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At least 1,423 records · Page 79

High aspect ratio organic light-emitting diodes

Reliability is particularly challenging for organic light-emitting diodes (OLEDs) used in solid-state lighting applications, because OLED lifetime is inversely proportional to luminance, and most lighting applications demand high luminance. Here we introduce a strategy to overcome this tradeoff by constructing OLEDs on a substrate with sub-mm, high aspect ratio surface texture. By creating more active OLED area per unit lighting panel area, the device current density required to generate a given panel luminance decreases. We validate this approach for fluorescent and phosphorescent OLEDs, demonstrating good thickness uniformity on corrugated substrates with area enhancement factors up to 1.4x using a standard thermal evaporator. Relative to planar controls at the same panel current density, the high aspect ratio devices achieve a 2.7-fold increase in operating lifetime and up to a 40% increase in external light extraction efficiency, indicating that this approach offers a powerful pathway to improve the efficiency and lifetime of OLED lighting.

OLED↗

Toward fully coherent soft x-ray free-electron laser via echo-enabled harmonic generation in fourth generation synchrotron light sources

Having previously reported on bunching via echo-enabled harmonic generation (EEHG) as an effective way to improve the longitudinal coherence in the NSLS-II storage ring [X. Yang et al., Sci. Rep. 12, 9437 (2022)], we demonstrate that this EEHG scheme can be easily adopted to any fourth generation diffraction-limited synchrotron light source with significant benefits. The advantage of the scheme is that it requires no change of the lattice and is fully compatible with other beamlines. Since the EEHG performance is mainly determined by the momentum compaction, beam emittances, and beta functions of a SR lattice, we have identified these crucial parameters and successfully built a generalized model, which can predict the performance of nearly any SLS. Regarding the fourth generation SLSs, momentum compactions are often significantly smaller; thus, to cover the x rays with a photon energy of up to 1 keV, we utilize a specific design, including a 250 nm seed-laser wavelength. Our model predicts that for most of the current and future fourth generation SLSs, the EEHG scheme can produce significant prebunching up to harmonic 200 and, thus, generate a few MW scale peak power at 1.25 nm wavelength.

47 OTHER INSTRUMENTATION↗

High Aspect Ratio OLEDs

Long-term reliability is especially challenging for organic light emitting diodes (OLEDs) used in solid-state lighting applications because OLED lifetime is inversely proportional to luminance, and most lighting applications demand high luminance. This project explored a new strategy to overcome this tradeoff by constructing OLEDs on a substrate with sub-mm, high aspect ratio surface texture. By creating more active OLED area per unit lighting panel area, the device current density required to generate a given panel luminance decreases. We validated this approach for both fluorescent and phosphorescent OLEDs, demonstrating good thickness uniformity on corrugated substrates with area enhancement factors up to 1.4x using a standard thermal evaporator. Relative to planar controls at the same panel current density, the high aspect ratio devices achieve a 2.7-fold increase in operating lifetime and up to a 40% increase in external light extraction efficiency. Experiments carried out on a pilot-line OLED manufacturing system demonstrated good coating uniformity, indicating that this approach has the potential to be implemented at scale and therefore offers a powerful pathway to improve the efficiency and lifetime of OLED lighting.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

MagicDraw Report Generation for the Resource Prospector Payload

Magic Draw is a tool currently being used by System Engineers to design model-based representations of the Resource Prospector (RP) Payload. Often, reports are needed to display and communicate the information and schematics within the MagicDraw model. Since constant changes are being made to the model, these reports also need to be maintained with each change. Because this is tedious and time consuming, I was assigned to implement MagicDraw Report Wizard Templates using Velocity Template Language (VTL) scripts. These report template scripts pull specific images, data, and elements directly from the MagicDraw model, allowing the user to have a report that is updated with the current state of the model upon its generation.

