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At least 1,423 records · Page 79

A note on the total mass of comets in the solar system

The assumption that the very low albedo determined for Halley's comet is typical of all short period comets, taken together with the assumption that the average sizes of long and short-period comets are approximately equal, leads to an increase in the total mass of comets in the solar system by almost two orders of magnitude. If gravitational ejection from the Uranus-Neptune zone during the later phases of planet formation is indeed responsible for the classical Oort cloud between 0.0001 and 0.00001 AU, then the mass of comets in this transplanetary region during cosmogonic times has to exceed the combined masses of Uranus and Neptune by over an order of magnitude. Furthermore, if the recent arguments for as many as 10 to the 14th comets in an 'inner' Oort cloud between about 40 and 10,000 AU are valid, then the total mass of comets in the solar system approaches 2 percent of a solar mass.

Mendis, D. A.↗

The solar-stellar connection - Internal rotation in low-mass stars

The problem of the internal rotation of stars with masses and internal evolution similar to the sun is investigated, emphasizing the need to construct models of stellar convection zones which are consistent with full interior models. The affect of the distribution of angular momentum within a star on the formation process in a gas cloud and on the internal evolution throughout the premain-sequence phase and the early postmain-sequence phase is considered. The generation of magnetic fields associated with chromospheric activity via the interaction of rotation with convection is discussed. It is noted that rotationally induced mixing can alter the rate of evolution, thus affecting the luminosity function of star clusters.

Demarque, Pierre↗

Chemical evolution of primitive solar system bodies

Observations on organic molecules and compounds containing biogenic elements in the interstellar medium and in the primitive bodies of the solar system are reviewed. The discovery of phosphorus molecular species in dense interstellar clouds, the existence of organic ions in the dust and gas phase of the comas of Comet Halley, and the presence of presolar, deuterium-hydrogen ratios in the amino acids of carbonaceous chondrites are discussed. The relationships between comets, dark asteroids, and carbonaceous chondrites are examined. Also, consideration is given to the chemical evolution of Titan, the primitive earth, and early Mars.

Oro, J.↗

Ice water path estimation and characterization using passive microwave radiometry

Model computations of top-of-atmospheric microwave brightness temperatures T(B) from layers of precipitation-sized ice of variable bulk density and ice water content (IWC) are presented. It is shown that the 85-GHz T(B) depends essentially on the ice optical thickness. The results demonstrate the potential usefulness of scattering-based channels for characterizing the ice phase and suggest a top-down methodology for retrieval of cloud vertical structure and precipitation estimation from multifrequency passive microwave measurements. Attention is also given to radiative transfer model results based on the multiparameter radar data initialization from the Cooperative Huntsville Meteorological Experiment (COHMEX) in northern Alabama. It is shown that brightness temperature warming effects due to the inclusion of a cloud liquid water profile are especially significant at 85 GHz during later stages of cloud evolution.

Vivekanandan, J.↗

Prevention of accretion onto white dwarfs by stellar winds

There is indirect observational evidence that hot white dwarfs may have weak stellar winds. In this paper, the interaction between such a wind and the flow of ISM material in the gravitational field of the white dwarf is investigated with the aim of finding limits on the mass-loss rate and terminal velocity of winds capable of preventing accretion from the ISM. The limiting cases of no relative motion of the star and the ISM and supersonic relative motion of the star through ISM are separately investigated. Each case is treated by generalizing models for the interaction between the solar wind and the local ISM to include the effects of gravity. It is found that, for wind velocities expected for radiatively driven winds, mass-loss rates as low as 10 exp -21 solar mass/yr are sufficient to prevent accretion from the hot phase of the ISM. To prevent accretion during passages through cold clouds, wind mass-loss rates of order 10 exp -18 to 10 exp -17 are required.

