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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Numerical methods for systems of conservation laws of mixed type using flux splitting

The essentially non-oscillatory (ENO) finite difference scheme is applied to systems of conservation laws of mixed hyperbolic-elliptic type. A flux splitting, with the corresponding Jacobi matrices having real and positive/negative eigenvalues, is used. The hyperbolic ENO operator is applied separately. The scheme is numerically tested on the van der Waals equation in fluid dynamics. Convergence was observed with good resolution to weak solutions for various Riemann problems, which are then numerically checked to be admissible as the viscosity-capillarity limits. The interesting phenomena of the shrinking of elliptic regions if they are present in the initial conditions were also observed.

Shu, Chi-Wang↗
NASA NTRS1990

Theoretical line shapes for rotational spectra of HCl in Ar

An interaction potential for HCl-Ar recently derived from spectra of van der Waals complexes (Hutson,1988) has been used to obtain converged close-coupling scattering S matrices from which pressure broadening (linewidth, line shift, and line coupling) cross sections have been computed within the Fano-Ben-Reuven formalism. Linewidths agree well with experimental data with the exception of the 0-1 line at low temperatures (an error of about 15 percent at 125 K). Line shifts, especially the largest, for the 0-1 line, are also in reasonable accord with experimental data. Line coupling is predicted to be quite small. The coupled-states molecular scattering approximation is found to be accurate except at very low collision energies. The infinite-order sudden approximations, on the other hand, is not reliable for this system. Inelastic scattering out of the spectroscopic levels accounts for only a fraction of the linewidth at thermal energies, especially in the lower rotational levels.

Green, Sheldon↗
NASA NTRS1990

Raman Q-branch line shapes as a test of the H2-Ar intermolecular potential

The line-shape cross sections of vibrational Raman Q-branch spectra are determined theoretically for D2 and H2 in Ar. The calculations are based on accurate close-coupling matrices and the intermolecular potential obtained by Le Roy and Hutson (1987) from spectra of van der Waals complexes. The calculation techniques applied are explained, and the results are presented in tables and graphs and discussed in detail with reference to published experimental data. Agreement to within about 25 percent is obtained for the line widths, but the line shifts are found to be a factor of two smaller than the measured values, and a temperature dependence of line-width cross sections is predicted which is not observed experimentally.

Green, Sheldon↗
NASA NTRS1990

Rheology of solid methane and nitrogen - Applications of Triton

The existing information about the rheological properties of solid methane and nitrogen is reviewed. The main limitation is the absence of creep data for solid nitrogen, but estimated properties are derived on the basis of simple scaling arguments for van der Waals bonded materials. On Triton solid methane and most likely nitrogen are too soft to support any topography over billions of years. Topographic support by water ice-rich materials seems almost certain. Nitrogen and methane do not intermix by solid-state diffusion. The weakness (absence?) of the opposition effect on Triton can be explained by annealing of nitrogen grains, provided the latter have sizes characteristic of freshly deposited frost.

Eluszkiewicz, Janusz↗
NASA NTRS1990

NGC 1058: Gas motions in an extended, quiescent spiral disk

Researchers investigate in detail the motion of gas in the galaxy NGC 1058 using the very large array (VLA) to map the emission in the 21-cm line. This galaxy is so nearly face-on that the contribution to the line width due to the variation of the rotational velocity across the D-array beam is small compared with the random z-motion of the gas. Researchers confirm results of earlier studies (Lewis 1987, A. and A. Suppl., 63, 515; van der Kruit and Shostak 1984, A. and A., 134, 258) of the galaxy's total neutral hydrogen (HI) and kinematics, including the fact that the rotation curve drops faster than Keplerian at the outer edge of the disk, which is interpreted as a fortuitous twist of the plane of rotation in the outer disk. However, their very high velocity resolution (2.58 km s(exp -1) after Hanning smoothing) coupled with good spatial resolution, allows researchers to measure more accurately the line width, and even to some extent its shape, throughout the disk. One of the most interesting results of this study is the remarkable constancy of the line width in the outer disk. From radius 90 to 210 seconds the Gaussian velocity dispersion (sigma sub nu) of the 21-cm line has a mean value of 5.7 km s(exp -1) (after correcting for the spectral resolution) with a dispersion of less than 0.9 km s(exp -1) (after correcting for the spectral resolution) with a dispersion of less than 0.9 km s(exp -1). Translating this directly into a kinetic temperature (Doppler temperature): T sub Dopp equals 121K (sigma sub mu exp 2/(km s(exp -1) (exp 2) gives 4000 K, with a dispersion of less than 1500 K over the outer disk. This constancy is observed even when comparing the spiral arms versus inter-arm regions, which in the radius range from 100 to 150 seconds the surface density modulates (defined as the ratio N sub peak -N sub trough/N sub peak + N sub trough) from 0.5 to 0.25 in the range 150 to 200 seconds.

