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At least 1,423 records · Page 79

Bi-metallic Nanoparticle Synthesis for Advanced Manufactured Melt Wires

Science Undergraduate Laboratory Internship (SULI) Program Report: Additive manufacturing (AM) based on direct-write technologies has emerged as the predominant method for the fabrication of passive sensors for the harsh operating environments seen in a nuclear reactor. Through the modification of previous methods, Idaho National Laboratory and Villanova University have improved the synthesis process for AM feedstock, which will allow for the improvement of advanced nuclear sensors and instrumentation. A major part of this work includes the synthesis process of relevant AM compatible feedstock to support the development, fabrication, and testing of AM sensors for peak temperature detection. For this report, bismuth, bismuth/platinum, tin, tin/silver, tin/zinc, indium, and indium/silver bi-metallic nanoparticles were synthesized using the polyol method, which will enhance temperature sensitivity and allow for miniaturization. To characterize the synthesized nanoparticles, we used x-ray fluorescence to evaluate the elemental composition of the nanoparticles and differential scanning calorimetry and thermogravimetric analysis to determine the melting point and mass loss of the samples. Results show that bi-metallic nanoparticles are a viable option for the fabrication of high-resolution AM melt wires. The temperature sensitivity can be brought to within 5°C and melt wires can be fabricated that are in the micrometer scale. This will expand the range of irradiation experiments melt wires can be used for and the measured temperature will be significantly more accurate.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Spectrophotometry of the 1.5-micron window of Jupiter.

The limb darkening of the 1.5-micron region and the variations of ammonia and methane absorptions over the Jovian belts, zones, and spots are studied on the basis of high-resolution infrared spectrometric data obtained for 86 areas on the Jovian surface. It is shown that the absorptions increase with increasing air mass between the equator and the poles, that they decrease linearly with increasing air mass between the central meridian and the limbs, and that the absorptions over the South Tropical Zone are greater and those over the Great Red Spot are smaller than the absorptions for other features. An ammonia absorption map of the planet is plotted for the period April-June, 1970.

Binder, A. B.↗

A directional low energy gamma-ray detector

The sensitivity of a directional gamma ray detector, which relies on blocking a source to determine its direction and energy spectrum, is calculated and compared to the more conventional well-shaped shielded detectors. It is shown that such an anticollimator detection system provides a basis for measuring the celestial diffuse gamma ray background, gamma ray sources and bursts with good energy, angular, and time resolution, and that additionally the system is 20 to 50 times as sensitive as conventional detectors when compared on a per unit mass basis.

Morfill, G.↗

A directional low energy gamma-ray detector

The sensitivity of a directional gamma ray detector, which relies on blocking a source to determine its direction and energy spectrum, is calculated and compared to the more conventional well shaped shielded detectors. It is shown that such an anticollimator detection system provides a basis for measuring the celestial diffuse gamma ray background, gamma ray sources and bursts with good energy, angular, and time resolution, and that additionally the system is 20 to 50 times as sensitive as conventional detectors when compared on a per unit mass basis.

Morfill, G.↗

Small satellites

Satellites smaller than Mimas (r = 195 km) are distinguished by irregular overall shapes and by rough limb topography. Material properties and impact cratering dominate the shaping of these objects. Long fragmentation histories can produce a variety of internal structures, but so far there is no direct evidence that any small satellite is an equilibrium ellipsoid made up of noncohesive gravitationally bound rubble. One many bodies that orbit close to their primary the tidal and rotational components of surface gravity strongly affect the directions of local g and thereby affect the redistribution of regolith by mass wasting. Downslope movement of regolith is extensive on Deimos, and is probably effective on many other small satellites. It is shown that in some cases observed patterns of downslope mass wasting cold produce useful constraints on the satellite's mean density. The diversity of features seen in the few high-resolution images of small satellites currently available suggests that these objects have undergone complex histories of cratering, fragmentation, and regolith evolution.

Thomas, P.↗

Application of Hoffman modulation contrast microscopy coupled with three-wavelength two-beam interferometry to the in situ direct observation of the growth process of a crystal in microgravity

Direct visualization of three dimensional transfer process of both heat and mass around a growing crystal and mono-molecular growth layers on the surface is possible in situ by means of high resolution Hoffman modulation contrast microscopy coupled with three wavelength two beam Mach-Zehnder interferometry. This in situ observation is very suitable for the verification of the growth mechanism of a crystal in a solution or a melt in microgravity.

Tsukamoto, Katsuo↗

A complete Arecibo map of H I 1225 + 01

Complete H I observations of a large low-density cloud, H I 1225 + 01, carried out at Arecibo with an angular resolution of 3.3 arcmin, are reported. The velocity field of the H I distribution is analyzed, and tentative models of the overall mass distribution are proposed. The implications of the observations for the structure and evolution of the system are discussed.

