Localization in disordered materials - Binary alloys
Electron states localization in disordered binary alloys, describing band structure
Cohen, M. H.↗
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High voltage electron microscopy and electron diffraction of lunar pyroxenes
Apollo 11 lunar rock pyroxenes, examining band structure and magnetic ordering by high voltage electron microscopy and electron diffraction
Fernandez-Moran, H.↗
Localization in disordered materials - Existence of mobility edges
Disordered materials electronic structure band states localization, examining mobility edges
Cohen, M. H.↗
Theoretical calculation of plane wave speeds for alkali metals under pressure.
Theoretical calculations of the variation with pressure of small amplitude plane wave speeds are performed for sodium and potassium at zero temperature. The results obtained for wave speeds associated with volume dependent second-order elastic coefficients show better agreement with experimental data than for wave speeds associated with shear dependent coefficients. This result is believed to be due to omission of the band structure correction to the strain energy density.
Eftis, J.↗
Development of gallium aluminum phosphide electroluminescent diodes
Work done on the development of gallium aluminum phosphide alloys for electroluminescent light sources is described. The preparation of this wide band gap semiconductor alloy, its physical properties (particularly the band structure, the electrical characteristics, and the light emitting properties) and work done on the fabrication of diode structures from these alloys are broadly covered.
Chicotka, R. J.↗
Astronomical Fourier spectropolarimetry
Spectra of the Stokes polarization parameters of Venus (resolution 0.5 per cm) are presented. They were obtained at the Cassegrain focus of the 154-cm telescope of the National Mexican Observatory, Baja California, Mexico, July 12 and 13, 1972, with the Fourier Interferometer Polarimeter (FIP). A preliminary, limited analysis of four spectral features and of the CO2 rotational band structures at 6080 and 6200 per cm has demonstrated that spectral polarization is indeed present. These experimental results, confirmed by two series of observations, provide substantiation for this theoretically predicted phenomenon. They also tend to show that the FIP represents a novel astronomical tool for variable spectral resolution studies of both the intensity and the state of polarization of astronomical light sources.
Forbes, F. F.↗
Magnetic field generated resistivity maximum in graphite
In zero magnetic field, B, the electrical resistivity, rho(O,T) of highly oriented pyrolytic (polycrystalline) graphite drops smoothly with decreasing T, becoming constant below 4 K. However, in a fixed applied magnetic field B, the resistivity rho(B,T) goes through a maximum as a function of T, with larger maximum for larger B. The temperature of the maximum increases with B, but saturates to a constant value near 25 K (exact T depends on sample) at high B. In single crystal graphite a maximum in rho(B,T) as a function of T is also present, but has the effects of Landau level quantization superimposed. Several possible explanations for the rho(B,T) maximum are proposed, but a complete explanation awaits detailed calculations involving the energy band structure of graphite, and the particular scattering mechanisms involved.
Wollam, J. A.↗
Phase separation of metallic hydrogen-helium alloys
Calculations are presented for the thermodynamic functions and phase separation boundaries of solid metallic hydrogen helium alloys at temperatures between 0 K and 19,000 K and at pressures between 15 and 90 megabars. Expressions for the band structure energy of a randomly disordered alloy (including third order in the electron ion interaction) are derived and evaluated. Short and long range order are included by the quasi-chemical method, and lattice dynamics in the virtual crystal harmonic approximation. We conclude that at temperatures below 4,000 K there is complete phase separation of hydrogen helium alloys, and that a miscibility gap remains at the highest temperatures and pressures considered. The relevance of these results to models of the deep interior of Jupiter is briefly discussed.
Straus, D. M.↗
Magnetic field generated resistivity maximum in graphite
In a zero magnetic field, the electrical resistivity of highly oriented pyrolytic (polycrystalline) graphite drops smoothly with decreasing temperature, becoming constant below 4 K. However, in a fixed applied magnetic field, the resistivity goes through a maximum as a function of temperature, with a larger maximum for a larger field intensity. The temperature of the maximum increases with field intensity, but saturates to a constant value near 25 K (the exact temperature depends on the sample) at high intensity. In single-crystal graphite, a maximum in resistivity as a function of temperature is also present, but has the effects of Landau level quantization superimposed. Several possible explanations for the resistivity maximum are proposed, but a complete explanation awaits detailed calculations involving the energy band structure of graphite, and the particular scattering mechanisms involved.
Woollam, J. A.↗
On the lattice dynamics of metallic hydrogen and other Coulomb systems
Numerical results for the phonon spectra of metallic hydrogen and other Coulomb systems in cubic lattices are presented. In second order in the electron-ion interaction, the behavior of the dielectric function of the interacting electron gas for arguments around the seond Fermi harmonic leads to drastic Kohn anomalies and even to imaginary phonon frequencies. Third-order band-structure corrections are also calculated. Properties of self-consistent phonons and the validity of the adiabatic approximation are discussed.
Beck, H.↗
Phase separation of metallic hydrogen-helium alloys
Calculations are presented for the thermodynamic functions and phase-separation boundaries of solid metallic hydrogen-helium alloys at temperatures between zero and 19,000 K and at pressures between 15 and 90 Mbar. Expressions for the band-structure energy of a randomly disordered alloy (including third order in the electron-ion interaction) are derived and evaluated. Short- and long-range orders are included by the quasi-chemical method, and lattice dynamics in the virtual-crystal harmonic approximation. It is concluded that at temperatures below 4000 K, there is essentially complete phase separation of hydrogen-helium alloys and that a miscibility gap remains at the highest temperatures and pressures considered. The relevance of these results to models of the deep interior of Jupiter is briefly discussed.
