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At least 145 records · Page 8

Reaction of beta-phase Ni-Al alloys with CrB2

Reaction of Ni-Al alloys within the beta-NiAl phase with CrB2 was studied at 1473 K as a function of Al concentration in the alloy. Reaction of 49-50 at. pct Al alloys with CrB2 occurred by interdiffusion of Ni into CrB2 and Cr into the alloy without forming a new product phase. On the other hand, a new product phase, rich in Ni and B, formed by the reaction of alloys having Al concentrations 48 at. pct or lower with CrB2. The reaction product was observed both at the CrB2/alloy interface and along the alloy grain boundaries.

Misra, Ajay K.↗

The effect of H2O gas on volatilities of planet-forming major elements. I - Experimental determination of thermodynamic properties of Ca-, Al-, and Si-hydroxide gas molecules and its application to the solar nebula

The vapor pressures of Ca(OH)2(g), Al(OH)3(g), and Si(OH)4(g) molecules in equilibrium with solid calcium-, aluminum, and silicon-oxides, respectively, were determined, and were used to derive the heats of formation and entropies of these species, which are expected to be abundant under the currently postulated physical conditions in the primordial solar nebula. These data, in conjunction with thermodynamic data from literature, were used to calculate the relative abundances of M, MO(x), and M(OH)n gas species and relative volatilities of Fe, Mg, Si, Ca, and Al for ranges of temperature, total pressure, and H/O abundance ratio corresponding to the plausible ranges of physical conditions in the solar nebula. The results are used to explain how Ca and Al could have evaporated from Ca,Al-rich inclusions in carbonaceous chondrites, while Si, Mg, and Fe condensed onto them during the preaccretion alteration of CAIs.

Hashimoto, Akihiko↗

Combustion synthesis of TiB2-Al2O3-Al composite materials

The oxide-aluminum exothermic reduction reaction is presently used in the combustion-synthesis of ceramic/metal composites. An excess of Al is used in the reacting materials, which rapidly generate enough heat to exceed Al's melting point. The molten Al thus evolved is allowed to infiltrate the porous ceramic matrix as the exothermic reaction proceeds; this feature of the process turns the disadvantage of high porosity levels in combustion-synthesized materials into an advantage. Attention is given to the system obtained with 3TiO2 + 3B2O3 + (10-x)Al starting materials.

Feng, H. J.↗

Redistribution of Ti and Al in deuterium charged TiAl

The redistribution of titanium and aluminum in a single-phase TiAl alloy that has been exposed to a high pressure of deuterium gas at high temperature is studied. The microstructure in the as-received, uncharged condition consisted of single-phase gamma TiAl grains and a random distribution of precipitates. Precipitates were distributed throughout the matrix and along the grain boundaries. The chemistry of the precipitates varied considerably; some were rich in Al, while other were mostly Ti with some Si and Al. The dislocation density in most grains was low, although in a few grains a high dislocation density was observed. FCC deuterides with a lattice parameter of 0.45 nm form in a Ti-52.1Al-2.1Ta (at. pct) alloy after exposure to 1.38 MPa of deuterium gas at 650 C for 213 hr. The structure and lattice parameter are consistent with the formation of Ti(l)D2. The deuterides that form in this alloy are enriched in Ti and deficient in Al and Ta compared to the deuteride-free matrix. Regions of the matrix contiguous with the deuterides have a correspondingly enhanced aluminum and tantalum concentration.

Legzdina, D.↗

Al Umchaimin depression, Western Iraq: An impact structure?