Giovanelli, Riccardo↗

Physical and performance characteristics of instruments selected for global change monitoring

The following appendix (appendix B) lists the instruments chosen for the Global Change Monitoring program. The instruments are described according to the following categories: (1) Title; (2) Measurement; (3) Contact; (4) Instrument Type; (5) Dimensions; (6) Mass; (7) Average Operational Power; (8) Data Rate; (9) Spectral/Frequency Range; (10) Number of Channels/Frequencies; (11) Viewing Field; (12) Scanning Characteristics; (13) Resolution (Horizontal/Vertical); (14) Swath Width; (15) Satellite Application; and (16) Technology Status. A technical drawing of each instrument is also provided.

Allen, Cheryl L.↗

Analysis of the impact of Seasat scatterometer data and horizontal resolution on GLA model simulations of the QE II storm

The impact of the Seasat-A satellite scatterometer wind data and the increased horizontal resolution on the Goddard Laboratory for Atmospheres model predictions of the Queen Elizabeth II (QE II) storm of 9-11 September 1978 was evaluated for four different GLA model simulations of the QE II storm. It is shown that the largest impact on the simulation was caused by doubling the model's horizontal resolution from 4 deg x 5 deg to 2 deg x 2.5 deg. The increased resolution resulted in a storm track which was much closer to the one observed, with a much deeper surface development, a stronger mass circulation, stronger heating, and stronger increase of angular momentum.

Lenzen, Allen J.↗

The updated statistical inversion technique to the evaluation of Umkehr observations

In the present study the standard retrieval Umkehr method to estimate the vertical distribution of ozone was updated using a statistical approach to the mathematical inversion scheme. The vertical ozone profile covariance matrix was used as a priori information for the inverse problem. A new method of the ozonesonde data organization according to air mass types helped to improve the covariance matrix quality. A retrieval method was developed using eigenvector technique. An optimal vertical ozone profile resolution was determined from the mathematical inversion scheme analysis based on the same technique. The sun radiation transfer was accounted for multiple scattering and atmospheric sphericity in this calculation. The retrievals using actual Umkehr Dobson spectrophotometer observations were also performed to provide the comparison of the standard and updated methods with concurrent ozone sound data at Boulder U.S. The comparison has revealed that the present method has some advantages in both resolution and accuracy, as compared to the standard one, especially for the atmospheric layers below ozone maximum.

Frolov, Alexander D.↗

An Efficient Objective Analysis System for Parallel Computers

A new atmospheric objective analysis system designed for parallel computers will be described. The system can produce a global analysis (on a 1 X 1 lat-lon grid with 18 levels of heights and winds and 10 levels of moisture) using 120,000 observations in 17 minutes on 32 CPUs (SGI Origin 2000). No special parallel code is needed (e.g. MPI or multitasking) and the 32 CPUs do not have to be on the same platform. The system is totally portable and can run on several different architectures at once. In addition, the system can easily scale up to 100 or more CPUS. This will allow for much higher resolution and significant increases in input data. The system scales linearly as the number of observations and the number of grid points. The cost overhead in going from 1 to 32 CPUs is 18%. In addition, the analysis results are identical regardless of the number of processors used. This system has all the characteristics of optimal interpolation, combining detailed instrument and first guess error statistics to produce the best estimate of the atmospheric state. Static tests with a 2 X 2.5 resolution version of this system showed it's analysis increments are comparable to the latest NASA operational system including maintenance of mass-wind balance. Results from several months of cycling test in the Goddard EOS Data Assimilation System (GEOS DAS) show this new analysis retains the same level of agreement between the first guess and observations (O-F statistics) as the current operational system.

Stobie, J.↗

Multi-Satellite Observations of Cygnus X-1 to Study the Focused Wind and Absorption Dips

High-mass X-ray binary systems are powered by the stellar wind of their donor stars. The X-ray state of Cygnus X-1 is correlated with the properties of the wind which defines the environment of mass accretion. Chandra-HETGS observations close to orbital phase 0 allow for an analysis of the photoionzed stellar wind at high resolution, but because of the strong variability due to soft X-ray absorption dips, simultaneous multi-satellite observations are required to track and understand the continuum, too. Besides an earlier joint Chandra and RXTE observation, we present first results from a recent campaign which represents the best broad-band spectrum of Cyg X-1 ever achieved: On 2008 April 18/19 we observed this source with XMM-Newton, Chandra, Suzaku, RXTE, INTEGRAL, Swift, and AGILE in X- and gamma-rays, as well as with VLA in the radio. After superior conjunction of the black hole, we detect soft X-ray absorption dips likely due to clumps in the focused wind covering greater than or equal to 95% of the X-ray source, with column densities likely to be of several 10(exp 23) cm(exp -2), which also affect photon energies above 20 keV via Compton scattering.

