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NASA NTRS1994

Separation of lithospheric, external, and core components of the south polar geomagnetic field at satellite altitudes

We present a new approach to producing scalar Magsat magnetic anomaly maps based on correlation coefficient filtering and the use of almost all of the available orbits. Our method differs from earlier techniques with respect to the following: (1) Passes are selected based on their variance properties rather than planetary indices such as Kp. (2) The core field model is least squares fit to individual passes and subsequently removed instead of substracting the model directly. This technique replaces band pass filtering or polynomial trend removal methods. (3) Each selected pass is sorted geographically and by local time, placed into one of four different altitude bands, and correlation coefficient filtered with the two adjacent passes. The filtering is the second step toward isolating the static lithospheric signal from the more dynamic external field signals. (4) Least squares collocation is used to grid the correlated passes; subsequently, the dawn and dusk maps are also correlation filtered providing another step toward removal of external fields. (5) The four resultant total field maps are continued to a common altitude and again correlation filtered for the static lithospheric anomalies. (6) The filtered results are then averaged together to provide a new total field map of the lithosphere south of 40 deg S latitude. Our total field map differs from previous efforts over the crustal blocks of West Antarctica. We obtained a positive anomaly over Edward VII Peninsula, extending into the Byrd subglacial basin and obtained a negative anomaly over the Ellsworth Mountains and parts of the Byrd subglacial basin. Also, a positive anomaly extending from the Ross Sea to offshore Wilkes Land is present in our map; however, this feature is absent in other maps. Positive anomalies marking the Weddell Sea in previous efforts are not present in our map. Prominent external field anomalies in the quadrant offshore of Wilkes Land are present in all previous efforts; however, these signatures are reduced in our total field map. This map significantly advances efforts for the identification and interpretation of magnetic anomalies of the south polar lithosphere.

Alsdorf, Douglas E.↗

NASA NTRS2001

Wind-Stress Simulations and Equatorial Dynamics in an AGCM: Basic Results from a 1979-1999 Forced SST Experiment - Part 1

This is the first of a two part study examining the connection of the equatorial momentum budget in an AGCM (Atmospheric General Circulation Model), with simulated equatorial surface wind stresses over the Pacific. The AGCM used in this study forms part of a newly developed coupled forecasting system used at NASA's Seasonal- to-Interannual Prediction Project. Here we describe the model and present results from a 20-year (1979-1999) AMIP-type experiment forced with observed SSTs (Sea Surface Temperatures). Model results are compared them with available observational data sets. The climatological pattern of extra-tropical planetary waves as well as their ENSO-related variability is found to agree quite well with re-analysis estimates. The model's surface wind stress is examined in detail, and reveals a reasonable overall simulation of seasonal interannual variability, as well as seasonal mean distributions. However, an excessive annual oscillation in wind stress over the equatorial central Pacific is found. We examine the model's divergent circulation over the tropical Pacific and compare it with estimates based on re-analysis data. These comparisons are generally good, but reveal excessive upper-level convergence in the central Pacific. In Part II of this study a direct examination of individual terms in the AGCM's momentum budget is presented. We relate the results of this analysis to the model's simulation of surface wind stress.

Bacmeister, Julio T.↗

NASA NTRS1981

A survey of load methodologies for shuttle orbiter payloads

Loads methods currently being used to design planetary spacecraft to be launched on the shuttle orbiter are summarized. Experiences gained from expendable launch vehicle payloads are used to develop methodologies for the space shuttle orbiter payloads. The objectives for the development of a new methodology for the shuttle payloads are to reduce the cost and schedule for the payload load analysis by decoupling the payload analysis from the launch vehicle to the maximum extent possible. Methods are described for payload member load estimation or obtaining upper bounds for dynamic loads, as well as load prediction or calculating actual transient member load time histories.

Chen, J. C.↗

NASA NTRS1982

The Middle Atmosphere Program: Winter In Northern Europe (MAP/WINE)

The goals of map/wind (winter in Northern Europe) are to better understand: (1) the interaction of planetary waves of tropospheric origin; (2) the temporal and spatial development of sudden stratospheric warmings; (3) the temporal and spatial development of mesospheric cooling events in conjunction with stratospheric warmings; (4) the vertical and horizontal transport of minor constituents; (5) the effects on the chemistry of neutral and charged species of the large temperature changes occurring during stratospheric warmings and mesospheric cooling; (6) sources of turbulent energy; (7) the temporal and spatial development of turbulent layers; and (8) the contributions of dynamical processes to the heating and cooling of the mesospheric and turbopause region.