Al Umchaimin, in Arabic 'hiding place' or 'place of ambush', is located at latitude 32 degrees 35.5 N and longitude 39 degrees 25 E. The nearly circular depression averages 2.75 km in diameter and is 33-42 m deep. It is floored with fine-grained, clay-rich deposits, estimated to be 36 m thick, the surface of which shows well-developed desiccation fissures or mudcracks when dry. Because of its nearly circular planimetric shape and its apparent isolation from other surface and subsurface features, it has been considered by some to be a possible meteorite impact structure and by others to be a surface collapse feature that originated following removal of magma from the subsurface as the magma extruded elsewhere. Al Umchaimin was listed in the U.S. Geological Survey tabulation of 110 structures worldwide for which a meteorite impact origin had been suggested. It was placed in Category 6 Structures for which more data are required for classification. It is concluded that, on the basis of the studies that have been made of Al Umchaimin and on the basis of the brief site visit made, Al Umchaimin probably is not an impact structure but most likely resulted from the enlargement and coalescence of sink holes and eventual collapse of the roof material into the resulting cavity.

Underwood, James R., Jr.↗

The fracture resistance of 1420 and 1421 Al-Mg-Li alloys

The resistance to stable crack growth in 1420-T6 (Al-5Mg-2.1Li-0.1Zr-0.01Sc, less than 0.06Fe, in wt pct) and 1421-T6 (Al-4.7Mg-1.9Li-0.09Zr-0.2Sc, less than 0.06Fe) Al-Mg-Li alloys was investigated, based on the R curves generated in accordance with ASTM E561-86 and fractography analyses. The crack resistance of 1420 and 1421 alloys was found to be comparable to that of the conventional Space Shuttle External Tank Al alloy, 2219-T87. The main differences in the fracture behaviors arose from differences in the alloys' microstructures. In the case of 1420 alloy, a slightly enhanced toughness behavior was observed, due to the T-phase precipitates, which may have promoted more homogeneous deformation and enhanced microvoid coalescence. In the case of 1421 alloy, the addition of Sc led to a refined grain size and resulted in slightly reduced toughness.

Birt, M. J.↗

Comment on 'The effect of liquid water on thunderstorm charging' by C.P.R. Saunders et al

This paper is a comment on the claims made in the paper by Saunders et al. (1991), which reports on a laboratory simulation of ice particle charging in thunderstorms, concerning the microphysical condition of riming ice particles and the conditions for sublimation and negative charging in thunderclouds. It is argued that the interpretation of Saunders is contrary to the findings of Williams et al. (1991), which support the hypothesis that sublimating graupel charge negatively (in collision with smaller ice particles) and graupel in deposition charge positively. Based on microphysical calculations as well as observations in thunderclouds, it is concluded that, while sublimation of the rimer surface and negative charging do not appear to account for the laboratory observations reported by Saunders et al., these authors do not have sufficient evidence for rejecting the sublimation hypothesis presented by Williams et al. (1991) for thunderstorms.

Williams, Earle↗

Ellipsometric characterization of In(0.52)Al(0.48)As and of modulation doped field effect transistor structures on InP substrates

The dielectric function of a thick layer of In(0.52)Al(0.48)As lattice matched to InP was measured by variable angle spectroscopic ellipsometry in the range 1.9-4.1 eV. The In(0.52)Al(0.48)As was protected from oxidation using a thin In(0.53)Ga(0.47)As cap that was mathematically removed for the dielectric function estimate. The In(0.52)Al(0.48)As dielectric function was then verified by ellipsometric measurements of other In(0.53)Ga(0.47)As/In(0.52)Al(0.48)As structures, including (MODFET), and is shown to provide accurate structure layer thicknesses.

Alterovitz, S. A.↗

Al-26 production profile and model comparisons in Canyon Diablo

The large preatmospheric size of the Canyon Diablo meteorite, a radius of about 15 m, makes it especially suitable for systematic studies of cosmogenic nuclide production rates of iron objects in a 2 pi geometry. To reconstruct the exposure history of the meteoroid, Heymann et al. investigated several fragments recovered from known geographic locations around the crater for their shock features and cosmogenic nobel gases. They applied the Signer-Nier noble gas production rate model to establish the preatmospheric depth of the specimens in the meteoroid. Cosmic ray exposure ages suggested a multi-episodic irradiation, with 170 or 540 Ma being inferred for most of the samples studied while two anomalous specimens indicated a possible third exposure age at 940 Ma. Be-10 and Cl-36 have been measured in a number of these same samples by accelerator mass spectrometry (AMS), with use being made of the preatmospheric depths determined in Heymann et al. to construct production profiles. The present study extends the cosmogenic radionuclide data to Al-26 and compares the results with both the production rate model of Reedy and Arnold and production rates determined from the cross sections used by the Reedy-Arnold model (for the major nuclear reactions making Al-26) in combination with differential fluxes calculated using the Los Alamos High Energy Transport (LAHET) Code System. Model calculations for Be-10 and Cl-36 have also been obtained.

