion sources, with the alkali metals as naturally occurring impurities. In the temperature and pressure regime where diffusion measurements were made, the solute atoms evaporated from the ribbon filaments when the impurities diffused to the surface, with a fraction of these impurity atoms ionized according to the Langmuir-Saha relation. The techniques developed can be applied to many other alloys important to space vehicles and supersonic transports; and, with appropriate modifications, to the diffusion of impurities in composites.

Koslin, M. E.↗

Impact of mid- Z gas fill on dynamics and performance of shock-driven implosions at the OMEGA laser

Shock-driven implosions with 100% deuterium (D 2 ) gas fill compared to implosions with 50:50 nitrogen-deuterium (N 2 ⁢D 2 ) gas fill have been performed at the OMEGA laser facility to test the impact of the added mid-Ζ fill gas on implosion performance. Ion temperature (Τ ion ) as inferred from the width of measured DD-neutron spectra is seen to be 34%±6% higher for the N 2⁢ D 2 implosions than for the D 2 -only case, while the DD-neutron yield from the D 2 -only implosion is 7.2±0.5 times higher than from the N 2⁢ D 2 gas fill. The T ion enhancement for N 2 ⁢D 2 is observed in spite of the higher Z, which might be expected to lead to higher radiative loss, and higher shock strength for the D 2 -only versus N 2 ⁢D 2 implosions due to lower mass, and is understood in terms of increased shock heating of N compared to D, heat transfer from N to D prior to burn, and limited amount of ion-electron-equilibration-mediated additional radiative loss due to the added higher-Z material. Further, this picture is supported by interspecies equilibration timescales for these implosions, constrained by experimental observables. The one-dimensional (1D) kinetic Vlasov-Fokker-Planck code ifp and the radiation hydrodynamic simulation codes hyades (1D) and xrage [1D, two-dimensional (2D)] are brought to bear to understand the observed yield ratio. Comparing measurements and simulations, the yield loss in the N 2 ⁢D 2 implosions relative to the pure D 2 -fill implosion is determined to result from the reduced amount of D 2 in the fill (fourfold effect on yield) combined with a lower fraction of the D 2 fuel being hot enough to burn in the N 2 ⁢D 2 case. The experimental yield and T ion ratio observations are relatively well matched by the kinetic simulations, which suggest interspecies diffusion is responsible for the lower fraction of hot D 2 in the N 2 ⁢D 2 relative to the D 2 -only case. The simulated absolute yields are higher than measured; a comparison of 1D versus 2D XRAGE simulations suggest that this can be explained by dimensional effects. The hydrodynamic simulations suggest that radiative losses primarily impact the implosion edges, with ion-electron equilibration times being too long in the implosion cores. The observations of increased T ion and limited additional yield loss (on top of the fourfold expected from the difference in D content) for the N 2 ⁢D 2 versus D 2 -only fill suggest it is feasible to develop the platform for studying CNO-cycle-relevant nuclear reactions in a plasma environment.

47 OTHER INSTRUMENTATION↗

Effects of thermophoresis on high-pressure binary-species boundary layers with uniform and non-uniform compositions

Direct numerical simulations of high-pressure binary-species temporal boundary layers are performed to investigate the flow physics for three situations: (1) uniform and equal composition, (2) uniform but unequal compositions and (3) non-uniform composition. Both colder- and hotter-wall situations compared with the free stream are simulated. The working fluid is a nitrogen/methane mixture. The analysis is performed at a case-specific self-similar state. Even when the initial composition is uniform, the methane mean mass fraction decreases near the colder wall, whereas it increases near the hotter wall and the mass fraction fluctuates in the entire boundary layer. Analysis of the species-mass diffusion balance and flow structures reveal that both mass-fraction variation and fluctuations are induced by the Soret effect. When the initial composition is non-uniform and the wall is colder, the methane mean mass fraction monotonically increases from the wall akin to its initial profile. However, when the wall is hotter the mean mass fraction decreases near the wall in contrast to its initial profile, a fact traced through the species-mass diffusion balance to the Soret effect being large and enriching methane near the wall. In contrast, the direction of the Soret flux is opposite for the colder wall, thus keeping the methane concentration small. Although the initial magnitude of the difference between the wall and free-stream temperature is the same in all cases, the situation is not symmetric between colder- and hotter-wall cases; the flow structure exhibits much smaller scales when the wall is hotter than when the wall is colder.