Straus, D. M.↗
Inverse isotope effect and the x dependence of the superconducting transition temperature in PdHx and PdDx
First-principles electron-band-structure calculations and measured phonon properties are employed in a calculation of the concentration dependence of the superconducting transition temperatures for PdHx and PdDx, including the inverse isotope effect. Excellent agreement with the experimental results is obtained. Our model also gives a qualitative understanding of the enhanced transition temperatures in the palladium-noble-metal hydrides.
Klein, B. M.↗
Study of polyphenyl ether fluid /5P4E/ in operating elastohydrodynamic contacts by infrared emission spectroscopy
Infrared emission spectra of 5P4E polyphenyl ether were obtained from an operating elastohydrodynamic sliding contact at different speeds and loads by Fourier emission microspectrophotometry. The spectra were found to be polarized with respect to the direction of the conjunction line, especially at high shear rates. Film and metal surface temperatures were calculated from the spectra, and film thicknesses were determined under various operating conditions. Changes of polarized band structure above a critical shear rate, at which the slope of the film temperature versus shear curve changes abruptly and at which the film thickness assumes a minimum value, are consistent with a transition of the lubricant from a viscous liquid to a viscoelastic liquid or to an elastic solid.
Lauer, J. L.↗
Iodine monofluoride emission spectrum and formation kinetics in electron-beam-produced plasmas
The observation of intense blue-green spontaneous emission attributed to IF from electron-beam-excited Ar/CF3I/NF3 gas mixtures is reported. Intense emission from a structured band centered at a wavelength of 484 nm was observed when mixtures of 2000-4000 Torr AR (or He or Ne), 3 Torr CF3I and 1 Torr NF3 (or F2) were irradiated with a 3-nsec FWHM electron beam. Analysis of ICl and IBr spectra, which the present spectrum closely resembles, indicates that the 484-nm emission originates from the E to A 3 pi 1 transition of IF. Examination of the time dependence of metastable IF and I2 emission reveals that the IF (E) level is formed primarily by excitation transfer from metastable I(4P) states. The fluorescence efficiency of the E-A transition and the radiative lifetime of the metastable IF (E) state are estimated to be approximately 6% and 15 nsec, respectively, and it is suggested that metastable IF is an attractive candidate for a blue-green laser.
Hutchison, S. B.↗
Fluorescence equilibrium in the ultraviolet spectra of Comets Seargent (1978 m) and Bradfield (1979 l)
Detailed fluorescence calculations for OH including the Swings effect were performed. These calculations were used to reproduce the high resolution spectra of Comets Seargent and Bradfield taken with IUE. The calculations also provide the OH fluorescence efficiencies (g factors), as a function of heliocentric radial velocity, which are needed to derive OH abundances from measured fluxes. A close examination of the spectra shows no sign of the corresponding emission bands of OD allowing upper limits to be placed on the ratio N(OD)/N(OH). Preliminary attempts to reproduce the CO+ band structure by fluorescence are discussed.
Donn, B.↗
The atmospheres of Jupiter, Saturn and Titan
Spacecraft observations of Jupiter, Saturn and Titan are discussed. The relative abundance of helium differs for the two planets, being about 10% for Jupiter and 6% for Saturn. These ratios are consistent with the same age of the planets and internal heat fluxes as measured; Saturn emits IR at about 2.5 to 3 times the incident solar flux, while Jupiter emits about 1.8 to 2 times. Jupiter's zonal jet system is more stable than the colorful markings on the planet. Anticyclonic and cyclonic motions are observed, with the Great Red Spot being the most prominent anticyclonic system. Compared with Jupiter, peak zonal velocities on Saturn are three times higher, reaching two-thirds of the speed of sound near the equator. The zonal jets are much wider and do not have any clear relation to the banded structure. Saturn lacks large oval spots, although features of diameter 1000 km are more abundant than on Jupiter. Titan's atmosphere consists of nitrogen (82%) methane (6%) H2 (0.2%) and, possibly, Argon (12%)
Bauer, S. J.↗
Quantum chemical calculations for polymers and organic compounds
The relativistic effects of the orbiting electrons on a model compound were calculated. The computational method used was based on 'Modified Neglect of Differential Overlap' (MNDO). The compound tetracyanoplatinate was used since empirical measurement and calculations along "classical" lines had yielded many known properties. The purpose was to show that for large molecules relativity effects could not be ignored and that these effects could be calculated and yield data in closer agreement to empirical measurements. Both the energy band structure and molecular orbitals are depicted.
Lopez, J.↗
Luminescence induced by dehydration of kaolin - Association with electron-spin-active centers and with surface activity for dehydration-polymerization of glycine
Experimental data concerning emission of light upon dehydration as a function of preheating and pre-gamma-irradiation are correlated with reported studies of electron-spin resonance (ESR) activity after similar pretreatments. The effect of these pretreatments on the kaolin-promoted incorporation of glycine into peptide oligomers in a wet/cold, hot/dry fluctuating environment is compared to their effect on the ESR and luminescent signals. The existence of spectroscopically active centers appears to be loosely anticorrelated with reaction yield; these yields are increased by increasing the overall energy content of the material. It is concluded that some part of the chemical yield is produced by a mechanism involving intrinsic, excited electronic states of the clay crystal lattice. These states may be derived from thermally, interfacially, and/or mechanically induced charge reorganization within interspersed energy levels in the band structure of the material.
Coyne, L.↗