Hanke, Manfred↗

The Astro-H High Resolution Soft X-Ray Spectrometer

We present the overall design and performance of the Astro-H (Hitomi) Soft X-Ray Spectrometer (SXS). The instrument uses a 36-pixel array of x-ray microcalorimeters at the focus of a grazing-incidence x-ray mirror Soft X-Ray Telescope (SXT) for high-resolution spectroscopy of celestial x-ray sources. The instrument was designed to achieve an energy resolution better than 7 eV over the 0.3-12 keV energy range and operate for more than 3 years in orbit. The actual energy resolution of the instrument is 4-5 eV as demonstrated during extensive ground testing prior to launch and in orbit. The measured mass flow rate of the liquid helium cryogen and initial fill level at launch predict a lifetime of more than 4 years assuming steady mechanical cooler performance. Cryogen-free operation was successfully demonstrated prior to launch. The successful operation of the SXS in orbit, including the first observations of the velocity structure of the Perseus cluster of galaxies, demonstrates the viability and power of this technology as a tool for astrophysics.

spectrometers↗

KELT-25 b and KELT-26 b: A Hot Jupiter and a Substellar Companion Transiting Young A Stars Observed by TESS

We present the discoveries of KELT-25 b (TIC 65412605, TOI-626.01) and KELT-26 b (TIC 160708862, TOI-1337.01), two transiting companions orbiting relatively bright, early A stars. The transit signals were initially detected by the KELT survey and subsequently confirmed by Transiting Exoplanet Survey Satellite (TESS) photometry. KELT-25 b is on a 4.40 day orbit around the V=9.66 star CD-24 5016(=-+T8280eff180440K,Må=-+2.180.110.12Me), while KELT-26 b is on a 3.34 day orbit around the V=9.95 star HD 134004 (Teff=-+8640240500K,Må=-+1.930.160.14Me), which is likely an Am star. We have confirmed the substellar nature of both companions through detailed characterization of each system using ground-based and TESS photometry, radial velocity measurements, Doppler tomography, and high-resolution imaging. For KELT-25, we determine a companion radius of RP=-+1.640.0430.039RJ and a 3σupper limit on the companion’s mass of64MJ. For KELT-26 b, we infer a planetary mass and radius of MP=-+1.410.510.43MJ and RP=-+1.940.0580.060RJ. From Doppler tomographic observations, we find KELT-26 b to reside in a highly misaligned orbit. This conclusion is weakly corroborated by a subtle asymmetry in the transit light curve from the TESS data. KELT-25 b appears to be in a well-aligned, prograde orbit, and the system is likely a member of the cluster Theia 449.

Exoplanet astronomy↗

Do Better Satellite Precipitation Algorithms Improve Landslide Hazard Assessment?

Satellites make it possible to estimate precipitation in near real time. Given the challenges of achieving global coverage by other means, these data are used widely. However, few systems for landslide hazard assessment rely on satellite precipitation estimates. This could be due in part to perceptions of accuracy, although latency, spatial resolution, and other factors may also be important. We test whether recent changes to data streams from the Global Precipitation Measurement mission (GPM) have improved its potential for use in landslide prediction. Specifically, we examine data produced by the Integrated Multi-satellitERetrievals for the GPM (IMERG) algorithm, which was upgraded to version 7 this year. IMERG relies upon other algorithms, including the Goddard Profiling Algorithm (GPROF) and the GPM Combined Radar-Radiometer Algorithm (CORRA). Many changes have been made during the switch from IMERG version 6 to version 7. These include upgrading CORRA and GPROF to version 7, to improve the accuracy of precipitation in frozen, mountainous, and coastal areas. The measured intensity of some storms has been enhanced with a new algorithm, the Scheme for Histogram Adjustment with Ranked Precipitation Estimates in the Neighborhood. Combined with many others, these changes to IMERG should improve its utility for landslide hazard assessment in a variety of contexts. To test this idea, we retrain the global Landslide Hazard Assessment for Situational Awareness (LHASA) model twice—first with data from IMERG version 6B and second with 7B. Since current daily rainfall is the most important variable in determining outcomes predicted by LHASA, it should reflect changes made to that input. First, we grid the landslides at a daily, thirty-arcsecond resolution. This serves as the response variable. At each of these sites current and antecedent rainfall are extracted, along with antecedent snow mass and soil moisture, slope, and PGA. In addition, one million grid cells are selected at random points to represent conditions under which landslides (probably) do not occur. After merging these data, we hold back 20% of the dataset for validation purposes and train a machine-learning model with the rest. We assess both the model’s overall ability to identify landslides and its ability to predict specific large landslide disasters.

