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At least 1,423 records · Page 79

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DOE OSTI2013

Electrodeposition of gold nanoparticle arrays on ITO glass as electrode with high electrocatalytic activity

Highlights: ► Electrodeposition of gold nanoparticle arrays on ITO glass as catalytic-electrodes. ► The sizes and densities of the gold nanoparticles can be easily controlled. ► Such arrays on ITO glass shows high electrocatalytic activity and good stability. - Abstract: Herein, we reported a templateless, surfactantless, and simple electrochemical method to directly fabricate gold nanoparticle (AuNP) arrays on indium tin oxide (ITO) glass substrates as effective electrocatalytic electrodes. The as-prepared AuNP arrays have been characterized by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), etc. AuNPs with small sizes (<20 nm) were uniformly deposited on the ITO glass under constant current densities, and particle densities can be adjusted by varying the applied charges. The resultant AuNP array electrode showed higher catalytic activity and good stability toward electro-oxidation of ascorbic acid compared with other electrodes, such as bare ITO electrode, bare glassy carbon electrode and bulk gold film electrode.

36 MATERIALS SCIENCE↗

DOE OSTI2022

Evaluating Contributions of Pitch-Carbon Coating to Improved Stability of Si Anodes Through Voltage-Resolved Multi-Phase Characterization

Silicon nanoparticles have emerged as a promising alternative to graphite to improve the energy density of next-generation lithium-ion battery anodes. Nano-sized Si domains facilitate rapid ion transport and minimize particle-scale mechanical degradation, but also exhibit increased (electro)chemical reactivity with Li-ion electrolyte components due to their high surface area. We have previously demonstrated that surface modification of Si nanoparticles with pitch-carbon is an effective strategy to reduce these parasitic reactions. In the present work, we holistically evaluate the mechanistic contribution of pitch-carbon coating to the observed stability improvement over uncoated Si. We utilize coupled in situ and ex situ methods to probe changes to solid-surface, volatile headspace, and gas-phase chemistry occurring during initial cycling. Measurements taken at targeted potentials associated with electrolyte species reduction enables the decoupling of specific reaction pathways tied to interfacial stability. Further, we demonstrate the non-trivial role of gas reconsumption in dictating the nature of the passivating surface layer evolved on both uncoated and pitch-coated Si. This multi-phase analysis offers insights into the mechanism of effective surface passivation, which may be applied to inform future Si material development.

ENERGY STORAGE↗

DOE OSTI2022

Stability analysis of Monte Carlo burnup calculation based on PWR fuel rods

The existing Monte Carlo burnup algorithms may give some unstable results when using multiple burnable cells during burnup calculations. A very small time step is required to maintain the stability of the system, which pose some limits for the realistic applications. In this paper, we firstly repeat the instability issue by using a Monte Carlo code based on a typical PWR fuel rod model. Then, a theoretical stability analysis was carried out by using the perturbation theory in order to get a better understanding about the property of system stability. We determine a perturbation matrix which relates some main influence factors, such as the time step and the height of fuel rod, it can help people estimate the stability of burnup calculation system and the results are quantitatively consistent with the Monte Carlo code. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

DOE OSTI2015

Structural stability and electronic properties of β-tetragonal boron: A first-principles study

