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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,423 records · Page 79
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Establishing rapid analysis of Pu isotopes in seawater to study the impact of Fukushima nuclear accident in the Northwest Pacific

In order to evaluate the impact of the Fukushima derived Pu isotopes on seawater, a new analytical method to rapidly determine Pu isotopes in seawater by SF-ICP-MS including Fe(OH)2 primary co-precipitation, CaF 2 /LaF 3 secondary co-precipitation and TEVA+UTEVA+DGA extraction chromatographic separation was established. High concentration efficiency (~100%) and high U decontamination factor (~10 7 ) were achieved. The plutonium chemical recoveries were 74–88% with the mean of 83 ± 5%. The precisions for both 240 Pu/ 239 Pu atom ratios and 239+240 Pu activity concentrations were less than 5% when 15 L of seawater samples with the typical 239+240 Pu activity of the Northwest Pacific were measured. It just needs 12 hours to determine plutonium using this new method. The limit of detection (LOD) for 239 Pu and 240 Pu were both 0.08 fg/mL, corresponding to 0.01 mBq/m 3 for 239 Pu and 0.05 mBq/m 3 for 240 Pu when a 15 L volume of seawater was measured. This method was applied to determine the seawater samples collected 446–1316 km off the FDNPP accident site in the Northwest Pacific in July of 2013. The obtained 239+240 Pu activity concentrations of 1.21–2.19 mBq/m 3 and the 240 Pu/ 239 Pu atom ratios of 0.198–0.322 implied that there was no significant Pu contamination from the accident to the Northwest Pacific.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2022

Trimethyloxonium-mediated methylation strategies for the rapid and simultaneous analysis of chlorinated phenols in various soils by electron impact gas chromatography–mass spectrometry

Abstract The efficient methylation of a panel of five industrial and environmentally-relevant chlorophenols (CPs) employing trimethyloxonium tetrafluoroborate (TMO) for their qualitative detection and identification by electron impact gas chromatography–mass spectrometry (EI-GC–MS) is presented. The protocol’s execution is simple and smoothly converts the phenols into their O-methylated counterparts conveniently at ambient temperature. The efficiency of two versions of the protocol was successfully tested in their ability to simultaneously derivatize five CPs (2-chlorophenol, 2,4-dichlorophenol, 2,4,6-trichlorophenol, pentachlorophenol and triclosan) in six distinct, separate soil matrices (Nebraska EPA standard soil, Virginia Type A soil, Ottawa sand, Baker sand, Silt and Georgia EPA standard soil) when present at low levels (~ 10 μgg −1 ). The first version involves the direct derivatization of the spiked soils with the methylating salt while the second one involves an initial soil extraction step of the CPs followed by methylation. The MDL values for each methylated CP were determined and lower values were found (4.1–13.2 ng . mL −1 ) for both sand matrices (Ottawa and Baker) as well as for the Georgia EPA standard soil, while larger values (8.2–21.8 ng . mL −1 ) were found for the Virginia Type soil, Nebraska EPA standard soil and Silt. The presented protocol offers a safer and more practical alternative to the universally employed diazomethane method and can be readily applicable to matrices other than soils. Furthermore, the protocols described herein may find applicability to the methylation of other analytes bearing acidic protons.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2014

Dose impact in radiographic lung injury following lung SBRT: Statistical analysis and geometric interpretation

