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At least 1,423 records · Page 79

Imaging based refractometer for hyperspectral refractive index detection

Refractometers for simultaneously measuring refractive index of a sample over a range of wavelengths of light include dispersive and focusing optical systems. An optical beam including the range of wavelengths is spectrally spread along a first axis and focused along a second axis so as to be incident to an interface between the sample and a prism at a range of angles of incidence including a critical angle for at least one wavelength. An imaging detector is situated to receive the spectrally spread and focused light from the interface and form an image corresponding to angle of incidence as a function of wavelength. One or more critical angles are identified and corresponding refractive indices are determined.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Temperature-Dependent Conformations of Model Viscosity Index Improvers

Lubricants are comprised of base oils and additives where additives are chemicals that are deliberately added to the oil to enhance properties and inhibit degradation of the base oils. Viscosity index (VI) improvers are an important class of additives that reduce the decline of fluid viscosity with temperature [1], enabling optimum lubricant performance over a wider range of operating temperatures. These additives are typically high molecular weight polymers, such as, but not limited to, polyisobutylenes, olefin copolymer, and polyalkylmethacrylates, that are added in concentrations of 2-5% (w/w). Appropriate polymers, when dissolved in base oil, expand from a coiled to an uncoiled state with increasing temperature [2]. The ability of VI additives to increase their molar volume and improve the temperature-viscosity dependence of lubricants suggests there is a strong relationship between molecular structure and additive functionality [3]. In this work, we aim to quantify the changes in polymer size with temperature for four polyisobutylene (PIB) based molecular structures at the nano-scale using molecular simulation tools. As expected, the results show that the polymers adopt more conformations at higher temperatures, and there is a clear indication that the expandability of a polymer is strongly influenced by molecular structure.

lubricants, base oils, viscosity↗

Reliability Indexing of Intra-Facility Dispatch Decisions

The Powertrain Reliability Index (PRI) quantifies the trade-offs made in system reliability for efficiency, water use, and environmental purposes for relevant stakeholders. Using historical data from five North American hydroelectric facilities on a shared river system, this metric characterizes the annual probabilistic reliability of intra-facility dispatch decisions. The metric characterizes the operational risk of actual dispatch based on the lowest risk-exposed dispatch and the highest risk-exposed dispatch. By normalizing facility reliability by the number of components described within the facility, constraining operation by the historic dispatch total of unit starts and generating hours, and bounding by required grid flexibility, each facility’s dispatch can be scored for reliability.

Signore, Stephen R.↗

Nanostructured layer for graded index freeform optics

The present disclosure relates to a method for creating an optical component having a spatially controlled refractive index. The method may involve applying a thin metal material layer to a substrate. The thin metal material layer may then be heated to create a mask having a spatially varying nano-particle distribution. The substrate may then be etched, using the mask, to imprint a spatially patterned nanostructure pattern on a surface the substrate.

36 MATERIALS SCIENCE↗

Heat Vulnerability Index Development and Mapping

Extreme heat is one of the leading causes of weather-related deaths in the U.S. Exposure to extreme heat will be exacerbated due to global climate change. It is thus crucial to design a key performance indicator, heat vulnerability index (HVI), to represent overall heat risk which can help identify susceptible regions and sub-populations in cities in the face of heatwaves. Most existing HVI tools only consider outdoor heat exposure. This paper developed an HVI web map tool incorporating both the outdoor and the indoor heat exposure, as well as population sensitivity and adaptation capability across census tracts in the city of Fresno, California. The tool can assist the planning of infrastructure and resources to reduce residents’ vulnerability to extreme heat events.

Xu, Yujie↗

Personal Resiliency Index

A plethora of information exists in literature focusing on different aspects of personal resilience. There are a number of questionnaires available to measure resilience in different aspects of an individual’s life, such as mental health. However, there is a lack of comprehensive information on the subject of personal resilience to natural and man-made disasters. A Personal Resiliency Index identifying four key areas of resilience related to natural and man-made disasters will help fill this gap by providing individuals an idea of where the stand comparatively to their peers on this topics. As an increasing amount of man-made disasters, natural disasters and pandemics occur, we realize that preparation is key.?“Crisis can be experienced at individual, group and mass levels and at local, regional, national or supra-national levels.” 1? Dr. Ron Fisher, the principal investigator has over 20 years’ critical infrastructure protection including developing vulnerability assessment methodology, risk and resiliency analyses and infrastructure interdependencies. Dr. Fisher and his team will research and develop a voluntary survey which evaluates the user’s personal resilience level to natural and man-made disasters. The research team is focusing on 4 main categories:? financial resilience, cyber security, physical and mental health, and emergency preparedness.?The web based application will?provide a resilience score for each of the categories and also a comprehensive personal resiliency score based on the voluntary survey. The application will also provide feedback to the user on actions to take to become more resilient to natural and man-made disasters. Through this effort, we will also be able to identify the areas where participants are excelling as well as opportunities for improvement in terms of resilience. This information will provide insight into areas of further investigation and identify potential areas of support needed for the general public to adopt strategies to become more resilient. 1 Lynott, William. “Surviving a Natural (or Man-Made) Disaster: How to Prepare for and Bounce Back? from a Crisis in Your Business | 2018-02-01 | NOLN.” Home Page, NOLN, 1 Feb. 2018, https://www.noln.net/articles/2683-surviving-a-natural-or-man-made-disaster-how-to-prepare-for-and-bounce-back-from-a-crisis-in-your-business.