Macdonald, James↗

Infrared emission spectra of candidate interstellar aromatic molecules

Interstellar dust is responsible, through surface reactions, for the creation of molecular hydrogen, the main component of the interstellar clouds in which new stars form. Intermediate between small, gas-phase molecules and dust are the polycyclic aromatic hydrocarbons (PAHs). Such molecules could account for 2-30% of the carbon in the Galaxy, and may provide nucleation sites for the formation of carbonaceous dust. Although PAHs have been proposed as the sources of the unidentified infrared emission bands that are observed in the spectra of a variety of interstellar sources, the emission characteristics of such molecules are still poorly understood. Here we report laboratory emission spectra of several representative PAHs, obtained in conditions approximating those of the interstellar medium, and measured over the entire spectral region spanned by the unidentified infrared bands. We find that neutral PAHs of small and moderate size can at best make only a minor contribution to these emission bands. Cations of these molecules, as well as much larger PAHs and their cations, remain viable candidates for the sources of these bands.

Non-NASA Center↗

Radiation-induced D/H Exchange Rate Constants in Aliphatics Embedded in Water Ice

Gas-phase and solid-state chemistry in low-temperature interstellar clouds and cores leads to a D/H enhancement in interstellar ices, which is eventually inherited by comets, meteorites, and even planetary satellites. Hence, the D/H ratio has been widely used as a tracer for the origins of extraterrestrial chemistry. However, the D/H ratio can also be influenced by cosmic rays, which are ubiquitous and can penetrate even dense interstellar molecular cores. The effects of such high-energy radiation on deuterium fractionation have not been studied in a quantitative manner. In this study, we present rate constants for radiation-induced D-to-H exchange for fully deuterated small (1–2 C) hydrocarbons embedded in H2O ice at 20 K and H-to-D exchange for the protiated forms of these molecules in D2O ice at 20 K. We observed larger rate constants for H-to-D exchange in the D2O ice versus D-to-H exchange in H2O ice, which we have attributed to the greater bond strength of C–D versus C–H. We find that the H-to-D exchange rate constants are smaller for protiated methane than ethane, in agreement with bond energies from the literature. We are unable to obtain rate constants for the unsaturated and reactive hydrocarbons ethylene and acetylene. Interpretation of the rate constants suggest that D/H exchange products are formed in abundance alongside radiolysis products. We discuss how our quantitative and qualitative data can be used to interpret the D/H ratios of aliphatic compounds observed throughout space.

Ice destruction↗

Gas-phase synthesis of anthracene and phenanthrene via radical-radical reaction induced ring expansions

Unraveling reaction mechanisms of aromatic and resonance-stabilized radicals is critical to understanding molecular mass growth processes to polycyclic aromatic hydrocarbons (PAHs) and carbonaceous nanoparticles in distinct astrophysical environments (molecular clouds, circumstellar envelopes) and combustion systems. Using photoelectron photoion coincidence spectroscopy (PEPICO), we explored the gas-phase reaction of the methyl radical (CH 3 • ) with the aromatic and resonance-stabilized fluorenyl radical (C 13 H 9 • ) under high-temperature conditions in a chemical microreactor. Anthracene and phenanthrene were detected isomer-selectively using photoionization efficiency (PIE) curves and mass-selected threshold photoelectron (ms-TPE) spectra. While phenanthrene is produced through a radical-radical recombination of the carbon-centered radicals, anthracene may plausibly be formed through an unconventional radical addition to a low spin-density fluorenyl carbon. These pathways result in five-membered ring expansion—a critical mechanism crucial to PAH mass growth converting bent PAHs into planar nanostructures.

Goettl, Shane J. [University of Hawai‘i at Mānoa, ↗

Scattering Properties of the Venusian Clouds Observed by the UV Imager on board Akatsuki

We analyze the albedo of Venus obtained from the UV Imager on board Akatsuki. A relative global mean albedo over phase angle is used in this study, and we confirm the glory feature at 283 and 365 nm in the data acquired in 2016 May. We successfully simulate the observation using a radiative transfer model. Our results show that cloud aerosols of r{sub eff}=1.26 μm and v{sub eff}=0.076 (mode 2) can explain the glory, consistent with a property of aerosols previously suggested by using the Venus Monitoring Camera on board Venus Express. We find that SO{sub 2} and the unknown UV absorber are necessary factors to explain the decreasing trend of the observed relative albedo at phase angles larger than 10°. We suggest a range of possible SO{sub 2} abundance from 80 to 400 ppbv at the cloud top level, depending on atmospheric conditions assumed.

