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Rh2CoGa crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Rh2CoGa ribbons oriented in the (1, 0, 0) direction. Rh is bonded in a linear geometry to one Co and one Ga atom. The Rh–Co bond length is 2.22 Å. The Rh–Ga bond length is 2.38 Å. Co is bonded in a linear geometry to two equivalent Rh atoms. Ga is bonded in a linear geometry to two equivalent Rh atoms.
MgRh2Bi crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two MgRh2Bi ribbons oriented in the (1, 0, 0) direction. Mg is bonded in a linear geometry to two equivalent Rh atoms. Both Mg–Rh bond lengths are 2.64 Å. Rh is bonded in a linear geometry to one Mg and one Bi atom. The Rh–Bi bond length is 2.47 Å. Bi is bonded in a linear geometry to two equivalent Rh atoms.
LaRh3C is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. La is bonded to twelve equivalent Rh atoms to form LaRh12 cuboctahedra that share corners with twelve equivalent LaRh12 cuboctahedra, faces with six equivalent LaRh12 cuboctahedra, and faces with eight equivalent CRh6 octahedra. All La–Rh bond lengths are 3.02 Å. Rh is bonded to four equivalent La and two equivalent C atoms to form a mixture of distorted corner, edge, and face-sharing RhLa4C2 octahedra. The corner-sharing octahedra tilt angles range from 0–60°. Both Rh–C bond lengths are 2.13 Å. C is bonded to six equivalent Rh atoms to form CRh6 octahedra that share corners with six equivalent CRh6 octahedra and faces with eight equivalent LaRh12 cuboctahedra. The corner-sharing octahedral tilt angles are 0°.
Ca3Rh4Ge13 crystallizes in the cubic Pm-3n space group. The structure is three-dimensional. Ca is bonded in a 8-coordinate geometry to four equivalent Rh and twelve equivalent Ge atoms. All Ca–Rh bond lengths are 3.20 Å. There are eight shorter (3.17 Å) and four longer (3.25 Å) Ca–Ge bond lengths. Rh is bonded in a 6-coordinate geometry to three equivalent Ca and six equivalent Ge atoms. All Rh–Ge bond lengths are 2.50 Å. There are two inequivalent Ge sites. In the first Ge site, Ge is bonded in a 2-coordinate geometry to three equivalent Ca, two equivalent Rh, and one Ge atom. The Ge–Ge bond length is 3.03 Å. In the second Ge site, Ge is bonded in a cuboctahedral geometry to twelve equivalent Ge atoms.
La2RhSi3 crystallizes in the hexagonal P-62c space group. The structure is three-dimensional. there are two inequivalent La sites. In the first La site, La is bonded to twelve equivalent Si atoms to form LaSi12 cuboctahedra that share edges with twelve equivalent LaSi8Rh4 cuboctahedra and faces with eight LaSi12 cuboctahedra. There are six shorter (3.22 Å) and six longer (3.24 Å) La–Si bond lengths. In the second La site, La is bonded to four equivalent Rh and eight equivalent Si atoms to form a mixture of edge and face-sharing LaSi8Rh4 cuboctahedra. All La–Rh bond lengths are 3.24 Å. There are four shorter (3.23 Å) and four longer (3.25 Å) La–Si bond lengths. Rh is bonded in a 3-coordinate geometry to six equivalent La and three equivalent Si atoms. All Rh–Si bond lengths are 2.42 Å. Si is bonded in a 1-coordinate geometry to six La, one Rh, and two equivalent Si atoms. There are one shorter (2.39 Å) and one longer (2.40 Å) Si–Si bond lengths.
DyRh2Tl is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Dy is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Dy–Rh bond lengths are 2.90 Å. Rh is bonded in a body-centered cubic geometry to four equivalent Dy and four equivalent Tl atoms. All Rh–Tl bond lengths are 2.90 Å. Tl is bonded in a body-centered cubic geometry to eight equivalent Rh atoms.
MgRhZn2 is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Mg is bonded in a distorted body-centered cubic geometry to six equivalent Rh and eight equivalent Zn atoms. All Mg–Rh bond lengths are 3.11 Å. All Mg–Zn bond lengths are 2.69 Å. Rh is bonded in a distorted body-centered cubic geometry to six equivalent Mg and eight equivalent Zn atoms. All Rh–Zn bond lengths are 2.69 Å. Zn is bonded in a body-centered cubic geometry to four equivalent Mg and four equivalent Rh atoms.
ZrRh3B is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Zr is bonded to twelve equivalent Rh atoms to form ZrRh12 cuboctahedra that share corners with twelve equivalent ZrRh12 cuboctahedra, faces with six equivalent ZrRh12 cuboctahedra, and faces with eight equivalent BRh6 octahedra. All Zr–Rh bond lengths are 2.94 Å. Rh is bonded to four equivalent Zr and two equivalent B atoms to form a mixture of distorted corner, edge, and face-sharing RhZr4B2 octahedra. The corner-sharing octahedra tilt angles range from 0–60°. Both Rh–B bond lengths are 2.08 Å. B is bonded to six equivalent Rh atoms to form BRh6 octahedra that share corners with six equivalent BRh6 octahedra and faces with eight equivalent ZrRh12 cuboctahedra. The corner-sharing octahedral tilt angles are 0°.