Hanson, Margaret Murray↗
NASA NTRS1990

High brightness neutral hydrogen in M31: A new probe of interstellar pressure

An observational parameter of our own Galaxy, the peak brightness temperature of neutral hydrogen in emission, was determined almost twenty years ago (Burton 1970). This quantity, although possessing a degree of local variations, has a remarkably consistent peak value of 125 K towards spiral arm segments with a few isolated peaks extending to 135 K, once sufficient spatial and velocity resolution are used (less than or equal to 70 pc, less than or equal to 5 km/s) to resolve the emission peaks. The higher spatial and velocity resolution of more recent surveys has not led to the detection of higher brightnesses. For many years this remarkable observational result has received little attention, primarily because similar data for other galaxies, which would allow a meaningful comparison and analysis, did not exist. Recently this situation has changed. A Westerbork survey of M33 (Deul and Van der Hulst 1987, and private comm.) with 40 pc x 8 km/s resolution has revealed consistent peak values of only 95 plus or minus 5 K (although there is still some question of whether the velocity resolution was sufficient in this case), while a Very Large Array (VLA) survey of M31 (Braun 1989a) with 35 pc x 5 km/s resolution has shown consistent peak values but at a temperature of 155 to 165 K. It has become clear that although peak HI brightness seems to be a well-defined quantity within individual galaxies (with a degree of local variation) there are very significant differences in this quantity amongst different galaxies. Researchers embarked on an observational program directed at a sample of 11 nearby galaxies: NGC 55, 247, 7793, 3031, 2366, 2403, 4236, 4826, 4736, 4244, and 5457. They hope to determine the gas properties and phases as a function of both galaxy type and position within the galaxies utilizing high resolution HI observations and optical narrow band imagery and spectroscopy which are now underway.

Braun, Robert↗
NASA NTRS1990

Unbound molecular complexes in M33

The HI content of the nearby spiral galaxy M33 (d approx. 0.8 Mpc) has been the subject of many detailed studies (most recently Deul and van der Hulst 1987), but similar data on the molecular gas component has been lacking. This galaxy is currently undergoing vigorous high-mass star formation, as evidenced by the many OB associations and HII regions, and so is expected to possess at least some molecular gas. Interferometric studies have detected molecular clouds similar to Galactic Giant Molecular Clouds (GMCs) (Boulanger et al. 1988; Wilson et al. 1988). Researchers have recently mapped the nuclear region of M33 in the CO J=1-0 line with a 12 m telescope (half power beam width 55 inches approx. 210 pc) out to a radius of 3.5 minutes in order to trace the detailed distribution of the molecular gas. The resulting map reveals six large complexes with diameters of 200 to 400 pc. Interferometer observations of these regions have resolved them into individual molecular clouds similar to Galactic GMCs (Wilson et al. 1988). The complexes shown are much larger than individual Galactic GMCs (Sanders, Scoville, and Solomon 1985), but are somewhat smaller on average than the large associations seen in the grand-design spiral galaxy M51 (Rand and Kulkarni 1989). If we extend the velocity-diameter relation observed for Galactic GMCs to these larger structures, the predicted velocity widths are a factor of 1.5 to 3 times greater than the observed full-width half-maximum velocities (13 to 29 km (s-1). The peak brightness temperatures are approx. 0.2 K, at least a factor of 10 lower than what is observed for Galactic GMCs. If these large structures are made up of objects similar to Galactic GMCs, the area filling factor of the small clouds is roughly 10 percent. These results suggest that these complexes are not very large GMCs, but rather are associations of many individual GMCs or GMCs embedded in a diffuse gas component.

