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At least 145 records · Page 8

The elements just beyond iron - Formation during explosive carbon burning

It is pointed out that the details of the synthesis of the elements just beyond iron are unclear. Thus, a reexamination of the role played by neutron-capture reactions during explosive carbon burning is indicated. A description is given of calculations of explosive carbon-burning nucleosynthesis using a complete neutron capture (n-process) computer code with a network extending from Cr through Zr and including not only (n,gamma), (gamma,n) reactions and beta-decay but also (p,n), (n,p), (p,gamma), and (p,alpha) reactions. Initial conditions indicative of the composition of a massive star following core helium burning were selected, and a comparison is made with conditions similar to those used by Howard et al. (1972). It is found that neutron reactions during explosive carbon burning are an important source for the elements just beyond iron.

Wefel, J. P.↗

Investigations into the burning-out of organic substances in the ceramic body

Pressed compacts were made of spray dried alumina containing water soluble polyvinyl alcohol or cellulose derivative binder. The burning out of organic binder on gradual heating was investigated by visual and microscopic observations of the cross section and by thermogravimetry. Burning out proceeds inward from the peripheries, gradually reducing the size of the black core, which first consists of a dark boundary layer and later turns uniformly black with a sharp boundary. A detailed mechanism of the burning out process between and within the spray dried granules is observed under the microscope. Oxygen atmosphere accelerates the burning out process.

Locher, C.↗

The direct effects of strain on burning rates of composite solid propellants

A mathematical model is developed to predict burn rate augmentation due to strain in a composite solid propellant. The model assumes the effect is due to the ability of the flame to penetrate the small fissures and voids that form when a propellant is strained. The number and size of these fissures is obtained by applying a flaw propagation analysis to randomly distributed flaws that form when the binder-oxidizer particle bonds break under stress. A flame height is calculated with Summerfield's burn rate equation and is used to compute the burn rate augmentation based upon the additional burn area created when the flame penetrates the fissures. Comparisons are made with data obtained from published sources. The existence of threshold pressure and strains, above which augmentation occurs, is verified although the model predicts a lower threshold pressure and higher threshold strain than expected. Further results and applications of the model are discussed.

Langhenry, M. T.↗

The variations of CO and O3 concentrations in a region subject to biomass burning

Carbon monoxide (CO) and ozone (O3) concentrations have been observed in the Brazilian Amazon region, at a site strongly affected by biomass burning (Cuiaba, 16 deg S, 58 deg W). Time variations are described for the first long-term program of studying the effect of biomass burning on O3 and CO over a complete seasonal cycle, including the seasonal maxima of 1987 and 1988. In order to obtain elements for comparison, an identical observational program was maintained at a site totally outside of the direct influence of biomass burning (Natal, 6 deg S, 35 deg W). The biomass burning contribution to the Cuiaba concentrations of CO and O3 is very large. Diurnal maxima concentrations exceeded 90 ppbv O3 in 1987 and 120 ppbv O3 in 1988, in September. For the wet season, the monthly average ozone concentration in March-April is about 10 ppbv. During the month of maxima, September, the O3 concentration average was 41 ppbv for 1987 and 71 ppbv for 1988. The CO concentrations are about 90 ppbv in the wet season. In September, 460 ppbv and 660 ppbv of CO were observed for 1987 and 1988, respectively. At Natal the seasonal variation is of the order of a factor of 2. During the wet season, the concentrations of CO and O3 at both stations are about the same.

Kirchhoff, V. W. J. H.↗

The effect of multi-periapse burns on planetary escape and capture

The use of multiple periapse burns to transfer between a planetocentric parking orbit and a hyperbolic trajectory with a high thrust propulsion system having constant, finite thrust is investigated. Such multiple burns offer propellant savings as a consequence of reduced velocity losses which accrue over the finite burn time of thrusting maneuvers. Velocity losses for an earth escape phase are calculated for an optimum steering program over a range of parameters that are typical of a Mars mission. These numerically integrated results are compared to velocity losses evaluated with a leading analytic approximation to establish boundaries within which the accuracy of the analytic approximation is adequate for preliminary mission planning purposes. Finally, results of the investigation are used to define typical benefits of the multi-periapse burn concept for Mars exploration missions.