Vonzahn, U.↗

NASA NTRS1989

A proposed non-intrusive method for finding coefficients of slip and molecular reflectivity in microgravity

A proposed experimental program to look at a series of vapor transport properties measured along solid and liquid surfaces is described. The research objectives proposed are: (1) with accuracy otherwise unobtainable on ground, to determine the coefficient of slip measured between gases and the surfaces of liquids and solids; (2) for the first time, to classify and tabulate dominant surface effects found for a variety of solids, particularly those crystalized by vapor transport; and (3) to extend understanding of settling rates predicted for cosmic dust and condensed vapor falling through planetary atmospheres. The method used to obtain these objectives, has aided, to an order of magnitude, understanding of various liquid-gas interfaces such as oil and water. But to date, no similar characterization has proved successful for solids or liquids of uncertain densities. Likewise, no data exist in either ground-based research or as part of a microgravity program that, when collected with the high accuracy expected in low gravity, could definitely settle outstanding questions in kinetic theory, molecular dynamics, and cosmic physics.

Noever, D. A.↗

NASA NTRS2000

Reconnection in Planetary Magnetospheres

Current sheets in planetary magnetospheres that lie between regions of "oppositely-directed" magnetic field are either magnetopause-like, separating plasmas with different properties, or tail-like, separating plasmas of rather similar properties. The magnetopause current sheets generally have a nearly limitless supply of magnetized plasma that can reconnect, possibly setting up steady-state reconnection. In contrast, the plasma on either side of a tail current sheet is stratified so that, as reconnection occurs, the plasma properties, in particular the Alfven velocity, change. If the density drops and the magnetic field increases markedly perpendicular to the sheet, explosive reconnection can occur. Even though steady state reconnection can take place at magnetopause current sheets, the process often appears to be periodic as if a certain low average rate was demanded by the conditions but only a rapid rate was available. Reconnection of sheared fields has been postulated to create magnetic ropes in the solar corona, at the Earth's magnetopause, and in the magnetotail. However, this is not the only way to produce magnetic ropes as the Venus ionosphere shows. The geometry of the reconnecting regions and the plasma conditions both can affect the rate of reconnection. Sorting out the various controlling factors can be assisted through the examination of reconnection in planetary settings. In particular we observe similar small-scale tearing in the magnetopause current layers of the Earth, Saturn. Uranus and Neptune and the magnetodisk current sheet at Jupiter. These sites may be seeds for rapid reconnection if the reconnection site reaches a high Alfven velocity region. In the Jupiter magnetosphere this appears to be achieved with resultant substorm activity. Similar seeds may be present in the Earth's magnetotail with the first one to reach explosive growth dominating the dynamics of the tail.

Russell, C. T.↗

NASA NTRS2013

Mars Entry Atmospheric Data System Trajectory Reconstruction Algorithms and Flight Results

The Mars Entry Atmospheric Data System is a part of the Mars Science Laboratory, Entry, Descent, and Landing Instrumentation project. These sensors are a system of seven pressure transducers linked to ports on the entry vehicle forebody to record the pressure distribution during atmospheric entry. These measured surface pressures are used to generate estimates of atmospheric quantities based on modeled surface pressure distributions. Specifically, angle of attack, angle of sideslip, dynamic pressure, Mach number, and freestream atmospheric properties are reconstructed from the measured pressures. Such data allows for the aerodynamics to become decoupled from the assumed atmospheric properties, allowing for enhanced trajectory reconstruction and performance analysis as well as an aerodynamic reconstruction, which has not been possible in past Mars entry reconstructions. This paper provides details of the data processing algorithms that are utilized for this purpose. The data processing algorithms include two approaches that have commonly been utilized in past planetary entry trajectory reconstruction, and a new approach for this application that makes use of the pressure measurements. The paper describes assessments of data quality and preprocessing, and results of the flight data reduction from atmospheric entry, which occurred on August 5th, 2012.