Wilson, Christine D.↗
NASA NTRS1990

Dissociation and ionization of molecular gas in the spiral arms of M51

Researchers derive the star formation rate and efficiency in the arm and interarm regions of M51 from observations of the molecular (Lo et al. 1987) and ionized (van der Hulst et al. 1988) phases of the interstellar medium, and show that the HI observations of Tilanus and Allen (1989) are consistent with dissociation of molecular gas by these young, massive stars if n sub H greater than or equal to 200 cm (-2). However, these stars are not able to dissociate or ionize all the gas, and at least 60 percent must remain molecular in the interarm regions. The efficiency of star formation in M51 seems to be similar to that in the Galaxy, and does not appear to be enhanced in the spiral arms. Therefore, the effect of the strong density wave may be only to concentrate the gas, and hence the young stars, to the arm regions.

Lees, J. F.↗
NASA NTRS1989

Dust coagulation in ISM

Coagulation is an important mechanism in the growth of interstellar and interplanetary dust particles. The microphysics of the coagulation process was theoretically analyzed as a function of the physical properties of the coagulating grains, i.e., their size, relative velocities, temperature, elastic properties, and the van der Waal interaction. Numerical calculations of collisions between linear chains provide the wave energy in individual particles and the spectrum of the mechanical vibrations set up in colliding particles. Sticking probabilities are then calculated using simple estimates for elastic deformation energies and for the attenuation of the wave energy due to absorption and scattering processes.

Chokshi, Arati↗
NASA NTRS1989

The discovery of a highly polarized bipolar nebula

During a search for the optical counterparts of IRAS sources whose flux peaks at 25 microns, a small faint bipolar nebula was discovered in Monoceros at the position of IRAS 07131-0147. The CCD images display the object's considerable structure. The central star seems relatively free of closeby nebulosity: the two lobes have a bow-tie structure with those parts nearest to the star consisting of series of small knots. The outer parts of the lobes seem to be made up of filaments streaming away from knots. On the basis of its optical spectrum, the central star was classified as a M5-6 giant. In the IRAS color classification scheme of Van der Veen and Habing (1988), the central star is VIb which indicates that there are distinct hot and cold components of circumstellar dust and that the mass loss process may have temporarily abated. Therefore, it is proposed that the object is in the post main sequence stage of evolution and is a protoplanetary nebulae. Young protoplanetary nebulae have totally obscured central stars illuminating reflective lobes whereas older ones such as M2-9 have lobes seen in emission from gas ionized by the central hot star which is clearly visible. Since the central object of IRAS07131-0147 is a relatively unobscured late type star and the lobes are seen only by reflection, it is suggested that this nebula is a protoplanetary nebula in an evolutionary stage intermediate between that of CRL2688 and M2-9.

Wolstencroft, Ramon D.↗
NASA NTRS1990

A perturbation method and some applications

For differential equations with one fast variable, a perturbation method is introduced that transforms a solution valid over only a short time interval to a new solution composed of averaged variables plus a periodic function of the averaged variables. The averaged variables are governed by a set of differential equations where the fast variable has been removed and thus can be numerically integrated quickly or solved directly. This method is applied to a perturbed harmonic oscillator with a cubic perturbation, van der Pol's equation, coorbital motion in the restricted three-body problem, and to nearly circular motion of a particle near one of the primaries in the restricted three-body problem.

Konopliv, Alex↗
NASA NTRS1991

Amorphization and recrystallization of epitaxial ReSi2 films grown on Si(100)

The effects of implantation damage and the chemical species of the implant on structural and electrical properties of epitaxial ReSi2 films on Si(100) implanted with Si-28 or Ar-40 ions, at doses ranging from 10 to the 13th/sq cm to 10 to the 15th/sq cm, were investigated using the backscattering spectrometry, XRD, and the van der Pauw techniques. Results showed that ion implantation produces damage in the film, which increases monotonically with dose; the resistivity of the film decreases monotonically with dose.

Kim, Kun HO↗
NASA NTRS1991

Pressure broadening data as a test of a recently proposed Ar-H2O interaction potential

An interaction potential for H2O-Ar that was recently determined from spectra of the van der Waals complex by Cohen and Saykally (1990) is used with accurate molecular scattering calculations to predict line broadening parameters for the 183 and 380 GHz transitions of water vapor. Theoretical values are about 15 percent higher than experiment. A comparison of experimental and theoretical pressure broadening cross sections for water in argon is presented.