MagicDraw↗

Robust Adaptive Decentralized Dynamic State Estimation with Unknown Control Inputs using Field PMU Measurements

This paper proposes a robust adaptive decentralized dynamic state estimation method for power system with unknown inputs of the highly detailed synchronous machine model. The temporal and spatial correlations among the unknown inputs are used to derive a vector auto-regressive model. The latter is further integrated together with state transition and measurement models for joint state and unknown inputs estimation. Thanks to the consideration of implicit cross-correlations between the states and the unknown inputs, only generator terminal voltage and current phasors are needed. Test results on the US WECC system using the field PMU measurements show that the proposed method is able to track both the system dynamic states and unknown controller inputs. These information could significantly benefit the validation and calibration of generator controller parameters.

Zhao, Junbo↗

Literature Review on Next Generation Solvent Isopar ® L Vapor Pressure Curve and the Partitioning of its Modifier and Extractant

The Next Generation Solvent (NGS) is set to replace the Original Caustic Side Solvent Extractant (CSSX) at the Salt Waste Processing Facility (SWPF). The Savannah River National Laboratory (SRNL) was requested by Savannah River Mission Completion (SRMC), formerly Savannah River Remediation (SRR), to perform a literature review on the following topics to address flammability concerns with the current solvent: Isopar ® L vapor pressure curve for NGS, partitioning ratio for the extractant MaxCalix and the modifier Cs-7SB, and high cesium concentration impacts on NGS radiolysis and potential solvent degradation rates in high cesium concentrations. The following conclusions and recommendations are made based on previous experimental work and literature: (1) Current SWPF flammable gas generation calculations use an Isopar ® L vapor pressure curve based on experimental testing with the Original CSSX solvent. No such testing to date has been performed with NGS. It is suggested that the decrease in Cs-7SB concentration for NGS compared to the Original CSSX solvent would lead to a slightly higher vapor pressure at all temperatures in SWPF vessels. A bounding NGS vapor pressure curve has been provided; it is recommended to see if these values would challenge current flammability controls and to perform testing if needed.(2) The partitioning ratio for Cs-7SB is known in the Original CSSX solvent with dilute nitric acid and caustic solutions. No tests could be found for the partitioning of Cs-7SB to dilute boric acid solutions; however, a similar partitioning ratio is expected. Due to the lipophilic alkyl chains on MaxCalix, it is expected to be even less soluble than BOBCalixC6 in the aqueous phase and should not be considered a significant contributor to the f organic term. Additionally, the reaction rate of N,N’,N’’-Tris(3,7-dimethyloctyl)guanidine (TiDG) or its degradation products with a hydrogen radical should be estimated/determined if they are found to be significant contributors to the f organic term. (3) NGS is expected to see much higher Cs concentrations at SWPF in comparison to its use at the Modular CSSX Unit (MCU). These higher Cs concentrations could influence radiolytic degradation rates of the solvent. NGS appears to be fairly stable to radiolytic degradation based on previous testing and its use at MCU. However, there has not been radiolytic flammable gas generation testing with NGS to date. There is a risk that the continued use of G-values obtained for flammable gases produced from the irradiation of the Original CSSX solvent is not bounding for NGS, but this is considered a very low risk due to the similarities in the composition of the solvents, as well as the conservatisms in the experimental design of the Original CSSX testing.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The interaction of a dipolar thunderstorm with its global electrical environment

The role of the thundercloud in the global electric circuit has been considered by many researchers. Thus, Holzer and Saxon (1952) have constructed a simple model of a bipolar thunderstorm. The global models considered provide insight into the atmospheric electric circuit but are restricted, both by various analytical mathematical representations and by computer size, to a grid of about five degrees in latitude and longitude. A need exists, therefore, for the development of a numerical regional model capable of resolving small-scale phenomena so that their coupling into the global-scale circuit can be examined. The construction of a two-dimensional quasi-static numerical model of atmospheric electricity is discussed. The model provides a basis for the calculation of the global electric field and current distribution produced by a single thunderstorm generator. In connection with the calculations, the thunderstorm was defined by a quasi-static current source function which generates a dipole charge configuration.

