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At least 1,423 records · Page 79
All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

Development and Validation of Two-Phase CFD Models for Key Elements of Propellant Tank CFM Operations in 1G and Microgravity – An Overview

This paper presents an overview of the state-of-the-art two-phase CFD models that have been developed for various propellant tank storage and transfer operations in 1g, partial gravity and microgravity. The models are developed in the framework of the industry standard ANSYS/Fluent CFD code, the capabilities of which have been significantly enhanced and customized through incorporation of unique submodels via User Defined Functions (UDF)s to satisfy the requirements of its intended variable gravity Cryogenic Fluid Management (CFM) applications. These models/submodels have been validated against experimental data that cross spatial scales, fluid types, and gravity levels in order to properly anchor the models’ physical and numerical fidelity. The CFM application/processes that have been modeled include tank self-pressurization, tank autogenous pressurization, tank pressure control using both subcooled jet mixing and droplet spray injection mechanisms, tank chilldown/filling, tank drainage, tank slosh for both volatile and non-volatile fluids. The strength and shortcomings of the two-phase models for each application is highlighted and discussed briefly.

Propellant Storage & Pressure Control↗
NASA NTRSDate not supplied

Development and Validation of Two-Phase CFD Models for Key Elements of Propellant Tank CFM Operations in 1G and Microgravity –An Overview

This paper presents an overview of the state-of-the-art two-phase CFD models that have been developed for various propellant tank storage and transfer operations in 1g, partial gravity, and microgravity. The models are developed in the framework of the industry standard ANSYS/Fluent CFD code, the capabilities of which have been significantly enhanced and customized through the incorporation of unique submodels via User Defined Functions (UDF)s to satisfy the requirements of its intended variable gravity Cryogenic Fluid Management (CFM) applications. These models/submodels have been validated against experimental data that cross spatial scales, fluid types, and gravity levels in order to properly anchor the models’ physical and numerical fidelity. The CFM application/processes that have been modeled include tank self-pressurization, tank autogenous pressurization, tank pressure control using both subcooled jet mixing and droplet spray injection mechanisms, tank chilldown/filling, tank drainage, tank slosh for both volatile and non-volatile fluids. The strength and shortcomings of the two-phase models for each application are highlighted and discussed briefly.

Computational Fluid Dynamics↗
DOE OSTI2026

Interface and Thermophysical Properties of R 32 Refrigerant

Driven by the urgent demand for efficient cooling in microelectronics and advanced thermal management systems, difluoromethane (R32/CH 2 F 2 ) has emerged as a promising candidate owing to its favorable thermophysical properties, including high heat transfer efficiency and low viscosity. While bulk properties such as density, viscosity, and thermal conductivity have been widely studied, interfacial properties, including surface tension and interfacial thickness, remain comparatively underexplored, despite their importance in phase-transition dynamics. Here, we perform molecular dynamics (MD) simulations from 180 to 300 K using an optimized transferable force field for fluoropropenes with enhanced electrostatics to assess both bulk and interfacial behavior of R32. Simulations reproduced density within ±2.1%, viscosity within 3.05%, and thermal conductivity within 7.41% of NIST reference data. Heat capacities (C p and C v ) were predicted within 5%. For interfacial properties, surface tension trends were reproduced within 13.58% deviation, and the vapor–liquid coexistence curve closely matched reference data, yielding a critical temperature of 345.7 K (1.6% deviation) and a critical density of 0.397 g/cm 3 (6.4% deviation). Importantly, the vapor–liquid interface exhibited pronounced temperature-dependent broadening across the 180–290 K range. This behavior correlates with increasing molecular kinetic energy, reduction in intermolecular cohesive interactions, and a progressive loss of preferential dipole alignment, which collectively enhance thermal fluctuation amplitudes at elevated temperatures. These validated results provide predictive molecular-level insights, particularly for interfacial properties that remain less characterized. By reducing property prediction errors in key parameters such as critical temperature, this work provides reliable inputs for heat-exchanger and system models. Such correlations can support optimized component sizing, improved performance, and reduced refrigerant charge. Beyond R32, the methodology offers a transferable framework for blended and next-generation low-GWP refrigerants, contributing to sustainable thermal management aligned with the 2027 EU F-Gas regulation and 2030 Kigali Amendment.