It is known that elemental boron has five polymorphs: α- and β-rhombohedral, α- and β-tetragonal, and the high-pressure γ phase. β-tetragonal (β-t) boron was first discovered in 1960, but there have been only a few studies since then. We have thoroughly investigated, using first-principles calculations, the atomic and electronic structures of β-t boron, the details of which were not known previously. The difficulty of calculation arises from the fact that β-t boron has a large unit cell that contains between 184 and 196 atoms, with 12 partially-occupied interstitial sites. This makes the number of configurations of interstitial atoms too great to calculate them all. By introducing assumptions based on symmetry and preliminary calculations, the number of configurations to calculate can be greatly reduced. It was eventually found that β-t boron has the lowest total energy, with 192 atoms (8 interstitial atoms) in an orthorhombic lattice. The total energy per atom was between those of α- and β-rhombohedral boron. Another tetragonal structure with 192 atoms was found to have a very close energy. The valence bands were fully filled and the gaps were about 1.16 to 1.54 eV, making it comparable to that of β-rhombohedral boron. - Graphical abstract: Electronic density distribution for the lowest-energy configuration (N=192) viewed from the 〈1 0 0〉 direction. Left: isosurface (yellow) at d=0.09 electrons/a.u.{sup 3} Right: isosurface (orange) at d=0.12 electrons/a.u.{sup 3}. - Highlights: • β-tetragonal boron was thoroughly investigated using first-principles calculations. • The lowest energy structure contains 192 atoms in an orthorhombic lattice. • Another tetragonal structure with 192 atoms has a very close energy. • The total energy per atom is between those of α- and β-rhombohedral boron. • The band gap of the lowest energy structure is about 1.16 to 1.54 eV.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2025

Virtual Cable Impedance based Load Sharing in a Microgrid for Parallel Connected Grid Forming Converters

This paper presents a novel approach to power sharing between direct connected grid-forming converters, utilizing virtual cable impedance and droop-based outer loop control. To enhance stability, resistive droop is implemented, while virtual cable impedance with non-zero resistive and inductive components ensures improved power sharing. The inner loop controller employs a Lyapunov energy function to achieve superior dynamic performance. The proposed control architecture is validated through comprehensive modeling and real-time processor-in-the-loop simulations, demonstrating its robustness and efficiency under various operating conditions. The results highlight the potential of this control strategy to improve the reliability and efficiency of renewable energy systems. Additionally, a comparative analysis with traditional methods underscores the advantages of the proposed approach in terms of stability and performance. The proposed control architecture offers a scalable and flexible solution for grid-forming converters, enabling seamless integration of renewable energy sources. Its robustness and adaptability make it an attractive solution for real-world applications. Furthermore, the approach can be extended to other power electronic systems, enhancing overall system performance and efficiency. By providing a reliable and efficient control strategy, this paper contributes to the advancement of renewable energy systems and their adoption in the energy sector. The proposed control strategy has far-reaching implications for the widespread adoption of renewable energy sources, enabling a more sustainable and efficient energy future. The overall system is modeled in MATLAB/Simulink and PLECS software domain.

grid forming converters (GFM)↗

DOE OSTI2016

The stability of H/V spectral ratios from noise measurements in Armutlu Peninsula (Turkey)

The horizontal to vertical spectral ratio (H/V) method has been successfully using in order to estimate the fundamental resonance frequency of the sedimentary cover, its thickness and amplification factor since at least 3 decades. There are numerous studies have been carried out on the stability of the H/V spectral ratios. Almost all studies showed that fundamental frequency is stable even measurements are repeated at different times. From this point of view, the results will show us an approach whether the stations are suitable for accurate estimate of earthquake studies and engineering purposes or not. Also we want to see if any effects of the amplification factor changing on the seismograms for Armutlu Seismic Network (ARNET) even though seismic stations are established far away from cultural noise and located on hard rock sites. It has been selected one hour recorded data of all stations during the most stationary times. The amplification and resonant frequency variations of H/V ratio were calculated to investigate temporal stability in time. There is a total harmony in fundamental frequencies values and H/V spectral ratio values in time-lagged periods. Some stations shows secondary minor peaks in high frequency band due to a shallow formation effect or cultural noises around. In the east side of the area ILYS station shows amplitude peak in lower fundamental frequency band from expected. This could compose a high amplification in lower frequencies and so that yield less reliable results in local earthquakes studies. By the experimental results from ambient noise analysis, it could be worked up for relocation of one station.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

DOE OSTI2017

Self-supported Zn/Si core-shell arrays as advanced electrodes for lithium ion batteries

