SEARCH · Engineering Papers

Results for “Breakthrough Curves”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 145 records · Page 8

All sources NASA NTRS DOE OSTI

NASA NTRS2007

Modelling of TES X-ray Microcalorimeters with a Novel Absorber Design

Our development of a novel x-ray absorber design that has enabled the incorporation of high-conductivity electroplated gold into our absorbers has yielded devices that not only have achieved breakthrough performance at 6 keV, but also are extraordinarily well modelled. We have determined device parameters that reproduce complex impedance curves and noise spectra throughout transition. Observed pulse heights, decay time and baseline energy resolution were in good agreement with simulated results using the same parameters. In the presentation, we will show these results in detail and we will also show highlights of the characterization of our gold/bismuth-absorber devices. We will discuss possible improvement of our current devices and expected performance of future devices using the modelling results.

Iyomoto, Naoko↗

NASA NTRS1986

Mathematical model for the Bridgman-Stockbarger crystal growing system

In a major technical breakthrough, a computer model for Bridgman-Stockbarger crystal growth was developed. The model includes melt convection, solute effects, thermal conduction in the ampule, melt, and crystal, and the determination of the curved moving crystal-melt interface. The key to the numerical method is the use of a nonuniform computational mesh which moves with the interface, so that the interface is a mesh surface. In addition, implicit methods are used for advection and diffusion of heat, concentration, and vorticity, for interface movement, and for internal gracity waves. This allows large time-steps without loss of stability or accuracy. Numerical results are presented for the interface shape, temperature distribution, and concentration distribution, in steady-state crystl growth. Solutions are presented for two test cases using water, with two different salts in solution. The two diffusivities differ by a factor of ten, and the concentrations differ by a factor of twenty.

Roberts, G. O.↗

DOE OSTI2021

LAMOST Time-Domain survey: first results of four K2 plates

From Oct. 2019 to Apr. 2020, LAMOST performed a time-domain (TD) spectroscopic survey of four K2 plates with both low- and medium-resolution observations. The low-resolution spectroscopic survey acquired 282 exposures ( ≈ 46.6 h) over 25 nights, yielding a total of about 767 000 spectra, and the medium-resolution survey took 177 exposures ( ≈ 49.1 h) over 27 nights, collecting about 478 000 spectra. More than 70%/50% of low-resolution/medium-resolution spectra have signal-to-noise ratio higher than 10. We determine stellar parameters (e.g., T eff , log g, [Fe/H]) and radial velocity (RV) with different methods, including LASP, DD-Payne and SLAM. In general, these parameter estimations from different methods show good agreement, and the stellar parameter values are consistent with those of APOGEE. We use the Gaia DR2 RV values to calculate a median RV zero point (RVZP) for each spectrograph exposure by exposure, and the RVZP-corrected RVs agree well with the APOGEE data. The stellar evolutionary and spectroscopic masses are estimated based on the stellar parameters, multi-band magnitudes, distances and extinction values. Finally, we construct a binary catalog including about 2700 candidates by analyzing their light curves, fitting the RV data, calculating the binarity parameters from medium-resolution spectra and cross-matching the spatially resolved binary catalog from Gaia EDR3. In conclusion, the LAMOST TD survey is expected to represent a breakthrough in various scientific topics, such as binary systems, stellar activity, stellar pulsation, etc.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2020

Impact of sub-core scale heterogeneity on CO2/brine multiphase flow for geological carbon storage in the Minnelusa sandstone

CO2 geological storage in deep saline aquifers is a mitigation option for CO2 emissions due to its large storage capacity and immediate accessibility. Accurately determining the CO2-brine relative permeability curves is key to the evaluation of CO2 injectivity and sweep efficiency in reservoir simulation as well as the CO2 injection in the field. This study highlights the remarkable effects of sub-core scale heterogeneity on the CO2-brine multiphase flow properties of the Minnelusa Sandstone in Wyoming. Two unsteady state CO2-brine drainage experiments were performed on the two samples. The first sample exhibits slanted laminated structure, while the second one represents a more homogeneous sandstone system. The CO2 saturation distributions during drainage reveals that the main variation in multiphase flow properties of two core samples were attributed to the porosity distribution that leads to the capillary pressure heterogeneity. Assisted history matching was used to obtain the respective relative permeability curves, which suggests heterogeneity-dependent behavior. In addition, sensitive and uncertainty analyses indicate that physical and petro-physical properties of low-porosity and low-permeability bedding layers exert marked effects on CO2 front breakthrough time and brine production. The results presented in this study help to gain insight into the CO2-brine multiphase flow properties in heterogeneous sandstones and can pave the way for the upscaling of CO2 migration and field-scale simulation accurately. This work is funded under the Department of Energy CarbonSAFE program (awards DE-FE0031624 DE0031891).