Karlgaard, Christopher D.↗

NASA NTRS2017

Mathematical Modeling of Electrodynamics Near the Surface of Earth and Planetary Water Worlds

An interesting feature of planetary bodies with hydrospheres is the presence of an electrically conducting shell near the global surface. This conducting shell may typically lie between relatively insulating rock, ice, or atmosphere, creating a strong constraint on the flow of large-scale electric currents. All or parts of the shell may be in fluid motion relative to main components of the rotating planetary magnetic field (as well as the magnetic fields due to external bodies), creating motionally-induced electric currents that would not otherwise be present. As such, one may expect distinguishing features in the types of electrodynamic processes that occur, as well as an opportunity for imposing specialized mathematical methods that efficiently address this class of application. The purpose of this paper is to present and discuss such specialized methods. Specifically, thin-shell approximations for both the electrodynamics and fluid dynamics are combined to derive simplified mathematical formulations describing the behavior of these electric currents as well as their associated electric and magnetic fields. These simplified formulae allow analytical solutions featuring distinct aspects of the thin-shell electrodynamics in idealized cases. A highly efficient numerical method is also presented that is useful for calculations under inhomogeneous parameter distributions. Finally, the advantages as well as limitations in using this mathematical approach are evaluated. This evaluation is presented primarily for the generic case of bodies with water worlds or other thin spherical conducting shells. More specific discussion is given for the case of Earth, but also Europa and other satellites with suspected oceans.

Tyler, Robert H.↗

NASA NTRSDate not supplied

A window on the composition of the early solar nebula: 2014MU69, Pluto, and Phoebe

The initial chemical composition of any solar nebula will depend upon the degree to which 1) organic and ice components form on dust grains, 2) organic and molecular species form in the gas phase, 3) organics and ices are exchanged between the gas and solid state, and 4) the precursor and newly formed (more complex) materials survive and are modified in the developing planetary system. Infrared and radio observations of star-forming regions reveal that complex chemistry occurs on icy grains, sometimes before stars even form. Additional processing, through the protosolar disk and within the solar nebula further modifies most, but probably not all, of the initial materials. In fact, the modern Solar System still carries a fraction of its interstellar inheritance [Alexander et al., 2017]. Here we focus on three examples of small bodies in our Solar System, each containing chemical and dynamical clues to its origin and evolution: the small, cold-classical Kuiper Belt object (KBO) 2014MU69 , Pluto and Saturn’s moon, Phoebe. The New Horizons flyby of 2014 MU69 has given the first view of an unaltered body composed of material originally in the solar nebula at ~45 AU. The spectrum reveals methanol ice (not commonly found), a possible detection of water ice (Stern et al. 2019). Pluto’s internal and surface inventory of volatiles and complex organics, together with active geological processes including cryo-volcanism, indicate a surprising level of activity on a body in the outermost region of the Solar System, and the fluid that emerges from subsurface reservoirs may contain material inherited from the solar nebula (Cruikshank et al. 2019). Meanwhile, Saturn's captured moon, Phoebe, carries high D/H in H2O [Clark et al. 2018)], and complex organics (Cruikshank et al. 2008), both consistent with its formation in, and inheritance from, the outer solar nebula. Together, these objects provide windows on the origin and evolution of our Solar System and constraints to be considered in future chemical and physical models of PPDs. The Spitzer Space telescope discovered the ring of dust around Saturn that emanated from the bombardment of Phoebe in the recent past, dislodging primitive Solar System material from deep within that satellite. In addition, Spitzer has provided detailed studies of the chemistry of star forming regions where methanol and other ices are readily observed. As a result of these and other observations, protoplanetary disk models are beginning to combine both dynamical and chemical complexities into their codes, resulting in new insights for exoplanetary systems.

Yvonne J. Pendleton↗

NASA NTRSDate not supplied

An Overview of Spacecraft Aerosols: Sources, Dynamics, and Knowledge Gaps

NASA has prioritized development of airborne particulate monitoring systems and mitigation strategies for future Lunar, Martian, and deep-space exploration missions. Airborne particles, also called aerosols, can cause human health problems ranging from mild respiratory discomfort to more severe disease. NASA’s suspended cabin particle and Lunar dust concentration requirements are motivated by protecting crew health and comfort during spaceflight, especially as mission durations lengthen and become increasingly ground-independent. Spacecraft cabin aerosols can originate from a variety of sources, including skin flakes, fibers from clothes and other materials, mechanical wear from equipment, and personal care products (e.g., antiperspirant). As NASA plans future expeditions to the Moon and Mars, Lunar and planetary dust compose an additional, under-characterized source for airborne particles. In addition to these known sources, recent studies on ISS cabin aerosols also revealed particles with unknown origins and poorly understood formation mechanisms, including some that may be formed by oxidative and/or heterogeneous chemical processes. The aerosol monitors payload, to be launched February 2025, will focus on understanding these unknown sources and processes, as well as demonstrating novel technologies for particulate monitoring to be infused in future space flight programs. In this presentation, we will present our knowledge of spacecraft cabin aerosols to date, summarizing aerosol measurement experiments from Shuttle through ISS. Cabin aerosol sources, known and unknown, will be summarized, and knowledge gaps for future long-duration space exploration missions will be discussed.