Thomas A Stanley↗

The mass and speed dependence of meteor air plasma temperatures

The speed and mass dependence of meteor air plasma temperatures is perhaps the most important data needed to understand how small meteoroids chemically change the ambient atmosphere in their path and enrich the ablated meteoric organic matter with oxygen. Such chemistry can play an important role in creating prebiotic compounds. The excitation conditions in various air plasma emissions were measured from high-resolution optical spectra of Leonid storm meteors during NASA's Leonid Multi-Instrument Aircraft Campaign. This was the first time a sufficient number and range of temperature measurements were obtained to search for meteoroid mass and speed dependencies. We found slight increases in temperature with decreasing altitude, but otherwise nearly constant values for meteoroids with speeds between 35 and 72 km/s and masses between 10(-5) g and 1 g. We conclude that faster and more massive meteoroids produce a larger emission volume, but not a higher air plasma temperature. We speculate that the meteoric plasma may be in multiphase equilibrium with the ambient atmosphere, which could mean lower plasma temperatures in a CO(2)-rich early Earth atmosphere.

Temperature↗

Ambient Ion Trapping and Separations for High Throughput Structurally Selective Material Deposition

While ion mobility coupled to mass spectrometry (IMS/MS) has been increasingly adapted to biological analysis, the structural and molecular specificity offered by IMS/MS has untapped potential for creating novel materials (for energy, catalysis, biomolecular switches etc.) with rationally tailored properties by precisely controlling the chemical structure and composition of these materials. While electrochemical and catalytic properties of the bulk material are understood by mass-selective ion-soft-landing, different structures of one molecule can exhibit distinct properties from the bulk. Many biological phenomenon occur at interfaces and are highly structurally specific. IMS/MS offers means to separate molecules in a sample (which is first ionized and released to gas phase from the condensed phase) based on mass and structure. Species thus separated can potentially be deposited onto surfaces with molecular and structural specificity, to perform fundamental investigations for understanding critical interfacial phenomenon. Key performance metrics for IMS/MS analysis are resolution of separations and sensitivity. Recently developed Structures for Lossless Ion Manipulations (SLIM)4 enabled unprecedented resolution in IMS separations. In addition, high sensitivity was enabled in SLIM due to lossless confinement of ions using radio frequency fields. Thus, SLIM enabled extremely long path length separations (up to 0.1 km thus far) providing efficient separation of molecular ions never before achieved (e.g. isotopologues, D&L amino acids). While SLIM has unprecedented analytical separations power/utility, the use of SLIM platform for depositing mobility and mass selected molecular ions has two specific technological challenges: (a) Pulsed nature of IMS separations and their low duty cycle and (b) the need for a low vacuum of ~4 torr for lossless ion confinement. These limitations lead to long deposition times due to loss of ions generated from the sample. Enabling ion confinement at atmospheric pressure will be path-breaking contribution to the fundamental understanding of ion manipulations and separations and will also enable novel science currently precluded due to the inability of the present technologies to confine ions under ambient conditions. Traditionally used radio frequency fields are ineffective in confining ions at high pressures due to ion/neutral collisions. To address these, we propose to (a) develop methods for confining and manipulating ions for lossless IMS separations at atmospheric pressure enabling high sensitivity and throughput and (b) use the high specificity of IMS/MS and high throughput from ambient ion confinement to perform mobility and mass selective ion deposition at atmospheric pressure. Our goal is to enable the study of the fundamental properties of energy/catalysis materials and biomolecules. This project paves the way for high-throughput, mass and structure selective material deposition for highly specific surface creation/functionalization (discussed in Section 2 of the report). Further, the developments reported continue to push the boundaries of this process to ambient conditions (discussed in Section 3 of the report). We conclude with a list of specific intellectual property and publications which have been the outcome of this funded project.

36 MATERIALS SCIENCE↗

Energetic ion mass spectrometer

A new type of spectrometer for space application has been developed to measure separately mass/charge and the three-dimensional velocity distribution of incident ions. The instrument has relatively high resolution and allows rapid measurement of the four-dimensional set of mass/charge, speed, elevation angle, and azimuth angle. The instrument includes a sector magnet, an electrostatic deflector, microchannel plate detectors with position sensitive readout, and a set of grids with variable applied voltage.

Neugebauer, M.↗