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At least 1,423 records · Page 79

Ambipolar diffusion drifts and dynamos in turbulent gases

Ambipolar drift in turbulent fluids are considered. Using mean-field electrodynamics, a two-scale theory originally used to study hydromagnetic dynamos, it is shown that magnetic fields can be advected by small-scale magnetosonic (compressional) turbulence or generated by Alfvenic (helical) turbulence. A simple dynamo theory is made and is compared with standard theories in which dissipation is caused by turbulent diffusion. The redistribution of magnetic flux in interstellar clouds is also discussed.

Zweibel, Ellen G.↗

Temporal and spatial distribution of stratospheric trace gases over Antarctica in August and September, 1987

There have been a large number of suggestions made concerning the origin of the Antarctic 'ozone hole' since its discovery; these changes include stratospheric chemistry, or changes in the solar input, or combinations of these effects. Supporting or refuting these theories requires a wide variety of data for comparison with the predictions. In Aug. and Sept., 1987, a field observation expedition was made over Antarctica from a base in Punta Arenas, Chile. Two aircraft, an ER-2 with in-situ instruments flew at altitudes up to 18 km measuring ozone, water, ClO, BrO, NO sub x, particles, and meteorological parameters in the ozone layer. A DC-8 flew at altitudes of 10 to 12 km, below the ozone layer, using remote sensing instruments for measuring composition and aerosol content of the ozone layer, as well as in-situ instruments for measuring composition at aircraft altitudes. The obsevation of a number of chemical species and their correlation with each other and with meteorological parameters gives a useful set of data for comparison with various theories.

Coffey, M. T.↗

Materials compatibility with oxidizer-rich gases at elevated temperatures and pressure

An investigation of oxygen compatibility and resistance to ignition of candidate materials for use in a liquid rocket engine designed to incorporate an oxidizer rich preburner-LOX turbopump configuration was discussed. The program was divided into two basic tasks. The first task was to develop a preliminary design of an oxidizer turbopump preburner section complete with thermal and MS Parameter analyses and to develop a conceptual design of the main injector with a preliminary engine specification as the final product. The second task was directed totally at testing materials in oxygen-rich environments.

Source record↗

Geochemical cycles of atmospheric gases

The processes that control the atmosphere and atmospheric changes are reviewed. The geochemical cycles of water vapor, nitrogen, carbon dioxide, oxygen, and minor atmospheric constituents are examined. Changes in atmospheric chemistry with time are discussed using evidence from the rock record and analysis of the present atmosphere. The role of biological evolution in the history of the atmosphere and projected changes in the future atmosphere are considered.

Walker, J. C. G.↗

Crustal diffusion of gases out of Mercury and the moon

An upper limit to the rate of diffusion of sodium and potassium out of Mercury and the moon was calculated, and the resulting flux was compared to that required to maintain the known exospheres. It was found that diffusion rates are inadequate by 12 orders of magnitude on the moon and 9 orders of magnitude on Mercury for diffusion out of orthoclase minerals. Diffusion will be more rapid out of pure glass by five to six orders of magnitude and out of shocked basalt by an amount depending on the microstructure of the mineral. The observed abundance and distribution of volatiles in small glass spherules on the moon indicates that diffusion is very inefficient after solidification and cooling. At Mercury, the limitation on sodium flux to the atmosphere is shown to be the rate at which new regolith is created. The discrepancy between the observed column abundance of sodium in the Mercurean atmosphere and the known sources may indicate that either Mercury's crust has a larger volatile content than the moon or that a recycling mechanism exists in the Mercurean atmosphere which is not present for the moon.

Killen, R. M.↗

Acoustic waves in gases with strong pressure gradients

The effect of strong pressure gradients on the acoustic modes (standing waves) of a rectangular cavity is investigated analytically. When the cavity response is represented by a sum of modes, each mode is found to have two resonant frequencies. The lower frequency is near the Viaesaela-Brundt frequency, which characterizes the buoyant effect, and the higher frequency is above the ordinary acoustic resonance frequency. This finding shows that the propagation velocity of the acoustic waves is increased due to the pressure gradient effect.

Zorumski, William E.↗

Hot ion plasmas from the cloud of neutral gases surrounding the Space Shuttle

Large intensities of hot positive ions are observed out to distances of several hundred meters from the Space Shuttle with a plasma analyzer on a small free-flying satellite, the Plasma Diagnostics Package. This ion plasma is inferred to be generated by the charge exchange of ionospheric O+ ions with a large cloud of water molecules from the Space Shuttle. The measured ion density ranges from about 30 to 10,000 H2O+ ions/cu cm. A model for the water vapor cloud provides the basis for density estimates as high as 10 to the 9th H2O molecules/cu cm at a distance of 50 m from the Space Shuttle. Thus, the Space Shuttle possesses a substantial coorbiting atmosphere.