Kou, Zuhao↗

DOE OSTI2014

Specific methodology for capacitance imaging by atomic force microscopy: A breakthrough towards an elimination of parasitic effects

On the basis of a home-made nanoscale impedance measurement device associated with a commercial atomic force microscope, a specific operating process is proposed in order to improve absolute (in sense of “nonrelative”) capacitance imaging by drastically reducing the parasitic effects due to stray capacitance, surface topography, and sample tilt. The method, combining a two-pass image acquisition with the exploitation of approach curves, has been validated on sets of calibration samples consisting in square parallel plate capacitors for which theoretical capacitance values were numerically calculated.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

NASA NTRS2009

X-Ray and Multi-Wavelength Observations of Gamma Ray Bursts (GRBs)

The launch of the Italian (with Dutch participation) satellite BeppoSAX in 1996 enabled the detection of the first X-ray GRB afterglow, which in turn led to GRB counterpart detection in multiple wavelengths. This breakthrough firmly established the cosmological nature of GRBs. However, afterglow observations of GRBs took off in large numbers after the launch of NASA's Swift satellite in 2004. Swift enabled multiple major discoveries, such as the early lightcurves of X-ray afterglows, the first detection of a short GRB afterglow and opened more questions such as where are the elusive breaks in afterglow light curves. I will describe here these results and will discuss future opportunities and improvements in the field.

Kouveliotou, Chryssa↗

DOE OSTI2015

Ultrafast electrochemical preparation of graphene/CoS nanosheet counter electrodes for efficient dye-sensitized solar cells

Utilizing inexpensive, high-efficiency counter electrodes (CEs) to replace the traditional platinum counterparts in dye-sensitized solar cells (DSSCs) is worthwhile. In this paper, we detail how we synchronously prepared composite CEs of CoS nanosheet arrays and reduced graphene oxide (rGO) layers for the first time via a low temperature, ultrafast one-step electrochemical strategy. With this approach, the whole fabrication process of the composite CEs was only a small percentage of the average time (~15 hours) using other methods. The DSSC assembled with the rGO–CoS composite CE achieved an enhanced power conversion efficiency (PCE) of 8.34%, which is dramatically higher than 6.27% of pure CoS CE-based DSSC and even exceeds 7.50% of Pt CE-based DSSC. The outstanding PCE breakthrough is undoubtedly attributed to the enhancement in electrocatalytic ability of the rGO–CoS composite CE due to the incorporation of highly conducting rGO layers and the GO layers-induced growth of CoS nanosheet arrays with higher density and larger surface area. Therefore, lower charge-transfer resistance and higher exchange current density can be achieved as corroborated by the electrochemical impedance spectra (EIS) and Tafel polarization curves (TPCs). As a result, further experiments also proved that the electrochemical strategy exhibited its universality of fabricating other graphene-enhanced chalcogenide functional composite films.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2025

Driven probe particle dynamics in a bubble and pattern forming system

We numerically examine the dynamics of a probe particle driven at a constant force through an assembly of particles with competing long-range repulsion and short-range attraction that forms a bubble or stripe state. In the bubble regime, we identify several distinct types of motion, including an elastic or pinned regime where the probe particle remains inside a bubble and drags all other bubbles with it. There is also a plastic bubble phase where the bubble in which the probe particle is trapped is able to move past the adjacent bubbles. At larger drives, there is a breakthrough regime where the probe particle jumps from bubble to bubble and, in some cases, can induce correlated rotations or plastic rearrangements of the particles within the bubbles. At the highest drives, the probe particle moves sufficiently rapidly that the background particles undergo only small distortions. The distinctive dynamic flow states and the transitions between them are accompanied by signatures in the effective drag on the driven particle, jumps in the velocity–force curves, and changes in the time-dependent velocity fluctuations. We map the dynamic phase diagram for this system for varied interaction lengths, bubble sizes, and densities.