Claire Fortenberry↗

DOE OSTI2021

Magnetopause Reconnection and Indents Induced by Foreshock Turbulence

Abstract Based on global hybrid simulation results, we predict that foreshock turbulence can reach the magnetopause and lead to reconnection as well as Earth‐sized indents. Both the interplanetary magnetic field (IMF) and solar wind are constant in our simulation, and hence, all dynamics are generated by foreshock instabilities. The IMF in the simulation is mostly Sun‐Earth aligned with a weak northward and zero dawn‐dusk component, such that subsolar magnetopause reconnection is not expected without foreshock turbulence modifying the magnetosheath fields. We show a reconnection example to illustrate that the turbulence can create large magnetic shear angles across the magnetopause to induce local bursty reconnection. Magnetopause reconnection and indents developed from the impact of foreshock turbulence can potentially contribute to dayside loss of planetary plasmas.

58 GEOSCIENCES↗

NASA NTRS1978

The rings of Saturn: State of current knowledge and some suggestions for future studies

The state of our current knowledge of the properties of the ring system as a whole, and of the particles individually, is assessed. Attention is primarily devoted to recent results and possibilities for exploration of the ring system by a Saturn orbiter. In particular, the infrared and microwave properties of the ring system are discussed. The behavior of the ring brightness is not well understood in the critical transition spectral region from approximately 100 micrometers to approximately 1 cm. Also, the dynamical behavior of the ring system is discussed. Recent theoretical studies show that ongoing dynamical effects continually affect the ring structure in azimuth (possibly producing the A ring brightness asymmetry) and in the vertical direction. Orbital spacecraft-based studies of the rings will offer several unique advantages and impact important cosmogonical questions. Bistatic radar studies and millimeter-wavelength spectrometer/radiometry will give particle sizes and composition limits needed to resolve the question of the density of the rings, and provide important boundary conditions on the state of Saturn's protoplanetary nebula near the time of planetary formation.

Cuzzi, J. N.↗

NASA NTRS1990

Autonomous planetary rover at Carnegie Mellon

This report describes progress in research on an autonomous robot for planetary exploration. In 1989, the year covered by this report, a six-legged walking robot, the Ambler, was configured, designed, and constructed. This configuration was used to overcome shortcomings exhibited by existing wheeled and walking robot mechanisms. The fundamental advantage of the Ambler is that the actuators for body support are independent of those for propulsion; a subset of the planar joints propel the body, and the vertical actuators support and level the body over terrain. Models of the Ambler's dynamics were developed and the leveling control was studied. An integrated system capable of walking with a single leg over rugged terrain was implemented and tested. A prototype of an Ambler leg is suspended below a carriage that slides along rails. To walk, the system uses a laser scanner to find a clear, flat foothold, positions the leg above the foothold, contacts the terrain with the foot, and applies force enough to advance the carriage along the rails. Walking both forward and backward, the system has traversed hundreds of meters of rugged terrain including obstacles too tall to step over, trenches too deep to step in, closely spaced rocks, and sand hills. In addition, preliminary experiments were conducted with concurrent planning and execution, and a leg recovery planner that generates time and power efficient 3D trajectories using 2D search was developed. A Hero robot was used to demonstrate mobile manipulation. Indoor tasks include collecting cups from the lab floor, retrieving printer output, and recharging when its battery gets low. The robot monitors its environment, and handles exceptional conditions in a robust fashion, using vision to track the appearance and disappearance of cups, onboard sonars to detect imminent collisions, and monitors to detect the battery level.