Graphical abstract: Zn/Si core-shell arrays prepared by combined hydrothermal plus sputtering method show good performance with high specific capacity and excellent cycling stability. - Highlights: • Construct Zn/Si core-shell arrays via sputtering. • The Zn/Si core-shell arrays show high capacity and good cycles. • Core-shell arrays is favorable for fast ion/electron transfer. - Abstract: Silicon is considered as the most promising substitute for the commercial graphite anode of lithium ion batteries (LIBs) due to its high capacity and low working voltage. In this work, we realize the rational combination between Zn nanorods and Si forming self-supported Zn/Si core-shell arrays with the aid of hydrothermal and sputtering methods. Amorphous Si layer is well coated on the backbone of Zn nanorods with diameters of 70–80 nm. As a preliminary test, the Zn/Si core-shell arrays are used as the anode of LIBs and demonstrated with a high initial reversible capacity of 2795 mAh g{sup −1} at 0.1C, good high-rate capability with 1985 mAh g{sup −1} at 1C and stable cycling life. The good performance is due to the highly conductive Zn nanorod network and porous core-shell structure providing good mechanical support and fast transport of ions/electrons.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Scalable fabrication and coating methods for perovskite solar cells and solar modules

Since the report in 2012 of a solid-state perovskite solar cell (PSC) with a power-conversion efficiency (PCE) of 9.7% and a stability of 500 h, intensive efforts have been made to increase the certified PCE, reaching 25.2% in 2019. The PCE of PSCs now exceeds that of conventional thin-film solar-cell technologies, and the rate at which this increase has been achieved is unprecedented in the history of photovoltaics. Moreover, the development of moisture-stable and heat-stable materials has increased the stability of PSCs. Small-area devices (<1 cm2) are typically fabricated using a spin-coating method; however, this approach may not be suitable for the preparation of the large-area (>100 cm2) substrates required for commercialization. Thus, materials and methods need to be developed for coating large-area PSCs. In this Review, we discuss solution-based and vapour-phase coating methods for the fabrication of large-area perovskite films, examine the progress in performance and the parameters affecting the properties of large-area coatings, and provide an overview of the methodologies for achieving high-efficiency perovskite solar modules.

14 SOLAR ENERGY↗

DOE OSTI2021

Sensitive parameter identification and uncertainty quantification for the stability of pipeline conveying fluid

In this study, several uncertainty quantification and sensitivity analysis methods are used to determine the most sensitive geometric and material input parameters of a cantilevered pipeline conveying fluid when uncertainty is introduced to the system at the onset of instability. The full nonlinear equations of motion are modeled using the extended Hamilton’s principle and then discretized using Galerkin’s method. A parametric study is first performed, and the Morris elementary effects are calculated to obtain a preliminary understanding of how the onset speed changes when each parameter is introduced to a ± 5% uncertainty. Then, four different input uncertainty distributions, mainly, uniform and Gaussian distribution, are chosen to investigate how input distributions affect uncertainty in the output. A convergence analysis is used to determine the number of samples needed to maintain simulation accuracy while saving the most computational time. Then, Monte Carlo simulations are run, and the output distributions for each input distribution at ± 1%, ± 3% and ± 5% input uncertainty range are found and discussed. Additionally, the Pearson correlation coefficients are evaluated for different uncertainty ranges. A final Monte Carlo study is performed in which single parameters are held constant while all others still have uncertainty. Overall, the flow speed at the onset of instability is the most sensitive to changes in the outer diameter of the pipe.

36 MATERIALS SCIENCE↗

DOE OSTI2017

Stability of gas atomized reactive powders through multiple step in-situ passivation

A method for gas atomization of oxygen-reactive reactive metals and alloys wherein the atomized particles are exposed as they solidify and cool in a very short time to multiple gaseous reactive agents for the in-situ formation of a protective reaction film on the atomized particles. The present invention is especially useful for making highly pyrophoric reactive metal or alloy atomized powders, such as atomized magnesium and magnesium alloy powders. The gaseous reactive species (agents) are introduced into the atomization spray chamber at locations downstream of a gas atomizing nozzle as determined by the desired powder or particle temperature for the reactions and the desired thickness of the reaction film.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Stability of gas atomized reactive powders through multiple step in-situ passivation