Fluids↗
NASA NTRS1997

Redox chemistry at liquid/liquid interfaces

The interface between two immiscible liquids with immobilized photosynthetic pigments can serve as the simplest model of a biological membrane convenient for the investigation of photoprocesses accompanied by spatial separation of charges. As it follows from thermodynamics, if the resolvation energies of substrates and products are very different, the interface between two immiscible liquids may act as a catalyst. Theoretical aspects of charge transfer reactions at oil/water interfaces are discussed. Conditions under which the free energy of activation of the interfacial reaction of electron transfer decreases are established. The activation energy of electron transfer depends on the charges of the reactants and dielectric permittivity of the non-aqueous phase. This can be useful when choosing a pair of immiscible solvents to decrease the activation energy of the reaction in question or to inhibit an undesired process. Experimental interfacial catalytic systems are discussed. Amphiphilic molecules such as chlorophyll or porphyrins were studied as catalysts of electron transfer reactions at the oil/water interface.

Non-NASA Center↗
NASA NTRS1974

The nature of Cygnus X-3 - A prototype for old population binary X-ray sources

Description of a model for Cyg X-3 based on a short-lived phase in the evolution of a U Geminorum-type binary where rapid mass transfer and mass loss occurs. X rays are generated by accretion on the white dwarf component, while both stars are enveloped in a thick stellar wind emanating from the red dwarf. Electron scattering in the cloud is responsible for the modulation of the X rays with the orbital period of 4.8 hours. Ultraviolet radiation and low-energy X rays absorbed in the cloud are reradiated in the optical and infrared, which, it is predicted, will display a 4.8-hr modulation in phase with the X-ray light curve. The X-ray absorption cutoff should also vary with phase, appearing at minimum energy when the source is at maximum light. The model also provides a framework in which certain aspects of the associated nonthermal radio source may be understood. Finally, it is suggested that the model may be applicable to Sco X-1 as well.

Davidsen, A.↗
DOE OSTI2025

Development of an Energy-Efficient and High-Productivity Ammonia Recovery and Removal Process Using Resin-Wafer Electrodeionization

As efforts to develop various energy resources, ammonia energy is emerging as a promising carbon-free fuel alternative. Recovering high-concentration ammonia and ammonium from wastewater potentially offers significant environmental and economic benefits. However, research on recovery technologies for industries such as semiconductors remains limited. This study develops an efficient, energy-saving ammonia recovery technology using Resin Wafer Electrodeionization (RW-EDI), specifically for the semiconductor industry. RW-EDI shows promise for recovering ammonia from high-concentration wastewater. By optimizing parameters, such as voltage and initial concentration, a balance between productivity and energy consumption is achieved. Results indicate that ammonium and fluoride ion transport kinetics are similar, with minimal competition and selectivity values between 0.95 and 1.08. As the initial ammonia/ammonium concentration increases from 500 to 8000 ppm, reaction rate constants and the overall mass transfer coefficient decrease. Increasing the voltage can enhance mass transfer and eliminate barriers. Ion transport primarily occurs in the RW solid phase, accounting for 93.89% of the total current. Additionally, RW-EDI shows superior specific energy consumption within a concentration range of 500 ppm to 8000 ppm, outperforming technologies like electrodialysis by reducing specific energy consumption from 8−15 kWh/kg-NH 4 + to 1.2−2.5 kWh/kg-NH 4 + . This study highlights RW-EDI’s potential for ammonia recovery, providing valuable insights for future applications in wastewater treatment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Hole doping in a negative charge transfer insulator

RE NiO 3 is a negative charge transfer energy system and exhibits a temperature-driven metal-insulator transition (MIT), which is also accompanied by a bond disproportionation (BD) transition. In order to explore how hole doping affects the BD transition, we have investigated the electronic structure of single-crystalline thin films of Nd 1-x Ca x NiO 3 by synchrotron based experiments and ab-initio calculations. Here we show that for a small value of x, the doped holes are localized on one or more Ni sites around the dopant Ca 2+ ions, while the BD state for the rest of the lattice remains intact. The effective charge transfer energy (Δ) increases with Ca concentration and the formation of BD phase is not favored above a critical x, suppressing the insulating phase. Our present study firmly demonstrates that the appearance of BD mode is essential for the MIT of the RE NiO 3 series.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2021

Ultrafast X-ray scattering offers a structural view of excited-state charge transfer