Horsewood, Jerry L.↗

Observations on a Slow Burning Regime for Hydrocarbon Droplets - N-Heptane/Air Results

Experiments on n-heptane/airdroplet combustion under reduced gravity have served as a benchmark for much of the existing theoretical efforts on the modeling of sphero-synmmetric droplet burning. New experiments conducted in the NASA-Lewis Research Center 2.2 second droptower (at less than 10 exp -5 g) which emphasize the production of sphero-symmetry and low relative droplet/gas convection produce burning rates in air (for about 1 mm droplets) as much as 40-percent lower than the classical result (0.78 sq mm/s). The burning rate is proportional to the measured droplet/gas relative velocity, and the observed functional dependence is much larger than predicted by published convective correlations. New results clearly indicate that the droplet/laboratory velocity does not correspond to the relative droplet/gas velocity. Thus, the convective effects on droplet combustion is not properly characterized by droplet motion alone. Differences in the burning rates are speculated to result from the effects of the accumulated soot as well as the asymmetry (caused by convection) in the temperature and species distributions surrounding the droplet.

Choi, Mun Y.↗

A regional estimate of convective transport of CO from biomass burning

A regional-scale estimate of the fraction of biomass burning emissions that are transported to the free troposphere by deep convection is presented. The focus is on CO and the study region is a part of Brazil that underwent intensive deforestation in the 1980s. The method of calculation is stepwise, scaling up from a prototype convective event, the dynamics of which are well-characterized, to the vertical mass flux of carbon monoxide over the region. Given uncertainties in CO emissions from biomass burning and the representativeness of the prototype event, it is estimated that 10-40 percent of CO emissions from the burning region may be rapidly transported to the free troposphere over the burning region. These relatively fresh emissions will produce O3 efficiently in the free troposphere where O3 has a longer lifetime than in the boundary layer.

Pickering, Kenneth E.↗

Global biomass burning - Atmospheric, climatic, and biospheric implications

The present volume discusses the biomass burning (BMB) studies of the International Global Atmospheric Chemistry project, GEO satellite estimation of Amazonian BMB, remote sensing of BMB in West Africa with NOAA-AVHRR, an orbital view of the great Chinese fire of 1987, BMB's role in tropical rainforest reduction, CO and O3 measurements of BMB in the Amazon, effects of vegetation burning on the atmospheric chemistry of the Venezuelan savanna, an assessment of annually-burned biomass in Africa, and light hydrocarbon emissions from African savanna burnings. Also discussed are BMB in India, trace gas and particulate emissions from BMB in temperate ecosystems, ammonia and nitric acid emissions from wetlands and boreal forest fires, combustion emissions and satellite imagery of BMB, BMB in the perspective of the global carbon cycle, modeling trace-gas emissions from BMB, NO(x) emissions from BMB, and cloud-condensation nuclei from BMB.

Levine, Joel S.↗

Carbonaceous aerosols from prescribed burning of a boreal forest ecosystem

During the boreal forest burn studied, the ambient concentrations for the particle carbon smoke aerosol are highest for the full-fire burn conditions and vary significantly throughout the burn. Collection strategies must accordingly define ranges in the smoke aerosol concentrations produced. While the highest elemental C concentrations are observed during full-fire conditions, the great majority of smoke aerosol particles are in the form of organic C particles irrespective of fire temperature. The formation of organic C light-scattering particles was a significant process in the burn studied.

Mazurek, Monica A.↗

The F/A-18 external burning flight test

A flight test program was undertaken to demonstrate the feasibility of obtaining external burning (EB) data in a flight environment, and to address the question of facility interference in ground test external burning data. Results showed that external burning was effective at reducing transonic base drag in a flight environment having dynamically changing conditions. The flight test program demonstrated that external burning is not just a laboratory phenomenon but is a viable technology for aerospace vehicles.

Yungkurth, C.↗

Studies of droplet burning and extinction

A project on droplet combustion, pursued jointly with F.L. Dryer of Princeton University, has now been in progress for many years. The project involves experiments on the burning of single droplets in various atmospheres, mainly at normal atmosperic pressure and below, performed in drop towers and designed to be performed aboard space-based platforms such as the Space Shuttle or the Space Station. It also involves numerical computations on droplet burning, performed mainly at Princeton, and asymptotic analyses of droplet burning, performed mainly at UCSD. The focus of the studies rests primarily on time-dependent droplet-burning characteristics and on extinction phenomena. The presentation to be given here concerns the recent research on application of asymptotic methods to investigation of the flame structure and extinction of hydrocarbon droplets. These theoretical studies are investigating the extent to which combustion of higher hydrocarbons - heptane, in particular - can be described by four-step reduced chemistry of the kind that has achieved a good degree of success for methane flames. The studies have progressed to a point at which a number of definite conclusions can now be stated. These conclusions and the reasoning that led to them are outlined here.