Purpose: To demonstrate a new method of evaluating dose response of treatment-induced lung radiographic injury post-SBRT (stereotactic body radiotherapy) treatment and the discovery of bimodal dose behavior within clinically identified injury volumes. Methods: Follow-up CT scans at 3, 6, and 12 months were acquired from 24 patients treated with SBRT for stage-1 primary lung cancers or oligometastic lesions. Injury regions in these scans were propagated to the planning CT coordinates by performing deformable registration of the follow-ups to the planning CTs. A bimodal behavior was repeatedly observed from the probability distribution for dose values within the deformed injury regions. Based on a mixture-Gaussian assumption, an Expectation-Maximization (EM) algorithm was used to obtain characteristic parameters for such distribution. Geometric analysis was performed to interpret such parameters and infer the critical dose level that is potentially inductive of post-SBRT lung injury. Results: The Gaussian mixture obtained from the EM algorithm closely approximates the empirical dose histogram within the injury volume with good consistency. The average Kullback-Leibler divergence values between the empirical differential dose volume histogram and the EM-obtained Gaussian mixture distribution were calculated to be 0.069, 0.063, and 0.092 for the 3, 6, and 12 month follow-up groups, respectively. The lower Gaussian component was located at approximately 70% prescription dose (35 Gy) for all three follow-up time points. The higher Gaussian component, contributed by the dose received by planning target volume, was located at around 107% of the prescription dose. Geometrical analysis suggests the mean of the lower Gaussian component, located at 35 Gy, as a possible indicator for a critical dose that induces lung injury after SBRT. Conclusions: An innovative and improved method for analyzing the correspondence between lung radiographic injury and SBRT treatment dose has been demonstrated. Bimodal behavior was observed in the dose distribution of lung injury after SBRT. Novel statistical and geometrical analysis has shown that the systematically quantified low-dose peak at approximately 35 Gy, or 70% prescription dose, is a good indication of a critical dose for injury. The determined critical dose of 35 Gy resembles the critical dose volume limit of 30 Gy for ipsilateral bronchus in RTOG 0618 and results from previous studies. The authors seek to further extend this improved analysis method to a larger cohort to better understand the interpatient variation in radiographic lung injury dose response post-SBRT.

62 RADIOLOGY AND NUCLEAR MEDICINE↗
DOE OSTI2014

Offshore Wind Market and Economic Analysis

This report is the third annual assessment of the U.S. offshore wind market. It includes the following major sections: Section 1: key data on developments in the offshore wind technology sector and the global development of offshore wind projects, with a particular focus on progress in the United States; Section 2: analysis of policy developments at the federal and state levels that have been effective in advancing offshore wind deployment in the United States; Section 3: analysis of actual and projected economic impact, including regional development and job creation; Section 4: analysis of developments in relevant sectors of the economy with the potential to affect offshore wind deployment in the United States

17 WIND ENERGY↗
DOE OSTI2016

Feeder Voltage Regulation with High-Penetration PV Using Advanced Inverters and a Distribution Management System: A Duke Energy Case Study

Duke Energy, Alstom Grid, and the National Renewable Energy Laboratory teamed up to better understand the impacts of solar photovoltaics (PV) on distribution system operations. The core goal of the project is to compare the operational - specifically, voltage regulation - impacts of three classes of PV inverter operations: 1.) Active power only (Baseline); 2.) Local inverter control (e.g., PF...not equal...1, Q(V), etc.); and 3.) Integrated volt-VAR control (centralized through the distribution management system). These comparisons were made using multiple approaches, each of which represents an important research-and-development effort on its own: a) Quasi-steady-state time-series modeling for approximately 1 year of operations using the Alstom eTerra (DOTS) system as a simulation engine, augmented by Python scripting for scenario and time-series control and using external models for an advanced inverter; b) Power-hardware-in-the-loop (PHIL) testing of a 500-kVA-class advanced inverter and traditional voltage regulating equipment. This PHIL testing used cosimulation to link full-scale feeder simulation using DOTS in real time to hardware testing; c) Advanced visualization to provide improved insights into time-series results and other PV operational impacts; and d) Cost-benefit analysis to compare the financial and business-model impacts of each integration approach.