Michlovich, E.↗

Al-26 and circumstellar envelopes

The effects of the radioactive decay of Al-26 on the circumstellar envelopes of asymptotic giant branch stars are analyzed. The gamma-rays emitted by the product nucleus Mg-26 escape most envelopes, but the beta-decay positrons are stopped and can ionize and heat the gas. The ionization may produce observable effects in C-rich circumstellar envelopes, particularly if the photospheric Al-26 abundance is as large as inferred from measurements of live Al-26 in the primitive solar nebula or the observations of interstellar 1.8 MeV gamma-rays. For the nearby carbon star IRC +10216, the measured abundance of the molecular ion HCO(+) provides an upper limit of about 4 x 10(exp -3) for the photospheric Al-26/Al-27 ratio, consistent with presolar SiC grains with about the same C-12/C-13 ratio.

Glassgold, A. E.↗

GRIS detection of Al-26 1809 keV line emission from the Galactic center region as a broad line

The gamma ray imaging spectrometer (GRIS) was used to observe the 1809 keV emission from the Galactic center region. The observed line is broader than the instrument resolution. The measured intrinsic width is 5.4 +/- 1.4 keV full width half medium, which is more than three times the maximum Doppler broadening expected due to Galactic rotation. The detection of such a wide feature, suggesting a high dispersion velocity has implications for the origin of Galactic Al-26. It suggests a supernova explosion origin or a Wolf-Rayet stellar wind origin of Al-26. The fact that the Al-26 has not come to rest after 10(exp 6) years presents a challenge to the current understanding of the Al-26 production and propagation in the Galaxy.

Naya, Juan E.↗

Analysis of X-Ray Microradiographs of Al-Au Interface Quench Profile using Modeling of Solidification Including Double-Diffusion and Convection in the Melt

Experimental data on Al-0.8Au horizontal solidification of a 1 mm thick specimen in a BN crucible shows the effect of growth rate on the solidification interface shape. For translation rates below 0.5 micron/s the interface maintains a plain and flat shape. When the translation rate is 3 to 5 micron/s or more, the interface appearance changes to two planar zones, with the zone closer to the bottom having higher inclination. The interface shapes were measured by first quenching in place during growth. X-ray microscopy shows the interface shape within the quenched sample by viewing through the side of the specimen. In order to provide theoretical explanation of the phenomena, numerical modeling was undertaken using finite element code FIDAP. Double diffusion convection in Al-0.8Au melt and crystal-melt interface curvature during directional solidification was analyzed numerically. Actual thermophysical properties of Al-0.8Au including the binary Al-Au phase diagram were used. Although convection in the sample is weak, for the slower translation rate convection and diffusion is sufficient for the redistribution of initial compositional stratification caused by gravity. When translation rate is raised, neither convection nor diffusion can provide proper mixing so that solidification temperatures differ significantly near the bottom within the bulk of the sample. As a result, the solid-liquid interface appears to have two planar zones with different inclination.