79 ASTRONOMY AND ASTROPHYSICS↗

Robust atom optics for Bragg atom interferometry

Multi-photon Bragg diffraction is a powerful method for fast, coherent momentum transfer of atom waves. However, laser noise, Doppler detunings, and cloud expansion limit its efficiency in large momentum transfer (LMT) pulse sequences. We present simulation studies of robust Bragg pulses developed through numerical quantum optimal control. Optimized pulse performance under noise and cloud inhomogeneities is analyzed and compared to analogous Gaussian and adiabatic rapid passage pulses in simulated LMT Mach–Zehnder interferometry sequences. The optimized pulses maintain robust population transfer and phase response over a broader range of noise, resulting in superior contrast in LMT sequences with thermal atom clouds and intensity inhomogeneities. Large optimized LMT sequences use lower pulse area than Gaussian pulses, making them less susceptible to spontaneous emission loss. The optimized sequences maintain over five times better contrast with tens of momentum separation and offer more improvement with greater LMT. Such pulses could allow operation of Bragg atom interferometers with unprecedented sensitivity, improved contrast, and hotter atom sources.

74 ATOMIC AND MOLECULAR PHYSICS↗

Evolving the Land Information System into a Cloud Computing Service

The Land Information System (LIS) was developed to use advanced flexible land surface modeling and data assimilation frameworks to integrate extremely large satellite- and ground-based observations with advanced land surface models to produce continuous high-resolution fields of land surface states and fluxes. The resulting fields are extremely useful for drought and flood assessment, agricultural planning, disaster management, weather and climate forecasting, water resources assessment, and the like. We envisioned transforming the LIS modeling system into a scientific cloud computing-aware web and data service that would allow clients to easily setup and configure for use in addressing large water management issues. The focus of this Phase 1 project was to determine the scientific, technical, commercial merit and feasibility of the proposed LIS-cloud innovations that are currently barriers to broad LIS applicability. We (a) quantified the barriers to broad LIS utility and commercialization (high performance computing, big data, user interface, and licensing issues); (b) designed the proposed LIS-cloud web service, model-data interface, database services, and user interfaces; (c) constructed a prototype LIS user interface including abstractions for simulation control, visualization, and data interaction, (d) used the prototype to conduct a market analysis and survey to determine potential market size and competition, (e) identified LIS software licensing and copyright limitations and developed solutions, and (f) developed a business plan for development and marketing of the LIS-cloud innovation. While some significant feasibility issues were found in the LIS licensing, overall a high degree of LIS-cloud technical feasibility was found.

54 ENVIRONMENTAL SCIENCES↗

Vertical structure and physical processes of the Madden-Julian Oscillation: Biases and uncertainties at short range

We present an analysis of diabatic heating and moistening processes from 12 to 36 h lead time forecasts from 12 Global Circulation Models as part of the “Vertical structure and physical processes of the Madden-Julian Oscillation (MJO)” project. A lead time of 12–36 h is chosen to constrain the large-scale dynamics and thermodynamics to be close to observations while avoiding being too close to the initial spin-up of the models as they adjust to being driven from the Years of Tropical Convection (YOTC) analysis. A comparison of the vertical velocity and rainfall with the observations and YOTC analysis suggests that the phases of convection associated with the MJO are constrained in most models at this lead time although the rainfall in the suppressed phase is typically overestimated. Although the large-scale dynamics is reasonably constrained, moistening and heating profiles have large intermodel spread. In particular, there are large spreads in convective heating and moistening at midlevels during the transition to active convection. Radiative heating and cloud parameters have the largest relative spread across models at upper levels during the active phase. A detailed analysis of time step behavior shows that some models show strong intermittency in rainfall and differences in the precipitation and dynamics relationship between models. In conclusion, the wealth of model outputs archived during this project is a very valuable resource for model developers beyond the study of the MJO. Additionally, the findings of this study can inform the design of process model experiments, and inform the priorities for field experiments and future observing systems.