Williams, Forman A.↗

Computational study of single-expansion-ramp nozzles with external burning

A computational investigation of the effects of external burning on the performance of single expansion ramp nozzles (SERN) operating at transonic speeds is presented. The study focuses on the effects of external heat addition and introduces a simplified injection and mixing model based on a control volume analysis. This simplified model permits parametric and scaling studies that would have been impossible to conduct with a detailed CFD analysis. The CFD model is validated by comparing the computed pressure distribution and thrust forces, for several nozzle configurations, with experimental data. Specific impulse calculations are also presented which indicate that external burning performance can be superior to other methods of thrust augmentation at transonic speeds. The effects of injection fuel pressure and nozzle pressure ratio on the performance of SERN nozzles with external burning are described. The results show trends similar to those reported in the experimental study, and provide additional information that complements the experimental data, improving our understanding of external burning flowfields. A study of the effect of scale is also presented. The results indicate that combustion kinetics do not make the flowfield sensitive to scale.

Yungster, Shaye↗

Multiple burn fuel-optimal orbit transfers: Numerical trajectory computation and neighboring optimal feedback guidance

This report describes current work in the numerical computation of multiple burn, fuel-optimal orbit transfers and presents an analysis of the second variation for extremal multiple burn orbital transfers as well as a discussion of a guidance scheme which may be implemented for such transfers. The discussion of numerical computation focuses on the use of multivariate interpolation to aid the computation in the numerical optimization. The second variation analysis includes the development of the conditions for the examination of both fixed and free final time transfers. Evaluations for fixed final time are presented for extremal one, two, and three burn solutions of the first variation. The free final time problem is considered for an extremal two burn solution. In addition, corresponding changes of the second variation formulation over thrust arcs and coast arcs are included. The guidance scheme discussed is an implicit scheme which implements a neighboring optimal feedback guidance strategy to calculate both thrust direction and thrust on-off times.

Chuang, C.-H.↗

Hot bottom burning in asymptotic giant branch stars and its effect on oxygen isotopic abundances

A self-consistent calculation of asymptotic giant branch (AGB) evolution was carried out, including nucleosynthesis at the base of the convective envelope (hot bottom burning). Hot bottom burning was found to occur for stars between approximately 4.5 and approximately 7 solar mass, producing envelopes with O-18/O-16 less than or equal to 10(exp -6) and 10(exp -3) approximately less than or equal O-17/O-16 approximately less than or equal to 10(exp -1). The O-17 abundance depends sensitively on the nuclear O-17-destruction rate; this rate is only loosely constrained by the requirement that first and second dredge-up models match O-isotope observations of red giant branch (RGB) stars (Boothroyd, Sackmann, & Wasserburg 1994). In some cases, high mass-loss rates can terminate hot bottom burning before further O-17 enrichment takes place or even before all O-18 is destroyed. These predictions are in accord with the very limited stellar observations of J type carbon stars on the AGB and with some of the circumstellar Al2O3 grains from meteorites. In contrast, precise data from a number of grains and data from most low-mass S and C AGB stars (approximately less than 1.7 solar mass) lie in a region of the O-18/O-16 versus O-17/O-16 diagram that is not accessible by first and second dredge-up or by hot bottom burning. We conclude that for AGB stars, the standard models of stellar evolution are not in accord with these observations. We surmise that an additional mixing mechanism must exist that transports material from the cool bottom of the stellar convective envelope to a depth at which O-18 is destroyed. This 'cool bottom processing' mechanism on the AGB is similar to extra mixing mechanisms proposed to explain the excess C-13 (and depleted C-12) observed in the earlier RGB stage of evolution and the large Li-7 depletion observed in low-mass main-sequence stars.

Boothroyd, Arnold I.↗

Studies of droplet burning and extinction

A project on droplet combustion, pursued jointly with F. L. Dryer of Princeton University, has now been in progress for many years. The project involves experiments on the burning of single droplets in various atmospheres, mainly at normal atmospheric pressure and below, performed in drop towers and designed to be performed aboard space-based platforms such as the Space Shuttle or the Space Station and currently manifest for Spacelab in the MSL-1 flight of the Space Shuttle in April of 1997. It also involves numerical computations on droplet burning, performed mainly at Princeton, and asymptotic analyses of droplet burning, performed mainly at UCSD. The focus of the studies rests primarily on time-dependent droplet-burning characteristics and on extinction phenomena. The presentation to be given here concerns the recent research on application of asymptotic methods to investigation of the flame structure and extinction of alcohol droplets. These theoretical studies are relevant to the second of the proposed space-flight tests and are currently investigating the extent to which combustion of alcohols can be described by four-step reduced chemistry similar to that which has achieved a good degree of success for alkane flames. These studies have progressed to a point at which a number of definite conclusions can now be stated. These conclusions and the reasoning that led to them are outlined.