Mechanics↗

Effects of Hydrodynamics of Soot Formation in Laminar Opposed-Jet Diffusion Flames

Effects of flow (hydrodynamic properties on the presence of soot in hydrocarbon-fueled laminar opposed-jet diffusion flames were studied experimentally at atmospheric pressure, emphasizing effects of velocities normal to the Rom sheet. These velocities were varied for conditions corresponding to combustion in air by transferring nitrogen from the oxidizer stream to the fuel stream which increases the stoichiometric mixture fraction of the flame and causes the stagnation plane of the flow to shift toward the fuel-rich side of the flame sheet. Fuels considered included acetylene, ethylene, ethane, propylene, propane, and 1-3 butadiene. Present measurements consisted of the critical strain rates for the flames to contain soot (the soot extinction limit) and for the flames to extinguish (the flame extinction limit) It was found that increasing the stoichiometric mixture fraction causes a progressive reduction of the critical strain rates for both flame and soot extinction; however, their ratio increases, and even becomes unbounded in most instances to yield a permanently-blue-flame regime. The results suggest that soot formation in nonpremixed flames can be controlled by varying velocities normal to the flame sheet. Nevertheless, definitive conclusions along these lines require evaluation of effects of corresponding variations of fuel and oxygen concentrations on soot formation when velocities normal to the flame sheet are changed by varying stoichiometric mixture fractions for laminar opposed-jet diffusion flames.

Lin, K.-C.↗

A new concept for exhaust diffusers of altitude test cells

A new exhaust diffuser concept for jet engine altitude test cells which greatly reduces operating power and cost requirements for exhausters is discussed. The concept utilizes the capture duct as an efficient diffuser only, while evacuating the secondary air via a separate path using an auxiliary suction system. Implementation of the concept would reduce the peak exhauster power requirement during a TF-30 altitude test by 48 percent and the overall exhaust power cost of the test program by 41 percent. The design accommodates various engine sizes and can achieve optimum pressure recovery performance during both A/B and IRP modes of engine operation. The pressure recovery performance of the proposed exhaust diffusers does not deteriorate with increasing cooling air fraction. The disadvantages of the proposed scheme are: increased mechanical complexity of the extended variable geometry diffuser duct and the need for an auxiliary suction system for evacuating cell-cooling air.

Parikh, P. G.↗

Divergence of Velocity Fields in Electrochemical Systems

The passage of current through electrochemical systems results in the development of concentration gradients in the electrolytic phase that can be modeled using concentrated solution theory. Application of this theory requires knowledge of three concentration-dependent transport coefficients, which are often taken to be conductivity, diffusion coefficient, and the cation transference number with respect to the solvent velocity. The governing diffusion equation for molar concentration contains two additional terms - the thermodynamic factor which is related to activity of the electrolytic species and the solvent velocity. The main advance in this paper is the derivation of an expression for the divergence of the solvent velocity. Solving this equation requires knowledge of the partial molar volume of the electrolyte. Analogous expressions are derived for the mass average and molar average velocities. These velocities occur naturally in the diffusion equation if concentration is expressed as weight fraction and mole fraction of the electrolytic species, respectively.

diffusion↗

Solute redistribution in dendritic solidification with diffusion in the solid

An investigation of solute redistribution during dendritic solidification with diffusion in the solid has been performed using numerical techniques. The extent of diffusion is characterized by the instantaneous and average diffusion parameters. These parameters are functions of the diffusion Fourier number, the partition ratio and the fraction solid. Numerical results are presented as an approximate model, which is used to predict the average diffusion parameter and calculate the composition of the interdendritic liquid during solidification.

Ganesan, S.↗

Mineralogy of three slightly palagonitized basaltic tephra samples from the summit of Mauna Kea, Hawaii

The paper characterizes the mineralogy and spectral properties of three slightly palagonitized basaltic tephra samples collected near the summit of Mauna Kea in order to contribute to the basis for inferring mineralogy and processes for Martian surface materials. The mineralogy of size fractions of these samples is examined by diffuse reflectance and FIR spectroscopy, optical microscopy, X-ray diffraction, Moessbauer spectroscopy, magnetic analysis, EMPA, TEM, and SEM. For the 20-1000 micron size fraction, sample HWMK11 (red) is essentially completely oxidized and has a hematite (Ti-hematite) pigment dispersed throughout the silicate matrix. Sample HWMK12 (black) has the lowest proportion of ferric-bearing phases and is thus least weathered. For HWMK11, the amount of hematite is essentially constant, and mica is present only in the coarse clay-sized fraction; smectites are low in structural Fe.