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2020

Stability of gas atomized reactive powders through multiple step in-situ passivation

36 MATERIALS SCIENCE↗

DOE OSTI2015

Heat-activated Plasmonic Chemical Sensors for Harsh Environments

A passive plasmonics based chemical sensing system to be used in harsh operating environments was investigated and developed within this program. The initial proposed technology was based on combining technologies developed at the SUNY Polytechnic Institute Colleges of Nanoscale Science and Engineering (CNSE) and at the University of Minnesota (UM). Specifically, a passive wireless technique developed at UM was to utilize a heat-activated plasmonic design to passively harvest the thermal energy from within a combustion emission stream and convert this into a narrowly focused light source. This plasmonic device was based on a bullseye design patterned into a gold film using focused ion beam methods (FIB). Critical to the design was the use of thermal stabilizing under and overlayers surrounding the gold film. These stabilizing layers were based on both atomic layer deposited films as well as metal laminate layers developed by United Technologies Aerospace Systems (UTAS). While the bullseye design was never able to be thermally stabilized for operating temperatures of 500oC or higher, an alternative energy harvesting design was developed by CNSE within this program. With this new development, plasmonic sensing results are presented where thermal energy is harvested using lithographically patterned Au nanorods, replacing the need for an external incident light source. Gas sensing results using the harvested thermal energy are in good agreement with sensing experiments, which used an external incident light source. Principal Component Analysis (PCA) was used to reduce the wavelength parameter space from 665 variables down to 4 variables with similar levels of demonstrated selectivity. The method was further improved by patterning rods which harvested energy in the near infrared, which led to a factor of 10 decrease in data acquisition times as well as demonstrated selectivity with a reduced wavelength data set. The combination of a plasmonic-based energy harvesting sensing paradigm with PCA analysis and wavelength down selection offers a novel path towards simplification and integration of plasmonic-based sensing methods using selected wavelengths rather than a full spectral analysis. Integration efforts were designed and modeled for thermal and mass transport considerations by UTAS which led to the 3D printing of scaled models that would serve as the housing for the alternative energy harvesting plasmonic chemical sensor design developed by CNSE.

47 OTHER INSTRUMENTATION↗

DOE OSTI2022

Long–Cycling Sulfide–Based All–Solid–State Batteries Enabled by Electrochemo–Mechanically Stable Electrodes

Anode significantly determines the energy density of all-solid-state Lithium batteries (ASLBs). Silicon (Si) and Lithium (Li) metal are two of the most attractive anodes because of their ultrahigh theoretical capacities. However, most investigations focus on Li metal; the great potential of Si is underrated. This study investigates Si anode's stability, processability, and cost in ASLBs and compares them with Li metal. Moreover, the single-crystal LiNi 0.8 Co 0.1 Mn 0.1 O 2 is stabilized with a lithium silicate (Li 2 SiO x ) through a scalable sol-gel method. ASLBs with a cell-level energy density of 285 Wh kg -1 are obtained through sandwiching Si anode, thin sulfide solid-state electrolyte membrane, and interface stabilized LiNi 0.8 Co 0.1 Mn 0.1 O 2 . The full cell delivered a high capacity of 145 mAh g -1 at C/3 and maintained stability for 1000 cycles. This work inspires commercializing the ASLBs on a large scale with exciting manufacturing lines for large-scale, safe, and economical energy storage.