36 MATERIALS SCIENCE↗

DOE OSTI2019

A luminosity distribution for kilonovae based on short gamma-ray burst afterglows

The combined detection of a gravitational-wave signal, kilonova, and short gamma-ray burst (sGRB) from GW170817 marked a scientific breakthrough in the field of multimessenger astronomy. But even before GW170817, there have been a number of sGRBs with possible associated kilonova detections. In this work, we re-examine these ‘historical’ sGRB afterglows with a combination of state-of-the-art afterglow and kilonova models. This allows us to include optical/near-infrared synchrotron emission produced by the sGRB as well as ultraviolet/optical/near-infrared emission powered by the radioactive decay of r-process elements (i.e. the kilonova). Fitting the light curves, we derive the velocity and the mass distribution as well as the composition of the ejected material. The posteriors on kilonova parameters obtained from the fit were turned into distributions for the peak magnitude of the kilonova emission in different bands and the time at which this peak occurs. From the sGRB with an associated kilonova, we found that the peak magnitude in H bands falls in the range [-16.2, -13.1] (95 percent of confidence) and occurs within 0.8-3.6d after the sGRB prompt emission. In g band instead we obtain a peak magnitude in range [-16.8, -12.3] occurring within the first 18 h after the sGRB prompt. From the luminosity distributions of GW170817/AT2017gfo, kilonova candidates GRB130603B, GRB050709, and GRB060614 (with the possible inclusion of GRB150101B, GRB050724A, GRB061201, GRB080905A, GRB150424A, and GRB160821B) and the upper limits from all the other sGRBs not associated with any kilonova detection we obtain for the first time a kilonova luminosity distribution in different bands.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2021

Coupling dynamic in situ X-ray micro-imaging and indentation: A novel approach to evaluate micromechanics applied to oil shale

Oil and gas shales are a system where understanding the mechanical properties at the microscale is of paramount importance, e.g. to better understand the behavior of proppant-shale contacts and their role in the evolution of propped fractures in unconventional reservoirs. Here we show for the first time an experiment coupling indentation testing with in situ X-ray imaging in a Green River shale sample. A full compliance curve has been measured with the sample in water, allowing to visualize the indentation of the sample in function of axial load, in a purpose-built system for combined in situ indentation and X-ray imaging. A series of 3D datasets were used for a digital volume correlation study to obtain local strain fields. This analysis has been complemented with the analysis of cracks. Finally, geomechanical modeling has been carried out to replicate and generalize the observed behavior in the shale. This study validated this experimental approach, providing a breakthrough in understanding micro-mechanics in shales, and demonstrates how this class of experiments can be important for studies involving the prediction of the evolution of propped fractures in shale reservoirs, with possible applications in a much larger number of application fields (geothermal, materials science, etc.)

04 OIL SHALES AND TAR SANDS↗

DOE OSTI2016

3D printed cellular solid outperforms traditional stochastic foam in long-term mechanical response

3D printing of polymeric foams by direct-ink-write is a recent technological breakthrough that enables the creation of versatile compressible solids with programmable microstructure, customizable shapes, and tunable mechanical response including negative elastic modulus. However, in many applications the success of these 3D printed materials as a viable replacement for traditional stochastic foams critically depends on their mechanical performance and micro-architectural stability while deployed under long-term mechanical strain. To predict the long-term performance of the two types of foams we employed multi-year-long accelerated aging studies under compressive strain followed by a time-temperature-superposition analysis using a minimum-arc-length-based algorithm. The resulting master curves predict superior long-term performance of the 3D printed foam in terms of two different metrics, i.e., compression set and load retention. To gain deeper understanding, we imaged the microstructure of both foams using X-ray computed tomography, and performed finite-element analysis of the mechanical response within these microstructures. As a result, this indicates a wider stress variation in the stochastic foam with points of more extreme local stress as compared to the 3D printed material, which might explain the latter’s improved long-term stability and mechanical performance.