Paterson, W. R.↗

Magnetic reconnection in partially ionized gases

Magnetic field lines in a plasma reconnect at a rate scaled by the Alfven speed. In a partially ionized gas there are two natural Alfven speeds: one determined by the ionized mass density alone, which applies when ion-neutral friction is negligible, and one determined by the total mass density, which applies when ion-neutral friction is strong. When the ionization fraction is low, as in a dense molecular cloud, these two speeds differ by several orders of magnitude. Both time-dependent tearing modes and steady-state magnetic reconnection in partially ionized gas are considered, and the regimes in which the charged and neutral components are strongly, intermediately, and weakly coupled are delineated. Molecular clouds are probably in the intermediate regime, while reconnection in solar prominences probably has strong ion-neutral coupling. Reconnection proceeds more rapidly when coupling is not strong.

Zweibel, Ellen G.↗

Do volcanic eruptions affect climate? Sulfur gases may cause cooling

The relationship between volcanic eruptions on earth and the observed climatic changes is investigated. The results of the comparison and analyses of volcanologic and climatologic data sets for the years between 1880 and 1980 indicate that changes in temperature caused by even of the largest eruptions recorded during this time were about the same as normal variations in temperature. However, when temperature records for several months or years preceding and following a given eruption were analyzed, a statistically significant temperature decrease of 0.2-0.5 C was found for the periods of one to two years immediately following some of the 19th and 20th century explosive events that prodiced large aerosol clouds (e.g., Krakatau and Agung eruptions). It is suggested that the content of sulfur in the erupted magma determines the size of aerosol cloud producing the cooling effect.

Self, Stephen↗

Quantification of several atmospheric gases from high resolution infrared solar spectra obtained at the South Pole in 1980 and 1986

High-resolution solar absorption spectra recorded at the Amundsen-Scott South Pole Station were analyzed to obtain total column amounts of O3, N2O, HNO3, CO2, CH4, and CF2Cl2, and to investigate the differences in the values obtained in December 1980 with those obtained in December 1986. In addition, vertical column amounts for HCl, NO, NO2, and C2H6 were derived for December 1986. One interesting feature of these results is that the total column amounts of HCl measured for several days at the South Pole (/6.4 + or - 0.8/ x 10 to the 15th molecules/sq cm) were high compared with the HCl column amounts reported for lower latitudes.

Goldman, Aaron↗

Trace gases in the Antarctic Atmosphere

Whole-air samples collected aboard the NASA ER-2 and DC-8 aircraft as part of the Airborne Antarctic Ozone Experiment were analyzed in a field laboratory set up at Punta Arenas, Chile. Mixing ratios obtained from gas chromatographic analyses of these samples are presented for CH4, CO, N2O, CFCl3, CF2Cl2, C2F3Cl3, CH3CCl3, and CCl4. A comparison of CFCl3/N2O mixing ratios from the flights of September 16-29, 1987 provides evidence of sustained subsidence.

Heidt, L. E.↗

Ground-based infrared measurements of tropospheric source gases over Antarctica during the 1986 austral spring

Simultaneous measurements of the atmospheric burdens of CH4, N2O, CO2, CF2Cl2, and CO above McMurdo Station, Antarctica, have been derived from solar absorption spectra obtained by the Jet Propulsion Laboratory high-resolution Fourier transform spectrometer. In all cases the burdens are smaller than midlatitude values. Furthermore, retrievals of N2O and CH4 indicate that the tropospheric mixing ratios were normal and that the depletion of the burdens can best be accounted for by a downward shift of the volume mixing ratio profiles by some 6-8 km. This rules out the possibility of large-scale upwelling of ozone-poor tropospheric air into the stratosphere being the cause of the Antarctic springtime ozone depletion.

Toon, G. C.↗

Absorption Of Gases By Glassy Polymers

Report discusses solubility of gas in glassy polymer, both above and below glass-transition temperature (Tg). Thermodynamic arguments brought to bear on previously-developed mathematical models, result being new model that enables calculation of infinite-dilution partial molar volume of solvent in glass or liquid solvent from data on pressure, volume, and temperature of solute in equilibrium with solvent.

Fedors, Robert F.↗