14 SOLAR ENERGY↗
DOE OSTI2019

Demonstration of the Coating Analysis Capabilities in BISON

In order to improve the accident tolerance of light water reactor (LWR) fuel, coated cladding materials have been proposed which exhibit much slower oxidation kinetics in high-temperature steam than Zr-alloys. This behavior should decrease the energy release due to oxidation and allow the cladding to remain integral longer in the presence of high-temperature steam, making accident mitigation more likely. In order to determine how these coating materials will adjust the behavior of the Zr-alloy cladding during normal reactor operation, simulations have been performed using the Bison fuel performance code. This analysis focused on modeling and comparing the integral thermo-mechanical performance of coated and uncoated zircaloy cladding with uranium dioxide fuel under normal operating conditions. This analysis demonstrates the ability to model a discrete meshed coating bonded to the cladding exterior and provides a comparison with an uncoated fuel rod. A generic range of coating material properties are implemented given the differences and unknowns regarding the proprietary coating properties used by the vendors. A main-effects analysis was performed to identify trends and sensitivities in how coating material properties affect key fuel performance metrics. Lastly, because residual stresses are expected to form in the coating, arising from the high temperature coating application process and application techniques, an additional analysis was performed to identify the impact of these stresses on the cladding behavior. Future analysis efforts will target more comprehensive documentation of this main effects analysis by sampling the results at the beginning and middle-of-life in order to capture important behavior before and during the onset of gap closure.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS1976

Methods for data reduction and loads analysis of Space Shuttle Solid Rocket Booster model water impact tests

The methodology used to predict full scale space shuttle solid rocket booster (SRB) water impact loads from scale model test data is described. Tests conducted included 12.5 inch and 120 inch diameter models of the SRB. Geometry and mass characteristics of the models were varied in each test series to reflect the current SRB baseline configuration. Nose first and tail first water entry modes were investigated with full-scale initial impact vertical velocities of 40 to 120 ft/sec, horizontal velocities of 0 to 60 ft/sec., and off-vertical angles of 0 to plus or minus 30 degrees. The test program included a series of tests with scaled atmospheric pressure.

Source record↗
NASA NTRS1983

Impact of LANDSAT MSS sensor differences on change detection analysis

Differences in overall sensor response, due to both factors within the sensor system, and external factors such as atmospheric effects, must be dealt with before change detection techniques using image differencing can be successfully implemented. The approach used to be coregister data to a base, followed by between image scatterogram generation and evaluation, and image differencing. Data from LANDSAT 2 and 3 were registered to LANDSAT 4 data. The area was limited to a small protion of the scene near the City of Santa Cruz because this was the only area cloud and haze free on all the images. Visual examination of each image, as well as the between image scatterograms, provide information on radiometric characteristics of each sensor. The image differencing, after normalizing for radiometric differences, provides a visual depiction of geometric distortions.

Likens, W.↗
NASA NTRS1983

Impact of LANDSAT MSS sensor differences on change detection analysis

Some 512 by 512 pixel subwindows for simultaneously acquired scene pairs obtained by LANDSAT 2,3 and 4 multispectral band scanners were coregistered using LANDSAT 4 scenes as the base to which the other images were registered. Scattergrams between the coregistered scenes (a form of contingency analysis) were used to radiometrically compare data from the various sensors. Mode values were derived and used to visually fit a linear regression. Root mean square errors of the registration varied between .1 and 1.5 pixels. There appear to be no major problem preventing the use of LANDSAT 4 MSS with previous MSS sensors for change detection, provided the noise interference can be removed or minimized. Data normalizations for change detection should be based on the data rather than solely on calibration information. This allows simultaneous normalization of the atmosphere as well as the radiometry.

Likens, W. C.↗
NASA NTRS1991

Analysis of delamination in cross ply laminates initiating from impact induced matrix cracking

Several two dimensional finite element analyses of (0 sub 2/90 sub 8/0 sub 2) glass/epoxy and graphite-epoxy composite laminates were performed to study some of the characteristics of damage development due to an impact load. A cross section through the thickness of the laminate with fixed ends, and carrying a transverse load in the center was analyzed. Inclined matrix cracks such as those produced by low velocity impact were modeled in the 90 deg ply group. The introduction of the matrix cracks caused large interlaminar tension and shear stresses in the vicinity of both crack tips in the 0/90 and 90/0 interfaces. The large interlaminar stresses at the ends of the matrix cracks indicate that matrix cracking may give rise to delamination. The ratio of mode I to total strain energy release rate at the beginning of delamination calculated at the two matrix crack tips was 60 and 28 pct., respectively, in the glass/epoxy laminate. The corresponding ratio was 97 and 77 pct. in the graphite-epoxy laminate. Thus, a significant mode I component of strain energy release rate may be present at the delamination initiation due to an impact load.