99 GENERAL AND MISCELLANEOUS↗

System and method for ablation assisted nanostructure formation for graded index surfaces for optics

A system and method is disclosed for forming a graded index (GRIN) on a substrate. In one implementation the method may involve applying a metal layer to the substrate. A fluence profile of optical energy applied to the metal layer may be controlled to substantially ablate the metal layer to create a vaporized metal layer. The fluence profile may be further controlled to control a size of metal nanoparticles created from the vaporized metal layer as the vaporized metal layer condenses and forms metal nanoparticles, the metal nanoparticles being deposited back on the substrate to form a GRIN surface on the substrate.

Yoo, Jae Hyuck↗

Low refractive index surface layers and related methods

The disclosure relates to a method for forming a low refractive index layer on a substrate. The method generally includes (a) applying a block copolymer layer on a substrate, the block copolymer including a polar polymeric block and a non-polar polymeric block; (b) swelling the block copolymer layer with a solvent to increase the block copolymer layer thickness; (c) depositing a metal oxide or metalloid oxide layer on polar polymeric blocks of the block copolymer layer; and (d) removing the block copolymer layer from the substrate, thereby forming a porous metal oxide or metalloid oxide layer on the substrate.

Shevchenko, Elena↗

Methodology to Account for Radiation and Temperature Influences on Optical Fibers compaction and Index of Refraction

The effects of radiation induced compaction and index of refraction change can cause significant drift in the measurements from intrinsic fiber optic temperature sensors. The work presented here aims to develop and test a methodology to measure these macroscopic properties that are responsible for the drift in order to correct the measurement. This report discusses the measurement methodology, theory, and sensor construction. Preliminary results from the first irradiation test using this sensor are provided here.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Dark Matter-Electron Interactions Alter the Luminosity and Spectral Index of M87

We investigate the possibility that cosmic-ray electron cooling through dark matter-electron scatterings contributes to the low radiative efficiency observed in radio-loud galaxies such as M87. Light dark matter can scatter efficiently off electrons in M87, lowering the observed bolometric luminosity compared to astrophysical expectations. This consideration allows us to probe previously unexplored regions of the parameter space of dark matter-electron interactions. We further model the cosmic-ray electron distribution by numerically solving a diffusion equation along the jet and find that efficient dark matter-electron interactions can induce a flattening of the spectral index at different distances from the central supermassive black hole, in better alignment with radio observations from M87.

Hussein, Abdelaziz [MIT] (ORCID:0000000255608668)↗

Highly efficient elliptical microcavity refractive index sensor with single detection unit

Here, an elliptical cavity is investigated in its vertical and horizontal arrangement as a single detection unit in a 2D hexagonal hole-type photonic crystal. The Q-factors are 3700, and 2600 for vertical and horizontally arranged cavities, respectively. The notable characteristic of the presented sensor is mainly its large detection range for refractive indices in range of n = 1 to over 2. The operation of the sensor can be divided into two distinct detection regions in separate spectra located next to lower and higher edges of photonic band gap. The design of cavities and their sensing characteristics are discussed in detail for each topology using FDTD and PWE methods.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Electrosynthesis of high purity ethylene using high-index facet Cu 2 O nanocrystals electrocatalyst

Electrochemical CO 2 reduction reaction (eCO2RR) to multi-carbon (C 2+ ) products with copper-based catalysts is often limited by poor selectivity. This challenge arises from the concurrent formation of various intermediates, dictated by the atomic arrangement and electronic properties of surface atoms. In this study, we found that copper (I) oxide (Cu 2 O) nanocrystals with 50 facets (50F-NC), predominantly featuring (211) facets that offers high density of under-coordinated sites, demonstrate superior ethylene (C 2 H 4 ) selectivity of 92% ± 2 with an overall current density of 212 mA/cm 2 at -650 mV vs RHE. Furthermore, after one month of storage in a 1 M KOH electrolyte, this catalyst demonstrated a C 2 H 4 Faradaic efficiency of 87% highlighting its stabile structure under strong alkaline environments. Here, operando electrochemical Raman spectroscopy revealed enhanced CO* intermediate coverage on the 50F-NC catalyst, correlating with improved C-C coupling. SEM, TEM, and XPS analyses, along with DFT calculations, suggested that Cu sites on the (211) facet of 50F-NC and those at the Cu/Cu 2 O interface formed in-situ due to the surface reconstruction during the reaction, are likely active sites for effective C-C coupling and sustained high-rate C 2 H 4 production.

Cu nano particle↗