Tzur, I.↗

Assessing First-Order Dependence of Thermolytic HGR on Glycolate at Low Glycolate Concentrations

This report describes the results of testing performed to investigate the assumed first-order behavior of glycolate at low concentrations in the current Glycolate Thermolytic Hydrogen Generation Rate (HGR) expression. Four experiments were performed at 100 °C using a simulant based on a Tank 28 supernate sample, and the glycolate concentration in the experiments ranged from 5 - 175 mg/L. The thermolytic HGR results from all tests were well-described by the current Glycolate Thermolytic HGR Model. A linear fit of the Ln(HGR) and Ln(Gly) gave a suggested reaction order of 1.15. Additionally, by taking into account prior knowledge on how varying chemistry impacts the HGR, a reaction order of 0.99 was obtained. Both cases suggest that the data validates the assumed first-order dependence of HGR on glycolate.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

An Approach to Establishing System Benefits for Technologies In NASA's Spaceliner Investment Area

NASA's has established long term goals for access-to-space. The third generation launch systems are to be fully reusable and operational around 2025. The goals for the third generation launch system are to significantly reduce cost and improve safety over current systems. The Advanced Space Transportation Program Office (ASTP) at the NASA's Marshall Space Flight Center in Huntsville, AL has the agency lead to develop space transportation technologies. Within ASTP, under the Spaceliner Investment Area, third generation technologies are being pursued. The Spaceliner Investment Area's primary objective is to mature vehicle technologies to enable substantial increases in the design and operating margins of third generation RLVs (current Space Shuttle is considered the first generation RLV) by incorporating advanced propulsion systems, materials, structures, thermal protection systems, power, and avionics technologies. Advancements in design tools and better characterization of the operational environment will result in reduced design and operational variabilities leading to improvements in margins. Improvements in operational efficiencies will be obtained through the introduction of integrated vehicle health management, operations and range technologies. Investments in these technologies will enable the reduction in the high operational costs associated with today's vehicles by allowing components to operate well below their design points resulting in improved component operating life, reliability, and safety which in turn reduces both maintenance and refurbishment costs. The introduction of advanced technologies may enable horizontal takeoff by significantly reducing the takeoff weight and allowing use of existing infrastructure. This would be a major step toward the goal of airline-like operation. These factors in conjunction with increased flight rates, resulting from reductions in transportation costs, will result in significant improvements of future vehicles. The real-world problem is that resources are limited and technologies need to be prioritized to assure the resources are spent on technologies that provide the highest system level benefits. Toward that end, a systems approach is being taken to determine the benefits of technologies for the Spaceliner Investment Area. Technologies identified to be enabling will be funded. However, the other technologies will be funded based on their system's benefits. Since the final launch system concept will not be decided for many years, several vehicle concepts are being evaluated to determine technology benefits. Not only performance, but also cost and operability are being assessed. This will become an annual process to assess these technologies against their goals and the benefits to various launch systems concepts. The paper describes the system process, tools and concepts used to determine the technology benefits. Preliminary results will be presented along with the current technology investments that are being made by ASTP's Spaceliner Investment Area.

Hueter, Uwe↗

Dephasingless two-color terahertz generation

A laser pulse composed of a fundamental and an appropriately phased second harmonic can drive a time-dependent current of photoionized electrons that generates broadband THz radiation. Over the propagation distances relevant to many experiments, dispersion causes the relative phase between the harmonics to evolve. This “dephasing” slows the accumulation of THz energy and results in a multi-cycle THz pulse with significant angular dispersion. Here, we introduce a novel optical configuration that compensates the relative phase evolution, allowing for the formation of a half-cycle THz pulse with almost no angular dispersion. The configuration uses the spherical aberration of an axilens to map a prescribed radial phase variation in the near field to a desired longitudinal phase variation in the far field. Simulations that combine this configuration with an ultrashort flying focus demonstrate the formation of a half-cycle THz pulse with a controlled emission angle and 1/4 the angular divergence of the multi-cycle pulse created by a conventional optical configuration.

47 OTHER INSTRUMENTATION↗

Generators and the (Accelerated) Future

With the High Luminosity LHC coming online in the near future, event generators will need to provide very large event samples to match the experimental precision. Currently, the estimated cost to generate these events exceeds the computing budget of the LHC experiments. To address these issues, the computing efficiency of event generators need to be improved. Many different approaches are being taken to achieve this goal. I will cover the ongoing work on implementing event generators on the GPUs, machine learning the matrix element, machine learning the phase space, and minimizing the number of negative weight events.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Ion-wave current instabilities and anomalous resistivity.