36 MATERIALS SCIENCE↗

DOE OSTI2017

Visualization and prediction of supercritical CO 2 distribution in sandstones during drainage: An in situ synchrotron X-ray micro-computed tomography study

Pore-scale distribution of supercritical CO 2 (scCO 2 ) exerts significant control on a variety of key hydrologic as well as geochemical processes, including residual trapping and dissolution. Despite such importance, only a small number of experiments have directly characterized the three-dimensional distribution of scCO 2 in geologic materials during the invasion (drainage) process. Here, we present a study which couples dynamic high-resolution synchrotron X-ray micro-computed tomography imaging of a scCO 2 /brine system at in situ pressure/temperature conditions with quantitative pore-scale modeling to allow direct validation of a pore-scale description of scCO2 distribution. The experiment combines high-speed synchrotron radiography with tomography to characterize the brine saturated sample, the scCO 2 breakthrough process, and the partially saturated state of a sandstone sample from the Domengine Formation, a regionally extensive unit within the Sacramento Basin (California, USA). The availability of a 3D dataset allowed us to examine correlations between grains and pores morphometric parameters and the actual distribution of scCO 2 in the sample, including the examination of the role of small-scale sedimentary structure on CO2 distribution. The segmented scCO 2 /brine volume was also used to validate a simple computational model based on the local thickness concept, able to accurately simulate the distribution of scCO 2 after drainage. The same method was also used to simulate Hg capillary pressure curves with satisfactory results when compared to the measured ones. Finally, this predictive approach, requiring only a tomographic scan of the dry sample, proved to be an effective route for studying processes related to CO 2 invasion structure in geological samples at the pore scale.

3D quantitative morphometric analysis↗

DOE OSTI2023

Enhanced Geothermal Shot Analysis for the Geothermal Technologies Office

In 2021, the U.S. Department of Energy (DOE) began the Energy Earthshots initiatives to accelerate breakthroughs of reliable clean energy solutions within the next 10 years. In 2022, the National Renewable Energy Laboratory (NREL) was asked by the DOE Geothermal Technologies Office (GTO) to provide analysis for developing Energy Earthshot targets for Enhanced Geothermal Systems (EGS), human-made underground reservoirs that extract thermal energy from the earth for electricity generation and/or heating applications. The Enhanced Geothermal Shot analysis is based on the technology assumptions in the 2019 GTO report GeoVision: Harnessing the Heat Beneath Our Feet. For Earthshot, we updated some of the technology cost and performance assumptions based on recent technology advances and updated the EGS resource potential to include more detailed analysis. We used the updated EGS supply cost curves to forecast the amount of geothermal electricity generation that could be deployed in the US by 2050 using a capacity expansion model. The results were used to develop a cost target for EGS. On September 8th, 2022, the Enhanced Geothermal Shot was announced. Its target - reduce the cost of EGS by 90%, to $45 per megawatt hour by 2035. This paper summarizes the cost and resource assumptions used in the Enhanced Geothermal Shot. It describes the assumptions used in the Regional Energy Deployment System (ReEDS) capacity expansion model to forecast geothermal deployment and discusses the results.

15 GEOTHERMAL ENERGY↗

DOE OSTI2023

Enhanced Geothermal Shot Analysis for the Geothermal Technologies Office: Preprint

analysis↗

NASA NTRS2006

A Preliminary Foil Gas Bearing Performance Map

Recent breakthrough improvements in foil gas bearing load capacity, high temperature tribological coatings and computer based modeling have enabled the development of increasingly larger and more advanced Oil-Free Turbomachinery systems. Successful integration of foil gas bearings into turbomachinery requires a step wise approach that includes conceptual design and feasibility studies, bearing testing, and rotor testing prior to full scale system level demonstrations. Unfortunately, the current level of understanding of foil gas bearings and especially their tribological behavior is often insufficient to avoid developmental problems thereby hampering commercialization of new applications. In this paper, a new approach loosely based upon accepted hydrodynamic theory, is developed which results in a "Foil Gas Bearing Performance Map" to guide the integration process. This performance map, which resembles a Stribeck curve for bearing friction, is useful in describing bearing operating regimes, performance safety margins, the effects of load on performance and limiting factors for foil gas bearings.

