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At least 145 records · Page 8

Role of chalcogen vacancies and hydrogen in the optical and electrical properties of bulk transition-metal dichalcogenides

Abstract Like in any other semiconductor, point defects in transition-metal dichalcogenides (TMDs) are expected to strongly impact their electronic and optical properties. However, identifying defects in these layered two-dimensional materials has been quite challenging with controversial conclusions despite the extensive literature in the past decade. Using first-principles calculations, we revisit the role of chalcogen vacancies and hydrogen impurity in bulk TMDs, reporting formation energies and thermodynamic and optical transition levels. We show that the S vacancy can explain recently observed cathodoluminescence spectra of MoS 2 flakes and predict similar optical levels in the other TMDs. In the case of the H impurity, we find it more stable sitting on an interstitial site in the Mo plane, acting as a shallow donor, and possibly explaining the often observed n-type conductivity in some TMDs. We also predict the frequencies of the local vibration modes for the H impurity, aiding its identification through Raman or infrared spectroscopy.

36 MATERIALS SCIENCE↗

Modulating the Pseudoelastic Response of NiTi Using Ion Implantation

Ni-ion irradiated NiTi is nearly 50% harder, retains 85% recoverable deformation, and has reduced hysteresis. This work explores the feasibility of using ion beam modification to modulate the austenite to martensite phase transformation in NiTi, thereby achieving novel or localized properties in near-surface regions.

36 MATERIALS SCIENCE↗

Multidisciplinary applications of ERTS and Skylab data in Ohio

Experimental studies of ERTS-1 and Skylab earth resources data, in combination with correlative aircraft and on-site data, for environmental quality, land use, and resource management applications in Ohio show several areas of operational promise. Prime data use candidates demonstrated to date include definition and enforcement of surface mining (all minerals) legislation; Lake Erie modeling/management; land use classification and mapping studies at state, regional, and localized levels; and resources' inventories particularly of forested areas on both regional (multicounty) and localized scales.

Sweet, D. C.↗

Foundations of variational discrete action theory

Variational wave functions and Green's functions are two important paradigms for solving quantum Hamiltonians, each having their own advantages. Here we detail the variational discrete action theory (VDAT), which exploits the advantages of both paradigms in order to approximately solve the ground state of quantum Hamiltonians. VDAT consists of two central components: the sequential product density matrix (SPD) ansatz and a discrete action associated with the SPD. The SPD is a variational ansatz inspired by the Trotter decomposition and characterized by an integer $\mathscr{N}$, recovering many well-known variational wave functions, in addition to the exact solution for $\mathscr{N}$ = ∞. The discrete action describes all dynamical information of an effective integer time evolution with respect to the SPD. We generalize the path integral to our integer time formalism, which converts a dynamic correlation function in integer time to a static correlation function in a compound space. We also generalize the usual many-body Green's function formalism to integer time, which results in analogous but distinct mathematical structures, yielding integer time versions of the generating functional, Dyson equation, and Bethe-Salpeter equation. We prove that the SPD can be exactly evaluated in the multiband Anderson impurity model (AIM) by summing a finite number of diagrams. For the multiband Hubbard model, we prove that the self-consistent canonical discrete action approximation (SCDA), which is the integer time analog of the dynamical mean-field theory, exactly evaluates the SPD for d = ∞. VDAT within the SCDA provides an efficient yet reliable method for capturing the local physics of quantum lattice models, which will have broad applications for strongly correlated electron materials. More generally, VDAT should find applications in various many-body problems in physics.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Explorer 45 wave observations during the large magnetic storm of August 4-5, 1972

The magnetospheric compression associated with the very large magnetic storm of August 4-5, 1972, provided an opportunity for Explorer 45 to observe plasma waves in the magnetosphere and the magnetosheath during extremely disturbed conditions. Electrostatic noise bursts were observed near the plasmapause in electric-field channels from 35 Hz to 5.62 kHz. In the outer magnetosphere, electric-field noise bands apparently harmonically related to the electron gyrofrequency with components as low as 3 kHz and as high as 50 kHz were observed. The electric field of the fundamental was perpendicular to the magnetic-field vector. A mechanism including the electron cyclotron instability may generate the noise band. Hiss of 100-1000 Hz was observed in the outer magnetosphere. The electromagnetic hiss was generally weak and was observed in the magnetic wide-band data only when it was strong. In the magnetosheath broad band, incoherent noise (hiss) was observed from 1 Hz to 100 kHz. This magnetosheath hiss was the strongest phenomenon observed by the plasma-wave detectors during the lifetime of Explorer 45. The highest intensities of magnetosheath hiss occurred at the magnetopause. Its broad-band nature suggests that magnetosheath hiss was generated locally. Broad-band noise bursts and short bursts of chorus were also observed in the magnetosheath.

Taylor, W. W. L.↗

Modelling of physical influences in sea level records for vertical crustal movement detection

Attempts to specify and evaluate such physical influences are reviewed with the intention of identifying problem areas and promising approaches. An example of linear modelling based on air/water temperatures, atmospheric pressure, river discharges, geostrophic and/or local wind velocities, and including forced period terms to allow for the long period tides and Chandlerian polar motion is evaluated and applied to monthly mean sea levels recorded in Atlantic Canada. Refinement of the model to admit phase lag in the response to some of the driving phenomena is demonstrated. Spectral analysis of the residuals is employed to assess the model performance. The results and associated statistical parameters are discussed with emphasis on elucidating the sensitivity of the technique for detection of local episodic and secular vertical crustal movements, the problem areas most critical to the type of approach, and possible further developments.