A theory of ion-wave current instabilities which takes into account, in a self-consistent manner, the inhomogeneities generated by field-aligned currents in a collisionless plasma is presented. Diamagnetic current associated with the current-produced density gradient is included in the distribution. The theory predicts that for a given frequency, the current threshold for ion-wave current instabilities is, in general, much below the threshold of ion acoustic instability in a uniform plasma as given by Fried and Gould. The current threshold is essentially zero in the limit when the ion Landau damping effect is negligible, or equivalently, the ion-wave current instabilities are absolute if there are no limitations on the wavelength. This is true even in the absence of externally applied density gradients in contrast to Kadomtsev's drift-wave results. For dimensions of interest in laboratory plasmas, the predicted linear growth rate increases with increasing longitudinal wavelength and with decreasing wavelength parallel to the diamagnetic current. Under the conditions of an experiment on anomalous resistivity (the dimensions but not the geometry of the machine have been considered), there is good agreement between the predicted onset of ion-wave current instabilities and the experimental data on the onset of anomalous resistivity.

Kan, J. R.↗

A modeling of magnetic field variations during magnetospheric substorms

Magnetic field variations in the noon-midnight plane during the magnetospheric substorm are studied in terms of changes of three current systems: the dynamo-driven current on the magnetopause, the cross-tail current and the field-aligned current-auroral electrojet system. The field-aligned current is assumed to be generated as a result of interruption and subsequent diversion of the cross-tail current to the ionosphere. It is concluded that the available observations are consistent with a large increase of the three currents.

Akasofu, S.-I.↗

Investigating Interference Term in DUNE & SBND Neutrino Interactions with ACHILLES

Understanding neutrino oscillations can help us answer some of the universe’s most fundamental questions like: Why is there more matter than antimatter? Neutrino-nucleus cross-sections (probability of neutrino interactions with nuclei) are a leading uncertainty in the measurements of neutrino oscillations. To meaningfully determine scattering parameters, measurements must be supported by robust theoretical modeling, which can be provided via event generators. In this poster, we use ACHILLES to investigate the interference term of neutrino interactions with both DUNE-ND and SBND flux configurations [1] [2]. The interference term is the quantum amplitude interference resulting from 1p1h or 2p2h neutrino-nucleon interactions, and isn't modeled in current industry standard event generators.

Serumaga, Peera [UC, San Diego (main); Fermilab]↗

The Analysis of a Vortex Type Magnetohydrodynamic Induction Generator

Consideration it is given to the performance to the characteristics of an AC magnetohydrodynamic power generator, A rotating magnetic field is imposed on the vortex flow of an electrically conducting fluid, which is injected tangentially into an annulus formed by two nonconducting concentric cylinders and two nonconducting end plates. A perturbation technique is used to determine the two dimensional velocity and three dimensional electromagnetic field and current distributions. Finally, the generated power, the ohmic losses, the effective power and the electrical efficiency of the converter system are calculated.

MAGNETOHYDRODYNAMIC GENERATOR↗

Diamagnetic mechanism of critical current non-reciprocity in multilayered superconductors

The suggestion that non-reciprocal critical current (NRC) may be an intrinsic property of non-centrosymmetric superconductors has generated renewed theoretical and experimental interest motivated by an analogy with the non-reciprocal resistivity due to the magnetochiral effect in uniform materials with broken spatial and time-reversal symmetry. Theoretically it has been understood that terms linear in the Cooper pair momentum do not contribute to NRC, although the role of higher-order terms remains unclear. In this work we show that critical current non-reciprocity is a generic property of multilayered superconductor structures in the presence of magnetic field-generated diamagnetic currents. In the regime of an intermediate coupling between the layers, the Josephson vortices are predicted to form at high fields and currents. Experimentally, we report the observation of NRC in nanowires fabricated from InAs/Al heterostructures. The effect is independent of the crystallographic orientation of the wire, ruling out an intrinsic origin of NRC. Non-monotonic NRC evolution with magnetic field is consistent with the generation of diamagnetic currents and formation of the Josephson vortices. This extrinsic NRC mechanism can be used to design novel devices for superconducting circuits.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Catalytic Removal of Oxygen and Pollutants in Exhaust Gases from Pressurized Oxy-Combustors