DellaCorte, Christopher↗

NASA NTRS2003

Estimating Terrestrial Carbon Exchange from Space: How Often and How Well?

Data from a new space mission measuring integrated light-use efficiency could provide a breakthrough in understanding of global carbon, water, and energy dynamics, and greatly improve the accuracy of model predictions for terrestrial carbon cycles and climate. Over the past decade, Gamon and others have shown that changes in photo-protective pigments are sensitive indicators of declines in light-use efficiency of plants and plant canopies. The requirements for integrated diurnal measurements from space need to be defined, before a space mission can be formulated successfully using this concept. We used towerbased CO 2 flux data as idealized proxies for remote measurements, examining their sampling properties. Thousands of half-hourly CO 2 flux measurements are needed before their average begins to converge on an average annual net CO 2 exchange. Estimates of daily integrated fluxes (i.e., diurnal curves) are more statistically efficient, especially if the spacing between measured days is quasiregular, rather than random. Using a few measurements per day one can distinguish among days with different net CO 2 exchanges. Fluxes sampled between mid-morning to mid-afternoon are more diagnostic than early morning or late afternoon measurements. Similar results (correlation >0.935) were obtained using 2 measurements per day with high accuracy ([:plusmn:]5%), 3 measurements per day with medium accuracy ([:plusmn:] 10%), or 5 measurements per day at lower accuracy ([:plusmn:]20%). An observatory in a geosynchronous or near-geosynchronous orbit could provide appropriate observations, as could a multi-satellite constellation in polar orbits, but there is a potential trade-off between the required number of observations per day and quality of each observation.

Knox, Robert G.↗

NASA NTRS1993

The coming technological singularity: How to survive in the post-human era

The acceleration of technological progress has been the central feature of this century. I argue in this paper that we are on the edge of change comparable to the rise of human life on Earth. The precise cause of this change is the imminent creation by technology of entities with greater than human intelligence. There are several means by which science may achieve this breakthrough (and this is another reason for having confidence that the event will occur): (1) the development of computers that are 'awake' and superhumanly intelligent (to date, most controversy in the area of AI relates to whether we can create human equivalence in a machine. But if the answer is 'yes, we can', then there is little doubt that beings more intelligent can be constructed shortly thereafter); (2) large computer networks (and their associated users) may 'wake up' as a superhumanly intelligent entity; (3) computer/human interfaces may become so intimate that users may reasonably be considered superhumanly intelligent; and (4) biological science may find ways to improve upon the natural human intellect. The first three possibilities depend in large part on improvements in computer hardware. Progress in computer hardware has followed an amazingly steady curve in the last few decades. Based largely on this trend, I believe that the creation of greater than human intelligence will occur during the next thirty years.

Vinge, Vernor↗

DOE OSTI2017

Relativistic Light Sails

One proposed method for spacecraft to reach nearby stars is by accelerating sails using either solar radiation pressure or directed energy. This idea constitutes the thesis behind the Breakthrough Starshot project, which aims to accelerate a gram-mass spacecraft up to one-fifth the speed of light toward Proxima Centauri. For such a case, the combination of the sail’s low mass and relativistic velocity renders previous treatments incorrect at the 10% level, including that of Einstein himself in his seminal 1905 paper introducing special relativity. To address this, we present formulae for a sail’s acceleration, first in response to a single photon and then extended to an ensemble. We show how the sail’s motion in response to an ensemble of incident photons is equivalent to that of a single photon of energy equal to that of the ensemble. We use this principle of ensemble equivalence for both perfect and imperfect mirrors, enabling a simple analytic prediction of the sail’s velocity curve. Using our results and adopting putative parameters for Starshot , we estimate that previous relativistic treatments underestimate the spacecraft’s terminal velocity by ∼10% for the same incident energy. Additionally, we use a simple model to predict the sail’s temperature and diffraction beam losses during the laser firing period; this allows us to estimate that, for firing times of a few minutes and operating temperatures below 300°C (573 K), Starshot will require a sail that absorbs less than one in 260,000 photons.

79 ASTRONOMY AND ASTROPHYSICS↗