SmPmRh2 is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Sm is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Sm–Rh bond lengths are 3.04 Å. Pm is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Pm–Rh bond lengths are 3.04 Å. Rh is bonded in a body-centered cubic geometry to four equivalent Sm and four equivalent Pm atoms.
Zr4Rh2N crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. there are two inequivalent Zr sites. In the first Zr site, Zr is bonded in a 6-coordinate geometry to six equivalent Rh atoms. All Zr–Rh bond lengths are 2.76 Å. In the second Zr site, Zr is bonded in a 2-coordinate geometry to two equivalent Rh and two equivalent N atoms. Both Zr–Rh bond lengths are 2.82 Å. Both Zr–N bond lengths are 2.32 Å. Rh is bonded in a 9-coordinate geometry to six Zr atoms. N is bonded to six equivalent Zr atoms to form corner-sharing NZr6 octahedra. The corner-sharing octahedral tilt angles are 36°.
Tb3Rh4Ge13 crystallizes in the cubic Pm-3n space group. The structure is three-dimensional. Tb is bonded in a 8-coordinate geometry to four equivalent Rh and twelve equivalent Ge atoms. All Tb–Rh bond lengths are 3.20 Å. There are eight shorter (3.14 Å) and four longer (3.24 Å) Tb–Ge bond lengths. Rh is bonded in a 6-coordinate geometry to three equivalent Tb and six equivalent Ge atoms. All Rh–Ge bond lengths are 2.51 Å. There are two inequivalent Ge sites. In the first Ge site, Ge is bonded in a 6-coordinate geometry to three equivalent Tb, two equivalent Rh, and two Ge atoms. There are one shorter (2.67 Å) and one longer (3.11 Å) Ge–Ge bond lengths. In the second Ge site, Ge is bonded in a cuboctahedral geometry to twelve equivalent Ge atoms.
GdRhGe crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Gd is bonded in a 12-coordinate geometry to six equivalent Rh and five equivalent Ge atoms. There are a spread of Gd–Rh bond distances ranging from 3.01–3.36 Å. There are a spread of Gd–Ge bond distances ranging from 3.03–3.07 Å. Rh is bonded in a 10-coordinate geometry to six equivalent Gd and four equivalent Ge atoms. There are a spread of Rh–Ge bond distances ranging from 2.57–2.65 Å. Ge is bonded in a 9-coordinate geometry to five equivalent Gd and four equivalent Rh atoms.
K3Rh crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. there are two inequivalent K sites. In the first K site, K is bonded in a linear geometry to two equivalent Rh atoms. Both K–Rh bond lengths are 3.14 Å. In the second K site, K is bonded in a distorted trigonal planar geometry to three equivalent Rh atoms. There are two shorter (3.41 Å) and one longer (3.44 Å) K–Rh bond lengths. Rh is bonded in a body-centered cubic geometry to eight K atoms.
Rh2FeIn is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Fe is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Fe–Rh bond lengths are 2.72 Å. Rh is bonded in a body-centered cubic geometry to four equivalent Fe and four equivalent In atoms. All Rh–In bond lengths are 2.72 Å. In is bonded in a body-centered cubic geometry to eight equivalent Rh atoms.
TmRhZn crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Tm is bonded in a 5-coordinate geometry to five equivalent Rh atoms. There are three shorter (2.88 Å) and two longer (2.92 Å) Tm–Rh bond lengths. Rh is bonded in a 9-coordinate geometry to five equivalent Tm and four equivalent Zn atoms. There are a spread of Rh–Zn bond distances ranging from 2.61–2.68 Å. Zn is bonded in a 4-coordinate geometry to four equivalent Rh atoms.
Li3Rh is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. there are two inequivalent Li sites. In the first Li site, Li is bonded to four equivalent Li and four equivalent Rh atoms to form a mixture of distorted corner, edge, and face-sharing LiLi4Rh4 tetrahedra. All Li–Li bond lengths are 2.61 Å. All Li–Rh bond lengths are 2.61 Å. In the second Li site, Li is bonded in a 8-coordinate geometry to eight equivalent Li and six equivalent Rh atoms. All Li–Rh bond lengths are 3.02 Å. Rh is bonded in a distorted body-centered cubic geometry to fourteen Li atoms.
Rh2FeSn crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Rh2FeSn ribbons oriented in the (1, 0, 0) direction. Fe is bonded in a linear geometry to two equivalent Rh atoms. Both Fe–Rh bond lengths are 2.26 Å. Rh is bonded in a linear geometry to one Fe and one Sn atom. The Rh–Sn bond length is 2.50 Å. Sn is bonded in a linear geometry to two equivalent Rh atoms.
Fe3Rh is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. there are two inequivalent Fe sites. In the first Fe site, Fe is bonded to four equivalent Fe and four equivalent Rh atoms to form a mixture of distorted corner, edge, and face-sharing FeFe4Rh4 tetrahedra. All Fe–Fe bond lengths are 2.55 Å. All Fe–Rh bond lengths are 2.55 Å. In the second Fe site, Fe is bonded in a 8-coordinate geometry to eight equivalent Fe and six equivalent Rh atoms. All Fe–Rh bond lengths are 2.95 Å. Rh is bonded in a distorted body-centered cubic geometry to fourteen Fe atoms.