The primary goal of this project was to develop and validate advanced catalytic materials and systems for purifying the flue gas generated from pressurized oxy-combustors in an effort to achieve the purity specifications of carbon dioxide (CO 2 ) streams required by the U.S. Department of Energy (USDOE) for application in enhanced oil recovery. The technology has shown great potential for improving energy efficiency, simplifying process complexity, and lowering costs compared with current state-of-the-art oxy-combustion flue gas purification technologies. Laboratory studies were conducted for the development, characterization, and screening of metal catalysts for residual oxygen (O 2 ) reduction with methane (CH 4 ) and multifunctional carbon catalysts for combined nitrogen oxides (NO x ), sulfur oxides (SO x ), and mercury (Hg) removal. A bench-scale reverse-flow fixed-bed (RFFB) reactor and a trickle-bed direct-contact cooler (DCC) reactor capable of treating 15 standard liters per min of pressurized oxy-combustion flue gas were fabricated and tested with both a simulated flue gas in the laboratory and a slipstream of actual flue gas at a 100 kW th Staged, Pressurized Oxy-Combustion (SPOC) pilot facility. Process simulation and techno-economic studies were performed to evaluate the energy efficiency and cost of the developed catalytic flue gas purification process integrated into a conceptual 550-MWe SPOC power plant. The goal and objectives of the project have been successfully accomplished. A cobalt-manganese (CoMn) oxide catalyst was developed and demonstrated in the bench-scale RFFB reactor in either a reverse-flow or one-direction flow mode of operation that met the success criterion of performance for residual O 2 reduction. A carbon catalyst was developed and demonstrated in the bench-scale DCC reactor that met the success criterion of performance for combined NO x /SO x /Hg removal. Slipstream testing of the integrated DCC-RFFB system at the SPOC pilot facility demonstrated stable operation and verified the superior performance obtained in the laboratory. The techno-economic analysis showed that a 550-MWe SPOC plant integrated with the catalytic flue gas purification process would result in costs of electricity of $\$$96.94/MWh and $\$$80.27/MWh in two assessed cases compared with $\$$91.07/MWh reported for the USDOE’s Current Technology Case, which generated only a partially pure CO 2 stream. On the basis of the results and findings from this project, scale-up studies of materials production and system demonstration and optimization studies of reactors and processes are recommended at the next stage of technology development.

20 FOSSIL-FUELED POWER PLANTS↗

Manipulating Neutral Atoms in Chip-Based Magnetic Traps

Several techniques for manipulating neutral atoms (more precisely, ultracold clouds of neutral atoms) in chip-based magnetic traps and atomic waveguides have been demonstrated. Such traps and waveguides are promising components of future quantum sensors that would offer sensitivities much greater than those of conventional sensors. Potential applications include gyroscopy and basic research in physical phenomena that involve gravitational and/or electromagnetic fields. The developed techniques make it possible to control atoms with greater versatility and dexterity than were previously possible and, hence, can be expected to contribute to the value of chip-based magnetic traps and atomic waveguides. The basic principle of these techniques is to control gradient magnetic fields with suitable timing so as to alter a trap to exert position-, velocity-, and/or time-dependent forces on atoms in the trap to obtain desired effects. The trap magnetic fields are generated by controlled electric currents flowing in both macroscopic off-chip electromagnet coils and microscopic wires on the surface of the chip. The methods are best explained in terms of examples. Rather than simply allowing atoms to expand freely into an atomic waveguide, one can give them a controllable push by switching on an externally generated or a chip-based gradient magnetic field. This push can increase the speed of the atoms, typically from about 5 to about 20 cm/s. Applying a non-linear magnetic-field gradient exerts different forces on atoms in different positions a phenomenon that one can exploit by introducing a delay between releasing atoms into the waveguide and turning on the magnetic field.

Aveline, David↗