Golden, D. C.↗

On the origin of the soft X-ray background

The angular autocorrelation function and spectrum of the soft X-ray background is studied below a discrete source detection limit, using two deep images from the Rosat X-ray satellite. The average spectral shape of pointlike sources, which account for 40 to 60 percent of the background intensity, is determined by using the autocorrelation function. The background spectrum, in the 0.5-0.9 keV band (M band), is decomposed into a pointlike source component characterized by a power law and a diffuse component represented by a two-temperature plasma. These pointlike sources cannot contribute more than 60 percent of the X-ray background intensity in the M band without exceeding the total observed flux in the R7 band. Spectral analysis has shown that the local soft diffuse component, although dominating the background intensity at energies not greater than 0.3 keV, contributes only a small fraction of the M band background intensity. The diffuse component may represent an important constituent of the interstellar or intergalactic medium.

Wang, Q. D.↗

Effects of Structure and Hydrodynamics on the Sooting Behavior of Spherical Microgravity Diffusion Flames

Recent experimental, numerical and analytical work has shown that the stoichiometric mixture fraction (Z(sub st)) can have a profound effect on soot formation in diffusion flames. These findings were obtained at constant flame temperature (T(sub ad)), employing the approach described in Du and Axelbaum (1995, 1996). For example, a fuel mixture containing 1 mole of ethylene and 11.28 moles of nitrogen burning in pure oxygen ((Z(sub st)) = 0.78) has the same adiabatic flame temperature (2370 K) as that of pure ethylene burning in air ((Z(sub st)) = 0.064). An important finding of these works was that at sufficiently high (Z(sub st)), flames remain blue as strain rate approaches zero in counterflow flames, or as flame height and residence time approach infinity in coflowing flames. Lin and Faeth (1996a) coined the term permanently blue to describe such flames. Two theories have been proposed to explain the appearance of permanently-blue flames at high (Z(sub st)). They are based on (1) hydrodynamics and (2) flame structure. Previous experimental studies in normal gravity are not definitive as to which, if either, mechanism is dominant because both hydrodynamics and structure suppress soot formation at high (Z(sub st)) in coflowing and counterflowing diffusion flames. In counterflow flames with (Z(sub st)) < 0.5 streamlines at the flame sheet are directed toward the fuel. Newly formed soot is convected into richer regions, favoring soot growth over oxidation. For (Z(sub st)) > 0.5, convection at the flame is toward the oxidizer, thus enhancing soot oxidization. Thus, in counterflow flames, hydrodynamics causes soot to be convected towards the oxidizer at high (Z(sub st)) which suppresses soot formation. Axelbaum and co-workers maintain that while the direction of convection can impact soot growth and oxidation, these processes alone cannot cause permanently-blue flames. Soot growth and oxidation are dependent on the existence of soot particles and the presence of soot is invariably accompanied by yellow luminosity. Soot-particle inception, on the other hand, arises from gas-phase reactions and its dependence on flow direction is weak, similar to that of other gas-phase reactions in flames. For example, when the flame moves across the stagnation plane no significant changes in flame chemistry are observed. Furthermore, since the soot-inception zone has a finite thickness, soot has been produced in counterflow flames with (Z(sub st)) > 0.5. For large (Z(sub st)) the fuel concentration decreases and oxygen concentration increases in the soot forming regions of the flame. This yields a shift in the OH profile toward the fuel side of the flame, and this shift can dramatically influence soot inception because it essentially narrows the soot inception zone. Soot-free (permanently-blue) conditions can be realized when the structure of the flame is adjusted to the extent that significant oxidizing species exist on the fuel side of the flame at temperatures above the critical temperature for soot inception, ca. 1250 K. In previously considered flames it was impossible to independently vary flame structure and convection direction. In contrast, spherical diffusion flames (which generally require microgravity) allow both properties to be varied independently. We altered structure (Z(sub st)) by exchanging inert between the oxidizer and the fuel and we independently varied convection direction at the flame sheet by interchanging the injected and ambient gases. In this work we established four flames: (a) ethylene issuing into air, (b) diluted ethylene issuing into oxygen, (c) air issuing into ethylene, and (d) oxygen issuing into diluted ethylene. (Z(sub st)) is 0.064 in flames (a) and (c) and 0.78 in flames (b) and (d). The convection direction is from fuel to oxidizer in flames (a) and (b) and from oxidizer to fuel in flames (c) and (d). Under the assumption of equal diffusivities of all species and heat, the stoichiometric contours of these flames have identical temperatures and nitrogen concentrations.