Anderson, E. G.↗

A statistical study of Pc 3-5 pulsations observed by the AMPTE/CCE magnetic fields experiment. I - Occurrence distributions

A classification system based on dynamic power spectra of AMPTE/CCE magnetic field data has been developed which allows semiquantitative specification of pulsation activity at all times. Fifteen months of 6.24-s AMPTE/CCE magnetic field data have been analyzed using this scheme to generate a comprehensive data base of all pulsation activity observed from L = 5 to L = 9 at all local times in the frequency range 0-80 mHz. The pulsation divide naturally into five basic categories: toroidal fundamental mode resonances, toroidal harmonic resonances, compressional low-frequency waves, radially polarized waves, and disturbed intervals. Additional distinctions among members of these classes are made to arrive at 14 categories which describe 95 percent of the pulsations observed. Normal spatial distributions in local time and L shell are determined for each category. Magnetic latitude distributions are determined for four coherent categories of activity.

Anderson, B. J.↗

Carbon star luminosity indicators

Results are presented of a proper motion survey of known faint high-latitude C stars using plates spanning a 30-yr baseline that reveals at least one additional new dwarf C star and also confirms the utility of the proposed luminosity indicators. Kinematic simulations suggest that to a limit of V of about 18, at least 10 percent of faint high-latitude C stars are dwarfs. The local space density of dwarf C stars may thus substantially exceed that of luminous C stars.

Green, Paul J.↗

Magmatic-Tectonic Evolution of Tharsis

The tectonic history of the western hemisphere region of Mars was dominated by the formation of the Tharsis rise. In this study, we identify local centers of tectonic activity and examine how each of the centers fit into the overall evolution of the Tharsis region.

Anderson, R. C.↗

Survey of Coherent Approximately 1 Hz Waves in Mercury's Inner Magnetosphere from MESSENGER Observations

We summarize observations by the MESSENGER spacecraft of highly coherent waves at frequencies between 0.4 and 5 Hz in Mercury's inner magnetosphere. This survey covers the time period from 24 March to 25 September 2011, or 2.1 Mercury years. These waves typically exhibit banded harmonic structure that drifts in frequency as the spacecraft traverses the magnetic equator. The waves are seen at all magnetic local times, but their observed rate of occurrence is much less on the dayside, at least in part the result of MESSENGER's orbit. On the nightside, on average, wave power is maximum near the equator and decreases with increasing magnetic latitude, consistent with an equatorial source. When the spacecraft traverses the plasma sheet during its equatorial crossings, wave power is a factor of 2 larger than for equatorial crossings that do not cross the plasma sheet. The waves are highly transverse at large magnetic latitudes but are more compressional near the equator. However, at the equator the transverse component of these waves increases relative to the compressional component as the degree of polarization decreases. Also, there is a substantial minority of events that are transverse at all magnetic latitudes, including the equator. A few of these latter events could be interpreted as ion cyclotron waves. In general, the waves tend to be strongly linear and characterized by values of the ellipticity less than 0.3 and wave-normal angles peaked near 90 deg. Their maxima in wave power at the equator coupled with their narrow-band character suggests that these waves might be generated locally in loss cone plasma characterized by high values of the ratio beta of plasma pressure to magnetic pressure. Presumably both electromagnetic ion cyclotron waves and electromagnetic ion Bernstein waves can be generated by ion loss cone distributions. If proton beta decreases with increasing magnetic latitude along a field line, then electromagnetic ion Bernstein waves are predicted to transition from compressional to transverse, a pattern consistent with our observations. We hypothesize that these local instabilities can lead to enhanced ion precipitation and directly feed field-line resonances.

ultra-low-frequency↗

E2C Cohorts: Implementation Funding Projects - Impact Summary [Slides]

From August 2024 to October 2025, 11 Clean Cities and Communities coalitions supported projects to advance transportation goals by gathering input from local stakeholders, and using the resulting insights to develop new plans and programs for local partners. This effort leveraged information and best practices shared during the 2024 E2C Cohort on Integrating Community Priorities into Electric Vehicle Plans and Projects. These coalitions supported partners across the country to develop plans for electric vehicle integration through one-on-one technical assistance and tailored local engagement. This deck summarizes the individual projects completed by coalitions, and the overall reach and impact of all of this program.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Rocket measurement of OH in the mesosphere.

A volume density profile of the OH radical throughout the 45- to 70-km region of the earth's upper atmosphere is presented. A high-resolution polarized Ebert-Fastie spectrometer flown aboard a sounding rocket was used to obtain the data. The molecule was found to have a scale height significantly greater than that of the atmosphere, with local densities of 4.4 million/cu cm at 50 km, 5.5 million/cu cm at 60 km, and 3.5 million/cu cm at 70 km.

Anderson, J. G.↗

Operating cost model for local service airlines

Several mathematical models now exist which determine the operating economics for a United States trunk airline. These models are valuable in assessing the impact of new aircraft into an airline's fleet. The use of a trunk airline cost model for the local service airline does not result in representative operating costs. A new model is presented which is representative of the operating conditions and resultant costs for the local service airline. The calculated annual direct and indirect operating costs for two multiequipment airlines are compared with their actual operating experience.

Anderson, J. L.↗