Bune, Andris V.↗

P/N In(Al) GaAs Multijunction Laser Power Converters

Eight In(Al)GaAs P/N junctions grown epitaxially on a semi-insulating wafer were monolithically integrated in series to boost the approx. 0.4 V photovoltage per typical In(Al)GaAs junction to over 3 volts for the 1 sq cm laser power converter (LPC) chip. This is the first report of a multijunction LPC for the 1.3 to 1.5 microns wavelength range. This wavelength range is optimum for laser power transmission over low- loss single-mode silica optical fiber, and is also useful with high efficiency 1.315 microns iodine lasers in free-space power transmission. Advantages of multijunction LPC designs include the need for less circuitry for power reconditioning and the potential for lower I(exp 2)R power loss. As an example, these LPCs have a responsivity of approx.1 amp/watt. With a single junction LPC, 100 watts/sq cm incident power would lead to about 100 A/sq cM short-circuit current at approx. 0.4 V open-circuit voltage. One disadvantage is the large current would lead to a large 1(exp 2)R loss which would lower the fill factor so that 40 wattS/sq cm output would not be obtained. Another is that few circuits are designed to work at 0.4 volts, so DC-DC power conversion circuitry would be necessary to raise the voltage to a reasonable level. The multijunction LPC being developed in this program is a step toward solving these problems. In the above example, an eight-junction LPC would have eight times the voltage, approx. 3 V, so that DC-DC power conversion may not be needed in many instances. In addition, the multijunction LPC would have 1/8 the current of a single-junction LPC, for only 1/64 the 1(exp 2)R loss if the series resistance is the same. Working monolithic multijunction laser power converters (LPCs) were made in two different compositions of the ln(x)Al(y)Ga(l-x-y)As semiconductor alloy, In(0.53)Ga(0.47)As (0.74 eV) and In(0.5)Al(0.1)Ga(0.4)As (0.87 eV). The final 0.8 sq cm LPCs had output voltages of about 3 volts and output currents up to about one-half amp. Maximum 1.3 microns power conversion efficiencies were approx. 22%. One key advantage of multijunction LPCs is that they have higher output voltages, so that less DC-DC power conversion circuitry is needed in applications.

Wojtczuk, Steven↗

Time-Temperature-Precipitation Behavior in Al-Li Alloy 2195

Transmission electron microscopy was used to study time-temperature-precipitation (TTP) behavior in aluminum-lithium (Al-Li) 2195 alloy. Al-Li 2195 (nominally Al + 4 percent Cu + 1 percent Li + 0.3 percent Ag + 0.3 percent Mg + 0.1 percent Zr) was initially solutionized for 1 hr at 950 F and then stretched 3 percent. Heat treatments were conducted for up to 100 hr at temperatures ranging from 200 to 1,000 F. TTP diagrams were determined for both matrix and subgrain boundaries. Depending upon heat treatment conditions, precipitate phases (such as GP zone, theta'', theta', theta, delta', T1, TB, and T2) were found in the alloy. The TTP diagrams were applied as a guide to avoid T1 precipitation at subgrain boundaries, as part of an effort to improve the alloy's cryogenic fracture toughness (CFT). New understanding of TTP behavior was instrumental in the development of a two-step artificial aging treatment that significantly enhanced CFT in Al-Li 2195.

Chen, P. S.↗

RASC-AL (Revolutionary Aerospace Systems Concepts-Academic Linkage): 2002 Advanced Concept Design Presentation

The Revolutionary Aerospace Systems Concepts-Academic Linkage (RASC-AL) is a program of the Lunar and Planetary Institute (LPI) in collaboration with the Universities Space Research Association's (USRA) ICASE institute through the NASA Langley Research Center. The RASC-AL key objectives are to develop relationships between universities and NASA that lead to opportunities for future NASA research and programs, and to develop aerospace systems concepts and technology requirements to enable future NASA missions. The program seeks to look decades into the future to explore new mission capabilities and discover what's possible. NASA seeks concepts and technologies that can make it possible to go anywhere, at anytime, safely, reliably, and affordably to accomplish strategic goals for science, exploration, and commercialization. University teams were invited to submit research topics from the following themes: Human and Robotic Space Exploration, Orbital Aggregation & Space Infrastructure Systems (OASIS), Zero-Emissions Aircraft, and Remote Sensing. RASC-AL is an outgrowth of the HEDS-UP (University Partners) Program sponsored by the LPI. HEDS-UP was a program of the Lunar and Planetary Institute designed to link universities with NASA's Human Exploration and Development of Space (HEDS) enterprise. The first RASC-AL Forum was held November 5-8, 2002, at the Hilton Cocoa Beach Oceanfront Hotel in Cocoa Beach, Florida. Representatives from 10 university teams presented student research design projects at this year's Forum. Each team contributed a written report and these reports are presented.