Sunderland, P. B.↗

Monte Carlo study of a model of diffusion-controlled reactions

The Monte Carlo method is used to perform averages over sink configurations in the present study of diffusion-controlled reactions occurring between solute particles and immobile spherical sinks. In order to determine the average steady state solute concentration profile in a locally perturbed solution for sink volume fractions phi of less than 0.3, the diffusion equation in the monopolar plus dipolar approximation of diffusive couplings between the sinks is solved numerically. The Monte Carlo method is shown to be the most accurate and efficient in the phi = 0.001-0.1 region, where a system of only 25 sinks suffices and the monopolar approximation alone is sufficiently accurate.

Beenakker, C. W. J.↗

Zircon (U-Th)/He Impact Crater Thermochronometry and the Effects of Shock Microstructures on Helium Diffusion Kinetics

Accurate and precise age determination of impact cratering events remains challenging and often contentious; less than half of all known craters are regarded as accurately and precisely dated. Zircon (U-Th)/He (ZHe) dating of impactites can be employed to date medium to large impact structures as ZHe ages can be fully reset in minutes at T >1000°C, a plausible scenario in the central melt pool. In contrast, complete resetting of ZHe at 200-300°C, encountered near the crater margins or due to post-impact hydrothermal overprinting, may take >103-6 years. To test the reliability of ZHe impact dating, we have quantified the effects of shock-induced microstructures on helium diffusion kinetics in well-characterized variably shocked zircon. We investigated samples from two impact structures, the Chicxulub multi-ring crater and Ries complex crater, to compare diffusion kinetics from structures with different size, age, and hydrothermal system longevity. Shock microstructures were characterized by backscattered-electron imaging prior to determining the He diffusion kinetics by prograde and retrograde fractional-release experiments via light-bulb furnace with incremental step-heating (10°C) from 300°C to 600°C. Next, we examine the internal interconnectivity and sizes of the diffusion domains by EBSD. While we found that zircon with few shock microstructures exhibited no marked deviation from helium diffusion kinetics of undamaged zircon, zircon grains with planar microstructures and granular textures are characterized by a dramatic decrease in helium retentivity due to the reduction in the effective domain size and the introduction of interconnected fast diffusion pathways. A subset of grains were ZHe dated and showed that less deformed grains yielded a weighted mean age within error of the accepted impact ages, while the grains with planar microstructures or granular textures gave systematically younger ages. These new diffusion data and ZHe ages demonstrate that highly shocked grains are unsuitable for ZHe impact crater dating. Therefore, detailed characterization of impact-induced microstructures is critical for determining accurate ZHe impact ages and offers the possibility of investigating post-impact hydrothermal circulation.

Zircon↗

Surface Radiation Budget (SRB) Release 2 Shortwave Monthly Data in Native Format (SRB_REL2_SW_MONTHLY)

The SRB data include the average upward and downward fluxes, photosynthetically active radiative flux, aerosol and cloud optical depth, cloud fraction, and solar zenith angle at three hourly intervals for each day for the entire globe between 07/01/1983 and 10/31/1995. These parameters were derived with the Shortwave algorithm of the NASA World Climate Research Programme /Global Energy and Water-Cycle Experiment (WCRP/GEWEX) Surface Radiation Budget (SRB) Project. [Location=GLOBAL] [Temporal_Coverage: Start_Date=1983-07-01; Stop_Date=1998-07-26] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=180] [Data_Resolution: Latitude_Resolution=1 degree; Longitude_Resolution=Ranges from 1 degree in the tropics to 120 degrees at the poles.; Temporal_Resolution=monthly; Temporal_Resolution_Range=monthly].

DIRECT/DIFFUSE SOLAR RADIATION↗

Surface Radiation Budget (SRB) Release 2 Shortwave 3 hourly Data in Native Format (SRB_REL2_SW_3HRLY)

The SRB data include the average upward and downward fluxes, photosynthetically active radiative flux, aerosol and cloud optical depth, cloud fraction, and solar zenith angle measured at three hourly intervals for each day for the entire globe between 07/01/1983 and 10/31/1995. These SW surface radiative parameters were derived with the Shortwave algorithm of the NASA World Climate Research Programme/Global Energy and Water-Cycle Experiment (WCRP/GEWEX) Surface Radiation Budget (SRB) Project. [Location=GLOBAL] [Temporal_Coverage: Start_Date=1983-07-01; Stop_Date=1998-07-26] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=180] [Data_Resolution: Latitude_Resolution=1 degree; Longitude_Resolution=Ranges from 1 degree (tropics and subtropics) to 120 degrees (the poles).; Temporal_Resolution=3 hourly; Temporal_Resolution_Range=3 hourly].

ALL SKY SW SURFACE DOWNWARD DIFFUSE FLUX↗