The effect of centrifugal distortion on CO2-laser frequencies
Values of the coefficient H for the appropriate carbon-dioxide laser levels are estimated on the basis of theoretical considerations. The values are compared with data obtained by Petersen et al. (1973). It is found that very small perturbations become important as the accuracy of the CO2-laser frequencies increases, especially for lines far away from the band center. Careful experimental frequency measurements are mandatory in the high J region if an accuracy of the order of 10 kHz is desired.