Whittaker, William↗

NASA NTRS2002

Measurement of Meteor Impact Experiments Using Three-Component Particle Image Velocimetry

The study of hypervelocity impacts has been aggressively pursued for more than 30 years at Ames as a way to simulate meteoritic impacts. Development of experimental methods coupled with new perspectives over this time has greatly improved the understanding of the basic physics and phenomenology of the impact process. These fundamental discoveries have led to novel methods for identifying impact craters and features in craters on both Earth and other planetary bodies. Work done at the Ames Vertical Gun Range led to the description of the mechanics of the Chicxualub crater (a.k.a. K-T crater) on the Yucatan Peninsula, widely considered to be the smoking gun impact that brought an end to the dinosaur era. This is the first attempt in the world to apply three-component particle image velocimetry (3-D PIV) to measure the trajectory of the entire ejecta curtain simultaneously with the fluid structure resulting from impact dynamics. The science learned in these experiments will build understanding in the entire impact process by simultaneously measuring both ejecta and atmospheric mechanics.

Heineck, James T.↗

NASA NTRS2012

Debris Disk Structure and Morphology as Revealed by Aggressive STIS Multi-Roll Coronagraphy: A New Look at Some Old Friends

We present new imaging results from a well-selected sample of II circumstellar debris disks, all with HST pedigree, using STIS visible-light 6-roll PSF-template subtracted coronagraphy (PSFTSC). These new observations, pushing HST to its highest levels of coronagraphic performance, simultaneously probe both the interior regions of these debris systems, with inner working distances < app 8 AU for half the stars in this sample (corresponding to the giant planet and Kuiper belt regions within our own solar system), and the exterior regions far beyond. These new images enable direct inter-comparison of the architectures of these exoplanetary debris systems in the context of our own Solar System: These observations also permit us, for the first time, to characterize material in these regions at high spatial resolution and identify disk sub-structures that are signposts of planet formation and evolution; in particular, asymmetries and non-uniform debris structures that signal the presence of co-orbiting perturbing planets, and dynamical interactions (e.g., resulting in posited small grain stripping and disk "pollution") with the ISM. We focus here on recently acquired and reduced images of he circumstellar debris systems about: AU Mic (edge-on, and @ 10 pc the closest star in our sample), HD 61005, HD 32297 and HD 15115 (all with morphologies strongly suggestive of ISM wind interactions), HD 181327 & HDI07146 (close to face-on with respectively narrow and broad debris rings), and MP Mus (a "mature" proto-planetary disk hosted by a cTTS). All of our objects were previously observed in the near-IR with inferior spatial resolution and imaging efficacy, but with NICMOS r = 0.3" inner working angle (IWA) comparable to STIS multi-roll coronagraphy. The combination of new optical and existing near-IR imaging can strongly constrain the dust properties, thus enabling an assessment of grain processing and planetesimal populations. These results will directly inform upon the posited planet formation mechanisms that occur after the approximately 10 My epoch of gas depletion, a time in our solar system when giant planets were migrating and terrestrial planets were forming, and directly test theoretical models of these processes. These observations lmiquely probe both into the interior regions of these systems and are sensitive to and spatially resolve low surface-brightness (SB) material at large stellocentric distances with spatial resolution comparable to ACS and with augmenting NICMOS near-IR disk photometry in hand.

Grady, Carol A↗

NASA NTRSDate not supplied

The Payload and Operations of the Hera Mission

On 26 September 2022, NASA’s DART mission successfully impacted on Dimorphos, the secondary of the binary asteroid Didymos. DART released the Light Italian Cubesat for Imaging of Asteroids (LICIACube) two weeks before the impact, and LICIACube flew by the asteroids three minutes after the impact. On approach, DART took images of both asteroids, which, supported by additional imagery from LICIACube, characterized the pre-impact state of the Didymos system. DART changed the orbit of Dimorphos around Didymos, reducing its orbital period by 33 minutes. DART will be followed by a detailed investigation of the Didymos system and the outcome of the impact by ESA’s Hera mission. Hera will be launched in October 2024 and arrive at Didymos in early 2027. The presentation will focus on the payload of the Hera mission and the operations at the asteroid system. The main objectives of the Hera mission are to: - Measure the mass of Dimorphos to accurately measure the momentum transfer efficiency of the DART impact. - Characterise the change of the surface of Dimorphos by DART, including the properties (and existence!) of the DART crater, to improve our understanding of impact physics and to observe unweathered material, recently exposed at the surface. - Determine the physical properties of Dimorphos, including its internal structure, to allow scaling of the impact to different types of asteroids. - Measure the dynamical and physical state of the Didymos and Dimorphos system to constrain binary formation scenarios. Hera is equipped with the following payload: Two Asteroid Framing Cameras (AFCs) for both science and navigation. There resolution is ~10-4 rad/pixel, or 40 cm/pixel for close observations from 4 km. They will provide the target global properties as well as local geomorphology and will investigate the crater and impact site. They will also measure the mass of Dimorphos through the “wobble” motion of Didymos. The Planetary ALTimeter (PALT) will measure the distance to the target and shape and topography information complementary to that from AFC images. The Thermal InfraRed Imager (TIRI) will provide information about the thermal properties of the Didymos system and spectral information in the mid-infrared (6 bands from 7 – 14 µm). The Hyperscout-H hyperspectral imager will provide mineralogical information from 25 spectral bands between 665 and 975 nm. Milani, a 6 unit cubesat, will carry a visible to near-IR imaging spectrometer (ASPECT, 500 – 2500 nm) to derive mineralogical information on the composition of the asteroids, and a thermogravimeter (VISTA) to measure the abundance and constrain the composition of ambient dust particles. Juventas, a 6 unit cubesat, will carry a monostatic low-frequency radar (JuRa), and a gravimeter (GRASS) to derive interior and surface properties of the asteroids. The Radio Science experiment will measure the gravity field of the Didymos system. Measurements of the acceleration of the Hera spacecraft by the asteroid pair through the radio link between Earth and Hera will be used as well as the inter-satellite link between Hera and the two cubesats. We will describe how the goals of Hera will be achieved with the different payload elements.

