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At least 1,423 records · Page 79
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

The role of material properties in adhesion

When two solid surfaces are brought into contact strong adhesive bond forces can develop between the materials. The magnitude of the forces will depend upon the state of the surfaces, cleanliness and the fundamental properties of the two solids, both surface and bulk. Adhesion between solids is addressed from a theoretical consideration of the electronic nature of the surfaces and experimentally relating bond forces to the nature of the interface resulting from solid state contact. Surface properties correlated with adhesion include, atomic or molecular orientation, reconstruction and segregation as well as the chemistry of the surface specie. Where dissimilar solids are in contact the contribution of each is considered as is the role of their interactive chemistry on bond strength. Bulk properties examined include elastic and plastic behavior in the surficial regions, cohesive binding energies, crystal structure, crystallographic orientation and state. Materials examined with respect to interfacial adhesive interactions include metals, alloys, ceramics, polymers and diamond. They are reviewed both in single and polycrystalline form. The surfaces of the contacting solids are studied both in the atomic or molecularly clean state and in the presence of selected surface contaminants.

Buckley, D. H.↗
NASA NTRS1983

Photochemistry of methane in the earth's early atmosphere

The photochemical behavior of methane in the early terrestrial atmosphere is investigated with a detailed model in order to determine how much CH4 might have been present and what types of higher hydroocarbons could have been formed. It is found that any primordial methane accumulated during the course of earth accretion would have been dissipated by photochemical reactions in the atmosphere in a geologically short period of time after the segregation of the core. Abiotic sources of methane are not likely to have been large enough to sustain CH4 mixing ratios as high as 10 to the -6th, the threshold for a possible methane greenhouse, with a CO-rich atmosphere being a possible exception. After the origin of life an increasing biogenic source of methane may have driven CH4 mixing ratios well above 10 to the 6th. The rise of atmospheric oxygen in the early Proterozoic may have led to a more rapid photochemical destruction of methane, lowering the mixing ratio to its present value.

Kasting, J. F.↗
NASA NTRS1983

Impact versus internal origins for mesosiderites

The textures, mineral compositions, and thermal history of mesosiderites are examined to see whether they are compatible with any kind of impact process or internal process which might produce stony-iron breccias. It was proposed that cratering by metal projectiles is not an adequate origin mechanism since it would not deposit enough metal in the stony-iron breccias. It was also proposed that such mechanisms as accretion of differentiated planitesimals must be considered for mesosiderite origins. But no single model for origins is fully satisfactory. Disruption and reassembly of two colliding bodies could form stony-iron breccias at depth, but, as with the previous models, the easiest way to explain the low olivine of mesosiderites is to postulate derivation from olivine-poor chondritic material. Turbulent metal-crust mixing during core formation and crustal blocks sinking into the core withhold olivine from the breccia but do not explain how the silicate and metal liquids in subgroup IV could have failed to segregate.

Hewins, R. H.↗
NASA NTRS1984

IUE observations of weak G-band stars

High- and low-resolution ultraviolet spectra of several weak G-band giants have been obtained with the IUE satellite, to derive Be abundances and to search for degenerate companions. The abundances of Be in these stars are about log epsilon (Be) approximately -0.5. These values are in good agreement with the Be abundances of Hyades giants, and are consistent with standard theories of post-main-sequence Be depletion in stars. However, the Be abundances do not fit with the large Li abundances in weak G-band stars. Post-main-sequence production of Li or element segregation in main-sequence stars may explain the high Li abundance in weak G-band stars. No direct evidence is seen for the presence of hot subluminous companions. The peculiar abundances in these stars probably are not due to binary mass transfer.

Parthasarathy, M.↗
NASA NTRS1983

Materials processing in space; Proceedings of the Special Conference, Cincinnati, OH, May 4, 5, 1982

An international review of materials processing in space is provided, taking into account the NASA materials processing in space program, European activities in the field of microgravity research, and Japanese material processing tests in space. The subjects considered are related to materials processing in a microgravity environment, industrial and university applications and involvement, and challenges and prospectives of microgravity research in space. Attention is given to a review of the containerless processing technologies and facilities, glass research in space, bubble behavior in molten glass in a temperature gradient, semiconductor crystal growth and segregation problems on earth and space, seeded crystal growth of pseudobinary systems with large liquidus-solidus separation, avenues and incentives for commercial use of a low-gravity environment, and the Universities Space Research Association and its role in the materials processing in space program.

Dunbar, B. J.↗
NASA NTRS1986

Cast Iron With High Carbon Content

Method proposed for solidifying high-carbon cast iron without carbon particles segregating at upper surface. Solidification carried out in low gravity, for example on airplane flying free-fall parabolic trajectory. Many different microstructures obtained by proposed technique, and percentage by weight of carbon retained in melt much higher than at present.