Intramolecular charge transfer and the associated changes in molecular structure in N,N'-dimethylpiperazine are tracked using femtosecond gas-phase X-ray scattering. The molecules are optically excited to the 3p state at 200 nm. Following rapid relaxation to the 3s state, distinct charge-localized and charge-delocalized species related by charge transfer are observed. The experiment determines the molecular structure of the two species, with the redistribution of electron density accounted for by a scattering correction factor. The initially dominant charge-localized state has a weakened carbon–carbon bond and reorients one methyl group compared with the ground state. Subsequent charge transfer to the charge-delocalized state elongates the carbon–carbon bond further, creating an extended 1.634 Å bond, and also reorients the second methyl group. At the same time, the bond lengths between the nitrogen and the ring-carbon atoms contract from an average of 1.505 to 1.465 Å. The experiment determines the overall charge transfer time constant for approaching the equilibrium between charge-localized and charge-delocalized species to 3.0 ps.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

2021 IC Project Report Viewgraph [Slides]

Here we show that cross-beam energy transfer (CBET) saturates through a resonance detuning that depends on the IAW phase velocity and that results from trapping-induced modifications to the ion distribution functions. For smaller phase velocities, the modifications to the distribution functions can rapidly thermalize in the presence of mid-Z ions, leading to a blueshift in the resonant frequency. For larger velocities, the modifications can persist, leading to a redshift in the resonant frequency.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2026

Autonomous Hydrogen Fueling Station

This project “Autonomous Hydrogen Fueling Station” covered the autonomous refueling with both gaseous hydrogen and liquid hydrogen. The part on gaseous hydrogen focused on the development of an autonomous robotic fueling arm that would couple to a fuel cell engine for hydrogen refueling without guidance from the forklift operator and budget period. Research was also covered for the robotic fueling with a commercial vehicle. The second phase of the project created the baseline for an autonomous liquid hydrogen transfer system that would minimize boil off losses by operating at thermodynamically efficient state points. For the development of the robotic fueling arm, testing was conducted to establish a baseline measurement of the accuracy and repeatability of a human operator positioning a lift truck in front of a dispenser. The goal was to establish the range of motion required for an autonomous fueling mechanism to mate a hydrogen nozzle with a receptacle on a fuel cell system installed in a forklift. The final design comprised a selective compliance articulated robot arm (SCARA)-type mechanism with two arms for horizontal motion and a ball screw for vertical movement and color and LIDAR cameras were used for marker identification and proximity awareness to guide the robotic arm to its target receptacle. Initial tests resulted in 199 out of 200 successful attempts at autonomous coupling of the dispensing coupler and a fuel cell engine, without hydrogen. The dispenser prototype was modified to include tubing for both hydrogen fuel and air purge lines, but subsequent tests were confounded by the shoulder motor over current errors which limited the robot from getting to the fully inserted position to achieve a positive latch. Robotic hydrogen refueling was successfully demonstrated over 1.5 hours of testing, Plug completed 29 successful latches with an average number of 4 sequential latches before failure. However, a robot capable of placing the nozzle with more force is required for higher reliability. For budget period two, a small scale (10 kg / transfer) automated control system was designed that would operate valves to control pressure and flow of liquid nitrogen between a source and receiving tank with an aim to minimize boil off losses by operating at the most thermodynamically efficient state points. Control system logic flow and a P&ID were developed prior to system safety characterization via HAZOP. A control narrative and system state points were defined. Delays in approval for a change of project objective and procurement issues precluded the construction and test of the final prototype system.

08 HYDROGEN↗
NASA NTRS1975

Multiple scattered radiation emerging from continental haze layers. 1: Radiance, polarization, and neutral points

The complete radiation field is calculated for scattering layers of various optical thicknesses. Results obtained for Rayleigh and haze scattering are compared. Calculated radiances show differences as large as 23% compared to the approximate scalar theory of radiative transfer, while the same differences are approximately 0.1% for a continental haze phase function. The polarization of reflected and transmitted radiation is given for various optical thicknesses, solar zenith angles, and surface albedos. Two types of neutral points occur for aerosol phase functions. Rayleigh-like neutral points arise from zero polarization that occurs at scattering angles of 0 deg and 180 deg. For Rayleigh phase functions, the position of these points varies with the optical thickness of the scattering layer. Non-Rayleigh neutral points are associated with the zeros of polarization which occur between the end points of the single scattering curve, and are found over a wide range of azimuthal angles.