54 ENVIRONMENTAL SCIENCES↗

Comparisons of CFD Simulations of Icing Wind Tunnel Clouds with Experiments Conducted at the NASA Propulsions Systems Laboratory

This paper evaluates simulation predictions against experimental test data of icing clouds that were produced during 2018 ice crystal icing physics tests conducted at the NASA Propulsion Systems Laboratory icing wind tunnel. Aero-thermal and cloud parameters are set and known upstream at the tunnel inlet and spray system, but change as the cloud and air thermodynamically interact as the flowing masses reach the tunnel test section. Utilizing the ANSYS Fluent Discrete Phase Model function, 3D computational fluid dynamics (CFD) simulations were performed, capturing the thermodynamic interactions between the test parameters, and providing predictions of the aero thermal and cloud conditions at the tunnel test section. Simulation predictions were compared with test data that were measured at the tunnel exit plane. Evaluations focused on the cloud concentration (total water content), humidity content, and air temperature. CFD simulation predictions showed areas of agreement and disagreement. Simulations showed that cloud concentration profiles at the test section are strongly related to the initial spray nozzle pattern used at the tunnel inlet. Experimental data suggest that greater dispersion of the cloud occurred as the simulated cloud predicted areas of high and low cloud concentration compared to test data profiles. Simulations, however, captured the magnitude and location of the change in humidity content and the change in air temperature due to the presence of the cloud reasonably well, when compared to test data. This result would suggest that while the ANSYS simulation did not fully predict the spreading of the cloud as measured during experiment, it did capture evaporation and the molecular movements of air and vapor relatively well.

CFD↗

Comparisons of CFD Simulations of Icing Wind Tunnel Clouds with Experiments Conducted at the NASA Propulsions Systems Laboratory

This paper evaluates simulation predictions against experimental test data of icing clouds that were produced during 2018 ice crystal icing physics tests conducted at the NASA Propulsion Systems Laboratory icing wind tunnel. Aero-thermal and cloud parameters are set and known upstream at the tunnel inlet and spray system, but change as the cloud and air thermodynamically interact as the flowing masses reach the tunnel test section. Utilizing the ANSYS Fluent Discrete Phase Model function, 3D computational fluid dynamics (CFD) simulations were performed, capturing the thermodynamic interactions between the test parameters, and providing predictions of the aero thermal and cloud conditions at the tunnel test section. Simulation predictions were compared with test data that were measured at the tunnel exit plane. Evaluations focused on the cloud concentration (total water content), humidity content, and air temperature. CFD simulation predictions showed areas of agreement and disagreement. Simulations showed that cloud concentration profiles at the test section are strongly related to the initial spray nozzle pattern used at the tunnel inlet. Experimental data suggest that greater dispersion of the cloud occurred as the simulated cloud predicted areas of high and low cloud concentration compared to test data profiles. Simulations, however, captured the magnitude and location of the change in humidity content and the change in air temperature due to the presence of the cloud reasonably well, when compared to test data. This result would suggest that while the ANSYS simulation did not fully predict the spreading of the cloud as measured during experiment, it did capture evaporation and the molecular movements of air and vapor relatively well.

CFD↗

Combining disdrometer, microscopic photography, and cloud radar to study distributions of hydrometeor types, size and fall velocity

Addressing solid precipitation poses additional challenges compared to warm rain due to complex hydrometeor shapes involved, including the dependence of fall velocity on hydrometeor sizes, hydrometeor size distributions, and hydrometeor classification. This study is an extension of our previous work (Niu et al., 2010) to address these challenges by combining measurements from a PARSIVEL disdrometer, microscope photography, and millimeter wavelength cloud radar. The combined measurements are analyzed to classify the precipitation hydrometeor types, examine the dependence of fall velocity on hydrometeor sizes for different hydrometeor types, and determine the best distributions to describe the hydrometeor size distributions of different hydrometeor types. The results show: (1) Hydrometeors can be classified to four main types of raindrop, graupel, snowflake and mixed-phase according to the dependence of terminal velocity on particle sizes, corresponding microscope photos and cloud radar observations; (2) There are significant scatters in fall velocity for a given hydrometer size velocities, and the fall velocity spread for the solid hydrometeors appear wider than that for raindrops across hydrometeor sizes, with that for the mixed-phase precipitation being largest, suggesting that the effects of hydrometeor shape on hydrometeor fall velocities; (3) Hydrometeor size distributions for the four types can all be well described by the Gamma or Weibull distribution; Weibull (Gamma) distribution performs better when skewness is less (larger) than 2.