Curreri, P. A.↗
NASA NTRS1984

The absence of convective stability in incongruent crystal growth on Earth

It is often assumed that convection can be excluded in materials processing by avoiding horizontal temperature gradients, and employing top-heating and horizontal interfaces. Model calculations for vapor transport processes show that this supposition holds only for strictly congruent vapor-solid transitions. This result can be generalized to all fluid-solid phase transitions. Due to the omnipresence of impurity segregation, it is concluded that convective stability is practically unattainable in materials processing on Earth.

Rosenberger, F. E.↗
NASA NTRS1984

Neutron activation analysis of stoney spherules from a marine sediment sample

The identification of extraterrestrial material in samples collected at the surface of the Earth is discussed. Criteria were established for black magnetic spherules which involve the presence of: Fe, Ni, and Co in iron meteoritic ratios, wustite, and Fe-Ni metal while reliable criteria for stoney spherules are not well established. Neutron activation analysis was performed on eight stony spherules separated from the same marine sediment used by Millard and Finkelman. The 22 elements were determined by Compton suppression and triple coincidence gamma counting. It is found that Fe, Mg, Al, Ni, Cr, Co, Ir, and Sc are the best discriminators between chondritic and terrestrial compositions. Three of the spherules have compositions very close to chondrites and of these, two contain 0.5 and 0.25 ppm Ir. The other five spherules contain much less than chondritic concentrations of Ni but this element may be segregated and lost during ablation of the parent meteorite. One of these five low Ni spherules contains 2.9 ppm Ir while the other four contain less than 0.05 ppm Ir.

Millar, H. T., Jr.↗
NASA NTRS1984

Experimental and theoretical study of the formation of the 2AB, 3AB, and 9A meteorite chemical groups from the parent liquid

Segregation of solute elements was measured in plane front solidified Fe-Ni-S-P alloys of meteoritic composition containing Ir, Ge and/or Cu. The Ni and P contents reach maximum values of 10.5 wt% and 1.1 wt%, respectively, in austenite (taenite) at the end of primary solidification. Distribution coefficients of Ni, P, Ir, Ge and Cu were determined from the solidified alloys. The distribution coefficients vary with the S and P content of the liquid. In addition the distribution coefficients of Ni, P, Ir and Ge increase and the distribution coefficient of Cu decreases with the S to P ratio. Equations that describe the concentration dependence of the distribution coefficients were developed and used to calculate solute redistribution during the solidification of IIAB, IIIAB and IVA parent bodies. The calculated P vs Ni, Ir vs Ni and Ge vs Ni trends are in good agreement with the observed meteoritic data. Since the calculated value of the maximum solid solubility of P agrees well with the observed maximum P composition data for IIAB and IIIAB irons, it is concluded that complete crystallization of the parent liquids of IIAB and IIIAB had occurred before any fragmentation of the solidified body.

Sellamuthu, R.↗
NASA NTRS1985

Crystal growth of device quality GaAs in space

The present program has been aimed at solving the fundamental and technological problems associated with Crystal Growth of Device Quality in Space. The initial stage of the program was devoted strictly to ground-based research. The unsolved problems associated with the growth of bulk GaAs in the presence of gravitational forces were explored. Reliable chemical, structural and electronic characterization methods were developed which would permit the direct relation of the salient materials parameters (particularly those affected by zero gravity conditions) to the electronic characteristics of single crystal GaAs, in turn to device performance. These relationships are essential for the development of optimum approaches and techniques. It was concluded that the findings on elemental semiconductors Ge and Si regarding crystal growth, segregation, chemical composition, defect interactions, and materials properties-electronic properties relationships are not necessarily applicable to GaAs (and to other semiconductor compounds). In many instances totally unexpected relationships were found to prevail.

Gatos, H. C.↗
NASA NTRS1985

Oxygen and carbon impurities and related defects in silicon

Oxygen and carbon are the predominant impurities in Czochralski-grown silicon. The incorporation of oxygen and carbon during crystal growth is reviewed and device effects are discussed. Methods for controlling oxygen and carbon incorporation during crystal growth are discussed and results supporting a segregation coefficient of k=0.5 for oxygen are presented. The nucleation and precipitation behavior of oxygen is complex. Temperature and doping level effects which add insight into the role of point defects in the nucleation process are highlighted. In general, precipitation is found to be retarded in N+ and P+ silicon. The types and quantities of defects resulting from the oxygen precipitates is of interest as they are technologically useful in the process called intrinsic gettering. A comparison is made between the available defect sites and the quantities of metallic impurities present in a typical wafer which need to be gettered. Finally, a discussion of the denuded-zone, intrinsic-gettered (DZ-IG) structure on device properties is presented.

Pearce, C. W.↗
NASA NTRS1984

Analysis of inclined growth of silicon sheet

A general-purpose finite element program was developed for analysis of silicon sheet growth in inclined configurations. This program will be used to study parametric sensitivity of various growth geometries with respect to thermal control and growth rate, dopant segregation, thermal stress and interface morphology and instability.