Williams, F. A.↗

Brief Communication: A Simplified Approach to Transient Convective Droplet Evaporation and Burning

Empirical correlations for evaporation rates from single fuel droplets have existed since the 1930s. These correlations, which will be referred to in this article as Froessling/Ranz-Marshall types of correlations, are appropriate to the special cases of steady-state evaporation in the absence of chemical reaction. In a previous article by the authors, the quasi-steady evaporation and burning processes associated with a fuel drop in a convective environment are examined through a droplet model based on the boundary layer approach. For droplet Reynolds numbers of practical interest, this model produces very reasonable steady state as well as quasi-time-dependent droplet simulations, requiring relatively short computational times and yielding good agreement with the above-mentioned empirical correlations. The steady-state case, however, is usually relevant to practical combustor situations only when the drop has reached a nearly uniform temperature since the heating process of the drop cannot be considered to be quasi-steady. In the present study, the transient heating process of the droplet interior during evaporation and/or burning is taken into account, and thus calculations pertaining to the entire life-time of the droplet are carried out. It is of particular interest here to obtain simplified correlations to describe the transient behavior of evaporating and burning droplets; these may be incorporated with greater ease into spray calculations. Accordingly, we have chosen to use stagnation conditions in the present model in a modification of the Froessling/Ranz-Marshall correlations. These modified correlations, incorporating an effective transfer number, produce a fairly accurate representation of droplet evaporation and burning, while requiring only one tenth the computational effort used in a full boundary layer solution.

Madooglu, K.↗

Leading Edge Flame Detachment: Effect on Burning Rate of Ammonium Perchlorate Propellants

Inner details of the transition from premixed to diffusion controlled burning are examined by considering the transition at the individual particle flamelet level. These considerations lead to prediction of observable singular burning rate behavior of bimodal AP formulations. Burning rate measurements verify the predictions, supporting the view that particle flamelets become detached and retreat to more remote premixed locations at definite (particles size dependent) pressures, revealed by the burning rate tests.

Price, E. W.↗

The 1985 Biomass Burning Season in South America: Satellite Remote Sensing of Fires, Smoke, and Regional Radiative Energy Budgets

Using satellite imagery, more than five million square kilometers of the forest and cerrado regions over South America are extensively studied to monitor fires and smoke during the 1985 biomass burning season. The results are characterized for four major ecosystems, namely: (1) tropical rain forest, (2) tropical broadleaf seasonal, (3) savannah/grass and seasonal woods (SGW), and (4) mild/warm/hot grass/shrub (MGS). The spatial and temporal distribution of fires are examined from two different methods using the multispectral Advanced Very High Resolution Radiometer Local Area Coverage data. Using collocated measurements from the instantaneous scanner Earth Radiation Budget Experiment data, the direct regional radiative forcing of biomass burning aerosols is computed. The results show that more than 70% of the fires occur in the MGS and SGW ecosystems due to agricultural practices. The smoke generated from biomass burning has negative instantaneous net radiative forcing values for all four major ecosystems within South America. The smoke found directly over the fires has mean net radiative forcing values ranging from -25.6 to -33.9 W m(exp -2). These results confirm that the regional net radiative impact of biomass burning is one of cooling. The spectral and broadband properties for clear-sky and smoke regions are also presented that could be used as input and/or validation for other studies attempting to model the impact of aerosols on the earth-atmosphere system. These results have important applications for future instruments from the Earth Observing System (EOS) program. Specifically, the combination of the Visible Infrared Scanner and Clouds and the Earth's Radiant Energy System (CERES) instruments from the Tropical Rainfall Measuring Mission and the combination of Moderate Resolution Imaging Spectrometer and CERES instruments from the EOS morning crossing mission could provide reliable estimates of the direct radiative forcing of aerosols on a global scale, thereby reducing the uncertainties in current global aerosol radiative forcing values.

Christopher, Sundar A.↗