54 ENVIRONMENTAL SCIENCES↗

Design and Performance of McRas in SCMs and GEOS I/II GCMs

The design of a prognostic cloud scheme named McRAS (Microphysics of clouds with Relaxed Arakawa-Schubert Scheme) for general circulation models (GCMs) will be discussed. McRAS distinguishes three types of clouds: (1) convective, (2) stratiform, and (3) boundary-layer types. The convective clouds transform and merge into stratiform clouds on an hourly time-scale, while the boundary-layer clouds merge into the stratiform clouds instantly. The cloud condensate converts into precipitation following the auto-conversion equations of Sundqvist that contain a parametric adaptation for the Bergeron-Findeisen process of ice crystal growth and collection of cloud condensate by precipitation. All clouds convect, advect, as well as diffuse both horizontally and vertically with a fully interactive cloud-microphysics throughout the life-cycle of the cloud, while the optical properties of clouds are derived from the statistical distribution of hydrometeors and idealized cloud geometry. An evaluation of McRAS in a single column model (SCM) with the GATE Phase III and 5-ARN CART datasets has shown that together with the rest of the model physics, McRAS can simulate the observed temperature, humidity, and precipitation without many systematic errors. The time history and time mean incloud water and ice distribution, fractional cloudiness, cloud optical thickness, origin of precipitation in the convective anvil and towers, and the convective updraft and downdraft velocities and mass fluxes all show a realistic behavior. Performance of McRAS in GEOS 11 GCM shows several satisfactory features but some of the remaining deficiencies suggest need for additional research involving convective triggers and inhibitors, provision for continuously detraining updraft, a realistic scheme for cumulus gravity wave drag, and refinements to physical conditions for ascertaining cloud detrainment level.

Sud, Yogesh C.↗

Mars dust and cloud opacities and scattering properties

We have recently completed an analysis of the visible emission-phase function (EPF) sequences obtained with the solar-band channel of the Infrared Thermal Mapping (IRTM) instrument onboard the two Viking Orbiters. Roughly 100 of these EPF sequences were gathered during the 1977-1980 period, in which the total broadband (.3-3.0 microns) reflectances of the atmosphere/surface above specific locations on Mars were measured versus emission angle as the spacecraft passed overhead. A multiple scattering radiative transfer program was employed to model the EPF observations in terms of the optical depths of dust/clouds, their single scattering albedos and phase functions, and the Lambert albedos and phase coefficient of the underlying surfaces. Due to the predominance of atmospheric scattering at large atmospheric pathlengths and/or large dust opacities, we were able to obtain strong constraints on the scattering properties of dust/clouds and their opacities for a wide range of latitudes, longitudes, and seasons on Mars.

Clancy, R. T.↗

Cation, Anion, and Radical Isomers of C4H4N: Computational Characterization and Implications for Astrophysical and Planetary Environments

Nitrogen-containing ions and molecules in the gas phase have been detected in non-Earth environments such as dark molecular clouds and more recently in the atmosphere of Saturn's moon Titan. These molecules may serve as precursors to larger heterocyclic structures that provide the foundation of complex biological molecules. On Titan, molecules of m/z 66 have been detected by the Cassini mission, and species of the empirical formula C 4 H 4 N may contribute to this signature. We have characterized seven isomers of C 4 H 4 N in anionic, neutral radical, and cationic states using density functional theory. Structures were optimized using the range-separated hybrid ωB97X-V with the cc-pVTZ and aug-cc-pVTZ basis sets. Anionic and radical C4H4N favor cyclic structures with aromatic and quasi-aromatic electron arrangements, respectively. Interestingly, ionization from the radical surface to the cation induces significant changes in structural stability, and the global minimum for positively charged isomers is CH 2 CCHCNH + , a pseudo-linear species reminiscent of cyanoallene. Select formation pathways to these structures from Titan's existing or postulated gas-phase species, reactions that are also relevant for other astrophysical environments, are discussed. By characterizing C 4 H 4 N isomers, we have identified energetically stable anionic, radical, and cationic structures that may be present in Titan's atmosphere and dark molecular clouds.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