Brown, R. A.↗
NASA NTRS1984

Benchmark data on the separability among crops in the southern San Joaquin Valley of California

Landsat MSS data were input to a discriminant analysis of 21 crops on each of eight dates in 1979 using a total of 4,142 fields in southern Fresno County, California. The 21 crops, which together account for over 70 percent of the agricultural acreage in the southern San Joaquin Valley, were analyzed to quantify the spectral separability, defined as omission error, between all pairs of crops. On each date the fields were segregated into six groups based on the mean value of the MSS7/MSS5 ratio, which is correlated with green biomass. Discriminant analysis was run on each group on each date. The resulting contingency tables offer information that can be profitably used in conjunction with crop calendars to pick the best dates for a classification. The tables show expected percent correct classification and error rates for all the crops. The patterns in the contingency tables show that the percent correct classification for crops generally increases with the amount of greenness in the fields being classified. However, there are exceptions to this general rule, notably grain.

Morse, A.↗
NASA NTRS1984

Deformation and fracture behavior of Ni-Mo-Al(gamma/gamma prime-alpha) in situ composite

Tensile properties of a directionally solidified (DS) eutectic alloy of the nominal composition Ni-33 Mo-5.7 Al (weight percent) have been investigated both at room temperature and elevated temperatures. The microstructure-mechanical property relationship has been studied for the alloy both in the as-DS and heat-treated conditions. Changes in the yield strength, the work hardening behavior, and the fracture morphology have been explained in terms of the microstructural changes due to the heat treatment. The yield drops observed have been attributed to the microdebonding due to the possible segregation of impurities at the fiber-matrix interface, and partly to the strain aging. The deformation mechanism has been identified to be the cutting of gamma prime particles.

Sriramamurthy, A. M.↗
NASA NTRS1984

Mechanical-contact-induced transformation from the amorphous to the partially crystalline state in metallic glass

Friction and wear tests were conducted with 3.2- and 6.4-millimeter-diameter aluminum oxide spheres sliding, in reciprocating motion, on a Fe67Co18B14Si1 metallic foil. Crystallites with a size range of 10 to 150 nanometers were produced on the wear surface of the amorphous alloy. A strong interaction between transition metals and metalloids such as silicon and boron results in strong segregation during repeated sliding, provides preferential transition metal-metalloid clustering in the amorphous alloy, and subsequently produces the diffused honeycomb structure formed by dark grey bands and primary crystals, that is, alpha-Fe in the matrix. Large plastic flow occurs on an amorphous alloy surface with sliding and the flow film of the alloy transfers to the aluminum oxide pin surface. Multiple slip bands due to shear deformation are observed on the side of the wear track. Two distinct types of wear debris were observed as a result of sliding: an alloy wear debris, and/or powdery-whiskery oxide debris.

Miyoshi, K.↗
NASA NTRS1985

H I properties of dwarf irregular galaxies in the Virgo Cluster

A neutral hydrogen survey was carried out at Arecibo on 91 dwarf irregular galaxies, with morphological types Sdm through Im, in and around the direction of the Virgo Cluster. Only nine of these were found to be background galaxies, and 19 remain undetected, i.e., most of the candidate galaxies are indeed members of the Virgo Cluster or Supercluster. The distribution of positions and systemic velocities (compared with large spirals) shows no evidence for mass segregation. The H I depletion for dwarfs in the cluster core is only moderate, no more than for spirals. The magnitude-velocity width correlation is continous from spirls to dwarfs. Satistics on H I masses agree only partially with a simple stochastic star formation model.

Hoffman, G. L.↗
NASA NTRS1985

The origin and history of the metal and sulfide components of chondrules

Instrumental and radiochemical neutron activation analysis is used to determine the concentrations of 14 siderophile and other nonlithophilic elements in 31 chondrules from the extremely unequilibrated chondrite Semarkona. The results are presented in tables and graphs, characterized in detail, and compared with the results obtained for lithophile elements in the same samples by Grossman and Wasson (1983). The elements studied are found to be significantly more fractionated than the lithophile elements, with variations in chondrule/whole-rock abundances of up to a factor of 1000, a mean ratio of 0.2, and differences between Ni-rich and Ni-depleted chondrules. It is argued that the metal and sulfides in the chondrules represent the composition of the solar nebula before chondrule formation and already contained the siderophile and chalcophile elements, although some Fe was contained in silicates along with Ni, Co, Au, Ge and Se. The segregation of metals during a molten stage is considered of minor importance.

Grossman, J. N.↗
NASA NTRS1985

Superalloy microstructural variations induced by gravity level during directional solidification

The Ni-base superalloy MAR-M246 (Hf) was directionally solidified during low gravity maneuvers aboard a NASA KC-135 aircraft. Gravity force variations during this process yielded a concomitant variation in microstructure and microsegregation. Secondary dendrite arm spacings are noted to be larger in the low-g portion; this, in turn, decreases the extent of interdendritic segregation. The amount of Hf in both the carbides and interdendritic eutectic increases as the gravity force diminishes. Fewer carbides are present in the low-g regions.

Johnston, M. H.↗