Kattawar, G. W.↗
NASA NTRS1975

High power ferrite microwave switch

A high power ferrite microwave switch was developed along with associated electronic driver circuits for operation in a spaceborne high power microwave transmitter in geostationary orbit. Three units were built and tested in a space environment to demonstrate conformance to the required performance characteristics. Each unit consisted of an input magic-tee hybrid, two non-reciprocal latching ferrite phase shifters, an out short-slot 3 db quadrature coupler, a dual driver electronic circuit, and input logic interface circuitry. The basic mode of operation of the high power ferrite microwave switch is identical to that of a four-port, differential phase shift, switchable circulator. By appropriately designing the phase shifters and electronic driver circuits to operate in the flux-transfer magnetization mode, power and temperature insensitive operation was achieved. A list of the realized characteristics of the developed units is given.

Bardash, I.↗
NASA NTRS1976

Titian/Centaur D-1TTC-4 Viking A flight data report

Titan/Centaur TC-4 was launched from the Eastern Test Range, Complex 41, at 05:22 PM EDT on Wednesday, August 20, 1975. This was the second operational flight of the newest NASA unmanned launch vehicle. The spacecraft was the Viking A, the first of two orbiting and landing missions to Mars planned for the 1975 Martian launch opportunity. The objective of the launch phase of the mission, to inject the Viking spacecraft onto the planned transfer orbit to Mars, was successfully accomplished. This report presents a review of the launch vehicle system flight data.

Source record↗
NASA NTRS1976

Titan/Centaur D-1T TC-3 Viking B Flight Data Report

Titan/Centaur TC-3 was launched from the Eastern Test Range, Complex 41, at 02:34 PM EDT on Tuesday, September 9, 1975. This was the third operational flight of the newest NASA unmanned launch vehicle. The spacecraft was the Viking B, the second of two orbiting and landing missions to Mars planned for the 1975 Martian launch opportunity. The objective of the launch phase of the mission, to inject the Viking spacecraft onto the planned transfer orbit to Mars, was successfully accomplished. A review of the launch vehicle system flight data is presented.

Source record↗
NASA NTRS1976

Pioneer 10 ultraviolet photometer observations of Jupiter - The helium to hydrogen ratio

Pioneer 10 UV photometric observations of solar He I 584-A emissions diffusely reflected from the atmosphere of Jupiter are discussed which establish the expected presence of He in the planet. The intensity and profile of the solar He line are remeasured and found to be more intense than originally supposed, implying a lower value for the diffuse 584-A reflectivity of Jupiter and less He than previously estimated. Other measurements of the solar He line are reviewed, resonance scattering by He is analyzed, and radiative-transfer calculations for Jovian model atmospheres are improved by including the anisotropic phase function for helium resonance scattering. The assumption of coherent scattering in the formation of the Jovian airglow line is shown to be an accurate approximation, and present estimates of the atmospheric temperature and eddy diffusion coefficient are examined. An atmospheric He/H abundance ratio greater than zero but less than approximately 28% is determined by assuming an isothermal atmosphere with a temperature of 150 K and the range of eddy-diffusion values given by Pioneer 10 Ly-alpha observations. The effect of higher temperatures on the He/H abundance is briefly evaluated.

Carlson, R. W.↗
NASA NTRS1979

Two-stream theory of reflectance of snow

Spectral reflectance of snow under diffuse illumination is studied using the two-stream approximation of the radiative transfer equation. The scattering and absorption parameters of the radiative transfer equation - the single scattering albedo, the optical depth, and the integrated phase function are obtained from the grain size and density of snow. Analytical expressions for the intensity within the snowpack, the reflectance, and the asymptotic flux extinction coefficient, are given. Good agreement is shown between the theory and available experimental data on visible and near-infrared reflectance, and the asymptotic flux extinction coefficient. The theory may also be used to explain the observed effect of aging on the snow reflectance.

Choudhury, B. J.↗
NASA NTRS1982

Cauchy integral method for two-dimensional solidification interface shapes

A method is developed to determine the shape of steady state solidification interfaces formed when liquid above its freezing point circulates over a cold surface. The solidification interface, which is at uniform temperature, will form in a shape such that the non-uniform energy convected to it is locally balanced by conduction into the solid. The interface shape is of interest relative to the crystal structure formed during solidification; regulating the crystal structure has application in casting naturally strengthened metallic composites. The results also pertain to phase-change energy storage devices, where the solidified configuration and overall heat transfer are needed. The analysis uses a conformal mapping technique to relate the desired interface coordinates to the components of the temperature gradient at the interface. These components are unknown because the interface shape is unknown. A Cauchy integral formulation provides a second relation involving the components, and a simultaneous solution yields the interface shape.

Siegel, R.↗