Salpekar, S. A.↗
NASA NTRS1992

Analysis of energy dissipation and deposition in elastic bodies impacting at hypervelocities

A series of impact problems were analyzed using the Eulerian hydrocode CTH. The objective was to quantify the amount of energy dissipated locally by a projectile-infinite plate impact. A series of six impact problems were formulated such that the mass and speed of each projectile were varied in order to allow for increasing speed with constant kinetic energy. The properties and dimensions of the plate were the same for each projectile impact. The resulting response of the plate was analyzed for global Kinetic Energy, global momentum, and local maximum shear stress. The percentage of energy dissipated by the various hypervelocity impact phenomena appears as a relative change of shear stress at a point away from the impact in the plate.

Medina, David F.↗
NASA NTRS2002

Impact of TRMM and SSM/I Rainfall Assimilation on Global Analysis and QPF

Evaluation of QPF skills requires quantitatively accurate precipitation analyses. We show that assimilation of surface rain rates derived from the Tropical Rainfall Measuring Mission (TRMM) Microwave Imager and Special Sensor Microwave/Imager (SSM/I) improves quantitative precipitation estimates (QPE) and many aspects of global analyses. Short-range forecasts initialized with analyses with satellite rainfall data generally yield significantly higher QPF threat scores and better storm track predictions. These results were obtained using a variational procedure that minimizes the difference between the observed and model rain rates by correcting the moist physics tendency of the forecast model over a 6h assimilation window. In two case studies of Hurricanes Bonnie and Floyd, synoptic analysis shows that this procedure produces initial conditions with better-defined tropical storm features and stronger precipitation intensity associated with the storm.

Hou, Arthur↗
NASA NTRS2011

Organic Compounds in Stardust

The successful return of the STARDUST spacecraft provides a unique opportunity to investigate the nature and distribution of organic matter in cometary dust particles collected from Comet 81P/Wild-2. Analysis of individual cometary impact tracks in silica aerogel using the technique of two-step laser mass spectrometry (L2MS) demonstrates the presence of complex aromatic organic matter. While concerns remain as to the organic purity of the aerogel collection medium and the thermal effects associated with hypervelocity capture, the majority of the observed organic species appear indigenous to the impacting particles and are hence of cometary origin. While the aromatic fraction of the total organic matter present is believed to be small, it is notable in that it appears to be N-rich. Spectral analysis in combination with instrumental detection sensitivities suggest that N is incorporated predominantly in the form of aromatic nitriles (R-C N). While organic species in the STARDUST samples do share some similarities with those present in the matrices of carbonaceous chondrites, the closest match is found with stratospherically collected interplanetary dust particles. These findings are consistent with the notion that a fraction of interplanetary dust is of cometary origin. The presence of complex organic N-containing species in comets has astrobiological implications since comets are likely to have contributed to the prebiotic chemical inventory of both the Earth and Mars.

McKay, David S.↗
NASA NTRS2019

Impact of Assimilating AIRS Cloud Cleared Radiances on the Analysis and Forecast of Polar Lows

Previous work by this team (Reale et al. 2018) has found that the current assimilation of AIRS (Atmospheric InfraRed Sounder) radiances on a regularly spaced thinning grid is suboptimal, probably because of horizontal error correlation over meteorologically inactive areas. Moreover, cloud-cleared radiances appear to be a better product than clear-sky radiances, but need to be assimilated at a much lower density globally, because of the higher information content. Specifically: 1. Assimilation of AIRS cloud-cleared radiances at a density of about one quarter of the clear-sky radiances improves global forecast skill; 2. An adaptive thinning strategy assimilating cloud-cleared radiances at reduced density globally except around tropical cyclones (TCs), leads to substantial improvement in the structure and intensity forecast of TCs without damaging global skill.

Polar Low↗