Michael Küppers↗

NASA NTRSDate not supplied

Advances in Stereo Photogrammetry Capabilities for in-Situ Ejecta Measurements in Lunar Plume-Surface Interactions

Plume-surface interaction is a critical topic of interest as human spaceflight programs establish a renewed presence on the Moon and push onwards to Mars. The erosion of regolith and high-speed ejection of soil and rocks which occurs during a powered spacecraft landing on lunar or terrestrial bodies can pose serious risks to the vehicle during landing and to existing ground assets. Ground testing campaigns have provided data sets in relevant environments (e.g., low pressure) in tandem with predictive computational model validation. To-date, limited in-situ flight data exists to inform the study of the key phenomena of plume-surface interaction: plume-flow physics, soil erosion, and ejecta dynamics. In two upcoming lunar missions, erosion of the lunar regolith will be measured in-situ using the stereo photogrammetry technique as part of NASA’s Commercial Lunar Payload Services (CLPS) Program. The Stereo Cameras for Lunar Plume Surface Studies (SCALPSS) will use a multiple-camera system to measure the erosion of the lunar regolith due to the vehicles’ rocket engine plumes during descent and after landing. The application of stereo photogrammetry to accurately measure a realistic eroded shape has been validated in laboratory work ahead of the scheduled flights. In preparation for future CLPS, Artemis, or other lunar science missions, recent advancements have been made to measure the ejecta structure and particle dynamics in addition to the erosion of regolith using a SCALPSS-like photogrammetry system. The thickness and ejection angle of entrained soil and dust produced during plume-induced erosion can be used to determine how far debris will travel, and thus how it may impact nearby infrastructure or the landing vehicle itself. The present work highlights the development of this new flight instrumentation capability and its value to advancements in the plume-surface interaction measurement topic for lunar or planetary landings.

Olivia K. Tyrrell↗

DOE OSTI2023

Gas phase synthesis of the C40 nano bowl C 40 H 10

Nanobowls represent vital molecular building blocks of end-capped nanotubes and fullerenes detected in combustion systems and in deep space such as toward the planetary nebula TC-1, but their fundamental formation mechanisms have remained elusive. By merging molecular beam experiments with electronic structure calculations, we reveal a complex chain of reactions initiated through the gas-phase preparation of benzocorannulene (C 24 H 12 ) via ring annulation of the corannulenyl radical (C 20 H 9 • ) by vinylacetylene (C 4 H 4 ) as identified isomer-selectively in situ via photoionization efficiency curves and photoion mass-selected threshold photoelectron spectra. In silico studies provided compelling evidence that the benzannulation mechanism can be expanded to pentabenzocorannulene (C 40 H 20 ) followed by successive cyclodehydrogenation to the C40 nanobowl (C 40 H 10 ) – a fundamental building block of buckminsterfullerene (C 60 ). This high-temperature pathway opens up isomer-selective routes to nanobowls via resonantly stabilized free-radical intermediates and ring annulation in circumstellar envelopes of carbon stars and planetary nebulae as their descendants eventually altering our insights of the complex chemistry of carbon in our Galaxy.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