25 ENERGY STORAGE↗

DOE OSTI2016

Studies on synthesis of reduced graphene oxide (RGO) via green route and its electrical property

Highlights: • RGO-1 and RGO-2 were synthesized by green method using different phytoextracts. • M. indica L., S. tuberosum L. phytoextracts act as reducing and stabilizing agents. • Conjugated structure of graphene is established following partial reduction of GO. • Electrical conductivities of RGO-1 and RGO-2 are higher than GO. - Abstract: An environmentally friendly method has been applied for the preparation of reduced graphene oxide (RGO). This method was developed by using polyphenols that contained a phytoextract of Mangifera indica L. along with Solanum tuberosum L. as reducing agents since they are non-toxic and naturally available. The phytoextracts used in the production of RGO was set between 60 and 70 °C. Graphene oxide (GO) was prepared by modified Hummer’s method as reported in earlier findings. Structural and morphological studies demonstrate that the part of the oxygen functionalities in GO can be removed by following green reduction. Characterizations of the resulting product have been done by X-ray diffraction, FTIR, UV–vis and Raman spectroscopy. FESEM, TEM, EDX spectrum, TGA, DLS and Zeta potential measurements of the samples have also been carried out to study the morphological, thermal and surface charge characteristics. Electrical conductivity was also measured to check the extent of reduction of GO to RGO.

36 MATERIALS SCIENCE↗

DOE OSTI2019

Real-Time Feedback-Based Optimization of Distribution Grids: A Unified Approach

This paper develops an algorithmic framework for real-time optimization of distribution-level distributed energy resources (DERs). The framework optimizes the operation of both DERs that are individually controllable and groups of DERs (i.e., aggregations) that are jointly controlled at an electrical point of connection. From an electrical standpoint, wye and delta single- and multi-phase connections are accounted for. The algorithm enables (groups of) DERs to pursue given performance objectives, while adjusting their (aggregate) powers to respond to services requested by grid operators and to maintain electrical quantities within engineering limits. The design of the algorithm leverages a time-varying bi-level problem formulation capturing various performance objectives and engineering constraints, and an online implementation of primal-dual projected-gradient methods. The gradient steps are suitably modified to accommodate appropriate measurements from the distribution network and the DERs. Stability and convergence claims are established in terms of tracking of the solution of the time-varying optimization problem. Finally, the method is tested in a realistic distribution.

24 POWER TRANSMISSION AND DISTRIBUTION↗

DOE OSTI2019

Analysis of Methods of Investigation of the Vibration–Rotation Spectrum of Monomers and Dimers of Sulphur Hexafluoride Isotopes

The stability of the system of sulphur hexafluoride dimer SF{sub 6} under the action of external laser radiation has been estimated using ab initio quantum-chemical calculations of the vibration–rotation spectrum of SF{sub 6} monomers as well as homo- and heterodimers. It is noted that for simple CO molecule as an example, the most widely used method of calculations based on the Hessian matrix approach cannot serve as a reliable instrument in quantitative calculations of some molecular systems. As a potential analog, we have tested the algorithm for obtaining the vibration–rotation spectrum based on molecular dynamics data.

74 ATOMIC AND MOLECULAR PHYSICS↗

DOE OSTI2018

Center for Extended Magnetohydrodrynamic Modeling

This work used the NIMROD code to solve two tokamak regimes found on the DIII-D tokamak. The first regime studied is the Quiescent H-mode regime that has the advantage of enabling tokamak high performance without the deleterious effects of Edge Localized Modes (ELMs). ELMs are a possible impediment to the success of tokamaks as a burning plasma reactor and the QH mode regime provides a mechanism for avoiding it. The QH mode achieves this state due to the appearance of long wavelength instability that saturates instead of reaching an ELM state. NIMROD simulations were able to describe many of the features of a particular discharge, including the importance of shear flow in reaching the state, the role of the parallel heat flux to decorrelate the temperature and velocity fluctations, and in the correlation of density and velocity fluctations to provide the density pumpout. This work resulted in two direct publications and an invited talk. Progress towards these publications resulted in two more publications (verification and solving the Grad-Shafranov equation with scrape-off-layer currents). The second regime studied was the Giant Sawtooth regime whereby energetic particles affect the stability of the 1/1 mode. This work resulted in performance improvements of NIMROD's energetic particle algorithms, and improvements to the drift-kinetic equation infrastructure used by both continuum and energetic particle closure methods. The studies proved more computationally demanding than expected because as the 1/1 is stabilized, the near marginal conditions cause long simulations times. Publication of this work is in progress under other funding.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