Green, Sheldon↗
NASA NTRS1991

Resonant frequency calculations using a hybrid perturbation-Galerkin technique

A two-step hybrid perturbation Galerkin technique is applied to the problem of determining the resonant frequencies of one or several degree of freedom nonlinear systems involving a parameter. In one step, the Lindstedt-Poincare method is used to determine perturbation solutions which are formally valid about one or more special values of the parameter (e.g., for large or small values of the parameter). In step two, a subset of the perturbation coordinate functions determined in step one is used in Galerkin type approximation. The technique is illustrated for several one degree of freedom systems, including the Duffing and van der Pol oscillators, as well as for the compound pendulum. For all of the examples considered, it is shown that the frequencies obtained by the hybrid technique using only a few terms from the perturbation solutions are significantly more accurate than the perturbation results on which they are based, and they compare very well with frequencies obtained by purely numerical methods.

Geer, James F.↗
NASA NTRS1992

Gibbs free energy of reactions involving SiC, Si3N4, H2, and H2O as a function of temperature and pressure

Silicon carbide and silicon nitride are considered for application as structural materials and coating in advanced propulsion systems including nuclear thermal. Three-dimensional Gibbs free energy were constructed for reactions involving these materials in H2 and H2/H2O. Free energy plots are functions of temperature and pressure. Calculations used the definition of Gibbs free energy where the spontaneity of reactions is calculated as a function of temperature and pressure. Silicon carbide decomposes to Si and CH4 in pure H2 and forms a SiO2 scale in a wet atmosphere. Silicon nitride remains stable under all conditions. There was no apparent difference in reaction thermodynamics between ideal and Van der Waals treatment of gaseous species.

Isham, M. A.↗
NASA NTRS1992

Microwave properties of peeled HEMT devices sapphire substrates

The focus of this research is to demonstrate the first full radio frequency characterization of high electron mobility transistor (HEMT) device parameters. The results of this research are used in the design of circuits with peeled HEMT devices, e.g. 10 GHz amplifiers. Devices were fabricated using two HEMT structures grown by molecular beam epitaxy methods. A 500 A AlAs release layer for 'peel off' was included under the active layers of the structure. The structures are a homogeneously doped Al(0.3)GA(0.7)As/GaAs and a delta doped square well Al(.23)Ga(.77)As/GaAs HEMT structure. Devices were fabricated using a mesa isolation process. Contacts were done by sequentially evaporating Au/Ge/Au/Ni/Au followed by rapid thermal anneal at 400 C for 15 seconds. Gates were wet etch recessed and 1 to 1.4 micron Ti/Au gate metal was deposited. Devices were peeled off the GaAs substrate using Apiezon wax to support the active layer and a HF:DI (1:10) solution to remove the AlAs separation layer. Devices were then attached to sapphire substrates using van der Waals bonding.

Young, Paul G.↗
NASA NTRS1991

The temperature dependence of collision-induced absorption by oxygen near 6 microns

Coefficients for oxygen absorption in the infrared induced by collisions with O2 and N2 are reported over the range 1400-1800/cm and 225-356 K. These coefficients are used to calculate the absorption for O2 in air as a function of temperature and wavenumber, and comparisons are made with previous determinations. In addition, structured absorption features superimposed on the broad collision-induced absorption band, which were observed at all temperatures studied, are interpreted in terms of the presence of (O2)2 and O2-N2 van der Waals molecules.

Orlando, John J.↗
NASA NTRS1991

Characterization of directionally solidified Hg(1-x)Zn(x)Se semiconducting alloys

Hg(1-x)Zn(x)Se alloys with composition between x = 0.08 and 0.115 were synthesized from elemental constituents and were resolidified using a Bridgman-Stockbarger growth technique. By performing precision mass-density measurements on selected wafers cut perpendicular to the growth axis, it was shown that the axial compositional profiles fit a numerical solution to the 1D diffusion equation which takes into account the variation of interface velocity with time. Infrared transmission-edge measurements performed on selected transverse slices from each ingot showed that the relative radial variations in composition decreased with decreasing growth rate. Van der Pauw measurements on selected wafers showed that the 10 exp 18/cu cm electron concentration, typical of as-grown crystals, could be reduced by approximately an order of magnitude by annealing in Se vapor.

Cobb, S. D.↗