Source record↗

Dynamic Modeling of ALS Systems

The purpose of dynamic modeling and simulation of Advanced Life Support (ALS) systems is to help design them. Static steady state systems analysis provides basic information and is necessary to guide dynamic modeling, but static analysis is not sufficient to design and compare systems. ALS systems must respond to external input variations and internal off-nominal behavior. Buffer sizing, resupply scheduling, failure response, and control system design are aspects of dynamic system design. We develop two dynamic mass flow models and use them in simulations to evaluate systems issues, optimize designs, and make system design trades. One model is of nitrogen leakage in the space station, the other is of a waste processor failure in a regenerative life support system. Most systems analyses are concerned with optimizing the cost/benefit of a system at its nominal steady-state operating point. ALS analysis must go beyond the static steady state to include dynamic system design. All life support systems exhibit behavior that varies over time. ALS systems must respond to equipment operating cycles, repair schedules, and occasional off-nominal behavior or malfunctions. Biological components, such as bioreactors, composters, and food plant growth chambers, usually have operating cycles or other complex time behavior. Buffer sizes, material stocks, and resupply rates determine dynamic system behavior and directly affect system mass and cost. Dynamic simulation is needed to avoid the extremes of costly over-design of buffers and material reserves or system failure due to insufficient buffers and lack of stored material.

Jones, Harry↗

Reply to Comment on “Coronal Mass Ejections, Interplanetary Ejecta and Geomagnetic Storms” by Gopalswamy Et Al.

The comment of Gopalswamy et al. (thereafter GMY) relates to a letter discussing coronal mass ejections (CMEs), interplanetary ejecta and geomagnetic storms. GMY contend that Cane et al. incorrectly identified ejecta (interplanetary CMEs) and hypothesize that this is because Cane et al. fail to understand how to separate ejecta from "shock sheaths" when interpreting solar wind and energetic particle data sets. They (GMY) are wrong be cause the relevant section of the paper was concerned with the propagation time to 1 AU of any potentially geoeffective structures caused by CMEs, i.e. upstream compression regions with or without shocks, or ejecta. In other words, the travel times used by Cane et al. were purposefully and deliberately distinct from ejecta travel times (except for those slow ejecta, approx. 30% of their events, which generated no upstream features), and no error in identification was involved. The confusion of GMY stems from the description did not characterize the observations sufficiently clearly.

Cane, H. V.↗

Al-Li Alloy 1441 for Fuselage Applications

A cooperative investigation was conducted to evaluate Al-Cu-Mg-Li alloy 1441 for long service life fuselage applications. Alloy 1441 is currently being used for fuselage applications on the Russian Be-103 amphibious aircraft, and is expected to be used for fuselage skin on a new Tupolev business class aircraft. Alloy 1441 is cold-rollable and has several attributes that make it attractive for fuselage skin applications. These attributes include lower density and higher specific modulus with similar strength as compared to conventional Al-Cu-Mg alloys. Cold-rolled 1441 Al-Li sheet specimens were tested at NASA Langley Research Center (LaRC) and at the All-Russia Institute of Aviation Materials (VIAM) in Russia to evaluate tensile properties, fracture toughness, impact resistance, fatigue life and fatigue crack growth rate. In addition, fuselage panels were fabricated by Tupolev Design Bureau (TDB) using 1441 skins and Al-Zn-Mg-Cu alloy stiffeners. The panels were subjected to cyclic pressurization fatigue tests at TDB and at LaRC to simulate fuselage pressurization/depressurization during aircraft service. This paper discusses the results from this investigation.

Bird, R. K.↗